URL:
|
|
|
- Lee Leonard
- 5 years ago
- Views:
Transcription
1 Peter orcid.org/ Other IDs Scopus Author ID: ( authorid= &partnerid=mn8toars) Education (1) University of Innsbruck: Innsbruck, Tyrol, Austria Prof. Dr.(Institute of General, Inorganic and Theoretical Chemistry) Employment (1) University of Innsbruck: Innsbruck, Tyrol, Austria University Professor(Institute of General, Inorganic and Theoretical Chemistry) Works (55) New High-Pressure Gallium Borate Ga2B3O7(OH) with Photocatalytic Activity Inorganic Chemistry 2016 journal-article /acs.inorgchem.5b02027( EID: 2-s URL: Unusual stability of dyads during photochemical hydrogen production Dalton Transactions 2015 journal-article /c5dt03414k( EID: 2-s URL: Linear α-olefins obtained with palladium(ii) complexes bearing a partially oxidized tetraphosphane Organometallics 2014 journal-article /om500573q( EID: 2-s URL: Luminescent dinuclear Cu(I) complexes containing rigid tetraphosphine ligands Inorganic Chemistry 2014 journal-article /ic ( EID: 2-s URL:
2 Versatile supramolecular coordination behaviour of a bis (bidentate) tetraphosphane European Journal of Inorganic Chemistry 2013 journal-article /ejic ( EID: 2-s URL: Oxidative quenching within photosensitizer-acceptor dyads based on bis(bidentate) phosphine-connected osmium(ii) bipyridyl light absorbers and reactive metal sites 2012 journal-article /j.inoche ( EID: 2-s URL: Regioselective hydromethoxycarbonylation of terminal alkynes catalyzed by palladium(ii)-tetraphos complexes Organometallics 2012 journal-article /om ( EID: 2-s URL: First microwave-assisted synthesis of an electron-rich phosphane and its coordination chemistry with platinum(ii) and palladium(ii) 2011 journal-article /j.ica ( EID: 2-s URL: Surprising photochemical reactivity and visible light-driven energy transfer in heterodimetallic complexes Dalton Transactions 2011 journal-article /c0dt00253d( EID: 2-s URL: Unusual ligand design: A platinum(ii) mediated [2+2] photocycloaddition followed by a nickel(ii) induced methoxyactivation 2010 journal-article /j.ica ( EID: 2-s URL:
3 A novel linkage-isomeric pair of dinuclear Pd(ii) complexes bearing a bis-bidentate tetraphos ligand Dalton Transactions 2009 journal-article /b815392b( EID: 2-s URL: Switching on the photochemical reactivity in heterodimetallic OsII-RuII bipyridyl complexes containing a bis(bidentate) phosphine 2007 journal-article /j.inoche ( EID: 2-s URL: The influence of steric pressure on the structure of homodimetallic rhodium(i) and iridium(i) complexes containing a bis(bidentate) phosphane ligand European Journal of Inorganic Chemistry 2007 journal-article /ejic ( EID: 2-s URL: Synthesis and characterization of palladium(ii) complexes with new diphosphonium-diphosphine and diphosphine ligands. Production of low molecular weight alternating polyketones via catalytic CO/ethene copolymerisation Dalton Transactions 2006 journal-article /b601154c( EID: 2-s URL: Unprecedented conformational modulation of the efficiency of luminescence in Ru(II) bipyridyl complexes containing a bis(bidentate) phosphine 2005 journal-article /j.inoche ( EID: 2-s URL: First true square-planar Hg(II) compound: Synthesis and full characterization of trans-[hg{ph2pnp(o)ph2-p,o}2] 2003 journal-article /S (02) ( EID: 2-s URL:
4 Regioselective versus complete chalcogen transfer reactions of the bis(bidentate) phosphine cis,trans,cis-1,2,3,4-tetrakis-(diphenylphosphino) cyclobutane: Full characterization of new, hemilabile ligands and their complexes with palladium(ii) and platinum (II) Journal of the Chemical Society. Dalton Transactions 2003 journal-article EID: 2-s URL: Schulz-Flory oligomerisation of ethylene by the binuclear nickel(ii) complex Ni2Cl4 [cis,trans,cis-1,2,3,4-tetrakis-(diphenylphosphino)c yclobutane] Journal of the Chemical Society. Dalton Transactions 2003 journal-article EID: 2-s URL: Synthesis, catalytic properties and biological activity of new water soluble(ruthenium cyclopentadienyl PTA complexes [(C5R5)RuCl(PTA)2] (R = H, me; PTA = 1,3,5-triaza-7-phosphaadamantane) Chemical Communications 2003 journal-article /b210102e( EID: 2-s URL: First regioselective protonation or selenization of a bis (bidentate) phosphine: Synthesis and characterization of cis,trans,cis-1,3-bis(diphenylphosphonium)-ph, P H -2,4-bis (diphenylphosphino)cyclobutane-diiodide and cis,trans,cis-1,3-bis(diphenylphosphinoselenoyl)-2,4-bis (diphenylphosphino) cyclobutane 2002 journal-article /S (02) ( EID: 2-s URL: Novel diphosphine-modified palladium catalysts for oxidative carbonylation of styrene to methyl cinnamate Journal of the Chemical Society. Dalton Transactions 2001 journal-article EID: 2-s URL:
5 Novel diphosphine-modified palladium catalysts for oxidative carbonylation of styrene to methyl cinnamate Journal of the Chemical Society, Dalton Transactions 2001 journal-article /b009635k ( EID: 2-s URL: Solution and solid state behaviour of binuclear mercury(ii) compounds containing cis,trans,cis-1,2,3,4-tetrakis- (diphenylphosphino)cyclobutane: First X-ray structural characterisation of mercury(ii) complexes with two different chelating phosphines 2001 journal-article /S (01) ( EID: 2-s URL: Unexpected photochemical reactivity of ruthenium(ii) polypyridine complexes induced by a bis(bidentate) phosphine Inorganic Chemistry 2001 journal-article /ic ( EID: 2-s URL: First heterodifunctional ligand derived from a tetradentate phosphine: Synthesis and characterization of cis, trans, cis-1,3-bis(diphenylphosphino) 2,4-bis (diphenylphosphinothioyl) cyclobutane and its complex with PdCl journal-article /S (00) ( EID: 2-s URL: New structurally rigid palladium catalysts for the alternating copolymerization of carbon monoxide and ethene Chemical Communications 2000 journal-article EID: 2-s URL:
6 Palladium(II), platinum(ii), and platinum(iv) complexes containing trans-1,2-bis(diphenylphosphino)ethene or cis,trans,cis-1,2,3,4-tetrakis(diphenylphosphino) cyclobutane: Complete X-ray structural characterization of binuclear compounds 2000 journal-article /S (00) ( EID: 2-s URL: First complex of the monoprotonated trioxodinitrate anion: Synthesis and characterization of [Hg2(HN2O3)2(NO3) 2 (Ph2PNHPPh2)2] 1999 journal-article EID: 2-s URL: Synthesis, platinum(ii) complexes and structural aspects of the new tetradentate phosphine cis,trans,cis-1,2,3,4-tetrakis (diphenylphosphino)cyclobutane 1999 journal-article EID: 2-s URL: Nickel(II), palladium(ii), and platinum(ii) complexes containing cis- or trans-1,2-bis(diphenylphosphino)ethene: Isomorphous crystal structures in the cyanide case 1998 journal-article EID: 2-s URL: Nickel(II), palladium(ii), platinum(ii) and platinum(iv) complexes of cis-1,2-bis(diphenylphosphino)ethene and nitrogen-containing heterocycles or sulfur ligands 1998 journal-article EID: 2-s URL: Structural impact of cis-1,2-bis(diphenylphosphino)ethene on the first hexanuclear palladium(ii)-silver(i) complex with triply-bridging sulfide ligands 1998 journal-article EID: 2-s URL:
7 Binary system of (R)- and (S)-nitrendipine - Polymorphism and structure Journal of Pharmaceutical Sciences 1997 journal-article /js ( EID: 2-s URL: Binuclear palladium(ii), platinum(ii) and platinum(iv) complexes containing 1,2-bis(diphenylphosphino) acetylene: Different orientations of the diphosphine-bridges due to metal-phosphorus dπ-dπ back bonding 1997 journal-article EID: 2-s URL: Structural differences in nickel(ii) and palladium(ii) complexes containing cis-1,2-bis(diphenylphosphino) ethene or 1,2-bis(diphenylphosphino)ethane 1997 journal-article EID: 2-s URL: Nickel(II) complexes containing 1,1,4,7,10, 10- hexaphenyl-1,4,7,10-tetraphosphadecane: First X-ray structures of nickel-tetraphos-1 complexes 1996 journal-article / (95) ( EID: 2-s URL: Palladium (II) and platinum (II) complexes of cis-1,2-bis (diphenylphosphino)ethene: completely planar structures due to π bonding in the case of platinum (II) 1995 journal-article / (95)04682-Y ( EID: 2-s URL: PdII and PtII complexes containing 1,1,4,7,10,10- hexaphenyl-1,4,7,10-tetraphosphadecane: First X-ray structure of a Pd-tetraphos complex 1995 journal-article / (94)00298-S ( EID: 2-s URL:
8 Binuclear platinum(ii) complexes of 1,1,4,7,10,10- hexaphenyl-1,4,7,10-tetraphosphadecane (P4) containing various bridging ligands as spacers between the P4 coordination units 1994 journal-article / (94) ( EID: 2-s URL: Binuclear platinum(ii) complexes containing 1,1,4,7,10,10- hexaphenyl-1,4,7,10-tetraphosphadecane (P4): first X-ray structure of a tetraphos dimer 1992 journal-article /S (00)85522-X ( EID: 2-s URL: Kristallographische Gegenüberstellung der Monokationen von Bis(fulvalen)dieisien und Bis(fulvalen) eisen-cobalt mit identischem Gegenion (PF6 -) Journal of Organometallic Chemistry 1991 journal-article / X(91)80206-Y ( EID: 2-s URL: Five-coordinate platinum(ii) hydrides containing 1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetraphosphadecane as a tetradentate monometallic ligand Inorganic Chemistry 1990 journal-article EID: 2-s URL: The reaction of [PtCl4]2- with 1,1,4,7,10,10- hexaphenyl-1,4,7,10-tetraphosphadecane: complete product selectivity via non-coordinating anions and isolation of two intermediates 1989 journal-article /S (00) ( EID: 2-s URL:
