2018 76 2 Vol. 76 No. 2
Editor-in-Chief ZHOU Qi-Lin( ) Nankai University Associate Editors EDITORIAL BOARD AND ADVISORY BOARD OF ACTA CHIMICA SINICA DING Kui-Ling( ) Shanghai Institute of Organic Chemisry, CAS HE Chuan( ) University of Chicago, USA LIU Zhong-Fan( ) Peking University ZHANG Xi( ) Tsinghua University WANG Li-Xiang( ) Changchun Institute of Applied Chemistry, CAS Editorial Board (Alphabetically arranged) GAO Song( ) Peking University JIANG Gui-Bin( ) Research Center for Eco-Environmental Sciences, CAS SUN Shi-Gang( ) Xiamen University SHUAI Zhi-Gang( ) Tsinghua University CHEN Chuan-Feng( ) CHEN Jun( ) CHEN Peng( ) CHEN Yong-Sheng( ) CUI Chun-Ming( ) DENG Zhao-Xiang( ) DING Kui-Ling( ) FAN Chun-Hai( ) FAN Qing-Hua( ) FENG Xiao-Ming( ) FU Yao( ) GAO Song( ) GONG Liu-Zhu( ) HE Chuan( ) HOU Yang-Long( ) HU Jin-Bo( ) HU Min( ) HU Wen-Hao( ) HU Zheng( ) HUANG Fei( ) HUANG Fei-He( ) HUANG Pei-Qiang( ) JIANG Gui-Bin( ) LI Zhan-Ting( ) LI Jing-Hong( ) LIU Dong-Sheng( ) LIU Guo-Sheng( ) LIU Hai-Chao( ) LIU Jing-Fu( ) LIU Lei( ) LIU Yu( ) LIU Zhong-Fan( ) LONG Yi-Tao( ) MA Jun-An( ) MENG Qing-Bo( ) PAN Yuan-Jiang( ) PENG Hui-Sheng( ) PENG Xiao-Jun( ) QU Liang-Ti( ) REN Bin( ) SHUAI Zhi-Gang( ) SONG Yan-Lin( ) SUN Shi-Gang( ) TONG Ming-Liang( ) WANG Guan-Wu( ) WANG Li-Xiang( ) WANG Peng( ) WANG Shu( ) WANG Wei( ) WANG Xun( ) XI Zhen-Feng( ) XIA Yong-Yao( ) XU Jing-Juan( ) YANG Huang-Hao( ) YOU Shu-Li( ) YU Gui( ) YU Jia-Guo( ) YU Zhi-Xiang( ) YU Biao( ) ZHANG Jin( ) ZHANG Li-Zhi( ) ZHANG Xi( ) ZHANG Ya-Wen( ) ZHENG Li-Min( ) ZHOU Jian( ) ZHOU Qi-Lin( ) ZHU Guang-Shan( ) ZHUANG Lin( ) Advisory Board AN Li-Jia( ) CHE Chi-Ming( ) CHEN Er-Qiang( ) CHEN Yi( ) CHENG Yi-Yu( ) DAI Li-Xin( ) FAN Kang-Nian( ) FENG Shou-Hua( ) GAO Zi( ) GUO Qing-Xiang( ) HAO Jing-Cheng( ) Henry N. C. WONG( ) HONG Mao-Chun( ) HOU Xue-Long( ) HU Ying( ) HU Yue-Fei( ) JI Guo-Zhen( ) LI Hao-Ran( ) LI Jun-Bai( ) LI Le-Min( ) LIAO Dai-Zheng( ) LIN Guo-Qiang( ) LÜ Long( ) LU Xi-Yan( ) MA Chun-An( ) MA Sheng-Ming( ) SHEN Yan-Chang( ) SONG Li-Cheng( ) SU Qiang( ) TIAN Wei-Sheng( ) WAN Hui-Lin( ) WANG De-Zheng( ) WANG Er-Kang( ) WANG Mei-Xiang( ) WU Yi-Kang( ) WU Yu-Lin( ) YANG Yu-Liang( ) YAO Jian-Nian( ) YE Jian-Nong( ) ZHAO Dong-Yuan( ) ZHAO Yu-Fen( ) ZHANG Yu-Kui( ) ZHENG Lan-Sun( ) ZHU Yong-Fa( ) ZOU Han-Fa( )
(Huaxue Xuebao) 76 2 2018 2 15......,,,, *,,, 2018, 76(2), 85-94 BI-32169......,,, *, *,, 2018, 76(2), 95-98 /......,, *,,,, 2018, 76(2), 99-102 / [1,2-a]......,,, *,, 2018, 76(2), 103-106......,,,,,,,, *,, 2018, 76(2), 107-112 Ir(III)......,, *, *,, 2018, 76(2), 113-120 - /......, *,, 2018, 76(2), 121-132...... *,,,, 2018, 76(2), 133-137 Kr-CS 2......,, *,, 2018, 76(2), 138-142 *. Acta Chim. Sinica 2018, 76, 79 79 2018 Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences http://sioc-journal.cn 79
