CHEMICAL ENGINEERING KINETICS/REACTOR DESIGN. Tony Feric, Kathir Nalluswami, Manesha Ramanathan, Sejal Vispute, Varun Wadhwa
|
|
- Edward Thomas
- 6 years ago
- Views:
Transcription
1 CHEMICAL ENGINEERING KINETICS/REACTOR DESIGN Tony Feric, Kathir Nalluswami, Manesha Ramanathan, Sejal Vispute, Varun Wadhwa
2 Presentation Overview Kinetics Reactor Design Non- Isothermal Design
3 BASICS OF KINETICS
4 Definition of Rate rate = 1 V (dn, dt ) = (dc, dt ) = [mol] L [s] Rate = measure of how fast the concentration changes r, = Σν 8, r 8 Rate of formation of the j th species is given by the sum of its rates in each reaction i Source: Essentials of Chemical Reaction Engineering 4 th Ed. by H. Scott Fogler
5 Rate Law Rate law is an empirical relationship between rate and conversion: A + 2B R + S r = f C A, C C, C D, C E kc H A C C k = Rate constant α = Reaction order with respect to A β = Reaction order with respect to B k is temperature dependent because as the temperature increases, # of successful collisions increases exponentially Arrhenius Equation: k = A exp E [ RT A = Pre-exponential factor R = Gas constant (8.314 J/mol.K) E a = Activation energy of the reaction T = Temperature (Kelvin)
6 Reaction Mechanisms Elementary reaction: Perfect connection between rate law and stoichiometry occurring by collisions (molecularity 2) E r = k ^ C, _`a Reaction mechanism is a sequence of elementary steps having its own activation energy E a and rate constant k,bc Correct Orientation Sufficient Energy
7 BASICS OF REACTOR DESIGN
8 Isothermal Reactor Mass Balance General Input - Output + Generation = Accumulation Batch CSTR (Steady state) PFR
9 Reactor Design Equations In terms of Conversion In terms of Concentration (Constant Density) Batch CSTR (Steady state) step change in concentration to exit value PFR concentration changes continuously
10 Reactors in Series For a single reactor, CSTRs require more volume than a PFR to reach the same conversion CSTRs used in series to reduce the total volume required to reach a given conversion
11 Series Reactions: Comparison of PFR and CSTR (Rxn: A B C) In PFR (solid line), higher concentration of product B in all cases compared to the CSTR (dotted line) To maximize intermediate concentration, use a moderate residence time
12 Parallel Reactions: Comparison of PFR and CSTR (Rxn: A B ; A C) PFR (solid line) and CSTR (dotted line) For both products (B and C), PFR gives greater exit concentration compared to CSTR Rate selectivity and overall selectivity of B is the same in both reactors
13 Design Equations: Multiple Reactions vs. Single Reaction In each reactor, v j r is replaced by D d ν 8, r 8 8bc for multiple reactions
14 NON-ISOTHERMAL REACTOR DESIGN
15 Non-Isothermal Reactors Non-isothermal reactors are advantageous because most reactions are exothermic à heat generated is used to increase rate and conversion Heat generated/removed does the following: Changes temperature in reactor Changes rate constant (Arrhenius Equation) Changes concentrations of gaseous reactions Change ΔH R (δh j =C p,j δt)
16 Non-Isothermal CSTR At steady state, heat removed = heat generated. Assumptions: Heat accumulation = 0 (steady state) Exothermic reaction Heat is removed via coolant U = overall heat transfer coefficient A c = area of heat transfer T c = temperature of coolant
17 Non-Isothermal PFR At steady state, heat removed = heat generated. Assumptions: Heat accumulation = 0 (steady state) Exothermic reaction Heat is removed via coolant U = overall heat transfer coefficient A c = area of heat transfer T c = temperature of coolant
18 Non-Isothermal PFR (cont.) Temperature ODE Where Concentration ODE
19 Non-Isothermal Adiabatic Adiabatic à No heat added or removed in system; set Q = 0. Adiabatic temperature rise: the maximum temperature rise Shows a linear relationship between temperature and conversion
20 Conclusion: Importance of Reactor Design Distinguishes Chemical Engineers from other engineers Reactor design is the heart of any chemical process Controls overall process economics Key to controlling a chemical plant's safety and efficiency
