REACTIVITE CHIMIQUE EN MILIEUX FLUIDES SUPERCRITIQUES. CHIMIE POUR UN DEVELOPPEMENT DURABLE

Size: px
Start display at page:

Download "REACTIVITE CHIMIQUE EN MILIEUX FLUIDES SUPERCRITIQUES. CHIMIE POUR UN DEVELOPPEMENT DURABLE"

Transcription

1 RECTIVITE CHIMIQUE EN MILIEUX FLUIDES SUPERCRITIQUES. CHIMIE POUR UN DEVELOPPEMENT DURBLE C. YMONIER, M. MJIMEL,. SERNI, F. CNSELL ICMCB-CNRS 87, avenue du Dr lbert Schweitzer Pessac cedex Tél. : +33 (0) Fax : +33 (0) / Group Supercritical Fluids E.mail: aymonier@icmcb-bordeaux.cnrs.fr

2 Institut de Chimie de la Matière Condensée de Bordeaux SOLID STTE CHEMISTRY MTERILS SCIENCE ND TECHNOLOGY MOLECULR SCIENCES 230 RESERCHERS Director : Dr Claude DELMS ICMCB-CNRS 87, avenue du Dr lbert Schweitzer Pessac cedex Tél. : +33 (0) Fax : +33 (0) E.mail directeur : dr@icmcb.u-bordeaux1.fr

3 ICMCB RESERCH GROUPS N N O M T E R I L S D V N C E D M T E R I L S CTLYSIS, ENERGY, MICROELECTRONIC, SNTE ENVIRONMENT ND SUSTINBLE DEVELOPMENT

4 TEM CHEMISTRY IN SUPERCRITICL FLUIDS CHEMISTRY IN SUPERCRITICL FLUIDS FOR DVNCED NNOSTRUCTURED MTERILS Multifunctional nanomaterials Nano-engineering of materials surface Nanostructuration in volume ENVIRONMENT Waste management Biomass liquefaction and gazeification TECHNOLOGY TRNSFER 18 PERSONS

5 Pressure SUPERCRITICL FLUID? Liquid Supercritical fluid Solid Critical point Gaz Gaz Temperature

6 SUPERCRITICL FLUID? One Substance - many different Solvents Small pressure changes - Density varies from LIQUID-LIKE (good solvent) to GS-LIKE (no solvent at all) Volatile solvents that just go away when pressure is decreased Liquid density, but mix completely with gases (H 2,O 2 ) Low viscosity, high diffusivity Low surface tension

7 SUPERCRITICL FLUIDS ND ENVIRONMENT Supercritical water oxidation (SCWO) 5 patents, 15 papers

8 SUPERCRITICL FLUIDS ND ENVIRONMENT RESULTTS Déchets Liquides Organiques (5 à 15%) + Eau (85 à 95%) Thermochimie - Récupération d énergie Thermodynamique - Séparation des gaz Echangeur Economiseur Refroidisseur Production de vapeur Vanne de détente 25 C 25 C CO 2 Eau Cinétiques et Mécanismes Réactionnels - Dimensionnement - Sous produits O 2 Pompe 250 bars Injections d O C 250 bars R E C T E U R S 250 C 300 C 300 C 400 C 400 C 550 C 250 bars 1 bar Minéraux Technologie des réacteurs - Nouveaux concepts - Matériaux - Simulation Pompe / Compresseur Oxygène 300 bars Pompe 250 bars BIOMSS GZEIFICTION ND LIQUEFCTION

9 SUPERCRITICL FLUIDS ND DVNCED NNOSTRUCTURED MTERILS Particle design based on physical transformation Particle design based on chemical transformation SCF + Solute SCF + Reagents Chemical reaction ORGNIC PRTICLE DESIGN Size, morphology, structure Pharmaceutical industry Food industry Pigment industry INORGNIC PRTICLE DESIGN Size, morphology, structure, composition

10 SUPERCRITICL FLUIDS ND DVNCED NNOSTRUCTURED MTERILS Chemical transformation in supercritical fluids Nanopowders of oxides, metals, semiconductors or nitrides TOWRDS MORE COMPLEX NNOBRICKS Nanowires, nanorods, CNTs Hybrid organic / inorganic nanoparticles Nanocomposites by nanostructuration on surface or in volume of materials NNOSTRUCTURED MTERILS WITH SPECIFIC PROPERTIES Catalysis, Microelectronic and Energy

11 SUPERCRITICL FLUIDS ND DVNCED NNOSTRUCTURED MTERILS Functional Pd nanoparticles for catalysis Supported nanoparticles pplication to hydrogen storage N ± 1.0 nm 10 0 Size (nm) nm JCS 2007 Core-shell nanoparticles for nanostructured ceramics pplication to microelectronic Nanotech nm nm J. Nanosci. Nanotech 2005

12 CONCLUSIONS SCF : INTERESTING MEDI FOR CHEMISTRY SCF ND ENVIRONMENT SCF ND DVNCED NNOSTRUCTURED MTERILS SCF ND SUSTINBLE DEVELOPMENT

SYNTHESIS IN SUPERCRITICAL AMMONIA AND CHARACTERIZATION OF NANOSTRUCTURED NICKEL OXINITRIDE

SYNTHESIS IN SUPERCRITICAL AMMONIA AND CHARACTERIZATION OF NANOSTRUCTURED NICKEL OXINITRIDE SYNTHESIS IN SUPERCRITICAL AMMONIA AND CHARACTERIZATION OF NANOSTRUCTURED NICKEL OXINITRIDE Sophie Desmoulins-Krawiec, Sandy Moisan, Cyril Aymonier, Anne Loppinet-Serani, François Weill, Jean Etourneau,