ACTA CHIMICA SINICA Vol. 76, No. 2 February 15, 2018 Contents On the cover: The human glucagon receptor peptide inhibitor BI-32169, with a unique bicyclic structure, was successfully synthesized utilizing an aryl boronate ester protecting group via an on-resin cyclization strategy, which provides a convenient and efficient synthetic method for the chemical synthesis of other analogues. [Hu, Honggang et al. on page 95-98.] Review Research Advances on the Applications of Immobilized Ionic Liquids Functional Materials Wang, Yinhang; Li, Wei; Luo, Sha; Liu, Shouxin; Ma, Chunhui*; Li, Jian Acta Chim. Sinica 2018, 76(2), 85-94 ILs were immobilized on inorganic porous materials or organic polymer materials by physical adsorption or chemical grafting. And the current applications of immobilized ionic liquid were illustrated with a multi-angle. The immobilized ionic liquid as catalysts were used in chemical catalytic field depending on the chemical structure of ionic liquid. While the immobilized ionic liquid as a functional materials were used in adsorption separation field depending on the surface characteristic of solid carrier. Communication Efficient Synthesis of Bicyclic Peptide BI-32169 Utilizing a Novel Aryl Boronate Ester Protecting Group Song, Hui; Liu, Chao; Wu, Yijun; Hu, Honggang*; Yan, Fang* Acta Chim. Sinica 2018, 76(2), 95-98 80 http://sioc-journal.cn 2018 Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences Acta Chim. Sinica 2018, 76, 80 82
Content A New Decarboxylation/Methylation Process of Cinnamic Acids Ye, Wenbo; Yan, Zicong; Wan, Changfeng*; Hou, Haoqing; Wang, Zhiyong Acta Chim. Sinica 2018, 76(2), 99-102 tert-butyl hydroperoxide (TBHP) as a methylation reagent was applied in the synthesis of propiophenone derivatives. Synthesis of Tetrahydropyrrolo/ indolo[1,2-a]pyrazines by Enantioselective Hydrogenation of Heterocyclic Imines Hu, Shu-Bo; Chen, Mu-Wang; Zhai, Xiao-Yong; Zhou, Yong-Gui* Acta Chim. Sinica 2018, 76(2), 103-106 A novel iridium-catalyzed asymmetric hydrogenation of nitrogen-containing heterocyclic imines 3,4-dihydropyrrolo/indolo[1,2-a]pyrazines has been successfully developed, providing a facile access to 1,2,3,4-tetrahydropyrrolo/indolo[1,2-a]pyrazines with up to 99% yield and 95% ee. The reaction features mild condition, high enantioselectivity and high atom-economy. Article Self N-Doped Porous Interconnected Carbon Nanosheets Material for Supercapacitors Zhao, Jing; Gong, Junwei; Li, Yiju; Cheng, Kui; Ye, Ke; Zhu, Kai; Yan, Jun; Cao, Dianxue; Wang, Guiling* Acta Chim. Sinica 2018, 76(2), 107-112 The N-ICNs were prepared by the one-step activation and carbonization process with large specific surface area and high specific capacitance. Hydride Source in Ethers Hydrosilylation Reaction Catalyzed by Brookhart s Ir(III) Pincer Complex Zhang, Qi; Liu, Ao; Yu, Hai-Zhu*; Fu, Yao* Acta Chim. Sinica 2018, 76(2), 113-120 Hydride Source in Ethers Hydrosilylation Reaction Catalyzed by Brookhart s Ir(III) Pincer Complex has been clarified by DFT calculations. Acta Chim. Sinica 2018, 76, 80 82 2018 Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences http://sioc-journal.cn 81
