Materials Research for Advanced Data Storage

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Materials Research for Advanced Data Storage University of Alabama Center for Materials for Information Technology Fall Review November 18, 2002

Center for Materials for Information Technology (MINT) at The University of Alabama A multidisciplinary research program focusing on new materials for advanced data storage. 22 faculty, 10 postdocs, and 40 graduate students from 7 academic programs in science and engineering. Support federal grants (including an NSF Materials Research Science & Engineering Center grant), industry (IBM, Seagate, Quantum, Sony, Fujitsu, Hitachi Maxell, INSIC), and University support.

Materials Research for Advanced Data Storage Fundamental Materials Problems in Magnetic Data Storage Storing Writing Reading Flexible Media Storage Molecular Storage Spintronics

TEM Images of Self-Assembled [Fe 49 Pt 51 ] 88 Ag 12 Nanoparticle Films (25 10 12 particles/in 2 ) Before Annealing Annealed at 400 o C for 30 min Contact: J.W. Harrell and Dave Nikles

Effect of Various Underlayers on Hc G/Underlayer(t nm)/fe65co35 (50 nm) Contact: Bill Doyle

AF(IrMn) CoFe CCP-CPP Spin Valves via Nano-Oxide Layers Cu Cu NOL (SiO 2 ) RA nom ~500m R/R~0.25% R CPP GMR device with current path constricted by nano-oxide layers increase R A MR transfer-curve observed for a CCP- CPP structure with a nominal area of 50µm 2. Contact: Hideo Fujiwara

Nanochannels via Nano-Oxide Layers (NOL) AF(IrMn) CoFe Cu Cu NOL (SiO 2 ) CPP GMR device with current path constricted by nano-oxide layers. RA nom ~500m R/R~0.25% R MR transfer-curve observed for a CCP-CPP structure with a nominal area of 50µm 2. Contact: Hideo Fujiwara

Particle Ordering In Flexible Media SANS Data Contact: JohnWiest Model Predictions

A Molecular Storage System RGD molecule 2-5 nm tip with voltage control + molecular storage layer (protective or adhesive layer) semi-conducting substrate + + + project goal: storage densities (2D) 10-100 Tb/in 2 Research Team Si Blackstock Greg Szulczewski

Contacts: Mankey, Schad, Zangari, Fujiwara Spin Transport in Confined Geometries Insulating layer with nanochannels Pinned layer Ni wires Cu lead Co Free layer 1-10 nm J σ Co Electrodes Nanochannels CPP GMR with Confined Current Paths Nanocontacts Very large magnetoresistance from nanoscale constrictions Cu lead Nanowires Spin transfer effect

Ilmenite-Hematite as Magnetic Semiconductors 150 Seebeck Coefficient ( µv/k) 100 50 0-50 - 100-150 p 0 0.1 0.2 0.3 0.4 0.5 n Composition x T=300K T=400K For 0.1< x < 0.5, I-H is ferrimagnetic and semiconducting. The magnetic properties depend on the degree of order of the cation lattice. Contacts: R. Schad and K. Pandey

Half-metallic ferromagnets Calculated electronic structure of CrO 2 - Only known stoichiometric binary oxide that is a conductive ferromagnet at 300 K. S. P. Lewis et al., Phys. Rev. B 55, 10253 (1997) - Known to be a half-metal, i.e., 98.4 % spin-polarized at E f. Contact: Greg Szulczewski

Half-metallic ferromagnets Proposed device structure metal 50nm CrO 2 (100) 1nm TiO 2 (100) 200nm CrO 2 (100) TiO 2 (100) Contact: Greg Szulczewski