More information

SYNTHESIS OF INORGANIC NANOPARTICLES IN SUPERCRITICAL FLUIDS. A SIMPLE MODEL TO PREDICT PARTICLE SIZE

SYNTHESIS OF INORGANIC NANOPARTICLES IN SUPERCRITICAL FLUIDS. A SIMPLE MODEL TO PREDICT PARTICLE SIZE SYNTHESIS OF INORGANIC NANOPARTICLES IN SUPERCRITICAL FLUIDS. A SIMPLE MODEL TO PREDICT PARTICLE SIZE A. Erriguible 1, F. Marias 2, F. Cansell 3, C. Aymonier* 3 1 Laboratoire TREFLE (UMR C.N.R.S. 8508),

More information

HYDROTHERMAL OXIDATION TREATMENT AND REACTION CONTROL BY OXYGEN INJECTION

HYDROTHERMAL OXIDATION TREATMENT AND REACTION CONTROL BY OXYGEN INJECTION HYDOTHEMAL OXIDATION TEATMENT AND EACTION CONTOL BY OXYGEN INJECTION David MATEOS 1, Juan POTELA 2, Christine MAAUD 3, François CANSELL 1 1 Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB)

More information

NANO SCIENCE AND TECHNOLOGY THE INDIAN SCENE

NANO SCIENCE AND TECHNOLOGY THE INDIAN SCENE NANO SCIENCE AND TECHNOLOGY THE INDIAN SCENE DR. PRAVEER ASTHANA MINISTRY OF SCIENCE AND TECHNOLOGY (DEPARTMENT OF SCIENCE AND TECHNOLOGY) GOVERNMENT OF INDIA WHAT HAVE WE DONE SO FAR? Basic Research in

More information

Supporting Information

Supporting Information Supporting Information Geometry Flexibility of Copper Iodide Clusters: Variability in Luminescence Thermochromism Quentin Benito, a Xavier F. Le Goff, b Gregory Nocton, b Alexandre Fargues, c Alain Garcia,

More information

AN INNOVATIVE APPLICATION OF POLYMER SWELLING BY scco 2 : THEIR NANOSTRUCTURATION WITH INORGANIC NANOPARTICLES

AN INNOVATIVE APPLICATION OF POLYMER SWELLING BY scco 2 : THEIR NANOSTRUCTURATION WITH INORGANIC NANOPARTICLES AN INNOVATIVE APPLICATION OF POLYMER SWELLING BY scco 2 : THEIR NANOSTRUCTURATION WITH INORGANIC NANOPARTICLES P. Vitoux 1, T. Tassaing 2, J.J. Letourneau 3, M. Majimel 1, F. Cansell 1 and C. Aymonier*

More information

Development of active inks for organic photovoltaics: state-of-the-art and perspectives

Development of active inks for organic photovoltaics: state-of-the-art and perspectives Development of active inks for organic photovoltaics: state-of-the-art and perspectives Jörg Ackermann Centre Interdisciplinaire de Nanoscience de Marseille (CINAM) CNRS - UPR 3118, MARSEILLE - France

More information

European Network of Materials Research Centres NAME : INTERDEPARTMENTAL MATERIALS SCIENCE AND ENGINEERING CENTER (CISIM)

European Network of Materials Research Centres NAME : INTERDEPARTMENTAL MATERIALS SCIENCE AND ENGINEERING CENTER (CISIM) NAME : INTERDEPARTMENTAL MATERIALS SCIENCE AND ENGINEERING CENTER (CISIM) INSTITUTION : UNIVERSITY OF PISA (UNIPI) COUNTRY : ITALY Profile : CISIM is the Interdepartmental Materials Science and Engineering

More information

Thermal behaviour of 2 nanostructures in various gas environments: a combined 3D and in-situ TEM approach

Thermal behaviour of 2 nanostructures in various gas environments: a combined 3D and in-situ TEM approach Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2018 Supporting Information Thermal behaviour of Pd@SiO 2 nanostructures in various gas environments:

More information

Nanopowder Production A Comparison of Several Methods

Nanopowder Production A Comparison of Several Methods Nanopowder Production A Comparison of Several Methods Gimena Gordillo Xavier Hailey Advisors: Prof. G. A. Mansoori Grad. Student Listowel Agyarko Outline Introduction to Nanotechnology 1. What is Nanotechnology

More information

CNRS Chemistry in France

CNRS Chemistry in France WELCOME to IRCELYON CNRS Chemistry in France Lille Rennes Paris Nancy Strasbourg Nantes Lyon Bordeaux Grenoble Toulouse Marseille Montpellier DOMAINS OF COMPETENCES OF THE LACE Environmental Domains Themes

More information

PART 2 Dr. Stephen Glover

PART 2 Dr. Stephen Glover Queens University Belfast Valorisation of Lignocellulosic Waste and the Potential of Supercritical Water and Wet Air Oxidation PART 2 Dr. Stephen Glover Workshop - Technology Foresight Conference, Cologne

More information

Contents. Preface XI List of Contributors XIII

Contents. Preface XI List of Contributors XIII V Contents Preface XI List of Contributors XIII 1 Introduction to Nanoparticles 1 1.1 General Introduction to Nanoparticles 1 1.2 Methods of Nanoparticle Synthesis 8 1.3 Surface Plasmon Resonance and Coloring

More information

SYNTHESIS OF INORGANIC MATERIALS AND NANOMATERIALS. Pr. Charles Kappenstein LACCO, Laboratoire de Catalyse en Chimie Organique, Poitiers, France

SYNTHESIS OF INORGANIC MATERIALS AND NANOMATERIALS. Pr. Charles Kappenstein LACCO, Laboratoire de Catalyse en Chimie Organique, Poitiers, France SYNTHESIS OF INORGANIC MATERIALS AND NANOMATERIALS Pr. Charles Kappenstein LACCO, Laboratoire de Catalyse en Chimie Organique, Poitiers, France Outline IV - FORMATION OF SOLIDS FROM SOLUTIONS 1) Glass

More information

HYDROTHERMAL OXIDATION OF ORGANIC COMPOUNDS: MODELLING AND SIMULATION OF MULTI- INJECTION REACTOR.

