2018 76 7 Vol. 76 No. 7 0 7 9 770567 735189
EDITORIAL BOARD AND ADVISORY BOARD OF ACTA CHIMICA SINICA (Alphabetically arranged) Editor-in-Chief ZHOU Qi-Lin( ) Nankai University Associate Editors CHEN Xiao-Ming( ) Sun Yat-sen University DING Kui-Ling( ) Shanghai Institute of Organic Chemisry, CAS HE Chuan( ) University of Chicago, USA SHUAI Zhi-Gang( ) Tsinghua University SUN Shi-Gang( ) Xiamen University TIAN He( ) East China University of Science and Technology WANG Li-Xiang( ) Changchun Institute of Applied Chemistry, CAS ZHAO Yu-Liang( ) National Center for Nanoscience and Technology Editorial Board CAI Qian( ) CHEN Chuan-Feng( ) CHEN Jun( ) CHEN Peng( ) CHEN Wei( ) CHEN Xiao-Ming( ) CUI Chun-Ming( ) DAI Zhi-Hui( ) DENG De-Hui( ) DENG Zhao-Xiang( ) DING Kui-Ling( ) FAN Chun-Hai( ) FAN Qing-Hua( ) FU Hong-Gang( ) FU Yao( ) GAO Chao( ) GONG Liu-Zhu( ) GONG Jin-Long( ) GUAN Zheng-Hui( ) HAN Hong-Wei( ) HAO Jing-Cheng( ) HE Chuan( ) HOU Jian-Hui( ) HU Jin-Bo( ) HU Min( ) HU Wen-Hao( ) HU Xian-Luo( ) HU Yong-Sheng( ) HU Zheng( ) HUANG Pei-Qiang( ) HUANG Wei-Yang( ) JIANG Hai-Long( ) JIANG Ying( ) JIANG Zhong-Yi( ) JIANG Xing-Yu( ) JIAO Ning( ) KANG Zhen-Hui( ) LEI Zi-Qiang( ) LI Zhan-Ting( ) LI Chun-Zhong( ) LI Jing-Hong( ) LI Jun-Bai( ) LI Xing-Wei( ) LI Yi( ) LI Zhen( ) LIU Dong-Sheng( ) LIU Guo-Sheng( ) LIU Jing-Fu( ) LIU Lei( ) LIU Shu-Shen( ) LIU Xiao-Gang( ) LIU Xiao-Hua( ) LIU Yi( ) LIU Yu( ) LIU Zhuang( ) LONG Yi-Tao( ) LÜ Long( ) MA Jun-An( ) MAI Li-Qiang( ) MAO Zong-Wan( ) MENG Qing-Bo( ) NIE Wan-Li( ) PAN Yuan-Jiang( ) PENG Hui-Sheng( ) PENG Xiao-Jun( ) QIN An-Jun( ) QIU Jie-Shan( ) QUAN Xie( ) SHI Bing-Feng( ) SHUAI Zhi-Gang( ) SONG Yan-Lin( ) SUN Shi-Gang( ) SUN Xiao-Ming( ) TANG Bo( ) TANG Zhi-Yong( ) TIAN He( ) TONG Ming-Liang( ) WANG Lian-Hui( ) WANG Bo( ) WANG Hai-Hui( ) WANG Ke( ) WANG Li-Xiang( ) WANG Mei-Xiang( ) WANG Shu-Tao( ) WANG Wei( ) WANG Xiang-Ke( ) WANG Xin-Chen( ) WANG Xun( ) WANG Zhao-Hui( ) WEI Min( ) WEI Zhi-Xiang( ) WEI Zi-Dong( ) WU Li-Zhu( ) XI Zhen-Feng( ) XIA Zhen-Hai( ) XIAO Wen-Jing( ) XIE Zhao-Xiong( ) XIONG Yu-Jie( ) XU Jing-Juan( ) YANG Shi-He( ) YOU Shu-Li( ) YU Chang( ) YU Biao( ) ZHAN Xiao-Wei( ) ZHANG Fan( ) ZHANG Jin( ) ZHANG Jun-Liang( ) ZHANG Li-Zhi( ) ZHANG Qiu-Yu( ) ZHANG Suo-Jiang( ) ZHANG Tie-Rui( ) ZHANG Wan-Bin( ) ZHANG Wei-Xian( ) ZHANG Xian-Zheng( ) ZHANG Xiao-Bing( ) ZHANG Xin-Bo( ) ZHAO Yi-Xin( ) ZHAO Yu-Liang( ) ZHENG Li-Min( ) ZHENG Nan-Feng( ) ZHOU Hao-Shen( ) ZHOU Jian( ) ZHOU Qi-Lin( ) ZHU Chen( ) ZHU Guang-Shan( ) ZHU Wei-Hong( ) ZHU Yong-Fa( ) Advisory Board AN Li-Jia( ) CHE Chi-Ming( ) DAI Li-Xin( ) FENG Shou-Hua( ) Henry N. C. WONG( ) HONG Mao-Chun( ) HU Ying( ) LI Le-Min( ) LIN Guo-Qiang( ) MA Sheng-Ming( ) SONG Li-Cheng( ) WAN Hui-Lin( ) WANG Er-Kang( ) YANG Yu-Liang( ) YAO Jian-Nian( ) ZHANG Yu-Kui( ) ZHAO Dong-Yuan( ) ZHAO Yu-Fen( ) ZHENG Lan-Sun( )
(Huaxue Xuebao) 76 7 2018 7 15......,, *,, 2018, 76(7), 501-514......, *,,,,,, 2018, 76(7), 515-525 Suzuki......,,, *,, *,, 2018, 76(7), 526-530 (TTF)...... *,,, 2018, 76(7), 531-536......,,,, *,,, 2018, 76(7), 537-542 MR-1 Cd......,, *,,, 2018, 76(7), 543-548 TiO 2......,,,, *,, 2018, 76(7), 549-555 (TNT)......,,, *,, 2018, 76(7), 556-563......,,, *,, 2018, 76(7), 564-574 *. Acta Chim. Sinica 2018, 76, 495 495 2018 Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences http://sioc-journal.cn 495