21 QUESTIONS?
PHEN 612 SPRING 2008 WEEK 1 LAURENT SIMON
PHEN 612 SPRING 2008 WEEK 1 LAURENT SIMON Chapter 1 * 1.1 Rate of reactions r A A+B->C Species A, B, and C We are interested in the rate of disappearance of A The rate of reaction, ra, is the number of
More informationCBE 142: Chemical Kinetics & Reaction Engineering
CBE 142: Chemical Kinetics & Reaction Engineering Midterm #2 November 6 th 2014 This exam is worth 100 points and 20% of your course grade. Please read through the questions carefully before giving your
More informationChemical Kinetics and Reaction Engineering
Chemical Kinetics and Reaction Engineering MIDTERM EXAMINATION II Friday, April 9, 2010 The exam is 100 points total and 20% of the course grade. Please read through the questions carefully before giving
More informationCHE 404 Chemical Reaction Engineering. Chapter 8 Steady-State Nonisothermal Reactor Design
Textbook: Elements of Chemical Reaction Engineering, 4 th Edition 1 CHE 404 Chemical Reaction Engineering Chapter 8 Steady-State Nonisothermal Reactor Design Contents 2 PART 1. Steady-State Energy Balance
More informationChemical Reaction Engineering Lecture 5
Chemical Reaction Engineering g Lecture 5 The Scope The im of the Course: To learn how to describe a system where a (bio)chemical reaction takes place (further called reactor) Reactors Pharmacokinetics
More information1/r plots: a brief reminder
L10-1 1/r plots: a brief reminder 1/r X target X L10-2 1/r plots: a brief reminder 1/r X target X L10-3 1/r plots: a brief reminder 1/r X target X Special Case: utocatalytic Reactions Let s assume a reaction
More informationChapter 1. Lecture 1
Chapter 1 Lecture 1 Chemical Reaction Engineering (CRE) is the field that studies the rates and mechanisms of chemical reactions and the design of the reactors in which they take place. 1 Lecture 1 Introduction
More informationPlug flow Steady-state flow. Mixed flow
1 IDEAL REACTOR TYPES Batch Plug flow Steady-state flow Mixed flow Ideal Batch Reactor It has neither inflow nor outflow of reactants or products when the reaction is being carried out. Uniform composition
More informationChemical reactors. H has thermal contribution, pressure contribution (often negligible) and reaction contribution ( source - like)
Chemical reactors - chemical transformation of reactants into products Classification: a) according to the type of equipment o batch stirred tanks small-scale production, mostly liquids o continuous stirred
More informationA First Course on Kinetics and Reaction Engineering. Class 20 on Unit 19
A First Course on Kinetics and Reaction Engineering Class 20 on Unit 19 Part I - Chemical Reactions Part II - Chemical Reaction Kinetics Where We re Going Part III - Chemical Reaction Engineering A. Ideal
More information1. Introductory Material
CHEE 321: Chemical Reaction Engineering 1. Introductory Material 1b. The General Mole Balance Equation (GMBE) and Ideal Reactors (Fogler Chapter 1) Recap: Module 1a System with Rxn: use mole balances Input
More informationMidterm II. ChE 142 April 11, (Closed Book and notes, two 8.5 x11 sheet of notes is allowed) Printed Name
ChE 142 pril 11, 25 Midterm II (Closed Book and notes, two 8.5 x11 sheet of notes is allowed) Printed Name KEY By signing this sheet, you agree to adhere to the U.C. Berkeley Honor Code Signed Name_ KEY
More informationChemical Kinetics and Reaction Engineering Midterm 1
Page 1 Chemical & Biomolecular Engineering 142 Chemical Kinetics and Reaction Engineering Midterm 1 Tuesday, October 4, 2011 The exam is 100 points total and 20% of the course grade. Please read through
More informationCHE 404 Chemical Reaction Engineering. Chapter 8 Steady-State Nonisothermal Reactor Design
Textbook: Elements of Chemical Reaction Engineering, 4 th Edition 1 CHE 404 Chemical Reaction Engineering Chapter 8 Steady-State Nonisothermal Reactor Design Contents 2 PART 1. Steady-State Energy Balance
More informationChE 344 Winter 2013 Mid Term Exam I Tuesday, February 26, Closed Book, Web, and Notes. Honor Code
ChE 344 Winter 2013 Mid Term Exam I Tuesday, February 26, 2013 Closed Book, Web, and Notes Name Honor Code (Sign at the end of exam period) 1) / 5 pts 2) / 5 pts 3) / 5 pts 4) / 5 pts 5) / 5 pts 6) / 5
More informationMathematical Modeling Of Chemical Reactors
37 Mathematical Modeling Of Chemical Reactors Keywords: Reactors, lug flow, CSTR, Conversion, Selectivity Chemical reactor calculations are based on the elementary conservation laws of matter and energy.