HYDROTHERMAL OXIDATION OF ORGANIC COMPOUNDS: MODELLING AND SIMULATION OF MULTI- INJECTION REACTOR. HYDROTHERMAL OXIDATION OF ORGANIC COMPOUNDS: MODELLING AND SIMULATION OF MULTI- INJECTION REACTOR. J. Mercadier *, S. Vielcazals*, D. Matéos **,, F. Marias *, C. Marraud ***, M. Bottreau **, F. Cansell

More information

SCALE-UP OF A SUPERCRITICAL WATER OXIDATION PROCESS FOR THE ELIMINATION OF BACK-END NUCLEAR ORGANIC WASTES

SCALE-UP OF A SUPERCRITICAL WATER OXIDATION PROCESS FOR THE ELIMINATION OF BACK-END NUCLEAR ORGANIC WASTES SCALE-UP OF A SUPERCRITICAL WATER OXIDATION PROCESS FOR THE ELIMINATION OF BACK-END NUCLEAR ORGANIC WASTES A. Roubaud*, S. Moussière, S. Coullet, H.-A. Turc, B. Fournel Supercritical fluids and membranes

More information

Polymers and Nanomaterials from Liquid-Liquid Interfaces: Synthesis, Self-Organisation and Applications

Polymers and Nanomaterials from Liquid-Liquid Interfaces: Synthesis, Self-Organisation and Applications Preface My interest in liquid liquid interfaces, the reactions occurring at them and through them, as well as their physical properties and potential applications was initiated during my early days of

More information

Catalytic oxidations: finding the optimum composition of AuPd coreshell nanoparticle catalysts

Catalytic oxidations: finding the optimum composition of AuPd coreshell nanoparticle catalysts Brazilian ChemComm Symposium Chemistry and Sustainable Energy 5 th November 2012, São Paulo, Brazil Catalytic oxidations: finding the optimum composition of AuPd coreshell nanoparticle catalysts Prof.

More information

PRODUCTION OF POLYMER PARTICLES USING SUPERCRITICAL CARBON DIOIXDE AS A PROCESSING SOLVENT IN AN EXTRUDER

PRODUCTION OF POLYMER PARTICLES USING SUPERCRITICAL CARBON DIOIXDE AS A PROCESSING SOLVENT IN AN EXTRUDER PRODUCTION OF POLYMER PARTICLES USING SUPERCRITICAL CARBON DIOIXDE AS A PROCESSING SOLVENT IN AN EXTRUDER Sameer P. Nalawade* and L. P. B. M. Janssen Email: S.P.Nalawade@chem.rug.nl, Fax: 0031-50-363 4479

More information

Zinc Catalysis: Applications In Organic Synthesis READ ONLINE

Zinc Catalysis: Applications In Organic Synthesis READ ONLINE Zinc Catalysis: Applications In Organic Synthesis READ ONLINE If looking for the book Zinc Catalysis: Applications in Organic Synthesis in pdf format, then you have come on to the faithful website. We

More information

Nano Materials and Devices

Nano Materials and Devices Nano Materials and Devices Professor Michael Austin Platform Technologies Research Institute Nano Materials and Devices Program Aim: to develop an integrated capability in nanotechnology Design and modelling

More information

SELF-ASSEMBLY AND NANOTECHNOLOGY A Force Balance Approach

SELF-ASSEMBLY AND NANOTECHNOLOGY A Force Balance Approach SELF-ASSEMBLY AND NANOTECHNOLOGY A Force Balance Approach Yoon S. Lee Scientific Information Analyst Chemical Abstracts Service A Division of the American Chemical Society Columbus, Ohio WILEY A JOHN WILEY

More information

INORGANIC SUPPORTED POLYMERIC CATALYSTS INORGANIC SUPPORTED POLYMERIC CATALYSTS PDF ELENA GROPPO UNIVERSITY OF TORINO - ACADEMIA.

INORGANIC SUPPORTED POLYMERIC CATALYSTS INORGANIC SUPPORTED POLYMERIC CATALYSTS PDF ELENA GROPPO UNIVERSITY OF TORINO - ACADEMIA. PDF ELENA GROPPO UNIVERSITY OF TORINO - ACADEMIA.EDU CATALYSIS - WIKIPEDIA 1 / 5 2 / 5 3 / 5 inorganic supported polymeric catalysts pdf A new heterogeneous catalyst for CO(2) activation was identified

More information

Basic Digestion Principles

Basic Digestion Principles Basic Digestion Principles 1 From Samples to Solutions Direct Analytical Method Solid Sample Problems: Mech. Sample Preparation (Grinding, Sieving, Weighing, Pressing, Polishing,...) Solid Sample Autosampler

More information

Fullerene growth from encapsulated graphene flakes

Fullerene growth from encapsulated graphene flakes Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2014 Supplementary figures for: Fullerene growth from encapsulated graphene flakes WAN Neng 1, #, LEI

More information

Materials and Structural Design for Advanced Energy Storage Devices

Materials and Structural Design for Advanced Energy Storage Devices Materials and Structural Design for Advanced Energy Storage Devices Imran Shakir Sustainable Energy Technologies Center (SET) King Saud University Saudi Arabia Specific Power (W/kg) Introduction and Motivation

More information

Phase Equilibria in a One-Component System I

Phase Equilibria in a One-Component System I 5.60 spring 2005 Lecture #17 page 1 Phase Equilibria in a One-Component System I Goal: Understand the general phenomenology of phase transitions and phase coexistence conditions for a single component

More information

CRYSTALLIZATION OF GRISEOFULVIN BY BATCH ANTI-SOLVENT PROCESS

CRYSTALLIZATION OF GRISEOFULVIN BY BATCH ANTI-SOLVENT PROCESS CRYSTALLIZATION OF GRISEOFULVIN BY BATCH ANTI-SOLVENT PROCESS B. De Gioannis, P. Jestin, P. Subra * Laboratoire d Ingénierie des Matériaux et des Hautes Pressions, CNRS, Institut Galilée, Université Paris

