Exam I 23 January 2004 Name:
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1 hem 36 W04 Page of 5 Kantorowski Exam I 23 January 2004 ame: This exam contains 5 pages of questions confirm this once you begin. You will have 70 minutes An abbreviated Periodic Table can be found on the last page. o calculators or models are permitted. Read all questions carefully answer the question that is asked! Illegible or indecipherable answers may not receive potential partial credit. Good luck!. (6 pts) Draw the Lewis structure for the compounds below. Be certain to show all lone pairs and formal charges. Your final structure must be in the box provided. a) a b) 3 a 2. (0 pts) ame or draw the following compounds, adhering to IUPA nomenclature rules. 5 3 ( 3 ) methylpentane 4 3 2,3-dimethyl-4-propyl-octane 8,,4-trimethylcyclooctane 4-(-methylethyl)decane
2 hem 36 W04 Page 2 Initials 3. (8 pts) Identify which of the following compounds (A - F) a) are the same compound? A = F b) are cis-trans isomers? _A (or F) D c) are constitutional isomers? _A (or F) R A (or F) E R E d) have no isomeric relationship? B any_ (B has a molecular formula of 86, whereas all of the other compounds are 74.) A B D E F 4. (6 pts) Identify each of the following alkenes as cis, trans, or neither. trans neither trans 5. (0 pts) Which of the electronic configurations shown below... a) violates und s rule? B If equal energy orbitals are available, don t pair e s b) violates the Aufbau principle? A Build up by adding e s from bottom to top c) violates the Pauli exclusion principle? 2e s max per orbital; must have different spins d) represents in the ground state? D und s, Pauli s, and the Aufbau are followed e) represents in the excited state? A An e has been promoted to a higher E orbital 2p 2s s A B D
3 hem 36 W04 Page 3 Initials 6. (8 pts) Taxol (paclitaxel) is an antitumor agent that was first isolated from the bark of the yew tree in 97. Arguably the greatest bio-prospected success ever, it is FDA approved for the treatment of many ovarian, breast, Kaposi's sarcoma, and lung cancers. sp 2 amide aromatic alcohol (2 ) alcohol (3 ) alkene ketone ester sp 3 sp 3 ether a) In the boxes provided indicate the hybridization of the specified atoms. b) Identify one of each of the following functional groups in taxol by circling and clearly labeling them in the structure above. If a functional group listed is not present then write one next to it. Aldehyde one Aromatic alide one Alkene arboxylic acid one Ketone Amide Ester Alcohol Amine one Ether Thiol one c) If you identified an amide or amine indicate (circle) whether it is primary, secondary, or tertiary. o 2 o 3 o d) If you identified a halide or alcohol indicate (circle) whether the one you selected is primary, secondary, or tertiary. o 2 o R 3 o
4 hem 36 W04 Page 4 Initials 7. (8 pts) learly circle the correct answer for the following questions. There is only one correct answer for each; no credit will be given if more than one answer is circled for each question. a) Which compound has the lowest boiling point? cannot form -bonds with itself b) Which compound has the highest boiling point? polar 3 3 c) Identify the Lewis acid from among the following compounds. Pl3 Bl3 3 2 d) Which of the following compounds is the weakest acid? F S e) Provide curved arrow notation for the following reaction step (hint: you might need to draw lone pairs): 2 Br Br f) The electron density of a π-bond is located the internuclear axis. above and below along 20 to g) Which of the following best describes the bonding scheme for the indicated bond? sp-sp 3 sp 2 -sp 2 sp-sp 2 h) Above each of the following compounds, draw the conventional dipole moment arrow to indicate the bond polarity for the bond shown. F 2 i) What is the dominant intermolecular force for l2? London -bonding ionic dipole-dipole
5 hem 36 W04 Page 5 Initials 8. (6 pts) Answer the questions that follow for acetonitrile (3) What is the hybridization for? sp What is the 2-- bond angle? 80 2 ow many total electrons are involved in pi bonds in acetonitrile? 4 9. (0 pts) Draw an M bonding picture for acetonitrile independently showing the σ-framework and the π-framework. σ-framework: π-framework: sp sp 3 0. (8 pts) Follow the instructions that follow for the reaction between propyne and hydroxide. (int: the acidic proton on propyne is explicitly shown.) a) Write an equation for the following acid-base reaction. b) Label the acid (A), base (B), conjugate acid (A), and conjugate base (B). c) Predict whether the equilibrium favors the reactants or products. d) Write the Keq value above the equilibrium arrows. A B K a = B A 2 pk a 25 pk a 5.7 Page Score Possible Total 00 I II III IV V VI VII VIII Li Be B F e e a K Mg a Al Si P S Se l Br Ar Kr I Xe
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