EUNSUNG LEE. Synthesis and application of inorganic/organometallic complexes and reactive organic compounds, which 1) allow facile access to 18
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1 EUNSUNG LEE Department of Chemistry Pohang University of Science and Technology (POSTECH) 77, Cheongam-ro, Nam-gu, Pohang-si, Gyeongbuk, , Korea RESEARCH INTERESTS Synthesis and application of inorganic/organometallic complexes and reactive organic compounds, which 1) allow facile access to 18 F-labeled PET tracers, from small molecules to supramolecules, in order to study neurosystems and the brain, 2) catalyze small molecules highly efficiently, and 3) show regioselective organic transformations in metal-organic frameworks (MOFs). EDUCATION Stanford University, Stanford, CA, USA Ph.D. Inorganic and Organometallic Chemistry Advisor: Prof. Dmitry V. Yandulov POSTECH, Pohang, Republic of Korea M.S. Inorganic Chemistry POSTECH, Pohang, Republic of Korea B.S. Inorganic Chemistry EXPERIENCE 2017 current POSTECH, Department of Chemistry Associate Professor Institute for Basic Science (IBS) Center for Self-assembly and Complexity (POSTECH Campus) Research Fellow Institute for Basic Science (IBS) Center for Self-assembly and Complexity (POSTECH Campus) Research Fellow POSTECH, Department of Chemistry Assistant Professor Harvard University, Department of Chemistry and Chemical Biology MGH (Massachusetts General Hospital), Department of Radiology, Postdoctoral Scholar Advisor: Prof. Tobias Ritter Stanford University, Department of Chemistry Teaching/Research Assistant 2004 Soongsil University, CAMDRC and Department of Chemistry Researcher Advisor: Prof. Jaheon Kim 2001 POSTECH, Center for Smart Supramolecules (CSS) Researcher
2 AWARDS 2000 POSTECH, Center for Smart Supramolecules: Excellent Research Award 2015 TJ Park Science Fellowship 2015 IBS Excellent Researcher Award Thieme Chemistry Journal Award PUBLICATIONS (37) Synthetic control of coincidental formation of N-heterocyclic carbene copper(i) complex and imidazolium cations within metal-organic frameworks CrystEngComm. 2017, 19, H.-J. Lee, H. Kwon, J. Sim, D. Song, Y. Kim, J. Kim,* K. Kim,* E. Lee.* (36) On the Mechanism of Oxidative Cleavage of N-heterocyclic Carbene (NHC) Palladium Bond with Iodine Eur. J. Inorg. Chem. 2017, accepted. E. Lee.*, D. Y. Bae, D. V. Yandulov (35) An N-heterocyclic Carbene TCNE Zwitterion: Experimental and Theoretical Study on its Formation and Reactivity Eur. J. Org. Chem. 2017, H. Song, Y. Kim, J. Park, Y. H. Ko, K. Kim, E. Lee.* (34) A Highly Substitutable Palladium(II) Complex Stabilized by the Smallest Steric N-heterocyclic Carbene, IMe (IMe = 1,3-Dimethylimidazole-2-ylidene) Bull. Korean Chem. Soc., 2016, 37, E. Lee.*, D. Y. Bae, D. V. Yandulov (33) A Palladium(II) Peroxide Complex Supported by the Smallest Steric N-Heterocyclic Carbene, IMe (IMe = 1,3- Dimetylimidazole-2-ylidene), and Its Reactivity by Oxygen Atom Transfer Eur. J. Inorg. Chem. 2016, E. Lee.*, D. Y. Bae, S. Park, A. G. Oliver, Y. Kim, D. V. Yandulov (32) Activation of C F Bonds in Fluoroarenes by N-Heterocyclic Carbenes as an Effective Route to Abnormal NHC Complexes Chem. Commun. 2016, 52, Y. Kim, E. Lee.* (31) Efficient Synthesis of Bulky N-Heterocyclic Carbene Ligands for Coinage Metal Complexes J. Organomet. Chem. 2016, 820, 1. Y. Kim, Y. Kim, M. Y. Hur, E. Lee.* (30) Theoretical Study on Electronic Properties of Deoxyfluorinating Sulfur-Based Reagents J. Radiopharm. Mol. Probes. 2016, 2, 51. (Korean). S. Lim, E. Lee.