More information

Hydroconversion catalytique de la lignine en aromatiques Lignin to aromatics by catalytic hydroconversion

Hydroconversion catalytique de la lignine en aromatiques Lignin to aromatics by catalytic hydroconversion Lignin to Aromatics Hydroconversion catalytique de la lignine en aromatiques Lignin to aromatics by catalytic hydroconversion Partenaire 1: IRCELYN (D. Laurenti, C. Geantet, P. Fongarland (LGPC)) Partenaire

More information

Solid to liquid. Liquid to gas. Gas to solid. Liquid to solid. Gas to liquid. +energy. -energy

Solid to liquid. Liquid to gas. Gas to solid. Liquid to solid. Gas to liquid. +energy. -energy 33 PHASE CHANGES - To understand solids and liquids at the molecular level, it will help to examine PHASE CHANGES in a little more detail. A quick review of the phase changes... Phase change Description

More information

Module : 10 Supercritical Fluid Extraction

Module : 10 Supercritical Fluid Extraction Module : 10 Supercritical Fluid Extraction Dr. Sirshendu De Professor, Department of Chemical Engineering Indian Institute of Technology, Kharagpur e-mail: sde@che.iitkgp.ernet.in Keywords: Separation

More information

Metal nanoparticles and nanomaterials: Radiolytic synthesis and applications

Metal nanoparticles and nanomaterials: Radiolytic synthesis and applications Metal nanoparticles and nanomaterials: Radiolytic synthesis and applications Hynd Remita Laboratoire de Chimie Physique, CNRS-UMR 8000 Université Paris-Sud, Orsay Radiolytic synthesis of metal clusters

More information

CURRICULUM VITAE.

CURRICULUM VITAE. CURRICULUM VITAE Name, First Name: SANCHEZ, Clément Married : 3 child Date and place of birth: 16 Mars 1949 at Paris (France) Address Chimie de la Matière Condensée de Paris, UMR 7574-UPMC/CNRS/Collège

More information

Pollution des sols et interaction avec la biosphère

Pollution des sols et interaction avec la biosphère Pollution des sols et interaction avec la biosphère Mazen SAAD Ecole Centrale de Nantes Laboratoire de Mathématiques Jean Leray FRANCE Mathématiques Pour La Planète La Rochelle 17 octobre 2013 Plan 1 Transport

More information

CAREER IN NATIONAL EDUCATION

CAREER IN NATIONAL EDUCATION CURRICULUM VITAE Name, First Name: SANCHEZ, Clément Married : 3 child Date and place of birth: 16 Mars 1949 at Paris (France) Address Chimie de la Matière Condensée de Paris, UMR 7574-UPMC/CNRS/Collège

More information

The application of nano aluminum powder on solid propellant

The application of nano aluminum powder on solid propellant The application of nano aluminum powder on solid propellant Metal incendiary agent is one of the important components of modern solid propellant, which can improve the explosion heat and density of propellant.

More information

performance electrocatalytic or electrochemical devices. Nanocrystals grown on graphene could have

performance electrocatalytic or electrochemical devices. Nanocrystals grown on graphene could have Nanocrystal Growth on Graphene with Various Degrees of Oxidation Hailiang Wang, Joshua Tucker Robinson, Georgi Diankov, and Hongjie Dai * Department of Chemistry and Laboratory for Advanced Materials,

More information

Electrophoretic Deposition. - process in which particles, suspended in a liquid medium, migrate in an electric field and deposit on an electrode

Electrophoretic Deposition. - process in which particles, suspended in a liquid medium, migrate in an electric field and deposit on an electrode Electrophoretic Deposition - process in which particles, suspended in a liquid medium, migrate in an electric field and deposit on an electrode no redox differs from electrolytic in several ways deposit

More information

CH676 Physical Chemistry: Principles and Applications. CH676 Physical Chemistry: Principles and Applications

CH676 Physical Chemistry: Principles and Applications. CH676 Physical Chemistry: Principles and Applications CH676 Physical Chemistry: Principles and Applications Contact Information Professor Chia-Kuang (Frank) Tsung Email: frank.tsung@bc.edu Office: Merkert 224; Phone: (617) 552-8927 Office Hours: Monday 5-6

More information

Chapter 10: Liquids and Solids

Chapter 10: Liquids and Solids Chapter 10: Liquids and Solids Chapter 10: Liquids and Solids *Liquids and solids show many similarities and are strikingly different from their gaseous state. 10.1 Intermolecular Forces Intermolecular

More information

Overview of Nanotechnology Applications and Relevant Intellectual Property NANO POWER PATENTS

Overview of Nanotechnology Applications and Relevant Intellectual Property NANO POWER PATENTS Overview of Nanotechnology Applications and Relevant Intellectual Property NANO POWER PATENTS Jeffrey H. Rosedale, Ph.D., J.D. Registered Patent Attorney Partner, Woodcock Washburn, LLP ~ 9000 Issued U.S.

