The subject of colloid chemistry. Why are so different the colloids? Classification, characterization of colloid systems.
|
|
- Brianna Richardson
- 6 years ago
- Views:
Transcription
1 Colloid chemistry for pharmacists The subject of colloid chemistry. Why are so different the colloids? Classification, characterization of colloid systems. Dr Berka Márta, associate professor Bányai István professor Univ. of Debrecen, Dep. of Colloid- and Environmental Chemistry 1. lecture 1
2 Reading Barnes, GT, Gentle, IR: Interfacial Science A, Oxford UP. ISBN , 2005 Cosgrowe T.: Colloid science Blackwell Publishing ISBN: , 2005 Erbil, H. Y.: Surface Chemistry Blackwell, ISBN , 2006 Pashley, R. M.: Applied Colloid & Surface Chemistry Wiley&Sons, ISBN X, 2004 McCash, E. M.: Surface Chemistry Oxford UP. ISBN , 2001 (2007) Crowe, J.:Chemistry for the Biosciences Oxford UP. ISBN ,
3 Exam, requirements Written test one test in an exam period (2 possibilities) (50-60% mark 2; 61-75% mark 3; 76-85% mark 4; >85% mark 5.) Slides 3
4 Place of colloid science 1. partly physical chemistry not the chemical composition is important the states are independent of the composition 2. partly physics the physical properties are important basic law of physics are used 3. partly biology the biological matters are colloids the mechanisms of living systems surface chemistry (enzymes) perfomation disappear, stability, interaction with external field, force colloid science biology physical chemistry biochemistry organic chemistry chemistry physics The word colloid was derived from the Greek, kolla for glue (1862), distinguish colloids from crystalloids such as sugar and salt. Colloids have been studied by scientists since the early 1800's. The early part of the 20th century saw a number of major developments in both chemistry and physics, some of which had direct influences on the study of colloids. A number of methods for studying colloidal particles were developed, including diffusion, electrophoresis, and scattering of visible light and X-rays. 4
5 Homogeneous, heterogeneous? Homogeneous: isotropic. (5% solution) heterogeneous, Gibbs phases rule Homogeneous one isotropic phase continuum? point like? In case of a colloid system the properties depend of the sampling scale. pv = nrt P + F = C + 2 Gold sol Michael Faraday 1857; Gustav Mie 1908 It is not distinguishable by appearance. Soup, jelly, milk, beer, bread, pudding-pie, fog, smoke, smog, soils, toothpaste, blood, mayonaise, whip, opal, solution of soap, etc. Heterogeneous more phase Colloids can not be classified as homogeneous or heterogeneous system tenzides Aerogel, frozen smoke liogel 5 Xerogel, modern opal
6 1. Definition of colloid state history: Solution and suspension theory, homogeneous-heterogeneous 2. Ultramicroscope, dark field microscope R. Zsigmondy Nobel price: 1925 The colloidal state "for his demonstration of the heterogenous nature of colloid solutions and for the methods he used, which have since become fundamental in modern colloid chemistry" They examined two types of colloids, After cooling one of them jellify, form a gelatin like matter and other type forms crystals they found that this behavior is in relation with the diffusibility that is with the size. He saw some illuminating particles and their conclusion was that this particles had interface so the system must be heterogeneous nature If he had examined a gelatin solution he would have explained that the colloids must be homogeneous systems. This experiment was the first evidence for that the Brown motion is a thermal motion and the Boltzmann-Maxwell kinetic gas theory 6
7 Homogeneous, heterogeneous? Why are not the colloids heterogeneous? Colloids don t obey the rule of Gibbs because the effect of interface between the phases can not be neglected. S/V surface molecules/ total nano the effect of surface can not be ignored 10 % R<10 nm nanotechnology 1 % 0.1 % F = C P+ The phase rule enabled the identification of the number of variables (or degree of freedom) depending on the system composition and conditions. It is generally written as F=C-P+2 where F is the number of possible independent changes of state or degrees of freedom. C is the number of independent chemical constituents and P the number of phases present in the system Increasing specific surface area and surface energy E-7 1.0E-6 1.0E-5 1.0E-4 1.0E-3 1.0E-2 1.0E-1 1.0E+0 R,cm kolloid Surface molecules/total molecules gold sol 7
8 Subject of colloid chemistry: systems consist of particles in size of 1nm 500 nm. (more phases system in which the surface plays a significant role) Homogeneous Atoms, small molecules colloid system smoke Heterogeneous systems (macroscopic phases) macromolecules fog m Homogeneous colloid microscopic heterogeneous 6 10 nm micelles virus pollen, bacterium 8
9 Submicroscopic discontinuity blocks: molecules sûrûség property sûrûség property particles Forming a disperse system by breaking of β phases (any kind of phases except from 2 gas) A: two homogeneous phase form a heterogeneous system D: two component form a homogeneous solution, particles are smaller than 1 nm x W. Ostwald: the colloidal state is independent on the chemical forms Aladár Buzágh : submicroscopic discontinuities x length 9
10 Coherent and incoherent systems Incoherent systems Fluid phase characters Particles moves individually (the cohesive forces attraction is weaker than the thermal energy) Coherent systems solid phase characters (crosslinking by covalent or interparticle forces) (the cohesive forces attraction is stronger than the thermal energy) network structure (the anisometry helps the formation of network ) Intermediate systems (semisolids) concentrated emulsions, suspensions, liofil solutions creams, pastes, gels (thixotropy); sol-gel transformation. 10