* (29) Activation of Small Molecules at N-Heterocyclic Carbene Centers Synlett 2016, 27, 477. H. Song, Y. Kim, J. Park, K. Kim, E. Lee.* (28) Recent advances of aromatic C F bond borylation and Its application to positron emission tomography J. Radiopharm. Mol. Probes. 2015, 1, 80. (Korean). D. Song, S. Lee, B. C. Lee, S. E. Kim, E. Lee.* (27) Hydrolytic Transformation of Microporous Metal Organic Frameworks to Hierarchical Micro- and Mesoporous MOFs Angew. Chem. Int. Ed. 2015, 54, Y. Kim, T. Yang, G. Yoon, M. B. Ghasemian, J. Koo, E. Lee, S. J. Cho, K. Kim* (26) Porphyrin Boxes: Rationally Designed Porous Organic Cages
3 Angew. Chem. Int. Ed. 2015, 54, S. Hong, M. R. Rohman, J. Jia, Y. Kim, D. Moon, Y. Kim, Y. H. Ko, E. Lee, K. Kim* (25) Designing Highly Active Metal-Free Oxygen Reduction Catalyst inmembrane Electrode Assemblies for Alkaline Fuel Cells: Effects of Pore Size and Doping-Site Position Angew. Chem. Int. Ed. 2015, 54, S. Lee, M. Choun, Y. Ye, J. Lee, Y. Mun, E. Kang, J. Hwang, Y.-H. Lee, C.-H. Shin, S.-H. Moon, S.-K. Kim, E. Lee, J. Lee* (24) N-Heterocyclic Carbene Nitric Oxide Radicals J. Am. Chem. Soc. 2015, 137, J. Park, H. Song, Y. Kim, B. Eun, Y. Kim, D. Y. Bae, S. Park, Y. M. Rhee, W. J. Kim, K. Kim, E. Lee.* (23) Mechanism of electrophilic fluorination with Pd(IV): fluoride capture and subsequent oxidative fluoride transfer Chem. Sci., 2014, 5, 169. J. R. Brandt, E. Lee, G. B. Boursalian, T. Ritter.* (22) Application of Palladium-Mediated 18F-Fluorination to PET Radiotracer Development: Overcoming Hurdles to Translation PLoS One 2013, 8, e A. Kamlet, C. Neumann, E. Lee, S. Carlin, C. Moseley, N. Stephenson, J. M. Hooker,* T. Ritter.* (21) Nickel-Mediated Oxidative Fluorination for PET with Aqueous [ 18 F]Fluoride J. Am. Chem. Soc. 2012, 134, Highlight (C&EN 2012, 90 (43), 34.) Synfacts 2013; 9(1): 0090 E. Lee, J. M. Hooker, T. Ritter.* (20) Connecting Binuclear Pd(III) and Mononuclear Pd(IV) Chemistry by Pd Pd Bond Cleavage J. Am. Chem. Soc. 2012, 134, D. C. Powers, E. Lee, A. Ariafard, M. S. Sanford, B. F. Yates,* A. J. Canty,* T. Ritter.* (19) Synthesis and Characterization of Pd(IMe)2, and its Reactivity by C-S Oxidative Addition of DMSO J. Organomet. Chem., 2011, 696, E. Lee,* D. V. Yandulov. (18) Synthesis and Structure of Solution-Stable One-Dimensional Palladium Molecular Wires Nature Chem., 2011, 3, 949. M. G. Campbell, D. C. Powers, J. Raynaud, M. J. Graham, P. Xie, E. Lee, T. Ritter.* (17) A Fluoride-derived Electrophilic Late-Stage Fluorination Reagent for PET Imaging Science 2011, 334, 639. Highlights (C&EN 2011, 89 (45), 7. Nat. Methods 2012, 9, 19. Angew. Chem. Int. Ed. 2012, 51, Nature Chem. 2012, 4, 152) E. Lee, A. Kamlet, D. C. Powers, C. Neumann, G. B. Boursalian, T. Furuya, D. C. Choi, J. M. Hooker,* T. Ritter.* (16) Silver-Mediated Trifluoromethoxylation of Aryl Stannanes and Arylboronic Acids J. Am. Chem. Soc. 2011, 133, C. Huang, T. Liang, S. Harada, E. Lee, T. Ritter.* (15) A Dinuclear Palladium Catalyst for -Hydroxylation of Carbonyls with O2 J. Am. Chem. Soc. 2011, 133, G. J. Chuang, W. Wang, E. Lee, T. Ritter.* (14) On the Isolation of Neat Allylic Fluorides J. Fluor. Chem. 2009, 130, 474. E. Lee, D. V. Yandulov.* (13) Crystal structures of (2-substituted-5-N-tosyl)bicyclo[3.3.0]-5-azacyclooct-2-enone: a pseudo achiral crystal from enantiopure compound and a counter-example of Wallach s rule Tetrahedron: Asymmetry 2009, 20, K. S. Jeong, D. E. Kim, E. Lee, Y. H. Jhon, H. Han, J. Kim, N. Jeong.*