More information

Chemical Transformations in Ultrathin Chalcogenide Nanowires

Chemical Transformations in Ultrathin Chalcogenide Nanowires Chemical Transformations in Ultrathin Chalcogenide Nanowires Geon Dae Moon, Sungwook Ko, Younan Xia, and Unyong Jeong Department Biomedical Engineering Washington University, St. Louis, Missouri 63130

More information

Solutions for Assignment-8

Solutions for Assignment-8 Solutions for Assignment-8 Q1. The process of adding impurities to a pure semiconductor is called: [1] (a) Mixing (b) Doping (c) Diffusing (d) None of the above In semiconductor production, doping intentionally

More information

A coherent picture for water at extreme negative pressure

A coherent picture for water at extreme negative pressure A coherent picture for water at extreme negative pressure Mouna El Mekki Azouzi 1, Claire Ramboz 2, Jean-François Lenain 3 and Frédéric Caupin 1 1 Laboratoire de Physique de la Matière Condensée et Nanostructures,

More information

Scalable Nanomaterials and Nanostructures for Energy and Flexible Electronics

Scalable Nanomaterials and Nanostructures for Energy and Flexible Electronics Scalable Nanomaterials and Nanostructures for Energy and Flexible Electronics Liangbing (Bing) Hu MSE & Energy Center University of Maryland College Park Email: binghu@umd.edu 1 Transparent Paper from

More information

Break-out group I: Morphological, Geometrical, and General Terminology ANSI-Nanotechnology Standards Panel

Break-out group I: Morphological, Geometrical, and General Terminology ANSI-Nanotechnology Standards Panel Break-out group I: Morphological, Geometrical, and General Terminology ANSI-Nanotechnology Standards Panel Presented by Dr. Donald Marlowe FDA 1 Top 5 Critical Issues Related to Nomenclature 1. Characterization

More information

Nanoparticle Synthesis and Assembly from Atomistic Simulation Studies

Nanoparticle Synthesis and Assembly from Atomistic Simulation Studies Nanoparticle Synthesis and Assembly from Atomistic Simulation Studies By Takumi Hawa School of Aerospace & Mechanical Engineering Oklahoma Supercomputing Symposium 2008 October 7 Supported by NSF, ARL,

More information

Nanomaterials Portfolio

Nanomaterials Portfolio Nanomaterials Portfolio CABRO, Tradition and Innovation Nanomaterials Portfolio 2 Product Name: AX01 - Gold BPA Description: spherical gold nanoparticles, narrow size distribution:2.5nm stabilized with

More information

Efficient Hydrogen Evolution. University of Central Florida, 4000 Central Florida Blvd. Orlando, Florida, 32816,

Efficient Hydrogen Evolution. University of Central Florida, 4000 Central Florida Blvd. Orlando, Florida, 32816, Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2017 MoS 2 /TiO 2 Heterostructures as Nonmetal Plasmonic Photocatalysts for Highly

More information

Applications of Titanium Dioxdie Nanocoating

Applications of Titanium Dioxdie Nanocoating Applications of Titanium Dioxdie Nanocoating Behzad Rezaei 1, Hamid Mosaddeghi 2 1, 2 Department of Chemistry, 1 rezaei@cc.iut.ac.ir 2 h.mosaddeghi@ch.iut.ac.ir Abstract Metal oxide semiconductors, such

More information

Research Grants Approved and Funded

Research Grants Approved and Funded Research Grants Approved and Funded Koratkar has won 35 grants (totaling ~ $9.7 Million) from several agencies such as the National Science Foundation, Office of Naval Research, Army Research Office, Advanced

More information

An Introduction to Ionic Liquids. Michael Freemantle. RSC Publishing

An Introduction to Ionic Liquids. Michael Freemantle. RSC Publishing An to Ionic Liquids Michael Freemantle RSC Publishing Chapter 1 1 1.1 Definition of Ionic Liquids 1 1.2 Synonyms 1 1.3 Attraction of Ionic Liquids 2 1.4 Cations and Anions 3 1.5 Shorthand Notation for

More information

Supporting information High density monodispersed cobalt nanoparticles filled into multi-walled carbon nanotubes

Supporting information High density monodispersed cobalt nanoparticles filled into multi-walled carbon nanotubes Supporting information High density monodispersed cobalt nanoparticles filled into multi-walled carbon nanotubes Walid Baaziz a, Sylvie Begin-Colin a*, Benoit P. Pichon a, Ileana Florea a, Ovidiu Ersen

More information

OneD Material LLC - Patent Portfolio Overview

OneD Material LLC - Patent Portfolio Overview OneD Material LLC - Patent Portfolio Overview List of Patents and Patent applications owned or licensed exclusively by OneD. Most of the inventions relate to nanostructure materials suitable for energy

More information

Nanotechnology 5 th lecture

Nanotechnology 5 th lecture Nanotechnology 5 th lecture (c) http://www.nccr-nano.org/nccr_data/ gallery/gallery_01/gallery_01_03/pics_06/ internet/nanotube_spiral.jpg Plan for today: http://www.nccr-nano.org/nccr_data/gallery/ gallery_01/gallery_01_03/pics_04/internet/

More information

InterdepartmentalCenter for Materials Science and Engineering. University of Pisa

InterdepartmentalCenter for Materials Science and Engineering. University of Pisa InterdepartmentalCenter for Materials Science and Engineering University Some history. On 1989, in the framework of the Engineering Faculty, the Center for Material Engineering (CIIM) was founded, regrouping

More information

Appendix A. Assessments Points 4 Mode of Assessments. New Course Code and Title Course Coordinator. MS741M Nanomaterials

Appendix A. Assessments Points 4 Mode of Assessments. New Course Code and Title Course Coordinator. MS741M Nanomaterials New Course Code and Title Course Coordinator Details of Course MS741M Nanomaterials AP Jason Xu (Course Coordinator) AP Xue Can Rationale for introducing this course This course will cover the subject

More information

INTERNATIONAL JOURNAL OF CIVIL 17 19, July ENGINEERING. COLOR REMOVAL FROM TEXTILE WASTEWATER USING CuO NANO- PARTICLE COATED ON SAND, CINDER AND GAC

INTERNATIONAL JOURNAL OF CIVIL 17 19, July ENGINEERING. COLOR REMOVAL FROM TEXTILE WASTEWATER USING CuO NANO- PARTICLE COATED ON SAND, CINDER AND GAC INTERNATIONAL JOURNAL OF CIVIL 17 19, July ENGINEERING 2014, Mysore, Karnataka, India AND TECHNOLOGY (IJCIET) ISSN 0976 6308 (Print) ISSN 0976 6316(Online) Volume 5, Issue 9, September (2014), pp. 79-84

More information

Chapter 12. Nanometrology. Oxford University Press All rights reserved.

