ICP Test Report Certification Packet

Transcription

1 ICP Test Report Certification Packet Company name : Littelfuse, Inc. Product Series: 3.6 x 10 mm Fuse Product #: 875xxx Series Issue Date: April 21, 2014 It is hereby certified by Littelfuse, Inc. that there is neither RoHS (EU Directive 2002/95/EC, 2011/65/EU)-restricted substance nor such use, for materials to be used for unit parts, for packing/packaging materials, and for additives and the like in the manufacturing processes. In addition, it is hereby reported to you that the parts and sub-materials, the materials to be used for unit parts, the packing/packaging materials, and the additives and the like in the manufacturing processes, are all composed of the following components. Issued : [Global EHS Engineer] (1) Parts, sub-materials and unit parts This document covers the 3.6 x 10 mm Fuse, RoHS-Compliant series products manufactured by Littelfuse, Inc. < Raw Materials Used Please see Table 1 (2) The ICP data on all measurable substances Please see appropriate pages as identifed in Table 1 Remarks: 1 Form Rev. A 2/21/06

2 Table 1: List of Raw Materials covered by this report ICP ID Raw Material Part Number Raw Material Description Page(s) ICP-0260 Y50/ YJM ( ) Ceramic Base - Body 3-13 ICP Cap & Lead Assembly ICP xxx Element- 5% by weight Ag Clad Cu ICP (497xxx) Element Ni42Fe58MCuAg5% ICP (497xxx-001) Element Ni42Fe58MCuMSn ICP (425672) Ink-Black ICP Solder Wire ICP Element - Sn Plated Cu Clad Cu55 Ni

3 Number : TWNC Applicant: Littelfuse Philippines Inc. Date : Mar 25, 2014 LIMA Technology Center, Lipa City, Malvar, Batangas Sample Description: One (1) group of submitted samples said to be : Part Description : Ceramic-Body Part Number : Date Sample Received : Mar 18, 2014 Date Test Started : Mar 18, 2014 Test Conducted : As requested by the applicant, for details please refer to attached pages. Authorized by: On Behalf of Intertek Testing Services Taiwan Limited K. Y. Liang Director *THJ * Page 1 of 11

4 Test Conducted Number: TWNC Test Result Summary: Test Item Unit Test Method Result Submitted sample RL Heavy Metal Cadmium (Cd) content ppm With reference to IEC : 2013, by microwave or acid digestion and determined by ND 2 ICP-OES. Lead (Pb) content ppm With reference to IEC : 2013, by microwave or acid digestion and determined by ND 2 ICP-OES. Mercury (Hg) content ppm With reference to IEC : 2013, by microwave or acid digestion and determined by ND 2 ICP-OES. Chromium VI (Cr 6+ ) content ppm With reference to IEC 62321: 2008, by alkaline digestion and determined by UV-Vis Spectrophotometer. ND 1 Polybrominated Biphenyls (PBBs) Monobrominated Biphenyls (MonoBB) Dibrominated Biphenyls (DiBB) Tribrominated Biphenyls (TriBB) Tetrabrominated Biphenyls (TetraBB) With reference to IEC 62321: Pentabrominated Biphenyls ppm 2008, by solvent extraction ND 5 (PentaBB) and determined by GC-MS and Hexabrominated Biphenyls ppm further HPLC-DAD confirmation ND 5 (HexaBB) when necessary. Heptabrominated Biphenyls (HeptaBB) Octabrominated Biphenyls (OctaBB) Nonabrominated Biphenyls (NonaBB) Decabrominated Biphenyl (DecaBB) ppm ND 5 *THJ * Page 2 of 11

5 Test Conducted Number: TWNC Test Item Unit Test Method Result Submitted sample Polybrominated Diphenyl Ethers (PBDEs) Monobrominated Diphenyl Ethers (MonoBDE) Dibrominated Diphenyl Ethers (DiBDE) Tribrominated Diphenyl Ethers (TriBDE) Tetrabrominated Diphenyl Ethers (TetraBDE) With reference to IEC 62321: Pentabrominated Diphenyl ppm 2008, by solvent extraction ND 5 Ethers (PentaBDE) and determined by GC-MS and Hexabrominated Diphenyl ppm further HPLC-DAD confirmation ND 5 Ethers (HexaBDE) when necessary. Heptabrominated Diphenyl Ethers (HeptaBDE) Octabrominated Diphenyl Ethers (OctaBDE) Nonabrominated Diphenyl Ethers (NonaBDE) Decabrominated Diphenyl Ether (DecaBDE) ppm ND 5 Halogen Content Fluorine (F) ppm With reference to EN ND 50 Chlorine (Cl) ppm 14582:2007 by combustion ND 50 bomb with oxygen and Bromine (Br) 0 determined by Ion Iodine (I) ppm Chromatography. ND 50 Phthalates Di(2-ethylhexyl) Phthalate ppm ND 10 (DEHP) With reference to EN 14372: Dibutyl Phthalate ppm 2004, by solvent extraction ND 10 (DBP) and determined by GC-MS. Benzyl Butyl Phthalate ppm ND 10 (BBP) RL *THJ * Page 3 of 11

6 Test Conducted Number: TWNC Others Test Item Unit Test Method Hexabromocyclododecane (HBCDD) ppm With reference to USEPA 3540C, by solvent extraction and determined by GC-MS. Result Submitted sample RL ND 10 Remarks: ppm = Parts per million based on weight of tested sample = mg/kg ND = Not detected RL = Reporting limit, quantitation limit of analyte in sample Responsibility of Chemist: Ryan Lin/ Pelny Hsiao/ Vico Lin Date Sample Received : Mar 18, 2014 Test Period : Mar 18, 2014 to Mar 21, 2014 RoHS Limit Restricted Substances Limits Cadmium (Cd) content 0.01% (100ppm) Lead (Pb) content 0.1% (1000ppm) Mercury (Hg) content 0.1% (1000ppm) Chromium VI (Cr 6+ ) content 0.1% (1000ppm) Polybrominated Biphenyls (PBBs) 0.1% (1000ppm) Polybrominated Diphenyl Ethers (PBDEs) 0.1% (1000ppm) The above limits were quoted from Annex II of 2011/65/EU for homogeneous material. *THJ * Page 4 of 11

