Schwer. A. Goudot-Perrot. Antibiotics - Antimitotics- Psychotropics. With 58 figures
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1 A. Goudot-Perrot Antibiotics - Antimitotics- Psychotropics Dr. A. Goudot Perrot Paris, France, Active Member of the New York Academy of Sciences Revision and English translation by Prof.Dr.habil. W.G.Wood Ph.D. (Leeds), Medical University of Lübeck, Germany With 58 figures and 3 tables Schwer Verlag Stuttgart 1992 Schwer
2 Contents Chapter 1. Molecular Structure in Quantum Chemistry Atoms Molecules Molecular Binding (Molecular Bonds) Chemical Bonds in Terms of Quantum Chemistry Quantum Chemistry and Molecular Structure Calculation of the Charges Calculation of the Index of Mobile Bonding Calculation of the Order of Binding - or Overall Binding Dissociation and Binding Energy Bathochromic and Hypsochromic Effects 7 Chapter 2. Sulfamides with Structures Similar to Those of Vitamins Vitamins Folie Acid Para-Aminobenzoic Acid (PABA) Chemical Structure of PABA Electronic Structure of Folie Acid Physiological Role of Folie Acid Sulfamides Sulfanilamide: Chemical and Electronic Structure Sulfamide Derivates - Additions to the Cyclic Part of the Molecule Sulfamidochrisoidine or Pontosil Pyrimidine Derivatives Methylated Derivates of Sulfadiazine (or Sulfapyrimidine) Monomethoxylated Derivatives of Pyrimidine Sulfamides Dimethoxy Derivatives of Pyrimidine Sulfamides Cyclopentane Derivatives Comparison Between the Structure and the Activity of Sulfamides Toxicity and Secondary Effects of Sulfamide Therapy 24 V
3 Chapter 3. The Antibiotics Penicillins Chemical Structure Electronic Structure Mode of Action on Bacterial Cultures Penicilin Resistance The Penicillins Streptomycins Mode of Action Chemical Structure Electronic Structure Mechanism of the Antibacterial Action Bacterial Resistance. Formation of Dependant Mutants Tetracyclins Chloramphenicol Chemical Structure Electronic Structure Modes of Actions of Antibiotics 41 Chapter 4. The Antimitotic Agents Nucleic Acids Natural Purine Bases Natural Pyrimidine Bases Desoxyribonucleic Acid (DNA) Ribonucleic Acid (RNA) Antimitotic Agents with Structures Analogous to Natural Occuring Purines (Pu) or Pyrimidines (Py) Adenine Analogues Guanine Analogues Thymine Analogues Uracil Analogues Cytosine Analogues Organometallic Complexes: Pu-M n+ -Py Alkaline Metals: Na +, K + 60 VI
4 Contents Alkaline Earth Metals: Mg 2+, Ca Metals of the First Transitional Period Antimitotic Effects of G-M M -C Complexes Sandwich Complexes Formation Complexes of the Type (Pu-Py)Mg 2+ (Pu-Py) 67 Chapter 5. Neurohormones and Drugs Acting on the Nervous System Chemical Mediators: Chemical and Electronic Structure Acetylcholine Catecholamines Serotonin Monoamine Oxidase (MAO) Gamma-Aminobutyric Acid or GABA Coordination Between Chemical Mediators in the Nervous System Psychotropic Drugs with Analogous Structures 79 A. Neuroleptic Drugs Phenothiazincs Promethazine Reserpine Alpha and Beta Blockers 81 B. Antidepressants Drugs Similar in Structure to Catecholamines Amphetamine DOM and DOET Mescaline Cathine and Cathinone Drugs which Inhibit Monoamine Oxidase (MAO) Iproniazide Imipramine Drugs Analogous to Serotonin Additions to the N of the Side Chain but not to the OH of the Ring Bufotenin 89 VII
5 N.N-Dimethyltryptamine DMT DETandDPT Additions to the Indole Ring and to the NH2 of the Side Chain Tetracyclic Alkaloids: Derivatives of Rye-Ergot Lysergic Acid Amide Lysergic Acid Diethylamide (LSD) Drugs Analogous to the Endorphins Endorphins Enkephalins Drugs Analogues to Enkephalins Morphine Cocaine Discussion 100 Subject Index 103 VIII
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