Igneous petrology EOSC 321 Laboratory 8: Intermediate and Felsic Volcanic Rocks. Pyroclastic Rocks

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321 Lab 8 Instructor: L. Porritt - 1 - Igneous petrology EOSC 321 Laboratory 8: Intermediate and Felsic Volcanic Rocks. Pyroclastic Rocks Learning Goals. After this Lab, you should be able: Identify fine-grained igneous rock-forming minerals observed in the groundmass Estimate modal mineral abundances for minerals of different grain sizes (phenocrysts and groundmass) Name felsic and intermediate rocks based on their textures and groundmass or phenocryst mineralogy Identify mode of fragmentation of pyroclastic rocks based on the textural features of the ash and pyroclasts Describe degree of welding of welded pyroclastic material based textural observations Duration: You will receive a thin section of an unknown mafic volcanic rock for your independent 30 minute-examination. Draw a sketch of the key features of the rock and write its petrographic description, finally give it a rock name. You may use your previous lab notes, textbooks etc., but NO ELECTRONIC DEVICES! The remaining 2.5 hours of the lab you will be looking at felsic and intermediate volcanic rocks. This lab is to be completed within the lab period. Material Needed: a) Microscope, b) a Manual on Optical Mineralogy (i.e. Minerals in Thin Section by Perkins and Henke)

321 Lab 8 Instructor: L. Porritt - 2 -

TEST 4 Mafic Volcanic 321 Lab 8 Instructor: L. Porritt - 3 - Rocks Your Name: Magnification ID: Field of view width Student Description: Rock name:

321 Lab 8 Instructor: L. Porritt - 4 -

321 Lab 8 Instructor: L. Porritt - 5 - Introduction: This lab introduces intermediate and felsic volcanic rocks ranging in composition from andesite to rhyolite. These magmas often fragment to form pyroclastic rocks, therefore we devote the second, minor part of the Lab (~ 30 mins) to look at these. For classification of intermediate and felsic volcanics you should plot quartz, plagioclase and alkali feldspar modes in the "Volcanic" triangle (attached below). Classification of these rocks is difficult because viscous silicic magmas tend to solidify into glasses rather than crystallize. You can examine such glassy rocks in T/s's 302, 581 (pumices) and in T/s 765 (vitrophyric andesite). Later devitrification of these glasses produces fine-grained aggregates of felsic minerals. In the rocks where it is impossible to determine mineral abundances of phases in the groundmass, the rock classification must be based on phenocrysts. The IUGS recommends that rocks identified in such a manner be called PHENOTYPES (like pheno-latite). If based on phenocrysts, the position of a rock on classification triangles will be biased to more mafic and basic rocks and usually erroneous for the rock as a whole. In intermediate-silicic volcanics, plagioclase is usually the most abundant phenocryst phase and generally displays complex oscillatory zoning. When you examine thin sections with zoned plagioclase, you need to determine the magnitude of the zoning by determining the composition of the plagioclase in the core and in the rime of grains. Quartz is the next most common felsic mineral, whereas alkali feldspar is not common in calc-alkaline volcanic rocks and is restricted only to the alkaline series. Clear (not zoned or twinned) low birefringent phenocrysts could be quartz or K feldspar. To identify them, you need to recall conoscopy (see Lab 1). In the conoscopic view, see the movement of the interference figure for the mineral. If isogyres move vertically or horizontally, the mineral is uniaxial and therefore is quartz. If isogyres rotate and change the curvatures, the mineral is biaxial and therefore is K feldspar or plagioclase. Observe Quartz phenocrysts in T/s 765. In volcanic felsic rocks you can come across 2 varieties of K-Fsp: sanidine and anorthoclase. The latter is very rare. Sanidine may have simple Carlsbad twinning or may have no twinning at all. As a simple rule of thumb, you should call any volcanic K-Fsp sanidine. Amphiboles in andesites are strongly pleochroic hornblendes frequently showing intense opaque reaction rims due to low-pressure instability. When reddish-brown, the amphiboles are termed oxyhornblende. They are also distinguished from hornblende by their higher birefringence and lower extinction angles. Oxyhornblende is not a distinct mineral species, but a hornblende in which a substantial amount of iron has been oxidized to the Fe 3+ state and (OH) - is replaces by O2 _ to balance the charge. There is a continuous range of compositions and properties between members of the hornblende and oxyhornblende. Conventional hornblende can be converted to oxyhornblende by heating in an oxydizing environment, and the process may be reversed by heating in a reduced environment.

