Estimation of 210 Po in Coastal Regions of Kannyakumari District of Tamil Nadu, India

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1 International Journal of Pure and Applied Physics. ISSN Volume 7, Number 3 (2011), pp Research India Publications Estimation of 210 Po in Coastal Regions of Kannyakumari District of Tamil Nadu, India V. Sarojini 1, K. Esaiselvan 2, K. Sreekumar 3 and T. Chithambra Thanu 4 1 Asst. Prof. Dept. of Physics, Lekshmipuram College of Arts and Science, Neyyoor , Tamil Nadu, India vsarog@gmail.com 2 Chemist, Indian Rare Earths Limited, Manavalakurichy, Tamil Nadu, India esaiselvan@yahoo.co.in 3 Scientific Officer, Health Physics Unit, Indian Rare Earths Limited, Manavalakurichy, Tamil Nadu, India hpuiremk@gmail.com 4 Associate Prof. Dept of Physics, S.T. Hindu College, Nagercoil, Tamil Nadu, India tcthanu@rediffmail.com Abstract The coastal regions of Kanyakumari district, Tamil Nadu in India between Midalam to Muttom stretch is witnessed as a naturally high back ground radiation area. Soil samples from the beach area were analysed for 210 Po activity. The activity concentration of 210 Po was measured by chemical deposition method in the beach soils along the coastal stretch from Muttom to Midalam. These studies were carried out from April 2010 to May 2010 in the Health Physics Unit of BARC located in the campus of Indian Rare Earths Limited, Manavalakurichy in Tamil Nadu. The activity of 210 Po in the beach soil were found to be varying from Bq/Kg to Bq/kg. The maximum 210 Po activity was found to be Bq/Kg estimated at Chinnavilai and the minimum 210 Po activity was found to be Bq/Kg estimated at Colachel. The results of these studies are presented and discussed in this paper in detail. Keywords: Polonium activity, Chemical deposition method, beach sands.

2 230 V. Sarojini et al Introduction Radioactivity is the process of spontaneous emission of certain invisible radiation from nucleus which can ionize the atom. Radiation is the energy traveling in form of particles or waves in bundles of energy called photons. It is a process in which the nuclei of certain elements undergo spontaneous disintegration emitting active radiation. The elements which undergo spontaneous decay are called radioactive elements. Radioactivity present in the soil is mainly due to the presence of radioactive elements in the earths crust. Southwest coastal region in Tamil Nadu, India has been reported as high radiation area 1 due to the existence of these elements. The radioactivity concentration of 210 Po was measured by chemical deposition method 2 in the beach soils along the coastal stretch from Muttom to Midalam, K.K district of Tamil Nadu in India. Polonium is a radioactive element that occurs naturally in very low concentration in the earth s crust 3. Although it can be produced by the chemical processing of Uranium ores or minerals. Uranium ores contain less than 0.1 mg 210 Po per ton. As 210 Po is produced from the decay of 222 Rn gas, it can be found in the atmosphere from which it is deposited on the earth s surface. Although direct root uptake by plants is generally small, 210 Po can be deposited on broad leaf vegetables. Deposition from the atmosphere on tobacco leaves results in elevated concentrations of 210 Po in tobacco smoke Po is a radioactive decay product in the natural Uranium-238 decay series along with lead Po has a half life of 138 days and it decays to stable lead-206 by emitting an alpha particle. The energy released by its decay is so large (140 w/g) that a capsule containing about half a gram reaches a temperature above C. 210 Po is highly radioactive and chemically toxic element. Direct damage occurs from energy absorption into tissues from alpha particles. As an alpha emitter 210 Po represents a radiation hazard only if taken into the body. One of the prime sources of high background radiation level is the presence of radioactive monazite. Monazite sands are known to contain thorium, with some amount of 238 U and 40 K 5. The existence of monazite deposits in coastal areas of K.K. district and Kerala have been reported by several investigators. One of the regions where high radiation level has been reported is coastal areas of Muttom to Midalam in Kanyakumari district of Tamil Nadu, India. 210 Po is a daughter product of 238 U and is found in varying concentration in soil. Therefore an attempt is made in the present investigation to studies on the estimation of 210 Po activity in the beach soils of coastal regions in K.K. district of Tamil Nadu, India. Materials and Methods Study Area and Sample Collection The study area is mainly the coastal stretch between Muttom to Midalam, in KK district of TamilNadu, India. The beach soils were collected from ten major sites namely Muttom, Kadiapattinam, Chinnavilai, Periyavilai, Puthoor, Kottilpad, Colachel, Simon colony, Kodimunai and Vaniakudi. The samples were collected in a polythene bag and brought to the laboratory.

Estimation of 210 Po in Coastal Regions of Kannyakumari District 231 Figure 1: Map of the Sampling Stations.

The soil samples were dried in an oven at 110 0 C till a constant dry weight is obtained.

residue. To the dried precipitate 20ml of 1:1 hydrochloric acid is added and heated to dryness. The precipitate was then dissolved in 0.5N hydrochloric acid and the solution is then ready for plating.