11 Type of colloids on the basis of structure colloids Incoherent (fluid) Solid-like consistency Coherent, gel Colloidal Dispersions sols Macromol. solutions Association Colloids Colloidal solutions Porodin (porous) Reticular Spongoid lyophobic lyofhilic lyophilic (IUPAC) gold sol, micro emulsion Gelatin solution, polyelectrolyte tenzid, soap, detergent inorganic catalyzer; fibroids, gel from fibrous molecules: gum, rubber, viscose, natural synthetic fibers, muscle-fibers; spongoid are formed from thin lamellas or films 11
12 Type of colloidal dispersions (sols) categorized by inner/outer phases aerosols liosols xerosols L/G liquid aerosol: fog, mists, spray, perfumes, pesticides S/G solid aerosol, solid in gas: smoke, colloidal powder Complex, smog G/L gas liosol, gas bubbles in liquid (sparkling water, foam, whipped cream) L/L liquid liosol, liquid droplets in liquid, emulsion S/L solid liosol, solid particles in liquid (gold sol, toothpaste, paint, ink) G/S bubbles in solid, solid foam: polystyrene foam L/S solidified emulsion: opals, pearls S/S solidified sols: pigmented plastics, stained glass 12
13 Macromolecules The probably shape and weight of some molecules Illustration of a polypeptide macromolecule Macromolecules are much larger than the solute in a solution, the properties of these particles depend on their size and shape! 13
14 Association colloids Surfactant (soap and detergent) amphiphilic spherical micelle Micelles are the simplest of all self-assembly structures 14
15 gels (coherent systems) Solid-like consistency Gel for example gelatin, collagen, pectin. Gelatin may be used for food as a stabilizer, thickener, or texturizer in foods such as ice cream, jams, yogurt, cream cheese, margarine; it is used, as well, in fat-reduced foods to simulate the mouth feel of fat and to create volume without adding calories. Pharmaceutical capsules in order to make their contents easier to swallow, microcapsule, for photographic films, hair styling cream. ( sol-gel: blood- coagulated blood, milk -sour cream) 15
16 Fundamental forces and energy Gravitational forces tending to settle or raise particles depending on their density relative to the solvent. Colloidal particles are to small to settle out of solution due to the gravity) Viscous drag force Arises as a resistance to motion, since the fluid has to be forced apart as the particle moves through it Kinetic energy of particles, Brownian motion The kinetic random motion will dominate the behavior of small particles if there is not attractive or repulsive force between them. Van der Waals force, a ubiquitous attractive force in nature, electromagnetic in origin Electrostatic repulsion between similarly charged particles Most materials when dispersed on water selectively adsorb ions from solution, and hence become charged. 16
17 Stability Thermodynamic Stable (true solutions): lyophilic colloids G solution < G initial, (ΔG=ΔH-TΔS) Macromolecular solution, association colloids give true solution in thermodynamic sense with the medium which surround them.this is entropic and enthalpic stabilization Not stable: Lyophobic colloids G sol > G initial Sols, of large specific surface area (ratio of surface to volume) Kinetic - Stable (unchanged within the examination ) - Unstable 17
18 Characterization of colloids Buzágh gh: colloidal state parameters 1. Dispersity (or size distribution) Monodispersed, isometric (spheres with the same radius) Heterodispersed, anisometric (rod, plate) 2. Morphology: shape as spheres, cubes, plates, rods etc., inner structure as crystal or amorphous. 3. Spatial distribution 4. Interparticle interaction 18
19 Dispersity (or size distribution) Heterodispersed systems The average diameters Number, surface and volume weighted diameters Polydispersity. Colloidal systems are polydisperse with regard to their size or/and shapes, to a greater or lesser extent. 19
20 d Average diameters The mean and the standard deviation are used to represent for polydispersed systems The arithmetic mean is relevant any time several quantities add together to produce a total. The arithmetic mean answers the question, "if all the quantities had the same value, what would that value have to be in order to achieve the same total?" Arithmetic mean d d φ i i = φi The mean diameter Φ the weighting factor i index the class or fraction Φ the multiplier may be number, surface, volume, intensity, credit etc.. hence number weighted, surface weighted, mass weighted, etc. 20
21 Number average Φ is the factor by which the contribution of the constituent is proportional in the measured property. In case of number average the weighting factor is the number in class. Number average is often referred to as simply the average or mean. Φ=N the weighting factor is number in class Example: colligative properties yield number averages. stb. diameters: 1, 2, 3, 4, 5, 6, 7, 8, 9,10 φ = i d N Ni Li 55 = = = N 10 i 5.5 Number of class, N i =1 N i = 10 The total number of particles The length of the string 55 is the same from the original spheres and from spheres of average 21 size
22 Calculation of the number average Properties, d i, diameter, N i the weighting factor, number Sample: L d N L Li dini = = = = = = N N N i i 4 N 1 =2, d 1 =1; N 2 =1, d 2 =10 L N=3, d N =4 The average diameter: 4. meaning: 3 pieces with length of d N =4 together give the same length (L) than the original string The number is known and remain valid for the average spheres 22