More information6. Multiple Reactions
6. Multiple Reactions o Selectivity and Yield o Reactions in Series - To give maximum selectivity o Algorithm for Multiple Reactions o Applications of Algorithm o Multiple Reactions-Gas Phase 0. Types
More informationHW Help. How do you want to run the separation? Safety Issues? Ease of Processing
HW Help Perform Gross Profitability Analysis on NaOH + CH4 --> Na+CO+H NaOH+C-->Na+CO+1/H NaOH+1/ H-->Na+HO NaOH + CO Na+CO+1/H How do you want to run the reaction? NaOH - Solid, Liquid or Gas T for ΔGrxn
More informationChemical Reaction Engineering. Multiple Reactions. Dr.-Eng. Zayed Al-Hamamre
Chemical Reaction Engineering Multiple Reactions Dr.-Eng. Zayed Al-Hamamre 1 Content Types of Reactions Selectivity Reaction Yield Parallel Reactions Series Reactions Net Rates of Reaction Complex Reactions
More informationChemical Reaction Engineering
Lecture 19 Chemical Reaction Engineering (CRE) is the field that studies the rates and mechanisms of chemical reactions and the design of the reactors in which they take place. oday s lecture Gas Phase
More informationDr. Trent L. Silbaugh, Instructor Chemical Reaction Engineering Final Exam Study Guide
Chapter 1 Mole balances: Know the definitions of the rate of reaction, rate of disappearance and rate of appearance Know what a rate law is Be able to write a general mole balance and know what each term
More informationReview: Nonideal Flow in a CSTR
L3- Review: Nonideal Flow in a CSTR Ideal CSTR: uniform reactant concentration throughout the vessel Real stirred tank Relatively high reactant concentration at the feed entrance Relatively low concentration
More informationExercise 1. Material balance HDA plant
Process Systems Engineering Prof. Davide Manca Politecnico di Milano Exercise 1 Material balance HDA plant Lab assistants: Adriana Savoca LAB1-1 Conceptual design It is a systematic procedure to evaluate
More informationChemical Reaction Engineering
Lecture 21 Chemical Reaction Engineering (CRE) is the field that studies the rates and mechanisms of chemical reactions and the design of the reactors in which they take place. Web Lecture 21 Class Lecture
More informationModule 1: Mole Balances, Conversion & Reactor Sizing (Chapters 1 and 2, Fogler)
CHE 309: Chemical Reaction Engineering Lecture-2 Module 1: Mole Balances, Conversion & Reactor Sizing (Chapters 1 and 2, Fogler) Module 1: Mole Balances, Conversion & Reactor Sizing Topics to be covered
More informationChemical Reaction Engineering. Dr. Yahia Alhamed
Chemical Reaction Engineering Dr. Yahia Alhamed 1 Kinetics and Reaction Rate What is reaction rate? It is the rate at which a species looses its chemical identity per unit volume. The rate of a reaction
More informationNext, make a stoichiometric table for the flow system (see Table 3-4 in Fogler). This table applies to both a PFR and CSTR reactor.
Cite as: William Green, Jr., and K. Dane Wittrup, course materials for.37 Chemical and Biological Reaction Engineering, Spring 27. MIT OpenCourseWare (http://ocw.mit.edu), Massachusetts Institute of Technology.