7 Test Conducted Measurement Flowchart: Test for Cd/Pb/Hg/Chromium (VI)/PBBs/PBDEs Contents Reference Standard:Cd/Pb: IEC :2013; Hg: IEC :2013; Chromium (VI)/PBBs/PBDEs: IEC 62321:2008 Number: TWNC For non-metal part Sample preparation For metal part Take sample and immerse into Aqua Regia, start to etch plating layer Stop the etching procedure upon color change completely Take the Aqua solution as plating component and etched body as substrate component PBBs/PBDEs Cr 6+ Cd/Pb/Hg Substrate Plating Weigh sample and add organic solvent Weigh sample and add alkaline solution For different material, digest the sample with appropriate acid *1 Cr 6+ By solvent extraction By spot test Definite temp. extraction Confirm the tested samples are totally dissolved Get 50cm 2 sample Negative *2 Concentrate the extract and make up with organic solvent Cool and filter the extract Make up with deionized water By boiling water extraction Analyzed by GC-MS Analyzed by ICP-OES Make up with deionized water and add diphenyl-carbazide solution Remarks: *1: List of Appropriate Acid: Material Acid Added for Digestion Polymers HNO 3,HCl,HF,H 2 O 2,H 3 BO 3 Metals HNO 3,HCl,HF Electronics HNO 3,HCl,H 2 O 2,HBF 4 Analyzed by UV-VIS *2: If the result of spot test is positive, Chromium VI would be determined as detected. *THJ * Page 5 of 11

8 Test Conducted Measurement Flowchart: Test for Halogen Contents Reference Method:EN Number: TWNC Sampling Add absorbent in a combustion bomb & place weighed sample into sample cup Fill oxygen into the combustion bomb Ignite then leave the bomb at room temperature Transfer the absorbent into a volumetric flask Make up with deionized water Analyzed by Ion Chromatography *THJ * Page 6 of 11

9 Test Conducted Measurement Flowchart: Number: TWNC Test for Phthalates Contents Reference Method: EN 14372: 2004 Sampling Weigh sample and add organic solvent By solvent extraction Concentrate the extract and make up with organic solvent Analyzed by GC-MS *THJ * Page 7 of 11

10 Test Conducted Measurement Flowchart: Test for Hexabromocyclododecane (HBCDD) Content Reference Method:USEPA 3540C Number: TWNC Sampling Weigh sample and add organic solvent By solvent extraction Concentrate the extract and make up with organic solvent Analyzed by GC-MS *THJ * Page 8 of 11

11 Test Conducted Number: TWNC End of Report This report is made solely on the basis of your instructions and/or information and materials supplied by you. It is not intended to be a recommendation for anyparticular course of action. Intertek does not accept a duty of care or any other responsibility to any person other than the Client in respect of this report and onlyaccepts liability to the Client insofar as is expressly contained in the terms and conditions governing Intertek's provision of services to you. Intertek makes nowarranties or representations either express or implied with respect to this report save as provided for in those terms and conditions. We have aimed to conductthe Review on a diligent and careful basis and we do not accept any liability to you for any loss arising out of or in connection with this report, in contract, tort, by statute or otherwise, except in the event of our gross negligence or wilful misconduct. *THJ * Page 9 of 11

12 Number: TWNC *THJ * Page 10 of 11

13 Number: TWNC *THJ * Page 11 of 11

14 Number : TWNC Applicant: Littelfuse Philippines Inc. Date : Oct 09, 2013 LIMA Technology Center, Lipa City, Malvar, Batangas Sample Description: One (1) group of submitted samples said to be : Part Description : Cap And Lead Assembly Part Number : Date Sample Received : Oct 07, 2013 Date Test Started : Oct 07, 2013 Test Conducted : As requested by the applicant, for details please refer to attached pages. Authorized by: On Behalf of Intertek Testing Services Taiwan Limited K. Y. Liang Director *THJ * Page 1 of 6

15 Test Conducted Number: TWNC Test Result Summary: Heavy Metal Cadmium (Cd) content Lead (Pb) content Mercury (Hg) content Test Item Unit Test Method Chromium VI (Cr 6+ ) content ppm ppm ppm mg/kg with 50 cm 2 With reference to IEC 62321: 2008, by microwave digestion and determined by ICP-OES. With reference to IEC 62321: 2008, by microwave digestion and determined by ICP-OES. With reference to IEC 62321: 2008, by microwave digestion and determined by ICP-OES. With reference to IEC 62321: 2008, by boiling water extraction and determined by UV-Vis Spectrophotometer. Result Silvery metal RL ND 2 ND 2 ND 2 Negative 0.02 Remarks: ppm = parts per million based on weight of tested sample = mg/kg ND = Not detected RL = Reporting Limit, Quantitation limit of analyte in sample mg/kg with 50cm 2 = milligram per kilogram with 50 square centimeter Negative = A negative test result indicated positive observation was not found at the time of test Responsibility of Chemist: Kevin Liu/ Irene Chiou Date Sample Received : Oct 07, 2013 Test Period : Oct 07, 2013 to Oct 09, 2013 RoHS Limit Restricted Substances Cadmium (Cd) content Lead (Pb) content Mercury (Hg) content Chromium VI (Cr 6+ ) content Limits 0.01% (100ppm) 0.1% (1000ppm) 0.1% (1000ppm) 0.1% (1000ppm) The above limits were quoted from Annex II of 2011/65/EU for homogeneous material. *THJ * Page 2 of 6