9 Syntheses and phosphorus-31 NMR studies of fivecoordinate platinum(ii) complexes of tris (2-(diphenylphosphino)ethyl)phosphine and monodentate phosphorus ligands Inorganic Chemistry 1987 journal-article EID: 2-s URL: The platinum(ii) hydride of tris(2-(diphenylphosphino)ethyl) phosphine: a novel five-coordinate platinum monohydride 1987 journal-article /S (00) ( EID: 2-s URL: Cooling of water/oil microemulsions: The cupric probe Journal of Physical Chemistry 1986 journal-article EID: 2-s URL: Trichlorostannatoplatinum(II) Complexes Containing Polyphosphines: Synthesis and NMR(119Sn, 31P) Characterization Polyphosphinhaltige Trichlorostannatoplatin(II)-Komplexe: Synthese und NMR (119Sn, 31P)-Charakterisierung Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences 1986 journal-article /znb ( EID: 2-s URL: Devitrification of glassy water. Evidence for a discontinuity of state? Journal of Physical Chemistry 1983 journal-article EID: 2-s URL: Evaluation of modified water by electron paramagnetic resonance: No evidence for long-range order of water on pore glasses Journal of Colloid And Interface Science 1983 journal-article / (83) ( EID: 2-s URL:
10 Freezing of water in w/o emulsions Journal of Dispersion Science and Technology 1982 journal-article / ( EID: 2-s URL: Vitrification of pure liquid water by high pressure jet freezing Nature 1982 journal-article /298715a0 ( EID: 2-s URL: EPR Investigation of the nonfreezing water/free water ratio in disperse systems Journal of Physical Chemistry 1981 journal-article EID: 2-s URL: Complete vitrification in pure liquid water and dilute aqueous solutions Nature 1980 journal-article /288569a0 ( EID: 2-s URL: Dimethylhalonium-Ions in Aluminium Halide/Methyl Halide Solutions Dimethylhalonium-Ionen in Alumiiiiumhalogenid/Methylhalogenid-Lösungen Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences 1979 journal-article /znb ( EID: 2-s URL: The tert-butyl-cation in Solutions of Aluminium Bromide in Mono-, Di- and Tribromomethane Das tert-butyl-kation in Lösungen von Aluminiumbromid in Mono-, Di- und Tribrommethan Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences 1979 journal-article /znb ( EID: 2-s URL:
Organometallic Chemistry and Homogeneous Catalysis
Organometallic Chemistry and Homogeneous Catalysis Dr. Alexey Zazybin Lecture N6 Kashiwa Campus, November 27, 2009 Group VIB: Cr, Mo, W -Oxidation states from -2 to +6 -While +2 and +3 for Cr are quite
Chemistry of Transition Metals. Part 1. General Considerations
Chemistry of Transition Metals Part 1. General Considerations Filling of 3d, 4d, and 5d shells In s- and p-block, electrons added to outer shell In I d-block, electrons added d to penultimate t shell expanding
Chapter 7 - Alkenes and Alkynes I
Andrew Rosen Chapter 7 - Alkenes and Alkynes I 7.1 - Introduction - The simplest member of the alkenes has the common name of ethylene while the simplest member of the alkyne family has the common name
1. Insertion reactions of Ga(DDP) into metal-halide and metal methyl bonds.
This study mainly focuses on the synthesis and characterisation of new transition metal complexes and compounds of the sterically encumbered aluminium- and gallium-heterocycles E I (DDP) in the low oxidation
π bonded ligands alkene complexes alkyne complexes allyl complexes diene complexes cyclopentadienyl complexes arene complexes metallacycles
π bonded ligands alkene complexes alkyne complexes allyl complexes diene complexes cyclopentadienyl complexes arene complexes metallacycles M Transition metal alkene complexes The report in 1825 by William
Reductive Elimination
Reductive Elimination Reductive elimination, the reverse of oxidative addition, is most often seen in higher oxidation states because the formal oxidation state of the metal is reduced by two units in
Transition Metal Chemistry
Transition Metal Chemistry 2 2011.12.2 Ⅰ Fundamental Organometallic Reactions Following four reactions are important formal reaction patterns in organotransition metal complexes, which would conveniently
Coordination Chemistry Prof. Debashis Ray Department of Chemistry Indian Institute of Technology Kharagpur. Lecture - 7 Coordination Number I
Coordination Chemistry Prof. Debashis Ray Department of Chemistry Indian Institute of Technology Kharagpur Lecture - 7 Coordination Number I (Refer Slide Time: 00:27) Good evening to everybody. So, today
11, Inorganic Chemistry III (Metal π-complexes and Metal Clusters) Module 31: Preparation and reactions of metal clusters
1 Subject Paper No and Title Module No and Title Module Tag Chemistry 11, Inorganic Chemistry III (Metal π-complexes and Module 31: Preparation and reactions of metal clusters CHE_P11_M31 2 TABLE OF CONTENTS
Contents. Preface XI Abbreviation XV List of Contributors XIX
V Preface XI Abbreviation XV List of Contributors XIX 1 The Chemistry of Gold 1 M. Concepción Gimeno 1.1 Introduction 1 1.1.1 History 1 1.1.2 Chemical and Physical Properties 2 1.1.3 Theoretical Considerations
Reaction chemistry of complexes Three general forms: 1. Reactions involving the gain and loss of ligands a. Ligand Dissoc. and Assoc. (Bala) b.