Chapter 12. Nanometrology. Oxford University Press All rights reserved. Chapter 12 Nanometrology Introduction Nanometrology is the science of measurement at the nanoscale level. Figure illustrates where nanoscale stands in relation to a meter and sub divisions of meter. Nanometrology

More information

Characterisation of hydraulic fractures in limestones using X-ray microtomography

Characterisation of hydraulic fractures in limestones using X-ray microtomography Characterisation of hydraulic fractures in limestones using X-ray microtomography François Renard *,** Dominique Bernard *** Jacques Desrues **** Erwan Plougonven *** Audrey Ougier-Simonin * * LGIT-CNRS-OSUG,

More information

ABSTRACT 1. INTRODUCTION

ABSTRACT 1. INTRODUCTION Organic-inorganic hybrid of polyaniline-vanadium oxide nanocomposites and their electrorheological behaviour Sumita Goswami, Tiago Brehm, Sergej Filonovich, *Maria Teresa Cidade Departamento de Ciência

More information

Supercritical Fluid Technology: Extraction and Aerogels

Supercritical Fluid Technology: Extraction and Aerogels Supercritical Fluid Technology: Extraction and Aerogels Mika Oksanen Ilari Maasilta 7.6.2010 OSKE Nano for Sale Contents Introduction to supercritical fluids Supercritical extraction Supercritical wood

More information

External Magnetic Field Enhanced Chemo-Photothermal Combination Tumor. Therapy via Iron Oxide Nanoparticles

External Magnetic Field Enhanced Chemo-Photothermal Combination Tumor. Therapy via Iron Oxide Nanoparticles Supporting information External Magnetic Field Enhanced Chemo-Photothermal Combination Tumor Therapy via Iron Oxide Nanoparticles Xiaomeng Guo, Wei Li, Lihua Luo, Zuhua Wang, Qingpo Li, Fenfen Kong, Hanbo

More information

Queen s Park High School Key Stage 3 Assessment Science - Earth IA6 target.

Queen s Park High School Key Stage 3 Assessment Science - Earth IA6 target. Year 7 Enquiry Skills Queen s Park High School Key Stage 3 Assessment Science - Earth IA6 target. EARTH STRUCTURE AND UNIVERSE Draw simple graphs outlining information about planets Construct models of

More information

New Materials for the Forest Products Industry. Bruce Lyne KTH, Dept. Surface and Corrosion Science

New Materials for the Forest Products Industry. Bruce Lyne KTH, Dept. Surface and Corrosion Science New Materials for the Forest Products Industry Bruce Lyne KTH, Dept. Surface and Corrosion Science S curves in music? Performance CDs Internet based? LPs Time S curves in joint replacement? Performance

More information

Carbon Black Supported Binary Pt-Pd Nanoparticles by Supercritical Deposition

Carbon Black Supported Binary Pt-Pd Nanoparticles by Supercritical Deposition Carbon Black Supported Binary Pt-Pd Nanoparticles by Supercritical Deposition Can Erkey*, Nazire Seda Yaşar, Betül Cangül Department of Chemical and Biological Engineering, Koc University, 34450 Sariyer,Istanbul,

More information

2D-BLACK PHOSPHORUS FUNCTIONALIZED WITH METAL NANOPARTICLES: FULL CHARACTERIZATION AND CATALYTIC ACTIVITY ON HYDROGENATION REACTIONS

2D-BLACK PHOSPHORUS FUNCTIONALIZED WITH METAL NANOPARTICLES: FULL CHARACTERIZATION AND CATALYTIC ACTIVITY ON HYDROGENATION REACTIONS 2D-BLACK PHOSPHORUS FUNCTIONALIZED WITH METAL NANOPARTICLES: FULL CHARACTERIZATION AND CATALYTIC ACTIVITY ON HYDROGENATION REACTIONS EWPC-13 Freie Universität Berlin Salvatore Interlandi CNR-ICCOM Sesto

More information

Electrically pulsatile responsive drug delivery platform for treatment of Alzheimer s disease

Electrically pulsatile responsive drug delivery platform for treatment of Alzheimer s disease Electronic Supplementary Material Electrically pulsatile responsive drug delivery platform for treatment of Alzheimer s disease Li Wu 1,2, Jiasi Wang 1,2, Nan Gao 1, Jinsong Ren 1, Andong Zhao 1,2, and

More information

Supplementary Figure 1. (a-b) EDX of Mo 2 and Mo 2

Supplementary Figure 1. (a-b) EDX of Mo 2 and Mo 2 Supplementary Figure 1. (a-b) EDX of Mo 2 C@NPC/NPRGO and Mo 2 C@NPC. Supplementary Figure 2. (a) SEM image of PMo 12 2-PPy, (b) TEM, (c) HRTEM, (d) STEM image and EDX elemental mapping of C, N, P, and

More information

Supercritical Antisolvent Precipitation of Sotalol Hydrochloride: Influence of Solvent and of Apparatus Design

Supercritical Antisolvent Precipitation of Sotalol Hydrochloride: Influence of Solvent and of Apparatus Design Supercritical Antisolvent Precipitation of Sotalol Hydrochloride: Influence of Solvent and of Apparatus Design P.Alessi*, I.Kikic, F. Vecchione T.Gamse (1) Dipartimento di Ingegneria Chimica, dell Ambiente

More information

Chemical processes for the synthesis of nanostructured materials

Chemical processes for the synthesis of nanostructured materials Manufacturing Nanostructures 50 2 Chemical processes for the synthesis of nanostructured materials M. Gusatti 1, D. A. R. Souza 1, M. Durazzo 2 and H. G. Riella 1 1 Materials and Corrosion Laboratory (LABMAC),

More information

Synthesis of oxide nano-particles with a continuous hydrothermal production process under supercritical conditions.