16 Test Conducted Measurement Flowchart: Test for Cd/Pb/Hg/Chromium (VI) Reference Method: IEC edition 1.0:2008 Number: TWNC Sampling Cd/Pb/Hg Metal Cr 6+ Polymers / Electronics For different material, digest the sample with appropriate acid *1 By spot test Weigh sample and add alkaline solution Confirm the tested samples are totally dissolved Negative *2 Get 50cm 2 sample Definite temp. extraction Make up with deionized water Boiling water extraction Cool and filter the extract Analyzed by ICP-OES Make up with deionized water and add diphenyl-carbazide solution Remarks: *1: List of Appropriate Acid: Material Acid Added for Digestion Polymers HNO 3,HCl,HF,H 2 O 2,H 3 BO 3 Metals HNO 3,HCl,HF Electronics HNO 3,HCl,H 2 O 2,HBF 4 Analyzed by UV-VIS *2: If the result of spot test is positive, Chromium VI would be determined as detected. *THJ * Page 3 of 6

17 Test Conducted Number: TWNC End of Report This report is made solely on the basis of your instructions and/or information and materials supplied by you. It is not intended to be a recommendation for anyparticular course of action. Intertek does not accept a duty of care or any other responsibility to any person other than the Client in respect of this report and onlyaccepts liability to the Client insofar as is expressly contained in the terms and conditions governing Intertek's provision of services to you. Intertek makes nowarranties or representations either express or implied with respect to this report save as provided for in those terms and conditions. We have aimed to conductthe Review on a diligent and careful basis and we do not accept any liability to you for any loss arising out of or in connection with this report, in contract, tort, by statute or otherwise, except in the event of our gross negligence or wilful misconduct. *THJ * Page 4 of 6

18 Test Report Number: SHA-001 Applicant: Applicant: Littelfuse Littelfuse Philippines Philippines Inc. Inc. Date: Date: Jan. Jan. 21, , 2014 Applicant: LIMA LIMA ELSCHUKOM Technology ELEKTROSCHUTZKOMPONENTENBAU Center, Center, Lipa Lipa City, City, GMBH Date: Jan. 21, 2014 Malvar, GEWERBESTRASSE Batangas 87, D-98669, VEILSDORF, GERMANY Sample Description: One (1) submitted sample said to be: Item Name : Wires with plating Item No. : silver plated copper wire Cu, Ag--% Country of Origin : GERMANY ***************************************************************************************************************************************************** Tests conducted: As requested by the applicant, for details refer to attached page(s). ***************************************************************************************************************************************************** Conclusion: Tested sample Standard Result Tested components of submitted sample Restriction of the use of certain hazardous substance in electrical and electronic equipment (RoHS Directive 2011/65/EU) See Test Conducted ***************************************************************************************************************************************************** To be continued Prepared and check by: For Intertek Testing Services Ltd., Shanghai Authorized by: For Intertek testing services Ltd., Shanghai Joy Zhou Jonny Jing Manager Intertek Testing Services Ltd., Shanghai Page 1 of 6 Block B, Jinling Business Square, No.801 YiShan Road, Shanghai, China B Telephone: Facsimile:

19 Tests Conducted Number: SHA-001 (A) Test result of RoHS Directive: Testing item Cadmium (Cd) content (mg/kg) /plating Lead (Pb) content (mg/kg) /plating Mercury (Hg) content (mg/kg) /plating Chromium (VI)(Cr 6+ ) result (by boiling water extraction on metal) (mg/kg with 50cm 2 ) /plating Result (1) ND ND ND ND Testing item Cadmium (Cd) content (mg/kg) Lead (Pb) content (mg/kg) Mercury (Hg) content (mg/kg) Chromium (VI)(Cr 6+ ) result (by boiling water extraction on metal) (mg/kg with 50cm 2 ) Result (2) ND ND ND ND Remark mg/kg with 50cm 2 = milligram per kilogram with 50 square centimeter ND = not detected Tested components: (1) Silver color metal wire plating (2) Silver color metal wire substrate (B) RoHS Requirement: Restricted substances Cadmium (Cd) Lead (Pb) Mercury (Hg) Chromium (VI) (Cr 6+ ) Limits 0.01% (100 mg/kg) 0.1% (1000 mg/kg) 0.1% (1000 mg/kg) 0.1% (1000 mg/kg) The above limits were quoted from RoHS Directive 2011/65/EU for homogeneous material. *********************************************************************************************************************************************** To be continued Intertek Testing Services Ltd., Shanghai Page 2 of 6 Block B, Jinling Business Square, No.801 YiShan Road, Shanghai, China B Telephone: Facsimile:

20 Tests Conducted Number: SHA-001 (C) Test method: Testing item Testing method Reporting limit Cadmium (Cd) content Lead (Pb) content Mercury (Hg) content Chromium (VI) (Cr 6+ ) content (for metal) With reference to IEC Edition 1.0: 2013, by acid digestion until the tested sample was totally dissolved, and determined by ICP-OES. With reference to IEC Edition 1.0: 2013, by acid digestion until the tested sample was totally dissolved, and determined by ICP-OES. With reference to IEC Edition 1.0: 2013, by acid digestion until the tested sample was totally dissolved, and determined by ICP-OES. With reference to IEC Edition 1.0: 2008, by boiling water extraction and determined by UV-VIS Spectrophotometer. 2 mg/kg 2 mg/kg 2 mg/kg Positive/Negative (Threshold of 0.02mg/kg with 50cm 2 ) Date sample received: Jan. 13, 2014 Testing period: Jan. 13, 2014 To Jan. 16, 2014 ***************************************************************************************************************************************************** To be continued Intertek Testing Services Ltd., Shanghai Page 3 of 6 Block B, Jinling Business Square, No.801 YiShan Road, Shanghai, China B Telephone: Facsimile:

21 Tests Conducted Number: SHA-001 (D) Measurement flowchart Test for Cd/Pb/Hg/Cr (VI) contents Reference standardiec Edition &2013 Sampling/grinding or cutting Cd/Pb/Hg Metal Cr 6+ Polymers / electronics Weigh sample and for different material, digest the sample with appropriate acid *1 Spot test Weigh sample and add alkaline solution Positive *2 Confirm the tested samples are totally dissolved Yes No Get 50cm 2 samples Boiling water extraction Definite temp. Extraction Cool and filter the extract Make up with deionized water Analyzed by ICP-OES Make up with deionized water and add diphenyl-carbazide solution Analyzed by UV-VIS Remarks *1list of appropriate acid Material Acid added for digestion Polymers HNO 3,HCl,HF,H 2O 2,H 3BO 3 Metals HNO 3,HCl,HF Electronics HNO 3,HCl,H 2O 2,HBF 4 *2If the result of spot test is positive, Chromium VI would be determined as detected. **************************************************************************************************************************************************** To be continued Intertek Testing Services Ltd., Shanghai Page 4 of 6 Block B, Jinling Business Square, No.801 YiShan Road, Shanghai, China B Telephone: Facsimile:

22 Tests Conducted Number: SHA-001 **************************************************************************************************************************************************** To be continued Intertek Testing Services Ltd., Shanghai Page 5 of 6 Block B, Jinling Business Square, No.801 YiShan Road, Shanghai, China B Telephone: Facsimile:

23 Tests Conducted Number: SHA-001 *************************************************************************************************************************************************** End of report This report is made solely on the basis of your instructions and/or information and materials supplied by you. It is not intended to be a recommendation for any particular course of action. Intertek does not accept a duty of care or any other responsibility to any person other than the Client in respect of this report and only accepts liability to the Client insofar as is expressly contained in the terms and conditions governing Intertek's provision of services to you. Intertek makes no warranties or representations either express or implied with respect to this report save as provided for in those terms and conditions. We have aimed to conduct the Review on a diligent and careful basis and we do not accept any liability to you for any loss arising out of or in connection with this report, in contract, tort, by statute or otherwise, except in the event of our gross negligence or wilful misconduct. Intertek Testing Services Ltd., Shanghai Page 6 of 6 Block B, Jinling Business Square, No.801 YiShan Road, Shanghai, China B Telephone: Facsimile:

24 Intertek Consumer Goods GmbH Würzburger Straße Fürth Littelfuse Polyfil AG Philippines Inc. Arsenio Gina Gregorio M. Cesista Jr. Jr. LIMA Oberallmendstrasse Technology Center, 20A SEZ Malvar Zug / Switzerland // Batangas Fürth, Test report No. FUHL E Testing of a material sample according to the RoHS directive 2011/65/EC Sample description: Ni42Fe58MCuMAg wire; part no. HL26351 Arrival in lab: ; Period of XRF analysis incl. sample preparation and photo documentation: Period of analysis for the reorder: Head of Inorganic Lab: Claudia List Copying this test report is permitted only in agreement with the contracted lab. The test results refer only to the tested item. This report consists of 6 page(s). The test methods signed with * are not listed in the attachment of the accreditation certificate. Conclusion based on tested item Test order Status testing according to the RoHS directive 2011/65/EC pass Please see overview of test results - Test results see next pages - Intertek Consumer Goods GmbH Tel.: Sitz Fürth Geschäftsführer Würzburger Straße 152 Fax: Amtsgericht Fürth, HRB 5756 Kay Grönhardt Fürth, Germany cg.germany@intertek.com USt-IdNr. DE Jan-Jörg Müller-Seiler Durch die DAkkS nach DIN EN ISO/IEC akkreditiertes Prüflaboratorium Die Akkreditierung gilt für die in der Urkunde aufgeführten Prüfverfahren.

25 Sample description: Ni42Fe58MCuMAg wire; part no. HL26351 nm = non Metal M = Metal cm = composite Material List of component parts: Sample No. Part No. Material Description M Ni42Fe58MCuMAg wire; part no. HL26351 Photo: Comment LOD BL OL X CS = Limit of Detection = Below Limit = Over Limit = Inconclusive, further test necessary = Standard deviation = Composite sample Remark: Results were obtained by EDXRF for primary screening. Additional chemical testing using ICP (for Cd, Pb), AAS (for Hg), IC-UC/VIS (for CrVI) and GC/MS (for PBBs/PBDEs) are recommended, if the concentration exceeds the below warning value according to IEC Element Unit non - metal metal Cd mg / kg BL (70-3) < X < (130+3) OL BL (70-3) < X < (130+3) OL Pb mg / kg BL (700-3) < X < (1300+3) OL BL (700-3) < X < (1300+3) OL Hg mg / kg BL (700-3) < X < (1300+3) OL BL (700-3) < X < (1300+3) OL Br mg / kg BL (300-3) < X -- Cr mg / kg BL (700-3) < X BL (700-3) < X Element Unit composite material Cd mg / kg LOD < X < (150+3) OL Pb mg / kg BL (500-3) < X < (1500+3) OL Hg mg / kg BL (500-3) < X < (1500+3) OL Br mg / kg BL (250-3) < X Cr mg / kg BL (500-3) < X Intertek Consumer Goods GmbH Tel.: Sitz Fürth Geschäftsführer Würzburger Straße 152 Fax: Amtsgericht Fürth, HRB 5756 Kay Grönhardt Fürth, Germany cg.germany@intertek.com Ust-IdNr. DE Jan-Jörg Müller-Seiler

26 Sample description: Ni42Fe58MCuMAg wire; part no. HL XRF screening Method: XRF according to IEC 62321:2008* Sample No. Part No. Pb Hg Cd Cr total Br Status BL BL BL BL -- pass Analysis of reorder 2. Analysis of metals by ICP-MS, results in mg/kg Method: Pb, Cd, Cr: DIN EN ISO ** Digestion: with conc. HNO 3 + HCl** Detection limit: Pb 0.5 mg/kg, Cd 0.2 mg/kg, Cr 1 mg/kg, Hg: 0.1 mg/kg Sample No. Part No. Pb Hg Cd Cr total Status <1 < 0.2 < pass Comment: Elements Lead (Pb) Mercury (Hg) Cadmium (Cd) Chromium VI (Cr VI) Polybrominated Biphenyle (PBBs) Polybrominated Diphenyl ether (PBDEs) RoHS-limit value 1000 mg/kg 1000 mg/kg 100 mg/kg 1000 mg/kg 1000 mg/kg 1000 mg/kg - Flow charts see next page(s) - Intertek Consumer Goods GmbH Tel.: Sitz Fürth Geschäftsführer Würzburger Straße 152 Fax: Amtsgericht Fürth, HRB 5756 Kay Grönhardt Fürth, Germany cg.germany@intertek.com Ust-IdNr. DE Jan-Jörg Müller-Seiler