23 Other weighted averages The measurement of colligative properties results number average The numbers or diameter are not known or there is not any tool for their determination. It is known the correlation between the volume and surface, V/S (the constants are neglected!): L S = d N 2 i i i hence V = d N 3 i i i V / S = d ( = 9,8)? N 1 =2, d 1 =1; N 2 =1, d 2 =10 We can measure the total volume and total surface and calculate the diameter. What kind of diameter is V/S? 23
24 Surface weighted averages When the numbers are not known, For example the number of drops in a mug of milk. d?( = 9,8) >> d N ( = 4) d? ( = 9,8) d2( = 10) Comparing the definition of arithmetic mean it can be seen, that the weighting factor is the surface S weighting factor x x φ i i = φi d S V V d S d N ~ = = = = = 9.8 S S S d N i i i i i i i i i 1 2 if d i and N i known S/d s2 = 1.06 pieces V/d s3 = 1.06 pieces 1.06 pieces of d~9.8 spheres have the same total volume and surface as the origin ones. The number changed! d N < d S 24
25 Mass weighted averages When the numbers are not known, for example particles in a sack of powder. Sample: We got a sack from the previous spheres. We select them by sieve, measure their weights and calculate an effective diameter. N 1 =?, d 1 =1; N 2 =?, d 2 =10 W But what kind of??? d? dw + dw dw i W + W W = = 1 2 i i x x φ i i = φi This is a volume or mass weighted average 25
26 Mass weighted averages When the numbers are not known. From the original system d w ( = 9,98) d ( = 10) 2 d W W 4 = dw i i di Ni W = d N = i i i W/d w3 = ps In this average the larger particles dominate. (for example the center of mass.) if d i and N i known The number changed! dn < ds < dw 26
27 Why we need the different average? The different experimental method perceive the polydispersity systems with different way. They are sensitive for different properties of the fractions so they result different averages. N 1 =2, d 1 =1; N 2 =1, d 2 =10 d N = 4 d S = 9,8 d W = 9,98 Φ=N Φ=S Φ=W (more dozens average exist) x x φ i i = φi The average does not say anything from the details Beside the average we have to give the average deviation or the polydispersity, PD for characterize the distribution. PD = d / d 2.5 w N 27
28 Polydispersity d d w N 1 Example: 1, M A = 1, N A = 100, M B =100, N B =1 2, M A = 1, N A = 100, M B =100, N B =100 3, M A = 1, N A = 1, M B =100, N B =100 1) 2) M / M = 25 W M / M = 2 W 3) M / M = 1.01 W N N N M n NM i = Ni i M M molar mass, W weight, N number w WM ( NM) M NM = = = W N M N M 2 i i i i i i i i i i i i 28
29 Polydispersity xn < xs < xw PD xw = 1 x N M NM 2 i i w = NM i i M n NM i = Ni i Sample: A M= 1, B M= pcs A + 1pc B 100 pcs A pcs B 1 pc A pcs B M W = = 50, M W = = 99, M W = = M N = = 1, M N = = 50, M N = = M / M = 25 W N M / M = 2 W Number or pc~ piece; pcs pieces N M / M = 1,01 W N 29
30 Polydispersity Sample A: M= 100, B: M= pcs A + 1pc B 100 pcs A pcs B 1 pc A pcs B M / M = 5050 /198 = 25 W N M / M = 9999 / 9902 = 1,01 W N M / M = 9902 / 5050 = 2 W N M molar mass, W weight, N number Only the ratio of the molar masses is important, not their absolute values pc~ piece; pcs pieces 30
31 Normal distribution, cumulative function 100 % mean + σ σ = 15 mean ± σ ~ 68 % The Φ cumulative distribution function describes probabilities for a random variable to fall in the intervals of the form (0, x) or (-, x). 16 mean - σ x f(x) probability density function is "bell"- shaped, and is known as the Gaussian function, it describes the relative likelihood for this random variable to occur at a given point 31
32 Normal distribution, dφ f x x dx ( ) = ( ) frequency function 1 ( x x) f( x) = exp 2 2πσ 2σ 2 ( x x) 2 dϕ 2 σ = ϕ where parameter is the mean (location of the peak) and σ 2 is the variance (the measure of the width of the distribution). The distribution with and is called the standard normal. x ± σ 68% 32
33 Determination of sizes Sieve 25 micron-125 mm Wet sieve 10mikron-100 mikron Microscope 200 nm-150 mikron Ultramicroscope 10 nm -1 mikron Electron microscope 1 nm- 1 mikron Sedimentation d>1 micron (colloidal particles are to small to settle out of solution due to the gravity) Centrifuge d<5 micron Light scattering 1 nm- some microns 33
34 2. Morphology (shape, inner structure) 1. Prolate (a>b), 2. oblate (a<b), 3. rod, 4. plate, 5. coil Irregular particle, equivalent radius 34
35 3. Spatial distribution, ordered structure Homogeneous Diffuse (or exponential) Heterogeneous Ordered Special behavior nematic smectic tactoid The diffuse distribution or Boltzmann distribution law says that if the energy associated with some state or condition of a system is ε then the frequency with which that state or condition occurs, or the probability of its occurrence, is proportional to exp ( ε/kt), where T is the system s absolute temperature and where k is the Boltzmann constant, 35
Colloid chemistry. The colloid state. Classification and characterization of colloid systems.
Colloid chemistry. The colloid state. Classification and characterization of colloid systems. Levente Novák István Bányai Zoltán Nagy Department of Physical Chemistry General information Lectures and examinations
More informationOverview. Lecture 5 Colloidal Dispersions
Physical Pharmacy Lecture 5 Colloidal Dispersions Assistant Lecturer in Pharmaceutics Overview Dispersed Systems Classification Colloidal Systems Properties of Colloids Optical Properties Kinetic Properties
More information*blood and bones contain colloids. *milk is a good example of a colloidal dispersion.