More informationChE 344 Winter 2011 Final Exam + Solution. Open Book, Notes, and Web
ChE 344 Winter 011 Final Exam + Solution Monday, April 5, 011 Open Book, Notes, and Web Name Honor Code (Please sign in the space provided below) I have neither given nor received unauthorized aid on this
More informationChemical Reactions and Chemical Reactors
Chemical Reactions and Chemical Reactors George W. Roberts North Carolina State University Department of Chemical and Biomolecular Engineering WILEY John Wiley & Sons, Inc. x Contents 1. Reactions and
More informationIntroduction to the course ``Theory and Development of Reactive Systems'' (Chemical Reaction Engineering - I)
Introduction to the course ``Theory and Development of Reactive Systems'' (Chemical Reaction Engineering - I) Prof. Gabriele Pannocchia Department of Civil and Industrial Engineering (DICI) University
More informationChemical Reaction Engineering - Part 14 - intro to CSTRs Richard K. Herz,
Chemical Reaction Engineering - Part 4 - intro to CSTRs Richard K. Herz, rherz@ucsd.edu, www.reactorlab.net Continuous Stirred Tank Reactors - CSTRs Here are a couple screenshots from the ReactorLab, Division
More informationReview for Final Exam. 1ChE Reactive Process Engineering
Review for Final Exam 1ChE 400 - Reactive Process Engineering 2ChE 400 - Reactive Process Engineering Stoichiometry Coefficients Numbers Multiple reactions Reaction rate definitions Rate laws, reaction
More informationName. Honor Code: I have neither given nor received unauthorized aid on this examination, nor have I concealed any violations of the Honor Code.
ChE 344 Fall 014 Mid Term Exam II Wednesday, November 19, 014 Open Book Closed Notes (but one 3x5 note card), Closed Computer, Web, Home Problems and In-class Problems Name Honor Code: I have neither given
More informationChE 344 Winter 2011 Final Exam. Open Book, Notes, and Web
ChE 344 Winter 2011 Final Exam Monday, April 25, 2011 Open Book, Notes, and Web Name Honor Code (Please sign in the space provided below) I have neither given nor received unauthorized aid on this examination,
More informationChemical Reaction Engineering
Lecture 24 Chemical Reaction Engineering (CRE) is the field that studies the rates and mechanisms of chemical reactions and the design of the reactors in which they take place. Web Lecture 24 Class Lecture
More informationReview of Fitting Kinetic Data
L6-1 Review of Fitting Kinetic Data True or false: The goal of fitting kinetic data is to find the true rate expression. What are the two general methods used to fit kinetic data? L6-2 Advantages and Drawbacks
More informationDevelopment of Dynamic Models. Chapter 2. Illustrative Example: A Blending Process
Development of Dynamic Models Illustrative Example: A Blending Process An unsteady-state mass balance for the blending system: rate of accumulation rate of rate of = of mass in the tank mass in mass out
More informationTheoretical Models of Chemical Processes
Theoretical Models of Chemical Processes Dr. M. A. A. Shoukat Choudhury 1 Rationale for Dynamic Models 1. Improve understanding of the process 2. Train Plant operating personnel 3. Develop control strategy
More informationExercise 1. Material balance HDA plant
Process Systems Engineering Prof. Davide Manca Politecnico di Milano Exercise 1 Material balance HDA plant Lab assistants: Roberto Abbiati Riccardo Barzaghi Valentina Depetri LAB1-1 Conceptual design It
More informationChemical Reaction Engineering
Chemical Reaction Engineering Dr. Yahia Alhamed Chemical and Materials Engineering Department College of Engineering King Abdulaziz University General Mole Balance Batch Reactor Mole Balance Constantly
More informationChE 344 Winter 2011 Mid Term Exam I + Solution. Closed Book, Web, and Notes
ChE 344 Winter 011 Mid Term Exam I + Thursday, February 17, 011 Closed Book, Web, and Notes Name Honor Code (sign at the end of exam) 1) / 5 pts ) / 5 pts 3) / 5 pts 4) / 15 pts 5) / 5 pts 6) / 5 pts 7)
More informationCE 329, Fall 2015 Second Mid-Term Exam
CE 39, Fall 15 Second Mid-erm Exam You may only use pencils, pens and erasers while taking this exam. You may NO use a calculator. You may not leave the room for any reason if you do, you must first turn
More information13 th Aug Chemical Reaction Engineering CH3010. Home work problems
13 th ug 18. Chemical Reaction Engineering CH31. Home work problems 1. Batch reactor, variable volume. Consider a gas phase reaction B, conducted isothermally and at constant pressure in a batch reactor.