eaction chemistry of complexes Three general forms: 1. eactions involving the gain and loss of ligands a. Ligand Dissoc. and Assoc. (Bala) b. Oxidative Addition c. eductive Elimination d. Nucleophillic
Organometallic Chemistry and Homogeneous Catalysis
rganometallic hemistry and omogeneous atalysis Dr. Alexey Zazybin Lecture N8 Kashiwa ampus, December 11, 2009 Types of reactions in the coordination sphere of T 3. Reductive elimination X-L n -Y L n +
Prof Saurav Chatterjee
Prof Saurav Chatterjee Associate Professor Email: saurav at nitrkl.ac.in Phone: +91-(0) 661-2462656 Office: # 305 B, Main building Personal Home Page: http://sites.google.com/site/sauravnitrkl/ Academic
Abstracts. p69. Keywords: C-H activation palladium catalysts arylation arenes polycyclic compounds biaryls natural products
I 1.1.1 Arylation Using a Palladium(0) Catalyst F. S. Melkonyan and V. Gevorgyan p5 The palladium(0)-catalyzed C- arylation reaction is one of the pioneering transformations in C- activation chemistry
Chapter 16. Aldehydes and Ketones I. Nucleophilic Addition to the Carbonyl Group. Physical Properties of Aldehydes and Ketones. Synthesis of Aldehydes
Nomenclature of Aldehydes and Ketones Chapter 16 Aldehydes and Ketones I. Aldehydes replace the -e of the parent alkane with -al The functional group needs no number Nucleophilic Addition to the Carbonyl
Organometallic Catalysis
Organometallic Catalysis The catalysts we will study are termed homogeneous catalysts as they are dissolved in th e same solvent as the substrate. In contrast, heterogeneous catalysts, such as palladium
THE ORGANOMETALLIC CHEMISTRY OF THE TRANSITION METALS
THE ORGANOMETALLIC CHEMISTRY OF THE TRANSITION METALS Second Edition ROBERT H. CRABTREE Yale University New Haven, Connecticut A Wiley-Interscience Publication JOHN WILEY & SONS New York / Chichester /
CHEM 251 (4 credits): Description
CHEM 251 (4 credits): Intermediate Reactions of Nucleophiles and Electrophiles (Reactivity 2) Description: An understanding of chemical reactivity, initiated in Reactivity 1, is further developed based
Andrew Yeung CHEM636
Andrew Yeung CHEM636 Scope verview olyketones and their synthesis Timeline of development Catalyst selection alladium vs. nickel Ligands Mechanism Initiation & termination ropagation roperties Low T g
CONTENTS PART I STRUCTURES OF THE TRANSITION-METAL COMPLEXES
CONTENTS Introduction... 1 1. Organization of the text... 1 2. Frontiers of organometallic chemistry... 2 3. Situation of the book with respect to teaching... 2 4. Reference books and other selected references...
Complexes. Commonly, transition metals can have molecules or ions that bond to them. These give rise to complex ions or coordination compounds.
Complexes Commonly, transition metals can have molecules or ions that bond to them. These give rise to complex ions or coordination compounds. Coordination Compounds Coordinate covalent bond both electrons
Detailed Course Content
Detailed Course Content Chapter 1: Carbon Compounds and Chemical Bonds The Structural Theory of Organic Chemistry 4 Chemical Bonds: The Octet Rule 6 Lewis Structures 8 Formal Charge 11 Resonance 14 Quantum
Inorganic Pharmaceutical Chemistry. Coordination compounds
Inorganic Pharmaceutical Chemistry Lecture No. 5 Date : 22/11 /2012 Dr. Mohammed Hamed --------------------------------------------------------------------------------------------------------------------------------------
1. Introduction. Introduction
1. The chemistry of organometallic compounds represents an important part of organic and pharmaceutical synthesis [1-6]. These compounds are used as catalysts in the stereospecific polymerization of olefins,
CHM 320 Laboratory Projects Spring, 2009
M 320 Laboratory Projects Spring, 2009 I. Enantioselective Reduction of Benzofuran-2-yl Methyl Ketone using Enzymes from arrots. Typically, the reduction of an unsymmetrical, achiral ketone with a hydride
Chapter 16 Aldehydes and Ketones I. Nucleophilic Addition to the Carbonyl Group
Chapter 16 Aldehydes and Ketones I. Nucleophilic Addition to the Carbonyl Group Nomenclature of Aldehydes and Ketones Aldehydes are named by replacing the -e of the corresponding parent alkane with -al
This reactivity makes alkenes an important class of organic compounds because they can be used to synthesize a wide variety of other compounds.
This reactivity makes alkenes an important class of organic compounds because they can be used to synthesize a wide variety of other compounds. Mechanism for the addition of a hydrogen halide What happens
Recent Publications (2010 present) 5. Synthesis and Mechanism of Formation of Metal Nanosponges and their Catalytic and
Recent Publications (2010 present) 1. Hydrogenation of CO 2, carbonyl and imine substrates catalyzed by [IrH 3 ( Ph PN H P)] complex- A. Ramaraj, M. Nethaji, B. R. Jagirdar, J. Organomet. Chem. 2019, 883,
Chapter 16 Aldehydes and Ketones I Nucleophilic Addition to the Carbonyl Group
Chapter 16 Aldehydes and Ketones I Nucleophilic Addition to the Carbonyl Group Nomenclature of Aldehydes and Ketones Aldehydes are named by replacing the -e of the corresponding parent alkane with -al
ummary Manipulating Radicals
Manipulating Radicals ummary Modern catalysis research tries to address issues such as material scarcity, sustainability or process costs. One solution is to replace expensive and scarce noble metal catalysts