Chap. 3. Colloids 3.1. Introduction - Simple definition of a colloid: a macroscopically heterogeneous system where one component has dimensions in between molecules and macroscopic particles like sand
More informationCOLLOID CHEMISTRY MD. KHAIRUL ISLAM
COLLOID CHEMISTRY MD. KHAIRUL ISLAM HISTORICAL BACKGROUND Thomas Graham (1861) observed that crystalline substances such as sugar, urea, and sodium chloride passed through the membrane, while others like
More informationCHAPTER :COLLOIDS. Subject: Physical Pharmacy. Subject code:phcy102
CHAPTER :COLLOIDS Subject: Physical Pharmacy Subject code:phcy102 INSTRUCTOR Dr. Jagadeesh G Hiremath Assistant Professor in Pharmaceutics College of Pharmacy & Nursing University of Nizwa P.O. Box 33,
More informationCOLLOIDAL STATE. INTRODUCTION: Thomas Graham originally classified all substances in two
COLLOIDAL STATE INTRODUCTION: Thomas Graham originally classified all substances in two group- 1. Crystalloids: These substances can easily be obtained in the crystalline from and their solution can diffused
More informationMIXTURES AND DISSOLVING. CE/Honors Chemistry Unit 10
MIXTURES AND DISSOLVING CE/Honors Chemistry Unit 10 TYPES OF MIXTURES Solution: homogeneous mixture of two or more substances in a single phase Two parts: solvent (greater amt) and solute Does not separate
More information1. The Classification of Dispersion Systems 2. Lyophobic Colloids 3. The Stability and Coagulation of Dispersion Systems 4. Properties of Colloids
Dispersion Systems 1. The Classification of Dispersion Systems 2. Lyophobic Colloids 3. The Stability and Coagulation of Dispersion Systems 4. Properties of Colloids Dispersion system is a heterogeneous
More informationColloidal Dispersions
Physical Pharmacy Lecture 5 Colloidal Dispersions Assistant Lecturer in Pharmaceutics Overview Dispersed Systems Classification Colloidal Systems Properties of Colloids Optical Properties Kinetic Properties
More informationName: Date: Class Notes Chemistry. Energy is the ability to move or change matter.
Name: Date: Class Notes Chemistry Energy Energy is the ability to move or change matter. Everything in the universe consists of two things: energy and matter. Actually, energy and matter are different
More informationIntroduction into the world of colloids. Joachim Koetz, Universität Potsdam
Introduction into the world of colloids Joachim Koetz, Universität Potsdam History of Colloid Chemistry Alchemy Alchemist Elexier of life? drinking gold-solution (aurum potabile) + reducing agent + 3 HAuCl
More informationCOLLOIDAL SOLUTIONS. Department of Medical Chemistry Pomeranian Medical University
COLLOIDAL SOLUTIONS Department of Medical Chemistry Pomeranian Medical University 1 COMPONENTS OF THE SYSTEM -chemicals which create the system. They create different type of mixtures - which makes the
More informationIstván Bányai, University of Debrecen Dept of Colloid and Environmental Chemistry
Colloid stability István Bányai, University of Debrecen Dept of Colloid and Environmental Chemistry www.kolloid.unideb.hu (Stability of lyophilic colloids see: macromolecular solutions) Stabilities 1.
More informationWater and Aqueous Systems
Water and Aqueous Systems The Water Molecule: a Review Water is a simple tri-atomic molecule, H 2 O Each O-H bond is highly polar, because of the high electronegativity of the oxygen (N, O, F, and Cl have
More informationSurface chemistry. Liquid-gas, solid-gas and solid-liquid surfaces.
Surface chemistry. Liquid-gas, solid-gas and solid-liquid surfaces. Levente Novák & István Bányai, University of Debrecen Dept of Colloid and Environmental Chemistry http://kolloid.unideb.hu/~kolloid/
More informationTypes of Mixtures. Main Idea. Heterogeneous and Homogeneous Mixtures. Key Terms soluble solute electrolyte solution suspension nonelectrolyte
Types of Mixtures Key Terms soluble solute electrolyte solution suspension nonelectrolyte solvent colloid It is easy to determine that some materials are mixtures because you can see their component parts.
More information1. Chemisorption is highly specific in nature. It occurs only if there is a possibility of chemical bonding between the adsorbent and the adsorbate.
Question 5.1: Write any two characteristics of Chemisorption. 1. Chemisorption is highly specific in nature. It occurs only if there is a possibility of chemical bonding between the adsorbent and the adsorbate.
More informationA.% by mass (like % composition)
Solutions; Colloids Key Words Solute Solvent Solubility effervescence Miscible saturated Supersaturated (metastable system)- a cooled solution contains more solute than it would at equilibrium, desolvation=
More informationColloid stability. Lyophobic sols. Stabilization of colloids.
Colloid stability. Lyophobic sols. Stabilization of colloids. Lyophilic and lyophobic sols Sols (lyosols) are dispersed colloidal size particles in a liquid medium (=solid/liquid dispersions) These sols
More informationApplied Surfactants: Principles and Applications
Applied Surfactants: Principles and Applications Tadros, Tharwat F. ISBN-13: 9783527306299 Table of Contents Preface. 1 Introduction. 1.1 General Classification of Surface Active Agents. 1.2 Anionic Surfactants.
More informationFoundations of. Colloid Science SECOND EDITION. Robert J. Hunter. School of Chemistry University of Sydney OXPORD UNIVERSITY PRESS
Foundations of Colloid Science SECOND EDITION Robert J. Hunter School of Chemistry University of Sydney OXPORD UNIVERSITY PRESS CONTENTS 1 NATURE OF COLLOIDAL DISPERSIONS 1.1 Introduction 1 1.2 Technological
More informationRheology The relationship between rheological response and material structure
Rheology The relationship between rheological response and material structure Márta Berka University of Debrecen Dept of Colloid and Environmental Chemistry http://dragon.unideb.hu/~kolloid/ Introduction
More informationA dispersion (system) Colloidal solutions High molecular mass compounds
A dispersion (system) Colloidal solutions High molecular mass compounds Outline Types of dispersions Characteristics of main types of dispersions Properties of colloidal solutions Structure of colloidal
More informationColloids Originally derived from a GREEK word KOLLA means GLUE
Colloids Originally derived from a GREEK word KOLLA means GLUE Definition: Colloidal dispersions discontinuous particle phase (dispersed phase) distributed uniformly in a finely divided sate in a continuous
More informationCLASSIFICATION OF MATTER AND MIXTURES
CLASSIFICATION OF MATTER AND MIXTURES NOTEBOOK SETUP Staple both to the top or side of Page 20 Staple to the top or side of Page 21 OBJECTIVES SWBAT classify a mixture as a suspension, colloid or solution.