More informationIDEAL REACTORS FOR HOMOGENOUS REACTION AND THEIR PERFORMANCE EQUATIONS
IDEAL REACTORS FOR HOMOGENOUS REACTION AND THEIR PERFORMANCE EQUATIONS At the end of this week s lecture, students should be able to: Differentiate between the three ideal reactors Develop and apply the
More informationCHEE 222: PROCESS DYNAMICS AND NUMERICAL METHODS
CHEE 222: PROCESS DYNAMICS AND NUMERICAL METHODS Winter 2017 Module 1: Introduction to Process Modeling Dr. Xiang Li 1 Module 1 Outline 1. Process and Model - Concepts of process and model - Classification
More informationChE 344 Winter 2013 Mid Term Exam II Tuesday, April 9, 2013
ChE 344 Winter 2013 Mid Term Exam II Tuesday, April 9, 2013 Open Course Textbook Only Closed everything else (i.e., Notes, In-Class Problems and Home Problems Name Honor Code (Please sign in the space
More informationChemical Reaction Engineering
Lecture 22 Chemical Reaction Engineering (CRE) is the field that studies the rates and mechanisms of chemical reactions and the design of the reactors in which they take place. Web Lecture 22 Class Lecture
More informationChemical Reaction Engineering
Lecture 2 Chemical Reaction Engineering (CRE) is the field that studies the rates and mechanisms of chemical reactions and the design of the reactors in which they take place. 1 Lecture 2 Review of Lecture
More informationChE 344 Winter 2013 Final Exam + Solution. Open Course Textbook Only Closed everything else (i.e., Notes, In-Class Problems and Home Problems
ChE 344 Winter 03 Final Exam + Solution Thursday, May, 03 Open Course Textbook Only Closed everything else (i.e., Notes, In-Class Problems and Home Problems Name Honor Code (Please sign in the space provided
More informationA First Course on Kinetics and Reaction Engineering Unit 33. Axial Dispersion Model
Unit 33. Axial Dispersion Model Overview In the plug flow reactor model, concentration only varies in the axial direction, and the sole causes of that variation are convection and reaction. Unit 33 describes
More informationCHE 611 Advanced Chemical Reaction Engineering
CHE 611 Advanced Chemical Reaction Engineering Dr. Muhammad Rashid Usman Institute of Chemical Engineering and Technology University of the Punjab, Lahore 54590 mrusman.icet@pu.edu.pk 1 Advanced Chemical
More informationCHEMICAL REACTORS - PROBLEMS OF REACTOR ASSOCIATION 47-60
2011-2012 Course CHEMICL RECTORS - PROBLEMS OF RECTOR SSOCITION 47-60 47.- (exam jan 09) The elementary chemical reaction in liquid phase + B C is carried out in two equal sized CSTR connected in series.
More informationProblems Points (Max.) Points Received
Chemical Engineering 142 Chemical Kinetics and Reaction Engineering Midterm 1 Tuesday, October 8, 2013 8:10 am-9:30 am The exam is 100 points total. Please read through the questions very carefully before
More informationChemical Engineering 140. Chemical Process Analysis C.J. Radke Tentative Schedule Fall 2013
Chemical Process Analysis C.J. Radke Tentative Schedule Fall 2013 Week 0 *8/30 1. Definition of Chemical Engineering: flow sheet, reactor trains and separation processes, raw materials, power production
More informationA First Course on Kinetics and Reaction Engineering Unit 4. Reaction Rates and Temperature Effects
Unit 4. Reaction Rates and Temperature Effects Overview This course is divided into four parts, I through IV. Part II is focused upon modeling the rates of chemical reactions. Unit 4 is the first unit
More informationCE 329, Fall 2015 First Mid-Term Exam
CE 39, Fall 15 First Mid-erm Exam You may only use pencils, pens and erasers while taking this exam. You may NO use a calculator. You may not leave the room for any reason if you do, you must first turn
More informationThermodynamics revisited
Thermodynamics revisited How can I do an energy balance for a reactor system? 1 st law of thermodynamics (differential form): de de = = dq dq--dw dw Energy: de = du + de kin + de pot + de other du = Work:
More informationLecture Series. Modern Methods in Heterogeneous Catalysis. Measurement and Analysis of Kinetic Data
