Search and Discovery Article #10532 (2013)** Posted October 21, Abstract

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Utilizing the Delta Log R Method for Determining Total Organic Carbon of the Niobrara Formation, B Bench, Denver-Julesburg Basin, Colorado and Wyoming* Madeline K. Beitz 1, Robert Cunningham 2, and Lisa E. LaChance 3 Search and Discovery Article #10532 (2013)** Posted October 21, 2013 *Adapted from oral presentation given at AAPG Rocky Mountain Section Meeting, Salt Lake City, Utah, September 22-24, 2013 **AAPG 2013 Serial rights given by author. For all other rights contact author directly. 1 Drillinginfo, Inc., Austin, TX (mbeitz@drillinginfo.com) 2 ChargeSearch, LLC, Llano, TX 3 Drillinginfo, Inc., Austin, TX Abstract The Niobrara Formation was deposited in the Western Interior Seaway during the Late Cretaceous Coniacian-Santonian stages which coincided with high eustatic sea-level. In the Denver-Julesburg Basin study area, the Niobrara Formation occurs as a mixed shale/marl/carbonate sequence comprised of parasequences interbedded with organic-rich shale/marl units. These parasequences are developed as the three primary carbonate (chalk) benches. Total thickness of the Niobrara Formation ranges from two hundred feet to four hundred feet. Weight percent Total Organic Carbon (TOC) was calculated for the B Bench of the Niobrara Formation using the Delta Log R method of Passey et al. (1990) within third-party well interpretation software. The study includes 136 wells that had both deep resistivity and sonic logs available digitally. The B Bench of the Niobrara Formation was the focus of the study because recent drilling has indicated this zone to be a primary target for unconventional resource development. The methodology for Delta Log R calculation of TOC involved overlay and base-lining of the resistivity and sonic logs and consideration of Niobrara thermal maturity patterns. Zonal statistics (maximum, minimum, mean) for Delta Log R predicted TOC were calculated for the B Bench and the results were gridded over the study area using the top and bottom of the B Bench as a zone. The resulting mean values range from <1% to 10% in the study area and reflect both thermal maturity and deposition controls. This work aligns with and extends the published source characteristics for the Niobrara Formation.

References Cited Bhattacharya, J., and R.G. Walker, 1991, Allostratigraphic subdivision of the Upper Cretaceous Dunvegan, Shaftesbury, and Kaskapau formations in the northwestern Alberta subsurface: Bulletin of Canadian Petroleum Geology, v. 349/2, p. 145-164. Longman, M.W., B.A. Luneau, and S.M. Landon, 1998, Nature and distribution of Niobrara lithologies in the Cretaceous Western Interior Seaway of the Rocky Mountain Region: The Mountain Geologist, v. 35/4, p. 137-170. Passey, Q.R., S. Creaney, J.B. Kulla, F.J. Moretti, and J.D. Stroud, 1990, A practical model for organic richness from porosity and resistivity logs: AAPG Bulletin, v. 74/12, p. 1777-1794. Matuszczak, R.A., 1973, Wattenberg Field, Denver Basin, Colorado: The Mountain Geologist, v. 10/3, p. 99-105. Sonnenberg, S.A., 2012, The Niobrara Petroleum System, Rocky Mountain Region: AAPG Search and Discovery Article #80206. Web accessed 16 October, 2013. http://www.searchanddiscovery.com/documents/2012/80206sonnenberg/ndx_sonnenberg.pdf Stark, P.H., and R.J. Coskey, 2011, The Niobrara Play, an Overview: Denver Petroleum Club Breakfast Talk, 31 p. Web accessed October 16, 2013. http://denverpetroleumclub.com/robert_coskey_dpc_20110210.pdf

Utilizing the Log R method for Determining Total Organic Carbon of the Niobrara Formation, B Bench, Denver- Julesburg Basin, CO and WY Madeline K. Beitz, Robert Cunningham, Lisa E. LaChance September 23, 2013

Outline Overview Stratigraphic Framework of the Niobrara Formation Regional Paleo-Environment & Depositional Controls Log R Methodology Calculated TOC Closing Remarks Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 2

Overview

Overview Recent drilling has identified the B bench of the Niobrara as a primary target for unconventional resource development Organic richness is a key control on resource potential, but measured data are often scarce Weight percent Total Organic Carbon (TOC) was calculated for the B Bench of the Niobrara Fm using well logs and the Log R method of Passey et al (1990) Organic richness trends reflect both thermal maturity and deposition controls Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 4

Study Area The study includes 136 wells that had both deep resistivity and sonic logs available digitally. Source: Drillinginfo Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 5

Stratigraphic Framework of the Niobrara Formation

Stratigraphic Column of the Niobrara Petroleum System Niobrara ~200-400 Smoky Hill Member Fort Hays Limestone Member Source: Sonnenberg, 2012 Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 7