The Role of METAMORPhos Ligands in Transition Metal Complex Formation and Catalysis S. Oldenhof
The Role of METAMORPhos Ligands in Transition Metal Complex Formation and Catalysis S. Oldenhof Summary Catalysis plays a key role in the prosperity of our society, as catalysts are applied in the majority
Chapter 23 Transition Metals and Coordination Chemistry
Lecture Presentation Chapter 23 and Coordination Chemistry James F. Kirby Quinnipiac University Hamden, CT Color Catalysts Magnets 23.1 The 1036 Why are of Interest? Biological roles Coordination compounds
Palladium-catalyzed cross-addition of triisopropylsilylacetylene to unactivated alkynes*
Pure Appl. Chem., Vol. 80, No. 5, pp. 1161 1166, 2008. doi:10.1351/pac200880051161 2008 IUPAC Palladium-catalyzed cross-addition of triisopropylsilylacetylene to unactivated alkynes* Naofumi Tsukada, Satoshi
Oxidative Addition and Reductive Elimination
xidative Addition and Reductive Elimination red elim coord 2 ox add ins Peter.. Budzelaar xidative Addition Basic reaction: n + X Y n X Y The new -X and -Y bonds are formed using: the electron pair of
Biological Anion Receptors
Binding of Anions 1 Binding of Anions 2 Biological Anion Receptors 3 Concepts in Anion Host Design FACTORS WITCH AFFECT ANION COMPLEXATION Prevailing interactions which take place in anion binding: hydrogen
Organic Chemistry Laboratory Summer Lecture 6 Transition metal organometallic chemistry and catalysis July
344 Organic Chemistry Laboratory Summer 2013 Lecture 6 Transition metal organometallic chemistry and catalysis July 30 2013 Summary of Grignard lecture Organometallic chemistry - the chemistry of compounds
Chapter 21: Transition Metals and Coordination Chemistry
Chapter 21: Transition Metals and Coordination Chemistry Mg, Cr, V, Co Pt Fe complexes O2 Mo and Fe complexes: nitrogen fixation Zn: 150 Cu, Fe: Co: B12 21.1 Transition Metals show great similarities within
Module 6 : General properties of Transition Metal Organometallic Complexes. Lecture 2 : Synthesis and Stability. Objectives
Module 6 : General properties of Transition Metal Organometallic Complexes Lecture 2 : Synthesis and Stability Objectives In this lecture you will learn the following Understand the role lead by ligands
Scientific Publications
Scientific Publications 1991 2000 1. Luminescent and Coordinatively Unsaturated Heterobimetallic d10-d8 Complexes. Photoredox Properties and X-Ray Crystal Structure of [AuPt(µdppm)2(CN)2]+ (dppm= bis(diphenylphosphino)methane),
Basic Organometallic Chemistry : Concepts, Syntheses, and Applications of Transition Metals. Table Of Contents: Foreword
Basic Organometallic Chemistry : Concepts, Syntheses, and Applications of Transition Metals Table Of Contents: Foreword v Preface vii List of abbreviations ix Chapter 1 Introduction 1 (15) 1.1 What is
Hydrogen iodide is a strong acid and will drive the reverse reaction, meaning the forward reaction will not occur.
EM 261 Oct 18, 2018 Photosynthesis and Related Reactions O 2 2 O 6 12 O 6 2 O N 3, S, Fe, u, o, other Natural Products D-Glucose R O R OR Ionic substitution S N 1 & R X X 2 hv Petroleum/ Alkanes R N 2
Final Scientific Report. October 2011 October 2016
Final cientific eport ctober 2011 ctober 2016 Title: Luminescent ionic liquid crystals Code: P-II-ID-PCE-2011-3-0384 Project manager: Conferentiar dr. Viorel Cîrcu Liquid crystals based on silver carbene
ORGANOMETALLICS IN SYNTHESIS: CHROMIUM, IRON & COBALT REAGENTS
- 1 - ORGANOMETALLICS IN SYNTHESIS: CHROMIUM, IRON & COBALT REAGENTS Introduction to Metal-Carbon Bonding Organometallic chemistry involves the interaction of an organic compound with a transition metal
Inorganic Chemistry GARY L. MIESSLER DONALD A. TARR. St. Olaf College Northfield, Minnesota
Inorganic Chemistry GARY L. MIESSLER DONALD A. TARR St. Olaf College Northfield, Minnesota Contents PREFACE xiii 1 INTRODUCTION TO INORGANIC CHEMISTRY 1 1-1 What Is Inorganic Chemistry? 1 1-2 Contrasts
Planar-Chiral Phosphine-Olefin Ligands Exploiting a (Cyclopentadienyl)manganese(I) Scaffold to Achieve High Robustness and High Enantioselectivity
Planar-Chiral Phosphine-Olefin Ligands Exploiting a (Cyclopentadienyl)manganese(I) Scaffold to Achieve High Robustness and High Enantioselectivity Reporter: Cong Liu Checker: Hong-Qiang Shen Date: 2017/02/27
11, Inorganic Chemistry III (Metal π-complexes and Metal Clusters) Module 32: Polynuclear metal carbonyls and their structure
1 Subject Paper No and Title Module No and Title Module Tag Chemistry 11, Inorganic Chemistry III (Metal π-complexes and Module 32: Polynuclear metal carbonyls and their structure CHE_P11_M32 2 TABLE OF
Aldehydes and Ketones : Aldol Reactions
Aldehydes and Ketones : Aldol Reactions The Acidity of the a Hydrogens of Carbonyl Compounds: Enolate Anions Hydrogens on carbons a to carbonyls are unusually acidic The resulting anion is stabilized by
14-1 Reactions Involving Gain or Loss of Ligands Reactions Involving Modification of Ligands
Organometallic Reaction and Catalysis 14-1 Reactions Involving Gain or Loss of Ligands 14-2 Reactions Involving Modification of Ligands 14-3 Organometallic Catalysts 14-4 Heterogeneous Catalysts Inorganic
Chapter 23. Transition Metals and Coordination Chemistry ( 전이금속과배위화학 ) Lecture Presentation