Lecture Series Modern Methods in Heterogeneous Catalysis Measurement and Analysis of Kinetic Data Raimund Horn Fritz-Haber-Institute of the MPG Department of Inorganic Chemistry Faradayweg 4-6 14195 Berlin
More informationLecture 8. Mole balance: calculations of microreactors, membrane reactors and unsteady state in tank reactors
Lecture 8 Mole balance: calculations of microreactors, membrane reactors and unsteady state in tank reactors Mole alance in terms of Concentration and Molar Flow Rates Working in terms of number of moles
More informationMultiple Reactions. ChE Reactive Process Engineering
Multiple Reactions We have largely considered single reactions so far in this class How many industrially important processes involve a single reaction? The job of a chemical engineer is therefore to design
More informationMATLAB Ordinary Differential Equation (ODE) solver for a simple example 1. Introduction
MATLAB Ordinary Differential Equation (ODE) solver for a simple example 1. Introduction Differential equations are a convenient way to express mathematically a change of a dependent variable (e.g. concentration
More informationPFR with inter stage cooling: Example 8.6, with some modifications
PFR with inter stage cooling: Example 8.6, with some modifications Consider the following liquid phase elementary reaction: A B. It is an exothermic reaction with H = -2 kcal/mol. The feed is pure A, at
More informationWeb Solved Problems Web Example SP-8.1 Hydrodealkylation of Mesitylene in a PFR CH 3 H 2. m-xylene can also undergo hydrodealkylation to form toluene:
Chapter 8 Multiple Reactions W8-1 Web Solved Problems Web Example SP-8.1 Hydrodealkylation of Mesitylene in a PFR The production of m-xylene by the hydrodealkylation of mesitylene over a Houdry Detrol
More information5. Collection and Analysis of. Rate Data
5. Collection and nalysis of o Objectives Rate Data - Determine the reaction order and specific reaction rate from experimental data obtained from either batch or flow reactors - Describe how to analyze
More informationUse of Differential Equations In Modeling and Simulation of CSTR
Use of Differential Equations In Modeling and Simulation of CSTR JIRI VOJTESEK, PETR DOSTAL Department of Process Control, Faculty of Applied Informatics Tomas Bata University in Zlin nám. T. G. Masaryka
More informationProcess design decisions and project economics Dr. V. S. Moholkar Department of chemical engineering Indian Institute of Technology, Guwahati
Process design decisions and project economics Dr. V. S. Moholkar Department of chemical engineering Indian Institute of Technology, Guwahati Module - 02 Flowsheet Synthesis (Conceptual Design of a Chemical
More informationBAE 820 Physical Principles of Environmental Systems
BAE 820 Physical Principles of Environmental Systems Type of reactors Dr. Zifei Liu Ideal reactors A reactor is an apparatus in which chemical, biological, and physical processes (reactions) proceed intentionally,
More informationH 0 r = -18,000 K cal/k mole Assume specific heats of all solutions are equal to that of water. [10]
Code No: RR320802 Set No. 1 III B.Tech II Semester Supplementary Examinations, November/December 2005 CHEMICAL REACTION ENGINEERING-I (Chemical Engineering) Time: 3 hours Max Marks: 80 Answer any FIVE
More informationCHEMICAL REACTION ENGINEERING
CHEMICL RECTION ENGINEERING Unit 5 nalysis of reactor DT Collection and analysis of rate data Batch reactor for homogenous and heterogeneous reactions measurement during the unsteady-state operation Differential
More informationChemical Reaction Engineering. Lecture 2
hemical Reaction Engineering Lecture 2 General algorithm of hemical Reaction Engineering Mole balance Rate laws Stoichiometry Energy balance ombine and Solve lassification of reactions Phases involved:
More informationCHAPTER 3 : MATHEMATICAL MODELLING PRINCIPLES
CHAPTER 3 : MATHEMATICAL MODELLING PRINCIPLES When I complete this chapter, I want to be able to do the following. Formulate dynamic models based on fundamental balances Solve simple first-order linear
More informationChemical Kinetics. System LENGTH: VOLUME MASS Temperature. 1 gal = 4 qt. 1 qt = in 3. 1 L = qt. 1 qt = L