Methodology Behind Stratigraphic Picks To build high resolution subsurface models, Drillinginfo interprets well log data within a third party well interpretation software package High-density interpretations are created using allostratigraphic methodology This interpretation will soon be done using inhouse software due to Drillinginfo s acquisition of Transform Software Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 8

Methodology Behind Stratigraphic Picks Allostratigraphy is a methodology defined by the North American Stratigraphic Code that uses bounding discontinuities to subdivide the sedimentary section into mappable units. Bounding Discontinuities include unconformities, disconformities, discontinuities, and omission surfaces The bounding surfaces may relate back to sequence stratigraphic boundaries such as Marine Flooding Surfaces (Bhattacharya and Walker, 1991) Source: Mark Robinson, Drillinginfo Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 9

Smoky Hill Member Stratigraphic Framework Type Log Atreyu F 34-23, Noble Energy The B Bench is a naturally fractured, thick chalk/marl reservoir sandwiched between organic shale source rocks. With porosity ranging from 10% to 13%, it is a primary target for horizontal development. Source: Drillinginfo Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 10

Regional Cross-Section W E Top of Niobrara Fort Hays Silo Grover 38 wells evenly spaced over 65 miles. Wattenberg Source: Drillinginfo Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 11

Regional Paleo-Environment & Depositional Setting

Late Cretaceous Paleogeography and Western Interior Seaway Colder Arctic Currents Warmer Gulf Currents From Sonnenberg, 2012 (Modified from Longman et al., 1998) Source: Drillinginfo Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 13

Structure Map Niobrara Feet Subsea Source: Drillinginfo Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 14

Isopach Map Smoky Hill Member of the Niobrara Thin areas of deposition related to deposition over northeast trending paleo-highs Thickness: Feet Source: Drillinginfo Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 15

Structure Map - B Bench Feet Subsea Source: Drillinginfo Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 16

Isopach Map - B Bench Source: Drillinginfo Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 17

Log R and Calculated TOC

Log R Methodology The methodology of Passey et al (1990) was used for Log R calculation of TOC and involved overlay and base-lining of the resistivity and sonic logs and consideration of Niobrara thermal maturity patterns Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 19

Log R Methodology LOG R Separation A Bench B Bench C Bench Source: Drillinginfo Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 20

Log R Methodology Zonal statistics (min., max., mean, etc.) for Log R were calculated for the B Bench and the results were gridded over the study area. Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 21

Minimum Log R - B Bench Source: Drillinginfo Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 22

Maximum Log R - B Bench Source: Drillinginfo Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 23

Mean Log R - B Bench Source: Drillinginfo Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 24

Level of Organic Metamorphism (LOM) LOM scale is used by Passey (1990) in his methodology Hand-contoured and Gridded Area of effective oil generation 13 12 11 10 9 8 7 6 5 Source: Stark and Coskey, 2011 Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 25

Calculated TOC TOC was calculated using a map calculator in third party interpretation software The min., max., and mean Log R grids were each used along with the LOM grid to calculate min., max., and mean TOC for the B Bench The resulting equation is from the TOC equation of Passey et al (1990) substituting grids required for mapping TOC variation at current LOM (i.e. not original TOC) TOC=( Log R)*10^(2.297-01688*LOM) Grid Grid Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 26

Minimum Calculated TOC - B Bench % Calculated TOC Source: Drillinginfo Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 27

Maximum Calculated TOC - B Bench % Calculated TOC Source: Drillinginfo Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 28

Mean Calculated TOC - B Bench % Calculated TOC Clastics Carbonates %TOC Source: Drillinginfo Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 29

Results and Remarks

Checking our Results GeoMark Research We used measured TOC values from core and cuttings to calibrate our calculated TOC values TOC data was contributed by GeoMark Research which granted us access to the Denver-Julesburg portion of their Rock and Fluid Database (RFDbase.com) Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 31

Checking our Results The Green points on the Calculated TOC curve represent Measured TOC data points from the GeoMark Rock and Fluid Database. Source: Drillinginfo Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 32

Remarks Two controlling phases contributed to the present B Bench TOC patterns discovered in this study: Deposition Original TOC a function of productivity, preservation, and dilution Higher TOC to the east is consistent with decreasing seafloor O2 and lower clastic dilution with more distal depositional conditions Burial maturity Original TOC reduction due to thermal Higher TOC to the east is consistent with decreasing thermal maturity and generative loss of TOC moving out of the foreland basin depocenter Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 33

Remarks This was a preliminary study for Drillinginfo to develop tools and workflows for calculating TOC over conventional and unconventional play areas using digitized well logs Resistivity and Sonic Baseline maps along with better maturity mapping will be used for future studies. Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 34

Acknowledgements Robert Cunningham working as a consultant with Drillinginfo to assist with expanding our analytical data offerings GeoMark Research http://www.geomarkresearch.com Copyright 2012, Drillinginfo, Inc. All rights reserved. All brand names and trademarks are the properties of their respective companies. 35