More informationmodels (three-dimensional representation containing essential structure of
Unit 2 Matter The universe consists of matter and energy. Chemistry is the branch of science the studies matter as well as the changes it undergoes and the energy changes that accompany such transformations.
More informationCHAPTER 7: Solutions & Colloids 7.2 SOLUBILITY. Degrees of Solution. Page PHYSICAL STATES of SOLUTIONS SOLUTION
CHAPTER 7: Solutions & Colloids Predict the relative solubility of materials on the basis of polarity Describe solution formation in terms of solutesolvent interactions Calculate solution concentrations
More informationHeat Capacity of Water A) heat capacity amount of heat required to change a substance s temperature by exactly 1 C
CHEMISTRY Ch. 13 Notes: Water and Its Solutions NOTE: Vocabulary terms are in boldface and underlined. Supporting details are in italics. 13.1 Notes I. Water Molecule Characteristics POLAR molecule (a
More informationContents. Preface XIII. 1 General Introduction 1 References 6
VII Contents Preface XIII 1 General Introduction 1 References 6 2 Interparticle Interactions and Their Combination 7 2.1 Hard-Sphere Interaction 7 2.2 Soft or Electrostatic Interaction 7 2.3 Steric Interaction
More informationLecture 5: Macromolecules, polymers and DNA
1, polymers and DNA Introduction In this lecture, we focus on a subfield of soft matter: macromolecules and more particularly on polymers. As for the previous chapter about surfactants and electro kinetics,
More informationParticle Characterization Laboratories, Inc.
Analytical services Particle size analysis Dynamic Light Scattering Static Light Scattering Sedimentation Diffraction Zeta Potential Analysis Single Point Titration Isoelectric point determination Aqueous
More information3 rd Food Emulsions Short Course November 13 th & 14 th, 2008 University of Massachusetts. David Julian McClements University of Massachusetts
3 rd Food Emulsions Short Course November 13 th & 14 th, 2008 University of Massachusetts David Julian McClements University of Massachusetts Program Objectives Review Basic Principles of Emulsion Science
More informationProperties of Solutions and Kinetics. Unit 8 Chapters 4.5, 13 and 14
Properties of Solutions and Kinetics Unit 8 Chapters 4.5, 13 and 14 Unit 8.1: Solutions Chapters 4.5, 13.1-13.4 Classification of Matter Solutions are homogeneous mixtures Solute A solute is the dissolved
More informationSols (liosols S/L), xerosols (*/S solid medium), gels. Bányai István.
Sols (liosols S/L), xerosols (*/S solid medium), gels Bányai István http://dragon.unideb.hu/~kolloid/ 1 Emulsifiers Emulsifiers: -surface active materials, -naturally occurring materials, -finely divided
More informationCHEMISTRY PHYSICAL. of FOODS INTRODUCTION TO THE. CRC Press. Translated by Jonathan Rhoades. Taylor & Francis Croup
Christos Ritzoulis Translated by Jonathan Rhoades INTRODUCTION TO THE PHYSICAL CHEMISTRY of FOODS CRC Press Taylor & Francis Croup Boca Raton London NewYork CRC Press is an imprint of the Taylor & Francis
More informationColloidal dosage Forms Dr. rer. nat. Rebaz H. Ali
University of Sulaimani School of Pharmacy Dept. of Pharmaceutics Third level - Second semester Colloidal dosage Forms Dr. rer. nat. Rebaz H. Ali Outlines Disperse systems Introduction Lyophilic Lyophobic
More informationCHEMISTRY Ch. 14 Notes: Mixtures and Solutions NOTE: Vocabulary terms are in boldface and underlined. Supporting details are in italics.
CHEMISTRY Ch. 14 Notes: Mixtures and Solutions NOTE: Vocabulary terms are in boldface and underlined. Supporting details are in italics. 14.1 notes I. Types of mixtures (mixture a physical blend of substances)
More informationScience For Class IX Is Matter Around Us Pure
Science For Class IX Is Matter Around Us Pure (Q.1) Name the process which can be used to recover sugar from an aqueous sugar solution. (Q.2) What happens when a saturated solution is heated? (Q.3) Name
More informationSurface interactions part 1: Van der Waals Forces
CHEM-E150 Interfacial Phenomena in Biobased Systems Surface interactions part 1: Van der Waals Forces Monika Österberg Spring 018 Content Colloidal stability van der Waals Forces Surface Forces and their
More informationChapter 9 Generation of (Nano)Particles by Growth
Chapter 9 Generation of (Nano)Particles by Growth 9.1 Nucleation (1) Supersaturation Thermodynamics assumes a phase change takes place when there reaches Saturation of vapor in a gas, Saturation of solute
More informationDownloaded from
Science For Class IX Is Matter Around Us Pure (Q.1) Name the process which can be used to recover sugar from an aqueous sugar solution. (Q.2) What happens when a saturated solution is heated?