Chemical Kinetics Practice Exam Chemical Kinetics Name (last) (First) Read all questions before you start. Show all work and explain your answers to receive full credit. Report all numerical answers to
More informationThe Energy Balance for Chemical Reactors
The Energy Balance for Chemical Reactors Copyright c 2015 by Nob Hill Publishing, LLC To specify the rates of reactions in a nonisothermal reactor, we require a model to determine the temperature of the
More informationThe Energy Balance for Chemical Reactors
The Energy Balance for Chemical Reactors Copyright c 2015 by Nob Hill Publishing, LLC To specify the rates of reactions in a nonisothermal reactor, we require a model to determine the temperature of the
More informationLecture 4. Mole balance: calculation of membrane reactors and unsteady state in tank reactors. Analysis of rate data
Lecture 4 Mole balance: calculation of membrane reactors and unsteady state in tank reactors. nalysis of rate data Mole alance in terms of Concentration and Molar Flow Rates Working in terms of number
More informationExample 8: CSTR with Multiple Solutions
Example 8: CSTR with Multiple Solutions This model studies the multiple steady-states of exothermic reactions. The example is from Parulekar (27) which in turn was modified from one by Fogler (1999). The
More informationChE 344 Chemical Reaction Engineering Winter 1999 Final Exam. Open Book, Notes, CD ROM, Disk, and Web
ChE 344 Chemical Reaction Engineering Winter 1999 Final Exam Open Book, Notes, CD ROM, Disk, and Web Name Honor Code 1) /25 pts 2) /15 pts 3) /10 pts 4) / 3 pts 5) / 6 pts 6) / 8 pts 7) / 8 pts 8) / 5
More information10.34 Numerical Methods Applied to Chemical Engineering
10.34 Numerical Methods Applied to Chemical Engineering Quiz 1 This quiz consists of three problems worth 0, 40 and 40 points respectively. The problem statements are found on pages, 3 and 5 in this exam
More informationFor a recycle reactor the relationship between the volume and other parameters is given by
9 ug 7. CRE Tutorial Problem. or a recycle reactor the relationship between the volume and other parameters is given by V R in R r or simple kinetics such as first order reaction (under isothermal conditions),
More informationReactors. Reaction Classifications
Reactors Reactions are usually the heart of the chemical processes in which relatively cheap raw materials are converted to more economically favorable products. In other cases, reactions play essential
More informationChemical Reaction Engineering
Lecture 13 Chemical Reaction Engineering (CRE) is the field that studies the rates and mechanisms of chemical reactions and the design of the reactors in which they take place. Today s lecture Complex
More informationThe Material Balance for Chemical Reactors
The Material Balance for Chemical Reactors Copyright c 2015 by Nob Hill Publishing, LLC 1 General Mole Balance V R j Q 0 c j0 Q 1 c j1 Conservation of mass rate of accumulation of component j = + { rate
More informationThe Material Balance for Chemical Reactors. Copyright c 2015 by Nob Hill Publishing, LLC
The Material Balance for Chemical Reactors Copyright c 2015 by Nob Hill Publishing, LLC 1 General Mole Balance V R j Q 0 c j0 Q 1 c j1 Conservation of mass rate of accumulation of component j = + { rate
More informationAdvanced Physical Chemistry CHAPTER 18 ELEMENTARY CHEMICAL KINETICS
Experimental Kinetics and Gas Phase Reactions Advanced Physical Chemistry CHAPTER 18 ELEMENTARY CHEMICAL KINETICS Professor Angelo R. Rossi http://homepages.uconn.edu/rossi Department of Chemistry, Room
More information4 th Edition Chapter 9
Insert Page 547A 4 th Edition Chapter 9 In summary, if any one of the following three things had not occurred the explosion would not have happened. 1. Tripled production 2. Heat exchanger failure for
More informationTABLE OF CONTENT. Chapter 4 Multiple Reaction Systems 61 Parallel Reactions 61 Quantitative Treatment of Product Distribution 63 Series Reactions 65
TABLE OF CONTENT Chapter 1 Introduction 1 Chemical Reaction 2 Classification of Chemical Reaction 2 Chemical Equation 4 Rate of Chemical Reaction 5 Kinetic Models For Non Elementary Reaction 6 Molecularity