Synthesis of oxide nano-particles with a continuous hydrothermal production process under supercritical conditions. Synthesis of oxide nano-particles with a continuous hydrothermal production process under supercritical conditions. F.Demoisson*, M.Ariane and F. Bernard Laboratoire Interdisciplinaire Carnot de Bourgogne

More information

ISO 6530 INTERNATIONAL STANDARD

ISO 6530 INTERNATIONAL STANDARD INTERNATIONAL STANDARD ISO 6530 Third edition 2005-02-01 Protective clothing Protection against liquid chemicals Test method for resistance of materials to penetration by liquids Vêtements de protection

More information

Nanostructured materials for solar energy

Nanostructured materials for solar energy Nanostructured materials for solar energy Water Splitting & Dye Solar Cells Journée Scientifique des Comices «Energie Solaire» du WARE 23 avril 2012 à Jambes Prof. Rudi Cloots, C. Henrist, Contributors:

More information

Elements, Compounds Mixtures Physical and Chemical Changes

Elements, Compounds Mixtures Physical and Chemical Changes Elements, Compounds Mixtures Physical and Chemical Changes Fundamentals of Chemistry 1 Classification of Matter Matter is any substance having distinct physical characteristics and chemical properties.

More information

Green nanoscience: Opportunities and challenges for innovation

Green nanoscience: Opportunities and challenges for innovation Green nanoscience: Opportunities and challenges for innovation Jim Hutchison Department of Chemistry, University of Oregon Director, UO Materials Science Institute Director, ONAMI Safer Nanomaterials and

More information

A new formulation of immiscible compressible two-phase flow in porous media

A new formulation of immiscible compressible two-phase flow in porous media A new formulation of immiscible compressible two-phase flow in porous media Brahim Amaziane a Mladen Jurak b a Laboratoire de Mathématiques Appliquées, CNRS UMR 51, Université de Pau, av. de l Université,

More information

Flame / wall interaction and maximum wall heat fluxes in diffusion burners

Flame / wall interaction and maximum wall heat fluxes in diffusion burners Flame / wall interaction and maximum wall heat fluxes in diffusion burners de Lataillade A. 1, Dabireau F. 1, Cuenot B. 1 and Poinsot T. 1 2 June 5, 2002 1 CERFACS 42 Avenue Coriolis 31057 TOULOUSE CEDEX

More information

SUPERCRITICAL WATER. A Green Solvent: Properties and Uses. Yizhak Marcus

SUPERCRITICAL WATER. A Green Solvent: Properties and Uses. Yizhak Marcus SUPERCRITICAL WATER SUPERCRITICAL WATER A Green Solvent: Properties and Uses Yizhak Marcus Copyright Ó 2012 by John Wiley & Sons, Inc. All rights reserved Published by John Wiley & Sons, Inc., Hoboken,

More information

Shell-isolated nanoparticleenhanced Raman spectroscopy: Insight from COMSOL simulations

Shell-isolated nanoparticleenhanced Raman spectroscopy: Insight from COMSOL simulations Shell-isolated nanoparticleenhanced Raman spectroscopy: Insight from COMSOL simulations Song-Yuan Ding, Jun Yi, En-Ming You, and Zhong-Qun Tian 2016-11-03, Shanghai Excerpt from the Proceedings of the

More information

CHEM 121 Lecture Planner

CHEM 121 Lecture Planner CHEM 121 Lecture Planner Lecture Lecture 1 Lecture 2 Lecture 3 Lecture 4 Lecture 5 Topics The Scientific Method Theories & Laws Quantitative Measurements vs Qualitative Measurements Accuracy & Precision

More information

Institut für Energie und Umwelttechnik e.v.

Institut für Energie und Umwelttechnik e.v. Institut für Energie und Umwelttechnik e.v. Continuous synthesis of highly-specific nanopowder on the pilot-plant scale Tim Hülser Successful R&I 2015, Düsseldorf Duisburg, North-Rhine-Westphalia, Germany

More information

SOLIDS AND LIQUIDS - Here's a brief review of the atomic picture or gases, liquids, and solids GASES

SOLIDS AND LIQUIDS - Here's a brief review of the atomic picture or gases, liquids, and solids GASES 30 SOLIDS AND LIQUIDS - Here's a brief review of the atomic picture or gases, liquids, and solids GASES * Gas molecules are small compared to the space between them. * Gas molecules move in straight lines

More information

Molecular dynamics simulation investigation of fuel droplet in

Molecular dynamics simulation investigation of fuel droplet in Molecular dynamics simulation investigation of fuel droplet in evolving ambient conditions I. Stankovic Scientific Computing Laboratory, Institute of Physics Belgrade, University of Belgrade, 11080 Zemun,

More information

Nanostructured Materials and New Processing Strategies Through Polymer Chemistry

Nanostructured Materials and New Processing Strategies Through Polymer Chemistry Nanostructured Materials and New Processing Strategies Through Polymer Chemistry Professor Christopher J. Ellison McKetta Department of Chemical Engineering and Texas Materials Institute The University

More information

CHEMISTRY. CHM202 Class #2 CHEMISTRY. Chapter 10. Chapter Outline for Class #2

CHEMISTRY. CHM202 Class #2 CHEMISTRY. Chapter 10. Chapter Outline for Class #2 CHEMISTRY Fifth Edition Gilbert Kirss Foster Bretz Davies CHM202 Class #2 1 Chemistry, 5 th Edition Copyright 2017, W. W. Norton & Company CHEMISTRY Fifth Edition Gilbert Kirss Foster Bretz Davies Chapter

More information

Lecture Presentation. Chapter 11. Liquids and Intermolecular Forces Pearson Education, Inc.