More informationPhysical Properties: Mass, Volume, Density, Conductivity, Magnetism, State of Matter, Solubility Mixtures, Heterogeneous mixtures, suspension,
Physical Properties: Mass, Volume, Density, Conductivity, Magnetism, State of Matter, Solubility Mixtures, Heterogeneous mixtures, suspension, Homogeneous mixtures, colloid, solution Unit: Physical Properties
More informationSoft matters end use properties analysis thanks to Microrheology
Soft matters end use properties analysis thanks to Microrheology Formulaction, 10 impasse Borde Basse, 31240 L Union, France, www.formulaction.com Abstract. We present a new technique of passive microrheology
More informationthe universal solvent
Chapter 7: Acids, Bases, and Solutions Solution a homogeneous mixture Solutions have the same properties throughout, containing solute particles (molecules or ions) that are too small to see Solvent the
More informationPhysics and Chemistry of Interfaces
Hans Jürgen Butt, Karlheinz Graf, and Michael Kappl Physics and Chemistry of Interfaces Second, Revised and Enlarged Edition WILEY- VCH WILEY-VCH Verlag GmbH & Co. KGaA Contents Preface XI 1 Introduction
More informationINTERMOLECULAR AND SURFACE FORCES
INTERMOLECULAR AND SURFACE FORCES SECOND EDITION JACOB N. ISRAELACHVILI Department of Chemical & Nuclear Engineering and Materials Department University of California, Santa Barbara California, USA ACADEMIC
More informationLesson 1 Substances and Mixtures
Lesson 1 Student Labs and Activities Page Launch Lab 8 Content Vocabulary 9 Lesson Outline 10 MiniLab 12 Content Practice A 13 Content Practice B 14 School to Home 15 Key Concept Builders 16 Enrichment
More informationSOLUTIONS. Heterogeneous Mixtures. Section 8.1: Solutions and Other Mixtures. Heterogeneous Mixtures (cont d) CHAPTER 8.
Section 8.1: Solutions and Other Mixtures CHAPTER 8 SOLUTIONS Key Questions What is a heterogeneous mixture? What is a homogeneous mixture? Heterogeneous Mixtures The tree of matter branches into two distinct
More informationSurface Chemistry & States of Matter
Surface Chemistry & States of Matter S. Sunil Kumar Lecturer in Chemistry 1. Adsorption is a. Colligative property b. Oxidation process c. Reduction process d. Surface phenomenon Ans. d 2. When adsorption
More informationTerminology related to Plant Physiology & Biochemistry. Dr. Harsh Manchanda Assistant Professor P. G. Govt. College for Girls Sector -11 Chandigarh
Terminology related to Plant Physiology & Biochemistry Dr. Harsh Manchanda Assistant Professor P. G. Govt. College for Girls Sector -11 Chandigarh Plant Physiology Study of life activities, responses and
More informationChemistry-STD-XII Science Question Bank with Solution Surface Chemistry
Adsorption Question 1 Chemistry-STD-XII Science Question Bank with Solution Surface Chemistry Question 2 Question 3 List conditions optimum for enzymatic reactions. Conditions optimum for enzymatic reactions
More informationPHRC 4110 Pharmaceutics I
CO01: Use interpretive tools for proper data handling CO01.01: Describe basic mathematics and statistic to interpret pharmaceutical data CO01.02: Work with exponents, powers, roots, logarithms, and antilogarithms
More informationInterfaces and interfacial energy
Interfaces and interfacial energy 1/14 kinds: l/g }{{ l/l } mobile s/g s/l s/s Example. Estimate the percetage of water molecules on the surface of a fog droplet of diameter (i) 0.1 mm (naked eye visibility
More informationDispersion systems. Dispersion system = dispersed phase in a continuum phase (medium) s/l, l/l,... According to the size of the dispersed phase:
Dispersion systems 1/20 Dispersion system = dispersed phase in a continuum phase (medium) s/l, l/l,... According to the size of the dispersed phase: coarse dispersion (suspension), > 1 µm colloid 1 µm
More informationSURFACE CHEMISTRY
Short Answer Questions: SURFACE CHEMISTRY *1. What is catalysis? How is catalysis classified? Give two examples for each type of catalysis? Ans. A catalyst is the substance that increases the rate of chemical
More informationColloid stability. Lyophobic sols. Stabilization of colloids. Levente Novák István Bányai Zoltán Nagy Department of Physical Chemistry
Colloid stability. Lyophobic sols. Stabilization of colloids. Levente Novák István Bányai Zoltán Nagy Department of Physical Chemistry Lyophilic and lyophobic sols Sols (lyosols) are dispersed colloidal
More informationOlle Inganäs: Polymers structure and dynamics. Polymer physics
Polymer physics Polymers are macromolecules formed by many identical monomers, connected through covalent bonds, to make a linear chain of mers a polymer. The length of the chain specifies the weight of
More informationSet 1: Set 2: Set 3: Set 4: Set 5:
Chapter 12 Physical Properties of Solutions Problems - Page 535 541 Set 1:16, 22, 24, 29, 31; Set 2: 34, 38, 45, 52, 60; Set 3: 62, 66, 74, 90, 93; Set 4: 94, 96, 101, 107, 108, 114 Set 5: 120, 123, 128,
More informationHow can homogeneous and heterogeneous mixtures be. 1. classified? 2. separated?
How can homogeneous and heterogeneous mixtures be 1. classified? 2. separated? 1. HETEROGENEOUS MIXTURE 2. COLLOID 3. EMULSION 4. SUSPENSION 5. FILTRATION 6. TYNDALL EFFECT 7. HOMOGENEOUS MIXTURE 8. SOLUTION
More informationColloidal dispersion
Dispersed Systems Dispersed systems consist of particulate matter, known as the dispersed phase, distributed throughout a continuous or dispersion medium. The dispersed material may range in size from
More informationLiquid crystal phase transitions in dispersions of rod-like colloidal particles
J. Phys.: Condens. Matter 8 (1996) 9451 9456. Printed in the UK Liquid crystal phase transitions in dispersions of rod-like colloidal particles M P B van Bruggen, F M van der Kooij and HNWLekkerkerker
More information1 Solutions and Other Mixtures
CHAPTER 8 SECTION Solutions 1 Solutions and Other Mixtures KEY IDEAS As you read this section, keep these questions in mind: What is a heterogeneous mixture? What is a homogeneous mixture? What Is a Mixture?