Lecture Presentation Chapter 23 and Coordination Chemistry ( 전이금속과배위화학 ) John D. Bookstaver St. Charles Community College Cottleville, MO 1 Most metals, including transition metals, are found in solid
PAPER No. 5:Organic Chemistry-2(Reaction Mechanism-1) MODULE No. 6: Generation, Structure, Stability and Reactivity of Carbocations
Subject Chemistry Paper No and Title Module No and Title Module Tag Paper No. 5: Organic Chemistry-II (Reaction Mechanism-1) Generation, Structure, Stability and Reactivity of Carbocations CHE_P5_M6 TABLE
Investigation of the Role and Form. Formation. Michael Enright
Investigation of the Role and Form of Silver Catalysts in C N Bond Formation Michael Enright Ripon College Importance Carbon Nitrogen Bonds Medicine Biological compounds Make C N bonds whenever we want
Chapter 10: Carboxylic Acids and Their Derivatives
Chapter 10: Carboxylic Acids and Their Derivatives The back of the white willow tree (Salix alba) is a source of salicylic acid which is used to make aspirin (acetylsalicylic acid) The functional group
C H activation of aliphatic amines without unnecessary mask M2 Takaya Togo
C H activation of aliphatic amines without unnecessary mask 2017.11.25 M2 Takaya Togo 1 Outline 1.Introduction 2.Free amines as DG Discovery of new activation mode Mechanistic studies Application of the
Chemistry 210 Organic Chemistry I Winter Semester 2001 Dr. Rainer Glaser
hemistry 210 rganic hemistry I Winter Semester 2001 Dr. Rainer Glaser Examination #3 Alkenes and Alkynes. Structure, Synthesis and Reactions. Friday, April 20, 2001, 9:00-9:50 Name: Answer Key Question
Microwave-promoted synthesis in water
Microwave-promoted synthesis in water icholas E. Leadbeater nicholas.leadbeater@uconn.edu Outline of what we do Synthesis / Methodology / ew techniques Pure organic synthesis eg. Baylis-Hillman eaction
Nitrogen Centered Radical Ligands Nagashima Nozomu
1 Nitrogen Centered Radical Ligands 2015. 7. 4. Nagashima Nozomu 1. Introduction 2 3 Aminyl radical 1) D. E. Wiliams, JACS, 1966, 88, 5665 2) Y. Teki et al. JOC, 2000, 65, 7889 Sterically protected aminyl
Handout IRTG, May Lectures overview. Ligands for metals
andout IRTG, ay 2009 Jan Reedijk. Leiden Institute of Chemistry Slide copies, stored as pdf; allowed for private use only. Bifunctionality in ligands and coordination compounds: application in design of
Conjugated Systems, Orbital Symmetry and UV Spectroscopy
Conjugated Systems, Orbital Symmetry and UV Spectroscopy Introduction There are several possible arrangements for a molecule which contains two double bonds (diene): Isolated: (two or more single bonds
Prof. Les Field. Organometallic Chemistry. Applied Science Building, Level 10. Phone:
1) rof. Les Field Applied Science uilding, Level 10 hone: 9385 2700 L.Field@unsw.edu.au Organometallic Chemistry Synthetic and mechanistic organometallic chemistry directed towards the applications of
1. Determine the oxidation state of the metal centre and count the number of electrons.
Exercise sheet : Organometallic chemistry Gunnar Bachem 1. Determine the oxidation state of the metal centre and count the number of electrons. 2. The metal fragment 1 reacts with the amine to give a carbene
QUESTIONSHEETS INORGANIC CHEMISTRY REACTIONS OF PERIOD 3 ELEMENTS WITH WATER REACTIONS OF PERIOD 3 ELEMENTS WITH OXYGEN
CHEMISTRY QUESTIONSHEETS A2 Level A2 TOPIC 21 INORGANIC CHEMISTRY Questionsheet 1 Questionsheet 2 Questionsheet 3 Questionsheet 4 Questionsheet 5 Questionsheet 6 Questionsheet 7 Questionsheet 8 Questionsheet
Transition Metal Chemistry and Coordination Compounds
Transition Metal Chemistry and Coordination Compounds Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display. 1 Properties of the Transition Metals All transition metals
Suggested solutions for Chapter 40
s for Chapter 40 40 PBLEM 1 Suggest mechanisms for these reactions, explaining the role of palladium in the first step. Ac Et Et BS () 4 2 1. 2. K 2 C 3 evision of enol ethers and bromination, the Wittig
Ligand Effects in Nickel Catalysis. Anthony S. Grillo Chem 535 Seminar October 22, 2012
Ligand in Nickel Catalysis Anthony S. Grillo Chem 535 Seminar October 22, 2012 Transition Metals in Chemistry Organotransition Metal Chemistry, Hartwig, J. F. University Science Books: Mill Valley, CA,
Computational Studies on the Electronic Structures and the Reaction Mechanisms of Rare-Earth- and Transition-Metal Complexes Name: Yi Luo
Project Title: Computational Studies on the Electronic Structures and the Reaction Mechanisms of Rare-Earth- and Transition-Metal Complexes Name: Yi Luo Laboratory at RIKEN: Organometallic Chemistry Laboratory
Organometallic Compounds of Magnesium *
OpenStax-CNX module: m32494 1 Organometallic Compounds of Magnesium * Andrew R. Barron This work is produced by OpenStax-CNX and licensed under the Creative Commons Attribution License 3.0 While beryllium
Organic Chemistry. M. R. Naimi-Jamal. Faculty of Chemistry Iran University of Science & Technology
Organic Chemistry M. R. Naimi-Jamal Faculty of Chemistry Iran University of Science & Technology Chapter 4-3: Continue Alkynes: An Introduction to Organic Synthesis Based on: McMurry s Organic Chemistry,
You are advised to spend an equal amount of time on each question. All questions carry an equal number of marks.