3 Estimation of 210 Po in Coastal Regions of Kannyakumari District 231 Figure 1: Map of the Sampling Stations. Sample processing and Activity determination The chemical deposition method was employed for the determination of 210 Po activity. The soil samples were dried in an oven at C till a constant dry weight is obtained. About 3gms of samples were leached with 4N HNO 3 and then organic matter present in the sample was destroyed by digestion by adding HNO 3 + H 2 O 2 mixture in a small increments to get a white residue. To the dried precipitate 20ml of 1:1 hydrochloric acid is added and heated to dryness. The precipitate was then dissolved in 0.5N hydrochloric acid and the solution is then ready for plating. A silver disc whose alpha count was previously determined is taken and concentration of 210 Po in the sample was deposited into the silver disc by stirring it at 97 0 C for 6 hrs with the help of a magnetic stirrer. The silver disc was then washed with distilled water and dried under an IR lamp. The silver disc was then counted on both the sides for α activity using Zns (Ag) detector for 2000 seconds. Results and discussion: The 210 Po activity concentration in soil samples of different locations is given in table1. The activity was found to be varying from Bq/Kg to Bq/Kg. The highest 210 Po activity was found in Chinnavilai and this may be due to higher monazite concentration in the soil of this area. The lowest activity was determined at Colachel. This may be due to low percentage of clay and organic matter in the soils of this region. Moreover in soil polonium also comes from the atmospheric precipitation due to decay of 222 Rn present in the atmosphere in addition to the decay of 238 U present in the soil.

232 V. Sarojini et al Table 1: Activity of 210 Po. No 1. 2. 3. 4. 5. 6. 7. 8. 9.

Kottilpad Colachel Simon Colony Kodimunai Vaniakudi Activity of 210 Po in Bq/Kg

20 Figure 2: Variation of 210 Po activity.

Po activity was higher at Chinnavilai (54.

in the beach sands of coastal Kanyakumari district are the major contributions

4 232 V. Sarojini et al Table 1: Activity of 210 Po. No Sampling Station Muttom Kadiapattinam Chinnavilai Periyavilai Puthoor Kottilpad Colachel Simon Colony Kodimunai Vaniakudi Activity of 210 Po in Bq/Kg Figure 2: Variation of 210 Po activity. Conclusion From the above analysis it is evident that the concentration of 210 Po activity was higher at Chinnavilai (54.53 Bq/Kg) and the lower concentration of 210 Po activity was reported at Colachel (11.32Bq/Kg). The presence of heavy minerals like ilmenite, rutile, garnet, Zircon, monazite, in the beach sands of coastal Kanyakumari district are the major contributions of radioactivity in this area. 232 Th and 238 U are reported from these regions, caused mainly due to the monazite bearing black sands. The presence of 210 Po in surface of soil is due to the deposition from atmosphere, leaching from soil

5 Estimation of 210 Po in Coastal Regions of Kannyakumari District 233 and rock courses formed from dissolved 226 Ra and 222 Rn. The surface soil activity of 210 Po depends on the clay and organic matter of the soil. List of symbols and abbreviations Symbols Po Polonium Bq/Kg Becquerl per Kilogram U - Uranium K - Potassium HNO 3 - Nitric Acid 6. H 2 O 2 - Hydrogen peroxide 7. α Alpha 8. ZnS - Zinc sulphide Rn Radon Th Thorium ml Milli litre 12. W/g Watt per gram Abbreviations BARC Babha Atomic Research Centre K.K.Dist. Kannyakumari District IR Infra Red References [1] Khanna D., Malathi J., Brahmanandhan, G.M.., and Selvasekarapandian, S., Measurment of Activity concentrations of 40K, 238 U and 232 Th in Soil samples of Agastheeswaram Taluk, Kanya kumari Dist, India., Paper presented in the Sixth Int.Conf. on High level Radiation Areas, Japan, September 5-9, [2] Iyengar M.A.R, Ganapathy, Kannan, Rajan S.V, Rajan M.P, Rajaram S, (1990) procedure manual workshop on Environmental Radioactivity held at Kaiga, India. [3] Pujol li., Sanchez- Cabeza, J.A., Natural and Artificial radioactivity in surface waters of the Ebo river basin (Northeast spain).journal of Environmental Radioactivity 51, pp [4] Carvalho F.P., Po and 210 Pb intake by the Portuguese population: The contribution of Sea food in the dietary intake of 210 Po and 210 Pb. Health Physics. 69(4). pp [5] Aswathanarayana U., Origin of the heavy mineral beach Sand deposits of the southwest coast of India. In: Eds. A.P. Subraminian and S.Balakrishna Advancing Frontiers in Geology and Geophysics, Indian Geophysical Union, Hyderabad, pp [6] Rajashekara K.M., Narayana Y., Karunakara N. and Siddappa K., 2005 Distribution of 210 Po in Riverine Environs of coastal Karnataka, Environmental Geo Chemistry, Vol.8, No. 1&2, pp

6 234 V. Sarojini et al [7] Narayana Y., Somashekarappa H.M., Karunakara N., Avadhani D.N., Mahesh H.M., and Sidappa K., Natural Radioactiviny in the soil samples of coastal Karnataka Health Phys. 80, pp [8] Radhakrishna A.P., Somashekarappa H.M., Narayana Y., Sidappa K., 1993.A new natural background radiation area on the south west coast of India. Health Phys. 65, pp [9] Mistry K.B., Gopal Iyengar A.R., Bharatan K.G., (1965)on the radioactivity from the high radiation areas of the Kerala coast and adjoining Regions Health Phys. 11 pp [10] Prakash, T.N., Sediment distribution and placer mineral enrichment in the innershelf of Quilon, south west coast of India. Indian Journal of Marine Science. Vol.29, pp [11] Iyengar, M.A.R., and Kannan.V., 1994.Natural Radiation aspects in the high background areas at Kalpakkam., Proc. 3 rd National Symposium on Environment, Thiruvananthapuram, March, 1994., pp [12] Shetty P.K, Narayana Y. and Sidappa. K., Enrichment and spatial variation of Natural radio nuclides in high background areas of coastal Kerala, Environmental Geo Chemistry, Vol.8, No. 1&2, pp

Journal of Chemical and Pharmaceutical Research, 2016, 8(11): Research Article

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