27 Test procedure Intertek Consumer Goods GmbH Tel.: Sitz Fürth Geschäftsführer Würzburger Straße 152 Fax: Amtsgericht Fürth, HRB 5756 Kay Grönhardt Fürth, Germany cg.germany@intertek.com Ust-IdNr. DE Jan-Jörg Müller-Seiler

28 Verification test procedure Intertek Consumer Goods GmbH Tel.: Sitz Fürth Geschäftsführer Würzburger Straße 152 Fax: Amtsgericht Fürth, HRB 5756 Kay Grönhardt Fürth, Germany cg.germany@intertek.com Ust-IdNr. DE Jan-Jörg Müller-Seiler

29 Intertek Consumer Goods GmbH Würzburger Straße Fürth Germany Polyfil Littelfuse AG Philippines Inc. Gina Arsenio Gregorio M. Cesista Jr. Jr. Oberallmendstrasse LIMA Technology Center, 20A SEZ Malvar Zug / Switzerland // Batangas Fürth, Test report No. FUHLP Testing of a material sample according to the RoHS directive 2011/65/EC Sample description: Ni42FeMCuMSn Arrival in lab: ; Period of analysis: Head of Inorganic Lab: Claudia List Copying this test report is permitted only in agreement with the contracted lab. The test results refer only to the tested item. This report consists of 6 page(s). The test methods signed with * are not listed in the attachment of the accreditation certificate. Conclusion based on tested item Test order Status testing according to the RoHS directive 2011/65/EC pass Please see overview of test results - Test results see next pages - Intertek Consumer Goods GmbH Tel.: Sitz Fürth Geschäftsführer Würzburger Straße 152 Fax: Amtsgericht Fürth, HRB 5756 Kay Grönhardt Fürth, Germany cg.germany@intertek.com USt-IdNr. DE Jan-Jörg Müller-Seiler Durch die DAkkS nach DIN EN ISO/IEC akkreditiertes Prüflaboratorium Die Akkreditierung gilt für die in der Urkunde aufgeführten Prüfverfahren.

30 Sample description: Ni42FeMCuMSn nm = non Metal M = Metal cm = composite Material List of component parts: Sample No. Part No. Material Description M Tinned copper plated nickel-iron wire Photo: Sample No Part No. 1 Analysis of metals by ICP-MS, results in mg/kg Method: Pb, Cd, Cr: DIN EN ISO ** Digestion: with conc. HNO 3 + HCl** Detection limit: Pb 5.0 mg/kg, Cd 1.0 mg/kg, Cr 10 mg/kg, Hg: 0.5 mg/kg Sample No. Part No. Pb Hg Cd Cr total Status <0.5 < pass Comment: Elements Lead (Pb) Mercury (Hg) Cadmium (Cd) Chromium VI (Cr VI) Polybrominated Biphenyle (PBBs) Polybrominated Diphenyl ether (PBDEs) RoHS-limit value 1000 mg/kg 1000 mg/kg 100 mg/kg 1000 mg/kg 1000 mg/kg 1000 mg/kg - Flow charts see next page(s) - Intertek Consumer Goods GmbH Tel.: Sitz Fürth Geschäftsführer Würzburger Straße 152 Fax: Amtsgericht Fürth, HRB 5756 Kay Grönhardt Fürth, Germany cg.germany@intertek.com Ust-IdNr. DE Jan-Jörg Müller-Seiler

31 Test procedure Intertek Consumer Goods GmbH Tel.: Sitz Fürth Geschäftsführer Würzburger Straße 152 Fax: Amtsgericht Fürth, HRB 5756 Kay Grönhardt Fürth, Germany cg.germany@intertek.com Ust-IdNr. DE Jan-Jörg Müller-Seiler

32 Verification test procedure Intertek Consumer Goods GmbH Tel.: Sitz Fürth Geschäftsführer Würzburger Straße 152 Fax: Amtsgericht Fürth, HRB 5756 Kay Grönhardt Fürth, Germany cg.germany@intertek.com Ust-IdNr. DE Jan-Jörg Müller-Seiler

33 Number : TWNC Applicant: Littelfuse Philippines Inc. Date : Apr 15, 2014 LIMA Technology Center, Lipa City, Malvar, Batangas Sample Description: One (1) group of submitted samples said to be : Part Description : Ink-Black Part Number : Date Sample Received : Apr 09, 2014 Date Test Started : Apr 09, 2014 Test Conducted : As requested by the applicant, for details please refer to attached pages. Authorized by: On Behalf of Intertek Testing Services Taiwan Limited K. Y. Liang Director *THJ * Page 1 of 12

34 Test Conducted Number: TWNC Test Result Summary: Test Item Unit Test Method Result Submitted samples RL Heavy Metal Cadmium (Cd) content ppm With reference to IEC : 2013, by microwave or acid digestion and determined by ND 2 ICP-OES. Lead (Pb) content ppm With reference to IEC : 2013, by microwave or acid digestion and determined by ND 2 ICP-OES. Mercury (Hg) content ppm With reference to IEC : 2013, by microwave or acid digestion and determined by ND 2 ICP-OES. Chromium VI (Cr 6+ ) content ppm With reference to IEC 62321: 2008, by alkaline digestion and determined by UV-Vis Spectrophotometer. ND 1 Polybrominated Biphenyls (PBBs) Monobrominated Biphenyls (MonoBB) Dibrominated Biphenyls (DiBB) Tribrominated Biphenyls (TriBB) Tetrabrominated Biphenyls (TetraBB) With reference to IEC 62321: Pentabrominated Biphenyls ppm 2008, by solvent extraction ND 5 (PentaBB) and determined by GC-MS and Hexabrominated Biphenyls ppm further HPLC-DAD confirmation ND 5 (HexaBB) when necessary. Heptabrominated Biphenyls (HeptaBB) Octabrominated Biphenyls (OctaBB) Nonabrominated Biphenyls (NonaBB) Decabrominated Biphenyl (DecaBB) ppm ND 5 *THJ * Page 2 of 12