Content Non-symmetric -Diketiminate Magnesium Complexes as Initiators for Ring-Opening Polymerization/Copolymerization of Lactide, -Caprolactone Maryam Keram; Ma, Haiyan* Acta Chim. Sinica 2018, 76(2), 121-132 A series of magnesium complexes bearing a non-symmetric -diketiminate ligand were synthesized and explored as active initiators for the polymerization of rac-lactide, -caprolactone and the copolymerization of L-lactide/ -caprolactone. PCL-block-PLLA diblock copolymers could be obtained via three different feeding strategies, as verified by NMR spectroscopy and DSC methods. Controllable Synthesis of One-dimensional Cryptomelane-type Manganese Dioxide and Its Electrochemical Performance Zhang, Chengming*; Pang, Xin; Wang, Yongzhao Acta Chim. Sinica 2018, 76(2), 133-137 Cryptomelane-type manganese dioxide is a very important nanomaterial in electrochemistry. Its intrinsic properties can be tailored by controlling shape or size. The diameter of one-dimensional OMS-2 nanomaterial is an important parameter in controllable synthesis and electrochemistry applications. Control of diameter of one-dimensional OMS-2 could be realized by adjusting the ratio of MnO 4 to Mn 2 in the aqueous solution. The samples synthesized at low ratio of MnO 4 to Mn 2 showed thinner and longer nanofibers or nanowires. The samples synthesized at high ratio of MnO 4 to Mn 2 exhibited higher diameter. Therefore, it can be concluded that MnO 4 can promote the lateral growth of one-dimensional OMS-2 nanomaterial and Mn 2 tends to promote the longitudinal growth. A New Four-Dimensional Potential Energy Surface and Predicted Infrared Spectra for the Kr-CS 2 Complex Hong, Qi; Qin, Miao; Zhu, Hua* Acta Chim. Sinica 2018, 76(2), 138-142 A four-dimensional (4D) ab initio potential energy surface (PES) for the Kr-CS 2 complex involving the Q 1 and Q 3 normal modes for the 1 symmetric stretching vibration and 3 antisymmetric stretching vibration of CS 2 was presented. The rovibrational energy levels and bound states are calculated. In addition, the spectroscopic parameters for the ground and the 1 3 excited states of Kr-CS 2 are predicted. 82 http://sioc-journal.cn 2018 Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences Acta Chim. Sinica 2018, 76, 80 82
SCI ( ) Huaxue Xuebao ACTA CHIMICA SINICA (Monthly) 1933 (Founded in 1933) 76 2 Vol. 76 No. 2 2018 2 15 February 15, 2018 Supervised by Chinese Academy of Sciences Sponsored by The Chinese Chemical Society and Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences Editor-in-Chief: ZHOU Qi-Lin ( 345, 200032) Edited and Published by Editorial Office of Acta Chimica Sinica (345 Lingling Lu, Shanghai 200032, China) Printed by Shanghai Newcabo Business Printing Co., Ltd. Subscriptions Domestic: Local Post Offices ( 399 ) Foreign: China International Book Trading Corporation (P.O. Box 399, Beijing, China) http://sioc-journal.cn E-mail: hxxb@sioc.ac.cn ISSN 0567-7351 CN 31-1320/O6 4-209 M56 80.00 : 3100420130007 84 http://sioc-journal.cn 2018 Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences Acta Chim. Sinica 2018, 76, 84 84