ACTA CHIMICA SINICA Vol. 76, No. 7 July 15, 2018 Contents On the cover: Tetrathiafulvalene (TTF) and its derivatives play important roles in self-assembly chemistry. Zhang Shangxi and co-workers have synthesized a series of flexible TTF derivatives. The C S bonds bridged TTF skeleton and terminal aryls of the molecules make the structures tunable via vibration upon and down the TTF central plane. The phenomenon could be observed by means of the X-ray diffraction of the molecule before and after assembling. [Zhang, Shangxi et al. on page 531-536.] Review Transition Metal Catalyzed Deoxydehydration of Alcohols Li, Cui; Zhang, Qi; Fu, Yao* Acta Chim. Sinica 2018, 76(7), 501-514 In this review, we detail the recent-evolutionary and efficient strategies of transition metal-catalyzed deoxydehydration of vicinal diols and polyols from renewable biomass sources into alkenes which could use as platform chemicals and fuels. Research Progress of Metallic Carbon Dioxide Batteries Chang, Shilei; Liang, Feng*; Yao, Yaochun; Ma, Wenhui; Yang, Bin; Dai, Yongnian Acta Chim. Sinica 2018, 76(7), 515-525 With the global climate becoming warm and the rapid development of the electric vehicle industry, the development of high-energy density metal carbon dioxide batteries are getting more and more attention. As a clean energy storage device, metal carbon dioxide batteries utilize carbon dioxide as resources, and provide technical support for human to explore Mars. This paper describes the research progress of metal carbon dioxide batteries in detail, and provides strategies for problems of this new battery system. 496 http://sioc-journal.cn 2018 Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences Acta Chim. Sinica 2018, 76, 496 499
Content Article Surface Enhanced Raman Spectroscopy Coupled with High Performance Liquid Chromatography for Real-time Monitoring of Suzuki Coupling Reaction Jiao, Cenlei; Wang, Wei; Liu, Jiao; Yuan, Yaxian*; Xu, Minmin; Yao, Jianlin* Acta Chim. Sinica 2018, 76(7), 526-530 The surface enhanced Raman spectroscopy (SERS) has been hyphenated with high performance liquid chromatography (HPLC), in which the individual advantages of high sensitivity of SERS and high efficiency in separation of HPLC were combined together, and it was extended successfully to real-time monitor of a Suzuki coupling reaction between 3-bromopyridine and phenylboronic acid. The SERS results were well associated with the chromatographic peaks in a certain duration. It indicated that the HPLC-SERS technique would be a promising tool as a complementary approach to traditional techniques (such as LC-MS) for on line monitoring the organic reaction processes. Flexible TTF Derivatives: Synthesis, Structure and Self-assembly Zhang, Shangxi*; Shao, Xiangfeng Acta Chim. Sinica 2018, 76(7), 531-536 Sulfur attached and aryls fused TTFs display unique properties in self-assembly chemistry due to the flexibility from C S bonds. In complex (TTF4)(C 60 ), the dihedral angle between the central C 2 S 4 plane and the terminal C 2 S 2 plane of the TTF framework change from 24.30 to 30.17 before and after assembly with C 60. Preparation and Characterization of Black Phosphorus Zhang, Dandan; Yuan, Zhenzhou; Zhang, Guoqing; Tian, Nan; Liu, Danmin*; Zhang, Yongzhe Acta Chim. Sinica 2018, 76(7), 537-542 Black phosphorus was prepared and characterized. The results show that black phosphorus with large size, good crystallinity, high purity, and high stability can be obtained by chemical vapor transport method. Acta Chim. Sinica 2018, 76, 496 499 2018 Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences http://sioc-journal.cn 497