UNIVERSITY OF EAST ANGLIA School of Chemistry Main Series UG Examination 2014-15 INORGANIC CHEMISTRY CHE-2C32/5301B Time allowed: 2 hours Answer THREE questions. You are advised to spend an equal amount
Preparation of alkenes
Lecture 11 אלקנים הכנה ותגובות של אלקנים: הידרוגנציה, סיפוח הידרוהלוגנים )כלל מארקובניקוב(, סיפוח הלוגנים והסטראוכימיה של תוצרי הסיפוח, הידרובורציה, אפוקסידציה, אוזונוליזה. 1 Preparation of alkenes 1.
Methyl Migration to Coordinated CO
Methyl Migration to ordinated EFEENCES EXPEIMENT 6 Meisler, G.L., Tarr, D.A. Inorganic Chemistry, 3 rd Ed., Prentice all, Upper Saddle iver, N, 2004, Chapters 13 and 14. SAFETY EMMENDATINS Cyclopentadienyl
sp 2 geometry tetrahedral trigonal planar linear ΔH C-C ΔH C-H % s character pk a 464 KJ/mol 33% 44
hapter 10: Alkynes 10.1 Introduction to Alkynes ~ 111 ~ 122 1.06 Å 180 1.1 Å ~ 116 1.08 Å 1.54 Å 1.34 Å 1.20 Å hybridization of sp 3 sp 2 sp geometry tetrahedral trigonal planar linear 368 KJ/mol 632 KJ/mol
Additions to Metal-Alkene and -Alkyne Complexes
Additions to tal-alkene and -Alkyne Complexes ecal that alkenes, alkynes and other π-systems can be excellent ligands for transition metals. As a consequence of this binding, the nature of the π-system
Chapter Name the following compounds: (a) 2,5-dimethyl-3-hexyne (b) 3,3-dimethyl-1-butyne (c) 2,4-octadiene-6-yne (d) 3,3-dimethyl-4-octyne (e)
hapter 8 8.1 Name the following compounds: 3 3 3 3 2,5-dimethyl-3-hexyne 3 3 3 3,3-dimethyl-1-butyne (c) 3 3 2,4-octadiene-6-yne (d) 3 3 2 2 2 3 3 3,3-dimethyl-4-octyne (e) 3 3 3 2 3 3 2,5,5-trimethyl-3-heptyne
Analysis of Nickel Pincer. Catalyst for Hydrogen. Production
Analysis of Nickel Pincer Catalyst for Hydrogen Production Abstract: Fuel cells have great potential as an alternative fuel source; however the hydrogen to power the cells is rather costly to produce.
FINAL EXAMINATION 12/17/93.
INORGANIC CHEMISTRY 413/571 FINAL EXAMINATION 12/17/93. DR. J. SHERIDAN Write all answers in the answer book. WRITE NEATLY. This will help me to understand your answers and maybe get you a few more points!
INVESTIGATION OF SURFACE CHEMISTRY PROPERTIES OF Ga 2 O 3 /Al 2 O 3 CATALYSTS BY FT-IR SPECTROSCOPY
INVESTIGATION OF SURFACE CHEMISTRY PROPERTIES OF Ga 2 O 3 /Al 2 O 3 CATALYSTS BY FT-IR SPECTROSCOPY Balázs Szabó 1, Tamás Ollár 1, Ákos Rédey 1 1 Department of Environmental Engineering and Chemical Technology,
به نام خدا. Organic Chemistry 1. Dr Morteza Mehrdad University of Guilan, Department of Chemistry, Rasht, Iran
به نام خدا 8 Organic Chemistry 1 Dr Morteza Mehrdad University of Guilan, Department of Chemistry, Rasht, Iran m-mehrdad@guilan.ac.ir 8 Alkynes: An Introduction to Organic Synthesis آلکین ها: مقدمه ای
Coordination chemistry and organometallics
Coordination chemistry and organometallics Double salt and Complex salt A salt that keeps its identity only in solid state is called a double salt. In solution they dissociate into component ions. E.g.:
MODERN INORGANIC CHEMISTRY
MODERN INORGANIC CHEMISTRY Second Edition William L. Jolly Professor of Chemistry University of California, Berkeley McGraw-Hill, Inc. New York St. Louis San Francisco Auckland Bogota Caracas Hamburg Lisbon
KOT 222 Organic Chemistry II
KOT 222 Organic Chemistry II Course Objectives: 1) To introduce the chemistry of alcohols and ethers. 2) To study the chemistry of functional groups. 3) To learn the chemistry of aromatic compounds and
Synthese und elektrochemische Anwendungen von modifizierten Kohlenstoffnanoröhren
Technische Universität Ilmenau Fakultät für Mathematik und Naturwissenschaften Institut für Chemie und Biotechnik Fachgebiet Chemie Synthese und elektrochemische Anwendungen von modifizierten Kohlenstoffnanoröhren
Oxidation Number Of 1
In Which Species Does Hydrogen Have An Oxidation Number Of 1 The oxidation state (OS) of an element The total OS of all atoms in: a neutral species is 0 and in an ion Group 1 metals have an OS of +1 and
N-HETEROCYCLIC CARBENES: STRUCTURE AND PROPERTIES
N-HETEROCYCLIC CARBENES: STRUCTURE AND PROPERTIES Zachery Matesich 24 February 2015 Roadmap 2 Introduction Synthetic Methods History of NHCs Properties of NHCs Nature of the carbene Structural properties
Thermodynamically Favored vs. Kinetically Favored Carbon-Sulfur Bond Activation. David Hoeft Carthage College 11/17/11
