Stickney Avenue Depositional Zone (SADZ) Investigation

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The Ottawa River: A Report to the Community Stickney Avenue Depositional Zone (SADZ) Investigation May 22, 2007 Presented by: Scott Bell, P.E., BCEE (LimnoTech) Kelly Bensman (Hull & Associates)

SADZ Location & Characteristics - Between RM 4.2 to the Stickney Avenue bridge RM 4.9 - Wide, relatively shallow, and slower moving section of the river - First major depositional zone downstream of the historic landfill section of the river

SADZ Previous Studies* Physical & hydraulic conditions in river favor sedimentation Relatively thick sediment layer with buried PCB impacts Conditions indicate that it may be feasible to manage contaminated sediments in place through capping and/or monitored natural recovery *(LimnoTech, 2001; Hull & Associates, 2004)

SADZ Physical Description

SADZ Backwater Area - Periodically inundated - Receives storm water runoff from nearby industrial and urban areas - Physical and chemical characteristics unknown

SADZ Project Scope Investigate sediment and hydrological characteristics Collect supplemental physical, chemical data to support remedial design Collect toxicity data to assist U.S. EPA in sediment toxicity evaluation Target investigation to fulfill the requirements of Great Lakes Legacy Act to position project for possible funding for remediation

SADZ Sediment Sampling - Completed Fall 2006 - Sample locations identified based on previous data (Hull, BBL) - Sediment Cores Collected along 7 transects

Sample Collection Sediment Cores - Supplemental physical and chemical data to assist in remedial design - 27 sediment cores collected - Located along 7 transects - 1-12 ft. core lengths Surficial Sediment - Data to assist U.S. EPA in sediment toxicity evaluation - 10 samples collected - located along length of SADZ (RM 4.2 RM 4.9)

Sediment Core Sample Collection Cores processed on-shore Visual Characterization Color Sediment texture Relative organic content Presence of non-soil materials

Sediment Core Sample Collection 57 composite samples collected Chemical Analysis - PCBS, PAHs,, Lead, TOC Physical Analysis (10 samples) - Grainsize Distribution - Atterberg Limits - Natural Moisture Content - Specific Gravity

Sediment Grab Sample Collection 10 grab samples collected Chemical Chemical Analysis -AVS/SEM (acid volatile sulfides/simultaneously extracted metals): As, Cd,, Cr, Cu, Pb,, Hg, Ni, Zn -PAHs -TOC

PCBs Sediment Analytical Results Only Only 2 of the 7 arochlors analyzed were detected Arochlor Arochlor 1242 detected in 61% of samples Arochlor Arochlor 1254 detected in 63% of samples Total Total PCB concentrations ranged from 0.08 26 ppm Results Results similar to historic sampling Highest Highest concentrations clustered near backwater area PCBs>1 PCBs>1 ppm (general accepted standard for remediation) located throughout the main channel

Sediment Analytical Results Surficial PCB Concentrations (mg/kg)

PAHs Sediment Analytical Results 1717 of the 18 PAHs analyzed detected in at least one sample PAHsPAHs detected in 74% of samples Total Total PAH concentrations ranged from 0.11 6.4 ppm Highest Highest concentrations clustered near the upstream portion of the SADZ, near the Stickney Bridge Results Results similar to historic sampling

Lead Sediment Analytical Results Naturally occurring element in soil Detected in 100% of samples Lead Lead concentrations range from 4.16 495 ppm Highest Highest concentrations clustered near backwater area Results Results similar to historic sampling

Sediment Analytical Results Geotechnical Physical Physical properties are variable Sediments vary from clays to sands Most Most sediments appear relatively fine-grained and contain some (clay/silt content) SADZ SADZ contains cohesive and non-cohesive sediments as characterized by predominance of clay/silt No No apparent relationship exists between sediment type and contaminant occurrence

Hydrodynamic Modeling Purpose: simulate extreme conditions to evaluate sediment stability Multiple computer models used: SADZ backwater area hydrology Used USEPA SWMM to simulate storm water flows Ottawa River Hydrodynamics Used large- scale model to simulate river conditions under a range of flows and Lake Erie seiche effects SADZ Hydrodynamics Used fine-scale model of SADZ to evaluate local conditions in SADZ

Hydrodynamic Modeling

Hydrodynamic Modeling Goals: To simulate river conditions under extreme conditions Interested in velocities and shear stresses, because they indicate the energy available to move sediment

Hydrodynamic Modeling

Hydrodynamic Modeling Findings: Peak shear stresses during extreme hydrologic events may exceed threshold shear stresses of the sediments, which could result in downstream transport of contaminants. However, these peaks are infrequent, isolated, and of short duration.

Conclusions The effectiveness of monitored natural attenuation as the sole remediation alternative for the SADZ uncertain. The distribution of PCB impacts above 1 ppm throughout the SADZ indicates that dredging alone would likely involve sediment removal from almost the entire SADZ.

Conclusions An engineered cap may be feasible, if it is constructed of material that will withstand the peak shear stresses that can potentially develop in the SADZ A potentially feasible remedial alternative would include capping in potentially erosive areas, with monitored natural attenuation in the rest of the SADZ.