35 Test Conducted Number: TWNC Test Item Unit Test Method Result Submitted samples Polybrominated Diphenyl Ethers (PBDEs) Monobrominated Diphenyl Ethers (MonoBDE) Dibrominated Diphenyl Ethers (DiBDE) Tribrominated Diphenyl Ethers (TriBDE) Tetrabrominated Diphenyl Ethers (TetraBDE) With reference to IEC 62321: Pentabrominated Diphenyl ppm 2008, by solvent extraction ND 5 Ethers (PentaBDE) and determined by GC-MS and Hexabrominated Diphenyl ppm further HPLC-DAD confirmation ND 5 Ethers (HexaBDE) when necessary. Heptabrominated Diphenyl Ethers (HeptaBDE) Octabrominated Diphenyl Ethers (OctaBDE) Nonabrominated Diphenyl Ethers (NonaBDE) Decabrominated Diphenyl Ether (DecaBDE) ppm ND 5 Halogen Content Fluorine (F) ppm With reference to EN ND 50 Chlorine (Cl) ppm 14582:2007 by combustion ND 50 bomb with oxygen and Bromine (Br) 0 determined by Ion Iodine (I) ppm Chromatography. ND 50 Phthalates Di(2-ethylhexyl) Phthalate ppm ND 10 (DEHP) With reference to EN 14372: Dibutyl Phthalate ppm 2004, by solvent extraction ND 10 (DBP) and determined by GC-MS. Benzyl Butyl Phthalate ppm ND 10 (BBP) RL *THJ * Page 3 of 12

36 Test Conducted Number: TWNC Others Test Item Unit Test Method Hexabromocyclododecane (HBCDD) Perfluorooctane Sulfonates (PFOS) Perfluorooctanoic Acid (PFOA) ppm ppm ppm With reference to USEPA 3540C, by solvent extraction and determined by GC-MS. With reference to CEN/TS 15968:2010, by solvent extraction and determined by LC-MS-MS. With reference to CEN/TS 15968:2010, by solvent extraction and determined by LC-MS-MS. Result Submitted samples RL ND 10 ND 1 ND 1 Remarks: ppm = Parts per million based on wet weight of tested sample = mg/kg ND = Not detected RL = Reporting limit, quantitation limit of analyte in sample Responsibility of Chemist: Ryan Lin/ Pelny Hsiao/ Vico Lin Date Sample Received : Apr 09, 2014 Test Period : Apr 09, 2014 to Apr 14, 2014 RoHS Limit Restricted Substances Limits Cadmium (Cd) content 0.01% (100ppm) Lead (Pb) content 0.1% (1000ppm) Mercury (Hg) content 0.1% (1000ppm) Chromium VI (Cr 6+ ) content 0.1% (1000ppm) Polybrominated Biphenyls (PBBs) 0.1% (1000ppm) Polybrominated Diphenyl Ethers (PBDEs) 0.1% (1000ppm) The above limits were quoted from Annex II of 2011/65/EU for homogeneous material. *THJ * Page 4 of 12

37 Test Conducted Measurement Flowchart: Test for Cd/Pb/Hg/Chromium (VI)/PBBs/PBDEs Contents Reference Standard:Cd/Pb: IEC :2013; Hg: IEC :2013; Chromium (VI)/PBBs/PBDEs: IEC 62321:2008 Number: TWNC For non-metal part Sample preparation For metal part Take sample and immerse into Aqua Regia, start to etch plating layer Stop the etching procedure upon color change completely Take the Aqua solution as plating component and etched body as substrate component PBBs/PBDEs Cr 6+ Cd/Pb/Hg Substrate Plating Weigh sample and add organic solvent Weigh sample and add alkaline solution For different material, digest the sample with appropriate acid *1 Cr 6+ By solvent extraction By spot test Definite temp. extraction Confirm the tested samples are totally dissolved Get 50cm 2 sample Negative *2 Concentrate the extract and make up with organic solvent Cool and filter the extract Make up with deionized water By boiling water extraction Analyzed by GC-MS Analyzed by ICP-OES Make up with deionized water and add diphenyl-carbazide solution Remarks: *1: List of Appropriate Acid: Material Acid Added for Digestion Polymers HNO 3,HCl,HF,H 2 O 2,H 3 BO 3 Metals HNO 3,HCl,HF Electronics HNO 3,HCl,H 2 O 2,HBF 4 Analyzed by UV-VIS *2: If the result of spot test is positive, Chromium VI would be determined as detected. *THJ * Page 5 of 12

38 Test Conducted Measurement Flowchart: Test for Halogen Contents Reference Method:EN Number: TWNC Sampling Add absorbent in a combustion bomb & place weighed sample into sample cup Fill oxygen into the combustion bomb Ignite then leave the bomb at room temperature Transfer the absorbent into a volumetric flask Make up with deionized water Analyzed by Ion Chromatography *THJ * Page 6 of 12

39 Test Conducted Measurement Flowchart: Number: TWNC Test for Phthalates Contents Reference Method: EN 14372: 2004 Sampling Weigh sample and add organic solvent By solvent extraction Concentrate the extract and make up with organic solvent Analyzed by GC-MS *THJ * Page 7 of 12