321 Lab 8 Instructor: L. Porritt - 6 - Make sure you see rhyolite with spherulitic textures (T/s 866) characteristic of felsic volcanics. Spherulites are spheroidal bodies in a rock composed of an aggregate of fibrous crystals of one or more minerals radiating from a nucleus, with glass or crystals in between. The most common occurrence of spherulitic texture is a radiating aggregate of acicular alkali feldspars with glass between them, though quartz or other mineral may also be present, resulting in the intergrowth texture. The colour variation in the spherulites is caused by variations in the density of fibres. Make sure that you see the following minerals and textures in the Reference Collection for Intermediate-Felsic Volcanics: Oxyhornblende Sanidine, with or without simple twinning Conoscopic evidence for quartz Trachytic, vitrophiric, spherulitic, perlitic amd pumiceous (in the order of importance)

321 Lab 8 Instructor: L. Porritt - 7 - Activity I There are several hand specimens of felsic and intermediate volcanic rocks available in the lab. Examine all of them and write down a list of the phenocrysts you can observe in hand specimen for each sample. Give each rock an appropriate rock name. P631, P581, P1580, P242, P1254, P514, P2067, P2441 Activity II Now we will examine these felsic and intermediate volcanic rocks under the microscope. Examine one thin section from each of the following groups and provide a sketch, rock description and rock name. 1) 1245, 765, 1448, 722, 2) 1465 3) 1006 4) 302, 581, 866,

321 Lab 8 Instructor: L. Porritt - 8 - Thin section Magnification Field of view width Description: Rock name:

321 Lab 8 Instructor: L. Porritt - 9 - Thin section Magnification Field of view width Description: Rock name:

321 Lab 8 Instructor: L. Porritt - 10 - Thin section Magnification Field of view width Description: Rock name:

321 Lab 8 Instructor: L. Porritt - 11 - Thin section Magnification Field of view width Description: Rock name:

321 Lab 8 Instructor: L. Porritt - 12 - Activity III Pyroclastic materials form through the fragmentation of magma either due to: 1) rupturing of bubble walls through the over pressure and expansion of magmatic gases giving bubble wall ash shards and highly vesicular glassy pyroclasts; 2) through the quench-fragmentation of lavas due to the interaction of lavas with large volumes of water in a sub-aqueous environment giving coarse angular particles of weakly vesicular glassy material; 3) or through the rapid quenching and explosive interaction of magma and smaller volumes of surface or ground-water in phreatomagmatic eruptions giving fine grained glassy ash, that has a blocky appearance which may stick together forming ash aggregates, and pyroclasts that have a wide range of vesicularities. Look at the following pyroclastic rocks and determine the mode of fragmentation of the material, the composition of the rock, and draw sketches of the features that have allowed you to determine this. How explosive do you think the eruptions were that produced these rocks? MM93-7, MSS-RX, KAS-3A and KAS-3B

321 Lab 8 Instructor: L. Porritt - 13 -

321 Lab 8 Instructor: L. Porritt - 14 - Activity IV Now look at the group of seven thin sections marked WT-85-?? These were all taken at different heights through a welded ash flow tuff deposit, but display different degrees of welding. Rock Explanation: This tuff formed as a pyroclastic flow deposit. It is from a unique ash flow deposit the Walcott tuff in Idaho. The hand samples from this tuff look to be lava flows. Some of them are even very similar to obsidian in character. However, if one looks close enough with a hand lens, small ash particles can be seen. These rocks are comprised of millions of tiny ash shards that have welded together because they were still above their glass transition when the pyroclastic flow came to rest. Most welded tuffs have distinct flattened pumice, or fiamme, which make them obvious in hand sample. (See other hand samples fiamme are elongated aligned material different from the matrix). In thin section it is obvious that these rocks are fragmental. Many glass shards are present in different stages of compaction. Originally, the glass shards were bubble walls. Hence, in a slightly welded deposit where very little compaction has occurred the shards will retain their shapes. These shapes will either be hollow circles (bubbles) or 120 degree Y shaped shards. The amount of compaction and welding can be surmised by looking at the deformation of these shards. The Y shapes will lessen or lose the angle in the Y and the bubbles will flatten. The flattening always occurs perpendicular to the principle stress direction (in this case the overburden of material is the stress). Original Y shaped shards Shards after 75% compaction

321 Lab 8 Instructor: L. Porritt - 15 - Look at the suite of thin sections. Knowing what you know about welded pyroclastic deposits, put the sections into an idealized single cooling unit welding section. Briefly explain why you put each sample in its respective location. Note: The numbers on the sections do not necessarily correspond with their stratigraphic position! Activity IV Now your TA will hand out a list containing a brief petrographic description of all the thin sections and their associated hand samples for you to compare against your own. Please make sure you understand the reference petrographic descriptions and can find all of the minerals mentioned. You should also be able to understand why a rock is given a particular name.