4 (12) A Three-dimensional MOF Assembled by Metal-organic Tapes Comprising of Copper(II) Tetranuclear Clusters and 5- Sulfoisophthalates Bull. Kor. Chem. Soc. 2008, 29, H. R. Jeon, D. W. Min, Y. Oh, E. Lee, Y.-J. Kim, D.-Y. Jung, J. Kim.* (11) Lanthanitin: A chiral nanoball encapsulating 18 lanthanum ions by ferritin-like assembly Angew. Chem. Int. Ed. 2006, 45, K. S. Jeong, Y. S. Kim, Y. J. Kim, E. Lee, J. H. Yoon, W. H. Park, Y. W. Park, S.-J. Jeon, Z. W. Kim, J. Kim, N. Jeong.* (10) Complexation of Ferrocene Derivatives by the Cucurbit[7]uril Host: A Comparative Study of the Cucurbituril and Cyclodextrin Host Families J. Am. Chem. Soc. 2005, 127, W. S. Jeon, K. Moon, S. H. Park, H. Chun, Y. H. Ko, J. Y. Lee, E. Lee, S. Samal, N. Selvapalam, M. V. Rekharsky, V. Sindelar, D. Sobransingh, Y. Inoue, A. E. Kaifer, K. Kim.* (9) A Double-chained Polyrotaxane: Cucurbituril Beads Threaded onto a Double-chained One-dimensional Coordination Polymer Bull. Kor. Chem. Soc. 2004, K. M. Park, E. Lee, S. C. Roh, J. Kim, K. Kim.* (8) Hydrogen adsorption experiments with IRMOF-3 as a sorbent, and the molecular modeling studies on the functionalized MOFs Transactions of the Korean Hydrogen and New Energy Society, 2004, 15, 105 (Korean). E. Lee, Y. Oh, J. Kim,* J. Yoon, T.-B. Lee, S.-H. Choi, D. Kim, J. Lee, S. J. Cho (7) Construction of a Square-wave-shaped One-dimensional Polyrotaxane Using a Preorganized L-shaped Pseudorotaxane Supramol. Chem. 2002, 14, 153. K. M. Park, S. C. Roh, E. Lee, J. Kim, J. W. Lee, H. J. Kim, K. Kim.* (6) Transition Metal Ion-Directed Supramolecular Assembly of One- and Two-dimensional Polyrotaxanes Incorporating Cucurbituril Chem. Eur. J. 2002, 8, 498. K. M. Park, D. Whang, E. Lee, J. Heo, K. Kim.* (5) Macrocycle in Macrocycle: Encapsulation of Metal Cyclen Complex in Cucurbit[8]uril Angew. Chem. Int. Ed. 2001, 40, S. -Y. Kim, I. S. Jung, E. Lee, J. Kim, S. Sakamoto, K. Yamaguchi, K Kim. (4) Selective Inclusion of a Hetero-Guest Pair in a Molecular Host Angew. Chem. Int. Ed. 2001, 40, H. -J. Kim, J. Heo, W. S. Jeon, E. Lee, J. Kim, S. Sakamoto, K. Yamaguchi, K. Kim.* (3) A Two-Dimensional Polyrotaxane with Large Cavities and Channels: a Novel Approach to Metal-Organic Open- Frameworks Using Supramolecular Building Blocks Angew. Chem. Int. Ed. 2001, 40, 399. E. Lee, J. Kim, J. Heo, D. Whang, K. Kim.* (2) A Three-Dimensional Polyrotaxane Network Angew. Chem. Int. Ed. 2000, 39, E. Lee, J. Heo, K. Kim.* (1) New Cucurbituril Homologues: Syntheses, Isolation, Characterization, and X-ray Crystal Structures of Cucurbit[n]uril (n = 5, 7, and 8) J. Am. Chem. Soc. 2000, 122, 540. J. Kim, I.-S. Jung, S.-Y. Kim, E. Lee, J.-K. Kang, S. Sakamoto, K. Yamaguchi, K. Kim* PATENT K. Kim, J. Kim, I. S. Jung, S. Y. Kim, E. Lee, J. K. Kang, Japan Patent No. 3,432,483; Europe Patent No.1,094,065; US Patent
5 No. 6,365,734, Cucurbituril Derivatives, their preparation methods and uses. T. Ritter, E. Lee, A. Kamlet, D. C. Powers, T. Furuya, WO/2012/024604, High-Valent Palladium Fluoride Complexes and Uses Thereof. October 9, T. Ritter, E. Lee, Nickel-Mediated Late-stage Fluorination and Uses Thereof U.S. WO A1 J. Park, Y. Kim, H. Song, K. Kim, E. Lee, N-Heterocyclic Carbene Nitric Oxide Radicals and application of the same P KR J. Lee, K. Kim, E. Lee, Pyrazolyl-Imidazolium Ligands, Metal Organic Frameworks Comprising the Same and Method of Preparing the Same PLA H. Song, S. Jeon, K. Kim, E. Lee, N-Heterocyclic carbene metallocene compounds and application of the same PLA S. Park, H. Song, K. Kim, E. Lee, Fluorosulfonyl Carboxylic Acid Compound and Uses Thereof PLA H. Kwon, K. Kim, E. Lee, Transition metal complexes and their preparation PLA
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