More informationContents. Preface XIII
V Contents Preface XIII 1 General Introduction 1 1.1 Fundamental Knowledge Required for Successful Dispersion of Powders into Liquids 1 1.1.1 Wetting of Powder into Liquid 1 1.1.2 Breaking of Aggregates
More informationMATTER Classification of Matter. Composition of Matter
MATTER Classification of Matter Composition of Matter Pure Substances Matter is classified as substances or a mixture of substances. A pure substance, or simply a substance, is a type of matter with a
More informationSurface and Interfacial Tensions. Lecture 1
Surface and Interfacial Tensions Lecture 1 Surface tension is a pull Surfaces and Interfaces 1 Thermodynamics for Interfacial Systems Work must be done to increase surface area just as work must be done
More informationCOLLOIDAL DISPERSIONS
COLLOIDAL DISPERSIONS Marlyn D. Laksitorini Lab. of Physical Pharmacy and Biopharmaceutics Dept.Pharmaceutics Gadjah Mada School of Pharmacy References Overview 1. Type of Dispersion 2. Example of Colloidal
More informationSurfactants. Oil does not mix with water; surface tension. Document prepared by Hervé This le 27th December 2010
Surfactants Document prepared by Hervé This le 27th December 2010 Oil does not mix with water; surface tension Why do we use soap in order to wash one's hands? Why do we pub soap in a cloth washing machine?
More information1. Which substance will conduct the current in the solid state? 1. Diamond 2.Graphite 3.Iodine 4.Sodium chloride.
CHAPTER :SOLIDS 1. Which substance will conduct the current in the solid state? 1. Diamond 2.Graphite 3.Iodine 4.Sodium chloride. 2. Molten sodium chloride conducts electricity due to the presence of ions:
More informationMATTER. Classifying Matter. Matter. Matter is ANYTHING that takes up space and has mass *even the air. Mixtures. Pure Substances
MATTER Matter is ANYTHING that takes up space and has mass *even the air Classifying Matter varying composition has multiple properties Mixtures constant composition Matter substances has same properties
More informationCHAPTER-2 NCERT SOLUTION
CHAPTER-2 NCERT SOLUTION Page no. 15 Question 1: What is meant by a pure substance? Answer 1: A pure substance is the one that consists of a single type of particles, i.e., all constituent particles of
More informationH 2 O WHAT PROPERTIES OF WATER MAKE IT ESSENTIAL TO LIFE OF EARTH? Good solvent High Surface tension Low vapor pressure High boiling point
Unit 9: Solutions H 2 O WHAT PROPERTIES OF WATER MAKE IT ESSENTIAL TO LIFE OF EARTH? Good solvent High Surface tension Low vapor pressure High boiling point Water is a polar molecule. It experiences hydrogen
More informationColloidal Suspension Rheology Chapter 1 Study Questions
Colloidal Suspension Rheology Chapter 1 Study Questions 1. What forces act on a single colloidal particle suspended in a flowing fluid? Discuss the dependence of these forces on particle radius. 2. What
More informationChapter 11 Properties of Solutions
Chapter 11 Properties of Solutions 11.1 Solution Composition. Molarity moles solute 1. Molarity ( M ) = liters of solution B. Mass Percent mass of solute 1. Mass percent = 1 mass of solution C. Mole Fraction
More informationNSW Higher School Certificate Senior Science 9.2 Lifestyle Chemistry
NSW Higher School Certificate Senior Science 9.2 Lifestyle Chemistry Section 2 Cleaning Products 9.2 Lifestyle Chemistry Section 2 ::: Cleaning Products 9.2.2 A wide range of cleaning products are made
More informationLESSON 15.3 Key Objectives
LESSON 15.3 Key Objectives 15.3.1 DISTINGUISH between a suspension and a solution. 15.3.2 IDENTIFY how to distinguish a colloid from a suspension and a solution. Additional Resources Reading and Study
More informationChapter 7. Pickering Stabilisation ABSTRACT
Chapter 7 Pickering Stabilisation ABSTRACT In this chapter we investigate the interfacial properties of Pickering emulsions. Based upon findings that indicate these emulsions to be thermodynamically stable,
More informationParticles, drops, and bubbles. Lecture 3
Particles, drops, and bubbles Lecture 3 Brownian Motion is diffusion The Einstein relation between particle size and its diffusion coefficient is: D = kt 6πηa However gravitational sedimentation tends
More informationMixtures and Solutions
Mixtures and Solutions Section 14.1 Heterogeneous and Homogeneous Mixtures In your textbook, read about suspensions and colloids. For each statement below, write true or false. 1. A solution is a mixture
More informationSolvent does the dissolving (acetone) Solute the substance being dissolved (Styrofoam ) Soluble able to be dissolved
Solvent does the dissolving (acetone) Solute the substance being dissolved (Styrofoam ) Soluble able to be dissolved Like dissolves Like Ionic & polar compounds dissolve each other. Nonpolar dissolves
More information(critical temp.) (B) Temperature of gas (C) Pressure of gas (D) All of them 2. The volume of gases NH 3
EXERCISE-01 CHECK YOUR GRASP SELECT THE CORRECT ALTERNATIVE (ONLY ONE CORRECT ANSWER) 1. Which of the following factors affects the adsorption of a gas on solid? (A) T c (critical temp.) (B) Temperature
More informationGuidelines for the characterization of dispersion stability
Provläsningsexemplar / Preview TECHNICAL REPORT ISO/TR 13097 First edition 2013-06-15 Guidelines for the characterization of dispersion stability Lignes directrices pour la caractérisation de la stabilité
More informationElements, Compounds & Mixtures