Lecture Presentation. Chapter 11. Liquids and Intermolecular Forces Pearson Education, Inc. Lecture Presentation Chapter 11 Liquids and States of Matter The fundamental difference between states of matter is the strength of the intermolecular forces of attraction. Stronger forces bring molecules

More information

Supporting Information for: Physics Behind the Water Transport through. Nanoporous Graphene and Boron Nitride

Supporting Information for: Physics Behind the Water Transport through. Nanoporous Graphene and Boron Nitride Supporting Information for: Physics Behind the Water Transport through Nanoporous Graphene and Boron Nitride Ludovic Garnier, Anthony Szymczyk, Patrice Malfreyt, and Aziz Ghoufi, Institut de Physique de

More information

THE IMPACT OF PROCESS PARAMETER ON SILANE MODIFICATION OF FUMED SILICA BY USING SUPERCRITICAL CO 2.

THE IMPACT OF PROCESS PARAMETER ON SILANE MODIFICATION OF FUMED SILICA BY USING SUPERCRITICAL CO 2. THE IMPACT OF PROCESS PARAMETER ON SILANE MODIFICATION OF FUMED SILICA BY USING SUPERCRITICAL CO 2 S. Glisic 1*, D. Stojanovic 2, G. Vukovic 2, P. S. Uskokovic 2, A. Orlovic 1, R. Aleksic 2, M. Dramićanin

More information

SHORT ANSWER QUESTIONS UNIT I: POLYMERS AND BUILDING MATERIALS

SHORT ANSWER QUESTIONS UNIT I: POLYMERS AND BUILDING MATERIALS SHORT ANSWER QUESTIONS UNIT I: POLYMERS AND BUILDING MATERIALS 1. Define polymer. Give one example. 2. What is monomer? Give one example. 3. What is polymerization? 4. What is degree of polymerization?

More information

Synthesis and Characterisation of Calcium Phosphate Nanoparticles

Synthesis and Characterisation of Calcium Phosphate Nanoparticles Chapter 3 Synthesis and Characterisation of Calcium Phosphate Nanoparticles Abstract The in-situ prepared nanoparticles of calcium phosphate were characterized by various analytical methods such as XRD

More information

SYNTHESIS OF CADMIUM SULFIDE NANOSTRUCTURES BY NOVEL PRECURSOR

SYNTHESIS OF CADMIUM SULFIDE NANOSTRUCTURES BY NOVEL PRECURSOR Nanomaterials: Applications and Properties (NAP-2011). Vol. 1, Part I 107 SYNTHESIS OF CADMIUM SULFIDE NANOSTRUCTURES BY NOVEL PRECURSOR M. Salavati Niasari 1,2* 1 Department of Inorganic Chemistry, Faculty

More information

Experimental procedures and characterization of the supramolecular complexes

Experimental procedures and characterization of the supramolecular complexes Supporting Information for Impact of cyclodextrins on the behavior of amphiphilic ligands in aqueous organometallic catalysis Hervé Bricout 1, Estelle Léonard 2, Christophe Len 2, David Landy 3, Frédéric

More information

Course file PPY15204 Nanoscience and Nanomaterials Table of Contents

Course file PPY15204 Nanoscience and Nanomaterials Table of Contents Department Physics Nanotechnology : M.sc Physics Course file PPY15204 Table Contents Second Year MSc Physics (2015-2016 Regulation) Detailed Lesson Plan UNIT-I: INTRODUCTION TO NANOTECHNOLOGY History Importance

More information

FACULTY OF ENGINEERING ALEXANDRIA UNVERSITY. Solid State lab. Instructors Dr. M. Ismail El-Banna Dr. Mohamed A. El-Shimy TA Noha Hanafy

FACULTY OF ENGINEERING ALEXANDRIA UNVERSITY. Solid State lab. Instructors Dr. M. Ismail El-Banna Dr. Mohamed A. El-Shimy TA Noha Hanafy FACULTY OF ENGINEERING ALEXANDRIA UNVERSITY Solid State lab Instructors Dr. M. Ismail El-Banna Dr. Mohamed A. El-Shimy TA Noha Hanafy 2017-2018 first term A. Experiments 1- Relationship between the intensity

More information

Zhenmeng Peng, Ph.D.

Zhenmeng Peng, Ph.D. CONTACT, Ph.D. Mail: Department of Chemical and Biomolecular Engineering 201A Whitby Hall University of Akron Akron, OH 44325 E-Mail: zpeng@uakron.edu Office: (330) 972-5810 PROFESSOIONAL EXPERIENCE UNIVERSITY

More information

Physicochemical Processes

Physicochemical Processes Lecture 3 Physicochemical Processes Physicochemical Processes Air stripping Carbon adsorption Steam stripping Chemical oxidation Supercritical fluids Membrane processes 1 1. Air Stripping A mass transfer

More information

Reactive Force Field & Molecular Dynamics Simulations (Theory & Applications)

Reactive Force Field & Molecular Dynamics Simulations (Theory & Applications) Reactive Force Field & Molecular Dynamics Simulations (Theory & Applications) Ying Li Collaboratory for Advanced Computing & Simulations Department of Chemical Engineering & Materials Science Department

More information

Synthesis of new type of Au-magnetic nanocomposite and application for protein separation thereof

Synthesis of new type of Au-magnetic nanocomposite and application for protein separation thereof Song et al. Nanoscale Research Letters 2012, 7:369 NANO EXPRESS Synthesis of new type of Au-magnetic nanocomposite and application for protein separation thereof Yu Song 1,2, Ling Tao 2 and Xiangchun Shen

More information

Rank the following in order from lowest to highest boiling point. Lowest 1 < 2 < 3 < 4 Highest. Which sketch shows the strongest hydrogen bond?

Rank the following in order from lowest to highest boiling point. Lowest 1 < 2 < 3 < 4 Highest. Which sketch shows the strongest hydrogen bond? Posting ID: 453368 Course: CHE_107_General_Ch emistry_2 Instructor: Blue Course Name: CHE_107_General_Chemistry_2 Question #: 1 Fill in one of the three common phases of matter for each one of these descriptions.

More information