Topology in the solid state sciences
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1 Topology in the solid state sciences José L. Mendoza- Cortés 2011 February 17th
2 Why is it important? What can we learn? Physics Materials Science Chemistry Biology What do they mean by Topology?
3 Main Questions Fundamental question: Given an spectra (e.g. sound), can you tell the shape of the source (e.g. the instrument shape) In other words: Is it possible that two molecules or solids can have the same properties, given the only difference is their topology? Topology is concerned with spatial properties that are preserved under continuous deformations of objects.
4 Familiarity Voronoi-Dirichlet polyhedron Wigner-Seitz cell First Brillouin zone All are example of Voronoi-Dirichlet polyhedron but applied to an specific field
5 Everything we are going to cover today it comes to this!
6 And this: Zeolites
7 From real stuff to abstract stuff node rod Different topologies could be obtained on varying the coordination geometry of the nodes...
8 From real stuff to abstract stuff honeycomb layer
9 Lets see abstract stuff Topological Entanglement Euclidean Entanglement
10 Borromean links
11 Lets see abstract stuff
12 Models: Lattice hxl/shubnikov plane net (3,6) Atom coordinates C Space Group: P6/mmm Cell Dimensions a= b= c= Crystallographic, not crystallochemical model
13 Models: Net Inherently crystallochemical, but no geometrical properties are analyzed
14 Models: Labeled quotient graph Chung, S.J., Hahn, Th. & Klee, W.E. (1984). Acta Cryst. A40, Wrapping NaCl 3D graph a NaCl labeled quotient graph b
15 Models: Embedded net Diamond (dia) net in the most symmetrical embedding
16 Models: Polyhedral subdivision Voronoi-Dirichlet polyhedron and partition: bcu net K d =0.5
17 Models: Polyhedral subdivision Tilings: dia and bcu nets dia bcu Normal crystal chemistry -> dual crystal chemistry
18 Abstract stuff
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23 3-connected graph means that the three vertex are connected with other three vertex (therefore they have three edges)
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31 Where can we apply this? Hsieh, D. et al. A tunable topological insulator in the spin helical Dirac transport regime. Nature 460, (2009).
32 Where can we apply this?
33 world records of Interpenetration fold dia MOF Ag(dodecandinitrile) 2 11-fold dia H-bond [C(ROH) 4 ][Bzq] 2 Class Ia fold srs H-bond (trimesic acid) 2 (bpetha) 3 Class IIIb
34 dia 12f interpenetrating nets TIV: [0,1,0] (13.71A) NISE: 2(1)[0,0,1] Zt=6; Zn=2 Class IIIa Z=12[6*2]
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37 ######################################### 12;RefCode:SOBTUY:C40 H42 Cd2 N12 O21 Pd1 Author(s): Abrahams B.F.,Hoskins B.F.,Robson R. Journal: J.AM.CHEM.SOC. Year: 1991 Volume: 113 Number: Pages: 3606 ######################################### Atom Pd1 links with R(A-A) Pd ( 0-1 1) A Pd (-1 0-2) A Pd ( 1 0 1) A Pd (-1 0-1) A Structure consists of 3D framework with Pd (SINGLE NET) Coordination sequences Pd1: Num Cum Vertex symbols for selected sublattice Pd1 Point/Schlafli symbol:{6^5;8} With circuits:[ (2).8(2)] With rings: [ (2).*] Total Point/Schlafli symbol: {6^5;8} TOPOS OUTPUT 4-c net; uninodal net Classification of the topological type: cds/cdso4 {6^5;8} - VS [ (2).*]
38 O Keffe & Delgado-Friedrichs 3dt 2002 SyStRe 2003 Symmetry Structure Realization one can determine without ambiguity whether two nets are isomorphic or not
39 SyStRe
40 3dt 3D Tiling
41 Thanks to: Delgado-Friedrich, O Keeffe, Hyde, Blatov, Proserpio.
42 Suplementary slides Suplementary slides
43 Self-entanglement
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45 POLYCATENATION INTERPENETRATION a) 0D 1D b) 0D 1D c) 1D 2D d) 1D 3D e) 2D 3D f) 2D 3D increase of dimensionality dimensionality unchanged
46 ..\libro_braga\figure\asufig.jpg
47 Polycatenation Borromean entanglements Topological self-catenation Interpenetration Polythreading Euclidean A new complexity of the solid state
48 Data: Electronic crystallographic databases CSD ~ entries ICSD ~ entries CrystMet ~ entries PDB ~50000 entries
49 Data: Electronic crystallochemical databases RCSR 1620 entries; TTD Collection entries; TTO Collection 3617 entries; Atlas of Zeolite Frameworks, 179 entries;
50 Data: Electronic databases of hypothetical nets EPINET entries; Atlas of Prospective Zeolite Frameworks entries;
51 History of crystallochemical analysis Mathematical fundamentals J. Hessel, geometric crystal classes O. Bravais, three-periodic lattices E. Fedorov and A. Shönflies, space groups
52 History of crystallochemical analysis Microscopic observations M. Laue, 1912 diffraction of X-rays in crystals W.G. Bragg and W.L. Bragg, 1913 first structure determinations
53 History of crystallochemical analysis Experimental technique and methods of X-ray analysis 1920s 1960s Photomethods and technique First printed manuals on crystal structures First really crystallochemical laws (L. Pauling, V. Goldschmidt, A. Kitaigorodskii) A.F. Wells, 1954 graph representation
54 History of crystallochemical analysis Time of automated diffractometers 1960s present time Rapid accumulation of experimental data Now the number of determined crystal structures exceeds 600,000 and grows faster and faster
55 Algorithms: building adjacency matrix Method of intersecting spheres Method of spherical sectors Distances Solid Angles For inorganic compounds For organic, inorganic and metal-organic compounds For all types of compounds, using atomic radii and Voronoi polyhedra For artificial nets, intermetallides, noble gases, using Voronoi polyhedra Van der Waals Specific Valence Valence Valence
56 Algorithms: building adjacency matrix Solid angle of a VDP face is proportional to the bond strength
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62 Topological insulators an extremely short explanation y Jose L. Mendoza-Cortes It is an insulator (or a semiconductor) at bulk At the surface, new states appears (The so called surface states) These new states suffer from spin-orbit coupling These surface states determines if they are topological insulators or not. This is that if electrons with a determined energy and momentum can be trapped in the surface. Real Space Reciprocal space
63 Topological insulators At bulk At the surface new states appears!
64 Topological insulators Topological these two surfaces are equivalent However, the bulk properties of the semiconductor (or isolator) makes the surfaces band to have spin-orbit coupling, so they stop being degenerated.
65 Topological insulators Depending of the properties of the bulk semiconductor (or the insulator), then the surface bands are going to have the topological constrains. Now, what does make a topological insulator one? The fact that one electron with certain energy and momentum would stay in that surface as it would with a conductor. and this is going to be determined by the topology of the surface band! Let s assume the red dot in the figure above is an electron from diffraction experiment, on the left figure, the electron would bounce with different momentum from the solid. However on figure on the right, the electron would get trapped.
66 Sources Nature Physics 4, (2008) doi: /nphys955 Nature 464, (11 March 2010) doi: /nature08916;
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