Classification of Matter Elements, Compounds & Mixtures Mr. Gilliland Honors Physical Science @ SHS The Classification of Matter Matter 109 20 million + infinite number Elements Compounds Mixtures Made
More informationSolutions and other Mixtures. Ch 20.1
Solutions and other Mixtures Ch 20.1 Mixture A A combination of more than one pure substances physically combined. Two Types: Homogeneous Same throughout Heterogeneous Different throughout Homogeneous
More informationMOLECULAR INTERACTIONS NOTES
- 1 - MOLECULAR INTERACTIONS NOTES Summary of Fundamental Molecular Interactions Q1Q Ion-Ion U ( r) = 4 r πεε o µ Q cosθ U ( r) = 4πεε o r µ 1µ U ( r) 3 r µ 1 µ U ( r) 6 r µ 1 α U ( r) 6 r Ion-Dipole Dipole-Dipole
More informationIntroduction to Dynamic Light Scattering for Particle Size Determination
www.horiba.com/us/particle Jeffrey Bodycomb, Ph.D. Introduction to Dynamic Light Scattering for Particle Size Determination 2016 HORIBA, Ltd. All rights reserved. 1 Sizing Techniques 0.001 0.01 0.1 1 10
More informationColloid & Interface Science Case Study Model Answers
Colloid & Interface Science Case Study Model Answers Distance Learning Course in Cosmetic Science Society of Cosmetic Scientists Common Features Formulations were examples of lyophobic colloidal systems
More informationPhysical Science. A study of chemistry and physics -Classifying Matter
Physical Science A study of chemistry and physics -Classifying Matter Classifying Matter Inquiry Cubes Classifying assorted objects Classification of Matter Matter Specific to General Pure Substance Homogenous
More informationSmall Angle X-ray Scattering (SAXS)
Small Angle X-ray Scattering (SAXS) We have considered that Bragg's Law, d = λ/(2 sinθ), supports a minimum size of measurement of λ/2 in a diffraction experiment (limiting sphere of inverse space) but
More informationUniversity of Pécs Institute of Pharmaceutical Technology and Biopharmacy
University of Pécs Institute of Pharmaceutical Technology and Biopharmacy Particle Definition In a continuous phase the particle is an (mostly in gaseous or liquid material) existing, dispersed, interface
More informationLes Houches School of Foam: Introduction to Coarsening
Les Houches School of Foam: Introduction to Coarsening Andrew Belmonte The W. G. Pritchard Laboratories Department of Mathematics, Penn State University 1 What is Coarsening? (for a foam) Initial foam
More informationMechanical properties of polymers: an overview. Suryasarathi Bose Dept. of Materials Engineering, IISc, Bangalore
Mechanical properties of polymers: an overview Suryasarathi Bose Dept. of Materials Engineering, IISc, Bangalore UGC-NRCM Summer School on Mechanical Property Characterization- June 2012 Overview of polymer
More informationFinal Morphology of Complex Materials
120314 Final Morphology of Complex Materials 1) Proteins are the prototypical model for hierarchy. a) Give the generic chemical structure for an amino acid and a protein molecule (a tripeptide). b) Label
More information1 Millimeter. 1 Micron. 1 Nanometer. 1 Angstrom ELECTRON SEPARATION PROCESS COMMON MATERIALS PARTICLE SIZE LOG SCALE MAGNETIC RANGE SPECTRUM
HANDOUT 3. Millimeter Micron Nanometer Angstrom 00 APPROX. MOLEC. WT. 0 000 00 0 000 00 0 8 7 6 5 4 3 2 0 Radio waves Infrared Ultraviolet Visible X-rays MACRO MICRO MOLECULAR IONIC MOLECULE MACRO 200k
More informationCHEMISTRY. 1). Solutions are classified into aqueous and non-aqueous solutions, based on. a) Nature of solute particles
CHEMISTRY 1). Solutions are classified into aqueous and non-aqueous solutions, based on. a) Nature of solute particles b) Nature of solvent c) Size of the particles d) Thickness of solvent 2). The solvent
More information1 General Introduction
1 1 General Introduction Several classes of formulations of disperse systems are encountered in the chemical industry, including suspensions, emulsions, suspoemulsions (mixtures of suspensions and emulsions),
More informationPharmaceutical compounding I Colloidal and Surface-Chemical Aspects of Dosage Forms Dr. rer. nat. Rebaz H. Ali
University of Sulaimani School of Pharmacy Dept. of Pharmaceutics Pharmaceutical Compounding Pharmaceutical compounding I Colloidal and Surface-Chemical Aspects of Dosage Forms Dr. rer. nat. Rebaz H. Ali
More informationMohamed Daoud Claudine E.Williams Editors. Soft Matter Physics. With 177 Figures, 16 of them in colour
Mohamed Daoud Claudine E.Williams Editors Soft Matter Physics With 177 Figures, 16 of them in colour Contents 1. Droplets: CapiUarity and Wetting 1 By F. Brochard-Wyart (With 35 figures) 1.1 Introduction
More informationLecture 7 Contact angle phenomena and wetting
Lecture 7 Contact angle phenomena and Contact angle phenomena and wetting Young s equation Drop on the surface complete spreading Establishing finite contact angle γ cosθ = γ γ L S SL γ S γ > 0 partial
More informationColloidal Dispersions, Freezing and Rheology
Chapter 2 Colloidal Dispersions, Freezing and Rheology A typical ice cream consists of about 30% ice, 50% air, 5% fat and 15% matrix (sugar solution) by volume. It therefore contains all three states of
More informationMolecular geometry. Multiple Bonds. Examples and Questions. Identify procane (an aesthetic) Larger Covalent Molecules. S h a p e
Molecular Geometry o e Pairs (Lewis Structure) Arrangement of Electron Pairs o of Bond Pairs o of Lone Pairs Molecular geometry Examples Linear Bel,, - The valence shell electron pair repulsion model (VSEPR
More information