Exfoliated NanoSilicate Platelets-Preparation and Application

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Exfoliate NanoSilicate Platelets-Preparation an Application 100 100 1 nm 3 0.

1 Exfoliate NanoSilicate Platelets-Preparation an Application nm nm ) 0.1~1 µm 0.2nm Fiure nm m nm 2~3 nm nm 3

: 2~4 nm 9 nm Macromolecules, 2001, 34, 8832 100 100 9 nm 3 ) Fiure 2.

2 : 2~4 nm 9 nm Macromolecules, 2001, 34, nm 3 ) Fiure nm 3 ) AMO;amine-terminate Mannich oliomers) Exfoliation) ; > 100 Å) 20-50Å) Fiure 3) Conventional Technoloy Polymer Matrix Alkylammonium salt Polymer Blenin Layere Silicate Basal Spacin = 12 Å Oranically Moifie Layere Silicate Basal Spacin = 20~40 Å Polymer Layere Silicate Nanocomposite Novel Technoloy Exfoliatin Aent Polymer Polymer Matrix Blenin Nano Silicate Platelets Polymer Layere Silicate Nanocomposite Fiure 3.

3 N a nm 3 One step Exfoliation ov el tec h nolo y Fiure 4. b. Aspect Ration electron beam)

4 Fiure 5. fatty amine salt + Ionic exchane Nano Silicate Plates Fatty amine quart Water rop Coatin on lass Self-assembly with a hyrophobic an coarse surface lass Lotus effect: contact anle >150 o A roplet must contact > nm 2 plates

Fiure 6. 1. - 20-40 Å : 100 100 1nm 3 Epoxy 7H 2. PU- Fiure 7.

5 Fiure Å : nm 3 Epoxy 7H 2. PU- Fiure nm 3 PU elastomer PU elastomer wt%) PU 1. Isocyanate PU PU ~ 800 m 2 / ,000 DNA PCR )

$[ T \ S ] H ' Â U ^ _ a) b) Fiure 8.! " : 4. = en v uv O! ² ³ l = % e{ ý «N * 0. q e P Q T n Ø N c a)k l m!$ " : p çz LM O ø " c I S w # % c ß '% x & v y Ü h r Ié mz% C N H q ef x ~ a 2 Ô r } Sj S U h 0 H T ` o K¹ f 0 J ³ S ¹

$V W 7 8 # X Y Z [ \ ] = ¹ 19 Åç58 Å) S ZN 3 ^ h I AFM Q R I Pb 1 < BSA 0 [ BSA [ ' Kk é Ò BSA, ù b _ J.$

6 [ T \ S ] H ' Â U ^ _ a) b) Fiure 8.! " : 4. = en v uv O! ² ³ l = % e{ ý «N * 0. q e P Q T n Ø N c a)k l m! " : O 1 : Õ Ì a) b) b)l m 0.01wt%! " : p çz LM O ø " c I S w # % c ß '% x & v y Ü h r Ié mz% C N H q ef x ~ a 2 Ô r } Sj S U h 0 H T ` o K¹ f 0 J ³ S ¹ b) R / ² c O ' 3 - y a) :, ' % M ` m+ L Åe 0 [ K c b m ¹ ` a b c e f 3 h i j i G k? ) ' S' G?s t N ) z Q R * Fiure 9. Newton-force imaes of atomic force microscopy A) 1 µm2, B) 3 µm2. 5. V W 7 8 # X Y Z [ \ ] = ¹ 19 Åç58 Å) S ZN 3 ^ h I AFM Q R I Pb 1 < BSA 0 [ BSA [ ' Kk é Ò BSA, ù b _ J. î 4 r ^ ê ZN 3 K 0 1 Så * r IQ R <= a 3 4 J ' k Z ÅBSA moel) o ^ ¹ I ILDHs ZN nm3 ý é a k k Z Ì Z Ó* N 3 F uk BSA [ clay l!ph ç2 3 þ G 0 ç

7 LDHs) ph BSA), : 12 Å) BSA 32Å POP Å) 61 Å BSA AFM BSA BSA POP2000/MMT 12Å ph 4 4 o C 32Å Na + -MMT 4414 nm 3 BSA 53Å POP2000/MMT ph 4 4 o C 61Å + POP2000 Fiure ) ) )

8 polystyrene-co-maleic anhyrie) SMA) methyl-polyethylene lycol MPEG) particle-particle space ) / Fiure 11. ) 1.0) ) cm) None None <9.0 ) SMA-MPEG JJLin Lab) D230/MMT ) D400/MMT

9 1wt% )

10 1. Chou, C. C; Lin, J. J. One-Step Exfoliation of Montmorillonite via Phase Inversion of Amphiphilic Copolymer Emulsion Macromolecules, 2005, 38, Lin, J. J.; Chu, C. C.; Chou, C. C.; Shieu, F. S. Self-Assemble Nanofibers from Ranom Silicate Platelets Avance Materials, 2005, 17, Chen, Y. M.; Huan, B. H.; Lin, J. J. Synthesis an Properties of Cross-linkable Macromers from the Selective Substitution of Polyoxyalkylene)-amines an Cyanuric Chlorie Polymer, 2005, 46, Chou, C. C.; Chan, Y. C.; Chian, M. L.;Lin, J. J. Amphiphilic Properties of Polyoxyalkylene)amine Intercalate Smectite Aluminosilicates Lanmuir, 2004, 20, Lin, J. J.; Chou, C. C.; Lin, J. L. Lenthy Ro Formation from Polyoxyalkylene)amine Intercalate Smectite Clay via Self-alinin Mechanism Macromolecular Rapi Communications, 2004, 25, Lin, J. J.; Chen, Y. M. Amphiphilic Properties of Polyoxyalkylene)amine Intercalate Smectite Aluminosilicates Lanmuir, 2004, 20, Lin, J. J.; Chan, Y. C.; Chen, I. J. Novel Mechanism for Layere Silicate Clay Intercalation by Polyoxypropylene)-Semente Carboxylic Aci Macromolecular Rapi Communication, 2004, 25, Chou, C. C.; Chan, Y. C.; Chian, M. L.; Lin, J. J. Conformational Chane of Tri-functional Polyoxypropylene)amine Intercalate in Layere Silicate Confinement Macromolecules, 2004, 37, Lin, J. J.; Juan, T. Y. Intercalation of layere ouble hyroxies by polyoxyalkylene)-amiocarboxylates: tailorin layere basal spacin Polymer, 2004, 45, Chou, C. C.; Shieu, F. S. ; Lin, J. J. Preparation, Oranophilicity an Self-Assembly of Polyoxypropylene)amine-Clay Hyris Macromolecules, 2003, 36, Lin, J. J.; Chen, I. J.; Chou, C. C. Critical Conformational Chane of Polyoxypropylene)iamines in Layere Aluminosilicate Confinement Macromolecular Rapi Communication, 2003, 24, Lin, J. J.; Hsu, Y. C.; Chou, C. C. Copolymer-Layere Silicate Hybri Surfactants from the Intercalation of Montmorillonite with Amphiphilic Copolymers Lanmuir, 2003, 19,

ETIKA V PROFESII PSYCHOLÓGA

P r a ž s k á v y s o k á š k o l a p s y c h o s o c i á l n í c h s t u d i í ETIKA V PROFESII PSYCHOLÓGA N a t á l i a S l o b o d n í k o v á v e d ú c i p r á c e : P h D r. M a r t i n S t r o u