Thermodynamically Favored vs. Kinetically Favored Carbon-Sulfur Bond Activation Carthage College 11/17/11 Abstract The study of carbon-sulfur bond activation is a topic that receives much attention because
CHEMISTRY PAPER No. : 7 MODULE No. : 23 (Optical Isomerism)
Subject Chemistry Paper No and Title Module No and Title Module Tag Paper 7 : Inorganic Chemistry-II (Metal-Ligand Bonding, Electronic Spectra and Magnetic Properties of Transition Metal Complexes) 23
Metallocenes WILEY-VCH. Volume 2. Synthesis Reactivity Applications. Edited by Antonio Togni and Ronald L. Halterman
Metallocenes Volume 2 Synthesis Reactivity Applications Edited by Antonio Togni and Ronald L. Halterman WILEY-VCH Weinheim New York Chichester Brisbane Singapore Toronto / Preface V Volume 1 Synthesis
CHEM 303 Organic Chemistry II Problem Set II Chapter 13 Answers
CEM 303 rganic Chemistry II Problem Set II Chapter 13 Answers 1) Explain the reason for the different chemical reactivity of cyclopentadiene and cycloheptatriene toward bromine. 2 + 2 + oth no doubt start
ALCOHOLS AND PHENOLS; ETHERS AND EPOXIDES; THIOLS AND SULFIDES
ALCOHOLS AND PHENOLS; ETHERS AND EPOXIDES; THIOLS AND SULFIDES A STUDENT SHOULD BE ABLE TO: 1. Give the IUPAC name when given the structure, and draw the structure given the name of open-chain and monocyclic
Organometallic Study Meeting Chapter 17. Catalytic Carbonylation
rganometallic Study Meeting Chapter 17. Catalytic Carbonylation 17.1 verview C or 3 3 C 3 C C 3 horrcat. Ar-X or alkene ' d cat. 2011/10/6 K.isaki or ' or N n 2 1 alkene, 2 Coorhcat. d cat. alkene C carbon
A Simple Introduction of the Mizoroki-Heck Reaction
A Simple Introduction of the Mizoroki-Heck Reaction Reporter: Supervisor: Zhe Niu Prof. Yang Prof. Chen Prof. Tang 2016/2/3 Content Introduction Intermolecular Mizoroki-Heck Reaction Intramolecular Mizoroki-Heck
Chapter 7 Alkenes and Alkynes I: Properties and Synthesis Elimination Reactions of Alkyl Halides"
Chapter 7 Alkenes and Alkynes I: Properties and Synthesis Elimination Reactions of Alkyl Halides The (E)-(Z) System for Designating Alkene Diastereomers The Cahn-Ingold-Prelog convention is used to assign
Chem 263 Nov 3, 2016
hem 263 Nov 3, 2016 Preparation of Aldehydes from Acid alides? + l l acid chloride aka acyl chloride aldehyde Needed: 2 Actual eagents: 2 /Pd Al This is lithium tri-t-butoxy aluminum hydride, a very sterically
Transition Metals and Complex Ion Chemistry
Transition Metals and mplex Ion Chemistry Definitions mplex ion - a metal ion with Lewis bases attached to it through coordinate covalent bonds. A mplex (or ordination compound) is a compound consisting
HOMEWORK PROBLEMS: ALKYNES. 1. Provide the complete IUPAC name for the following compounds:
CEM 31 MEWRK PRBLEMS: ALKYNES 1. Provide the complete IUPAC name for the following compounds: 2. When the compound below is treated with one equivalent of B 3, where does it react Explain. Where would
1. Which of the following compounds is the weakest base?
I. Multiple-choice Questions Fall 2018 1. Which of the following compounds is the weakest base? a. C3C2 b. C3C2 c. N3 d. C3 e. N2 2. Which of the following functional groups is indicated by a strong and
The Chemistry of Ethers, Epoxides, Glycols, and Sulfides
The Chemistry of Ethers, Epoxides, Glycols, and Sulfides The chemistry of ethers is closely intertwined with the chemistry of alkyl halides, alcohols, and alkenes. Ethers, however, are considerably less
Organometallic Chemistry and Homogeneous Catalysis
Organometallic Chemistry and Homogeneous Catalysis Dr. Alexey Zazybin Lecture N1 Kashiwa Campus, October 9, 2009 What compounds we can call organometallic compounds? Compounds containing direct metal-carbon
H Organometallic Catalysis in Industry
H Organometallic Catalysis in Industry Some terminology: Catalytic cycles: a circular path meant to show productive reactions, in order, that lead from the catalytically active species and its reaction
CH 3 TMG, DMF N H 3 CO 2 S. (PPh 3 ) 2 Pd 0
1. (a) rovide a reasonable mechanism for the following transformation. I S 2 C 3 C 3 ( 3 ) 2 2, CuI C 3 TMG, DMF 3 C 2 S TMG = Me 2 Me 2 ICu ( 3 ) 2 0 I S 2 C 3 S 2 C 3 Cu I 3 3 3 C 2 S I 3 3 3 C 2 S 3
Chemistry 201: General Chemistry II - Lecture
Chemistry 201: General Chemistry II - Lecture Dr. Namphol Sinkaset Chapter 23 Study Guide Concepts 1. In the transition metals, the ns orbital fills before the (n-1)d orbitals. However, the ns orbital