40 Test Conducted Measurement Flowchart: Test for Hexabromocyclododecane (HBCDD) Content Reference Method:USEPA 3540C Number: TWNC Sampling Weigh sample and add organic solvent By solvent extraction Concentrate the extract and make up with organic solvent Analyzed by GC-MS *THJ * Page 8 of 12

41 Test Conducted Measurement Flowchart: Number: TWNC Test for Perfluorooctane Sulfonates (PFOS) / Perfluorooctanoic Acid (PFOA) Contents Reference Method: CEN/TS 15968:2010 Sampling Get appropriate weigh or surface of sample and add organic solvent By solvent extraction Concentrate the extract and make up with organic solvent Analyzed by LC-MS-MS *THJ * Page 9 of 12

42 Test Conducted Number: TWNC End of Report This report is made solely on the basis of your instructions and/or information and materials supplied by you. It is not intended to be a recommendation for anyparticular course of action. Intertek does not accept a duty of care or any other responsibility to any person other than the Client in respect of this report and onlyaccepts liability to the Client insofar as is expressly contained in the terms and conditions governing Intertek's provision of services to you. Intertek makes nowarranties or representations either express or implied with respect to this report save as provided for in those terms and conditions. We have aimed to conductthe Review on a diligent and careful basis and we do not accept any liability to you for any loss arising out of or in connection with this report, in contract, tort, by statute or otherwise, except in the event of our gross negligence or wilful misconduct. *THJ * Page 10 of 12

43 Number: TWNC *THJ * Page 11 of 12

44 Number: TWNC *THJ * Page 12 of 12

45 Number : TWNC Applicant: Littelfuse Philippines Inc. Date : Sep 12, 2013 LIMA Technology Center, Lipa City, Malvar, Batangas Sample Description: One (1) group of submitted samples said to be : Part Description : Solder Part Number : Date Sample Received : Sep 06, 2013 Date Test Started : Sep 09, 2013 Test Conducted : As requested by the applicant, for details please refer to attached pages. Authorized by: On Behalf of Intertek Testing Services Taiwan Limited K. Y. Liang Director *THJ * Page 1 of 6

46 Test Conducted Number: TWNC Test Result Summary: Heavy Metal Test Item Unit Test Method Cadmium (Cd) content Lead (Pb) content Mercury (Hg) content Chromium VI (Cr 6+ ) content ppm ppm ppm mg/kg with 50 cm 2 With reference to IEC 62321: 2008, by microwave digestion and determined by ICP-OES. With reference to IEC 62321: 2008, by microwave digestion and determined by ICP-OES. With reference to IEC 62321: 2008, by microwave digestion and determined by ICP-OES. With reference to IEC 62321: 2008, by boiling water extraction and determined by UV-Vis Spectrophotometer. Result Silvery metal RL ND ND 2 Negative 0.02 Remarks: ppm = parts per million based on weight of tested sample = mg/kg ND = Not detected RL = Reporting Limit, Quantitation limit of analyte in sample mg/kg with 50cm 2 = milligram per kilogram with 50 square centimeter Negative = A negative test result indicated positive observation was not found at the time of test. Responsibility of Chemist: Kevin Liu/ Irene Chiou Date Sample Received : Sep 06, 2013 Test Period : Sep 09, 2013 to Sep 11, 2013 RoHS Limit Restricted Substances Limits Cadmium (Cd) content 0.01% (100ppm) Lead (Pb) content 0.1% (1000ppm) Mercury (Hg) content 0.1% (1000ppm) Chromium VI (Cr 6+ ) content 0.1% (1000ppm) The above limits were quoted from Annex II of 2011/65/EU for homogeneous material. *THJ * Page 2 of 6

47 Test Conducted Measurement Flowchart: Test for Cd/Pb/Hg/Chromium (VI) Reference Method: IEC edition 1.0:2008 Number: TWNC Sampling Cd/Pb/Hg Metal Cr 6+ Polymers / Electronics For different material, digest the sample with appropriate acid *1 By spot test Weigh sample and add alkaline solution Confirm the tested samples are totally dissolved Negative *2 Get 50cm 2 sample Definite temp. extraction Make up with deionized water Boiling water extraction Cool and filter the extract Analyzed by icp-oes Make up with deionized water and add diphenyl-carbazide solution Remarks: *1: List of Appropriate Acid: Material Acid Added for Digestion Polymers HNO 3,HCl,HF,H 2 O 2,H 3 BO 3 Metals HNO 3,HCl,HF Electronics HNO 3,HCl,H 2 O 2,HBF 4 Analyzed by UV-VIS *2: If the result of spot test is positive, Chromium VI would be determined as detected. *THJ * Page 3 of 6

48 Test Conducted Number: TWNC End of Report This report is made solely on the basis of your instructions and/or information and materials supplied by you. It is not intended to be a recommendation for anyparticular course of action. Intertek does not accept a duty of care or any other responsibility to any person other than the Client in respect of this report and onlyaccepts liability to the Client insofar as is expressly contained in the terms and conditions governing Intertek's provision of services to you. Intertek makes nowarranties or representations either express or implied with respect to this report save as provided for in those terms and conditions. We have aimed to conductthe Review on a diligent and careful basis and we do not accept any liability to you for any loss arising out of or in connection with this report, in contract, tort, by statute or otherwise, except in the event of our gross negligence or wilful misconduct. *THJ * Page 4 of 6