$&7$ &+,0,&$ 6,1,&$ Content Shewanella oneidensis MR-1 Affects the Mechanism of Cd Electrodeposition on Glassy Carbon Electrode Lin, Weifen; Chen, Nianjia; You, Lexing*; Zhou, Shungui Acta Chim. Sinica 2018, 76(7), 543-548 In nature, microbes always affect the geochemical cycle of metal ion. In this work, the nucleation mechanism of Cd electrodeposition on glassy carbon electrode in the present of Shewanella oneidensis MR-1 was studied. MR-1 could influence the diffusion rate of Cd(II) from bulk solution to electrode surface and further change the nucleation mechanism of Cd(II)-Cd. This work would be beneficial to the environmental remedy of heavy metal ion. Influence Factors on the Microstructure of Ultrathin TiO2 Nanosheets Synthesized by Liquid Phase Method Chu, Wanyi; Tang, Xiao; Li, Zhen; Lin, Jingcheng; Qian, Jueshi* Acta Chim. Sinica 2018, 76(7), 549-555 At 0 4 ć, the hydrolysates of tetrabutyl titanate in the dilute nitric acid solution with an appropriate concentration can peptize into ultra-small nanoclusters and form a two-dimensional network structure under the effect of hydrogen bonds. After further aging, they become to be ultra-thin TiO2 nanosheets with a thickness smaller than 1 nm. Carbon-rich Clusters and Graphitelike Structure Formation during Early Detonation of 2,4,6-Trinitrotoluene (TNT) via Molecular Dynamics Simulation Zhang, Yaping; Yang, Zhen; Li, Qikai; He, Yuanhang* Acta Chim. Sinica 2018, 76(7), 556-563 498 http://sioc-journal.cn 2018 Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences Acta Chim. Sinica 2018, 76, 496 499
Content Aggregation in the Mixture of Branched Carboxylate Salts and Sulfonate Surfactants with Different Oligomeric Degrees Li, Haofei; Qiao, Fulin; Fan, Yaxun; Wang, Yilin* Acta Chim. Sinica 2018, 76(7), 564-574 The effects of branched carboxylate molecules on surface activities, micellization and emulsification ability of star-shaped oligomeric surfactants have been investigated. The results show that the addition of branched carboxylates can significantly reduce the surface tension at CMC, and the CMC values increase slightly with the increase of the carboxylate molar fraction. Moreover the addition of carboxylates into these two sulfonate surfactants leads to different aggregate transitions in the solution. These mixtures also show excellent performance in emulsification. Acta Chim. Sinica 2018, 76, 496 499 2018 Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences http://sioc-journal.cn 499
SCI ( ) Huaxue Xuebao ACTA CHIMICA SINICA (Monthly) 1933 (Founded in 1933) 76 7 Vol. 76 No. 7 2018 7 15 July 15, 2018 Supervised by Chinese Academy of Sciences Sponsored by The Chinese Chemical Society and Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences Editor-in-Chief: ZHOU Qi-Lin ( 345, 200032) Edited and Published by Editorial Office of Acta Chimica Sinica (345 Lingling Lu, Shanghai 200032, China) Printed by Shanghai Newcabo Business Printing Co., Ltd. Subscriptions Domestic: Local Post Offices ( 399 ) Foreign: China International Book Trading Corporation (P.O. Box 399, Beijing, China) http://sioc-journal.cn E-mail: hxxb@sioc.ac.cn ISSN 0567-7351 CN 31-1320/O6 4-209 M56 80.00 : 3100420130007 500 http://sioc-journal.cn 2018 Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences Acta Chim. Sinica 2018, 76, 500 500