More informationChemE Chemical Kinetics & Reactor Design Solutions to Exercises for Calculation Session 3
ChemE 3900 - Chemical Kinetics & Reactor Design Solutions to Exercises for Calculation Session 3. It is useful to begin by recalling the criteria for the steady-state approximation (on B), the pre-equilibrium
More informationCHAPTER 2 CONTINUOUS STIRRED TANK REACTOR PROCESS DESCRIPTION
11 CHAPTER 2 CONTINUOUS STIRRED TANK REACTOR PROCESS DESCRIPTION 2.1 INTRODUCTION This chapter deals with the process description and analysis of CSTR. The process inputs, states and outputs are identified
More informationLecture 8. Mole balance: calculations of microreactors, membrane reactors and unsteady state in tank reactors
Lecture 8 Mole balance: calculations of microreactors, membrane reactors and unsteady state in tank reactors Mole alance in terms of oncentration and Molar low Rates Working in terms of number of moles
More informationDetermining the Components of the Rate Equation aa + bb yy + zz
Determining the Components of the Rate Equation aa + bb yy + zz Rate k[a] [B] The coefficients and components of the rate equation Must be found by experiment Cannot be deduced from stoichiometry Do not
More informationAdvanced Chemical Reaction Engineering Prof. H. S. Shankar Department of Chemical Engineering IIT Bombay. Lecture - 03 Design Equations-1
(Refer Slide Time: 00:19) Advanced Chemical Reaction Engineering Prof. H. S. Shankar Department of Chemical Engineering IIT Bombay Lecture - 03 Design Equations-1 We are looking at advanced reaction engineering;
More informationwhere R = universal gas constant R = PV/nT R = atm L mol R = atm dm 3 mol 1 K 1 R = J mol 1 K 1 (SI unit)
Ideal Gas Law PV = nrt where R = universal gas constant R = PV/nT R = 0.0821 atm L mol 1 K 1 R = 0.0821 atm dm 3 mol 1 K 1 R = 8.314 J mol 1 K 1 (SI unit) Standard molar volume = 22.4 L mol 1 at 0 C and
More informationCE 329, Fall 2015 Assignment 16, Practice Exam
CE 39, Fall 15 Assignment 16, Practice Exam You may only use pencils, pens and erasers while taking this exam. You may NO use a calculator. You may not leave the room for any reason if you do, you must
More informationChemical Engineering Applications in Scilab
Chemical Engineering Applications in Scilab Prashant Dave Indian Institute of Technology Bombay (IIT Bombay) Introduction In Chemical Engineering the type of problems that occur are Modeling and Simulation
More informationElementary Reactions
Elementary Reactions Elementary reactions occur in a single encounter Unimolecular: A Rate = k[a] Bimolecular: A + B Rate = k[a][b] Termolecular: A + B + C Rate = k[a][b][c] Termolecular reactions are
More informationBAE 820 Physical Principles of Environmental Systems
BAE 820 Physical Principles of Environmental Systems Acquisition of reaction rate data Dr. Zifei Liu Uncertainties in real world reaction rate data Most interesting reaction systems involves multiple reactions,
More informationReaction rate. reaction rate describes change in concentration of reactants and products with time -> r = dc j
Reaction rate ChE 400 - Reactive Process Engineering reaction rate describes change in concentration of reactants and products with time -> r = dc j /dt r is proportional to the reactant concentrations
More informationNONISOTHERMAL OPERATION OF IDEAL REACTORS Plug Flow Reactor
NONISOTHERMAL OPERATION OF IDEAL REACTORS Plug Flow Reactor T o T T o T F o, Q o F T m,q m T m T m T mo Aumption: 1. Homogeneou Sytem 2. Single Reaction 3. Steady State Two type of problem: 1. Given deired
More informationA First Course on Kinetics and Reaction Engineering Unit 30.Thermal Back-Mixing in a PFR
Unit 30.Thermal Back-Mixing in a PFR Overview One advantage offered by a CSTR when running an exothermic reaction is that the cool feed gets heated by mixing with the contents of the reactor. As a consequence
More informationA First Course on Kinetics and Reaction Engineering Example 14.3
Example 14.3 Problem Purpose This problem illustrates differential analysis using data from a differentially operated PFR. Problem Statement The isomerization of cyclopropane, equation (1), was known from
More information