49 Test Report Number: SHA-005 Applicant: Applicant: Littelfuse Littelfuse Philippines Philippines Inc. Inc. Date: Date: Jan. Jan. 21, , 2014 Applicant: LIMA LIMA ELSCHUKOM Technology ELEKTROSCHUTZKOMPONENTENBAU Center, Center, Lipa Lipa City, City, GMBH Date: Jan. 21, 2014 Malvar, GEWERBESTRASSE Batangas 87, D-98669, VEILSDORF, GERMANY Sample Description: One (1) submitted sample said to be: Item Name : Wires with plating Item No. : tin plated copper plated copper nickel alloy wire Elcon30, Sn--% Country of Origin : GERMANY ***************************************************************************************************************************************************** Tests conducted: As requested by the applicant, for details refer to attached page(s). ***************************************************************************************************************************************************** Conclusion: Tested sample Standard Result Tested components of submitted sample Restriction of the use of certain hazardous substance in electrical and electronic equipment (RoHS Directive 2011/65/EU) See Test Conducted ***************************************************************************************************************************************************** To be continued Prepared and check by: For Intertek Testing Services Ltd., Shanghai Authorized by: For Intertek testing services Ltd., Shanghai Joy Zhou Jonny Jing Manager Intertek Testing Services Ltd., Shanghai Page 1 of 6 Block B, Jinling Business Square, No.801 YiShan Road, Shanghai, China B Telephone: Facsimile:

50 Tests Conducted Number: SHA-005 (A) Test result of RoHS Directive: Testing item Cadmium (Cd) content (mg/kg) /plating Result Lead (Pb) content (mg/kg) /plating 28 Mercury (Hg) content (mg/kg) /plating Chromium (VI)(Cr 6+ ) result (by boiling water extraction on metal) (mg/kg with 50cm 2 ) /plating (1) ND ND ND Testing item Cadmium (Cd) content (mg/kg) Lead (Pb) content (mg/kg) Mercury (Hg) content (mg/kg) Chromium (VI)(Cr 6+ ) result (by boiling water extraction on metal) (mg/kg with 50cm 2 ) Result (2) ND ND ND ND Remark mg/kg with 50cm 2 = milligram per kilogram with 50 square centimeter ND = not detected Tested components: (1) Silver color metal wire plating (2) Silver color metal wire substrate (B) RoHS Requirement: Restricted substances Cadmium (Cd) Lead (Pb) Mercury (Hg) Chromium (VI) (Cr 6+ ) Polybrominated biphenyls (PBBs) Polybrominated diphenyl ethers (PBDEs) Limits 0.01% (100 mg/kg) 0.1% (1000 mg/kg) 0.1% (1000 mg/kg) 0.1% (1000 mg/kg) 0.1% (1000 mg/kg) 0.1% (1000 mg/kg) The above limits were quoted from RoHS Directive 2011/65/EU for homogeneous material. *********************************************************************************************************************************************** To be continued Intertek Testing Services Ltd., Shanghai Page 2 of 6 Block B, Jinling Business Square, No.801 YiShan Road, Shanghai, China B Telephone: Facsimile:

51 Tests Conducted Number: SHA-005 (C) Test method: Testing item Testing method Reporting limit Cadmium (Cd) content Lead (Pb) content Mercury (Hg) content Chromium (VI) (Cr 6+ ) content (for metal) With reference to IEC Edition 1.0: 2013, by acid digestion until the tested sample was totally dissolved, and determined by ICP-OES. With reference to IEC Edition 1.0: 2013, by acid digestion until the tested sample was totally dissolved, and determined by ICP-OES. With reference to IEC Edition 1.0: 2013, by acid digestion until the tested sample was totally dissolved, and determined by ICP-OES. With reference to IEC Edition 1.0: 2008, by boiling water extraction and determined by UV-VIS Spectrophotometer. 2 mg/kg 2 mg/kg 2 mg/kg Positive/Negative (Threshold of 0.02mg/kg with 50cm 2 ) Date sample received: Jan. 13, 2014 Testing period: Jan. 13, 2014 To Jan. 16, 2014 ***************************************************************************************************************************************************** To be continued Intertek Testing Services Ltd., Shanghai Page 3 of 6 Block B, Jinling Business Square, No.801 YiShan Road, Shanghai, China B Telephone: Facsimile:

52 Tests Conducted Number: SHA-005 (D) Measurement flowchart Test for Cd/Pb/Hg/Cr (VI) contents Reference standardiec Edition &2013 Sampling/grinding or cutting Cd/Pb/Hg Metal Cr 6+ Polymers / electronics Weigh sample and for different material, digest the sample with appropriate acid *1 Spot test Weigh sample and add alkaline solution Positive *2 Confirm the tested samples are totally dissolved Yes No Get 50cm 2 samples Boiling water extraction Definite temp. Extraction Cool and filter the extract Make up with deionized water Analyzed by ICP-OES Make up with deionized water and add diphenyl-carbazide solution Analyzed by UV-VIS Remarks *1list of appropriate acid Material Acid added for digestion Polymers HNO 3,HCl,HF,H 2O 2,H 3BO 3 Metals HNO 3,HCl,HF Electronics HNO 3,HCl,H 2O 2,HBF 4 *2If the result of spot test is positive, Chromium VI would be determined as detected. **************************************************************************************************************************************************** To be continued Intertek Testing Services Ltd., Shanghai Page 4 of 6 Block B, Jinling Business Square, No.801 YiShan Road, Shanghai, China B Telephone: Facsimile:

53 Tests Conducted Number: SHA-005 **************************************************************************************************************************************************** To be continued Intertek Testing Services Ltd., Shanghai Page 5 of 6 Block B, Jinling Business Square, No.801 YiShan Road, Shanghai, China B Telephone: Facsimile:

54 Tests Conducted Number: SHA-005 **************************************************************************************************************************************************** End of report This report is made solely on the basis of your instructions and/or information and materials supplied by you. It is not intended to be a recommendation for any particular course of action. Intertek does not accept a duty of care or any other responsibility to any person other than the Client in respect of this report and only accepts liability to the Client insofar as is expressly contained in the terms and conditions governing Intertek's provision of services to you. Intertek makes no warranties or representations either express or implied with respect to this report save as provided for in those terms and conditions. We have aimed to conduct the Review on a diligent and careful basis and we do not accept any liability to you for any loss arising out of or in connection with this report, in contract, tort, by statute or otherwise, except in the event of our gross negligence or wilful misconduct. Intertek Testing Services Ltd., Shanghai Page 6 of 6 Block B, Jinling Business Square, No.801 YiShan Road, Shanghai, China B Telephone: Facsimile: