Electronic Supplementary Information
|
|
- Tiffany Montgomery
- 5 years ago
- Views:
Transcription
1 Electronic Supplementary Information Pyrene-Directed Growth of Nanoporous Benzimidazole-Linked Nanofibers and their Application to Selective Capture and Separation Mohammad Gulam Rabbani, Ali Kemal Sekizkardes, Oussama M. El-Kadri, Bilal R. Kaafarani and Hani M. El-Kaderi* Mohammad Gulam Rabbani, Ali Kemal Sekizkardes, H. M. El-Kaderi* (Corresponding-Author) Department of Chemistry Virginia Commonwealth University 1001 W. Main St. Richmond, VA , US Tel.: (804) Prof. O. M. EL-Kadri Department of Biology, Chemistry, and Environmental Sciences Tel.: (971) American University of Sharjah PO Box 26666, Sharjah United Arab Emirates oelkadri@aus.edu Prof. B. R. Kaafarani Department of Chemistry American University of Beirut Beirut , Lebanon Tel.: (961) bilal.kaafarani@aub.edu.lb S1
2 Table of Contents Section S1 NMR Spectral Characterization of TFPPy 3 Section S2 Characterization of BILP-10 4 TGA Trace for BILP-10 4 PXRD Pattern for BILP-10 5 Scanning Electron Microscopy Imaging (SEM) 6 FT-IR Spectroscopy of Starting Materials and BILP-10 7 Solid-State 13 C CP-MAS NMR Spectrum for BILP-10 9 Section S3 Low Pressure (0 1.0 bar) Gas Adsorption Studies 10 Section S4 High-Pressure (0 40 bar) Gas Adsorption Studies 28 S2
3 Section S1: NMR Spectral Characterization of 1,3,6,8-tetrakis(4-formylphenyl)pyrene 1 H NMR spectra for 1,3,6,8-tetrakis(4-formylphenyl)pyrene (TFPPy) in CDCl 3 : Note that 13 C NMR spectrum could not be measured due to the low solubility of TFPPy. S3
4 Section S2: Characterization of BILP-10 Figure S1: TGA trace of BILP BILP Weigth (%) Temperature ( o C) S4
5 Figure S2: PXRD- pattern for BILP-10 indicating amorphous materials (degrees) S5
6 Figure S3: Scanning Electron Microscopy Imaging (SEM) for BILP μm S6
7 Figure S4: FT-IR spectra ( cm -1 ) of starting materials and BILP-10: 3412 cm -1 (N-H, free), 3205 cm -1 (N-H, hydrogen bonded), cm -1 (C-H), 1638 cm -1 (C=N), 1604 cm -1 (C=C), 1484 and 1435 cm -1 (benzimidazole ring), 1370 and 1275 cm -1 (C-N). TFPPy BTA BILP Wavenuber (cm -1 ) Wavenuber (cm -1 ) S7
8 Figure S5: 13 C NMR for 1,2,4,5-Benzenetetramine tetrahydrochloride (BTA) (in d 6 DMSO). H 2 N NH 2 a b NH 2 NH 2 4HCl S8
9 Figure S6: Solid state 13 C CP-MAS NMR spectrum of BILP-10. Asterisks denote spinning side bands H N N 1 10 N N H * * ppm S9
10 Section S3: Low-Pressure (0 1 bar) Gas Adsorption Measurements for BILP- 10 Low-pressure gas sorption experiments were performed for Ar, N 2, H 2, and CH 4. The surface properties, for example, surface areas, pore size distributions, pore volume etc. were evaluated from Ar (87 K) and N 2 (77 K) adsorption isotherms. Gas storage and selective adsorption properties were evaluated by measuring the adsorption isotherms for H 2 (77 K and 87 K), (273 K and 298 K), CH 4 (273 K and 298 K) and N 2 (273 K and 298 K). The binding affinity (isosteric heats of adsorption) for H 2,, and CH 4 was evaluated from singlecomponent adsorption isotherms using virial equation and/or Clausius-Clapeyron equation. Calculation of isosteric heats of adsorption for BILP-10 Virial Equation The virial equation was used to determine the binding affinity and isosteric heats of adsorption. The virial equation can be written in the form 1 N ln P A0 N A1 N A2 N.... (I) Where N is the amount adsorbed at pressure P and A 0, A 1, etc. are virial coefficients. A 0 is related to adsorbate-adsorbent interactions, whereas describes adsorbate-adsorbate interactions. Under condition of low surface coverage, the higher terms (A 2, etc.) in the virial equation can be neglected. A virial-type expression in the following form can also be used to fit the experimental isotherm data for a given material at different temperatures. 2 1 ln( P) ln( N) T m i0 a N i i n i0 b N i i (II) S10
11 Where N is the amount adsorbed at pressure P, T is the temperature, a i and b i are temperature independent empirical parameters, and m and n determine the number of terms required to adequately describe the isotherm. The resulting virial coefficients a 0 through a m can then be used to calculate the isosteric heats of adsorption as function of uptake: Q st R m i0 a i N i (III) Where R is the universal gas constant (8.314 J K -1 Mol -1 ) It follows that the zero-coverage isosteric heats of adsorption is given by Qst Ra 0 (IV) Isosteric heats of adsorption can also calculated from the Clausius-Clapeyron equation. 3 2 lnp Qst RT (V) T N Where T is the temperature, R is the universal gas constant and P is the pressure for given quantity of gas adsorbed (N). The temperature dependent experimental data are fit to model isotherms to obtain P for given N. Adsorption isotherms for and CH 4 collected at 273 K, 288 K and 298 K were fitted here using the Tóth equation. 4 Tóth equation has the advantage that it appears to satisfy both limits of the isotherm, at p 0 and p. It is given by, N N s * kp kp t1 t 1/t (VI) N = Gas adsorbed (mmol/g) at a given pressure N s = Gas adsorbed (mmol/g) at saturation P = Pressure (atm) k and t are constants. S11
12 Equation (VI) can be rearranged to the following form to calculate P for equation (V). P k 1 - N N s N N s t(vii)t1/ Q st was then obtained from the slope of ln(p) vs. 1/T plot in the following form of equation (V): ( lnp) N - st Q R1 T C (VIII) S12
13 Figure S7: N 2 adsorption isotherm for BILP-10 measured at 77K. The filled circles are adsorption points and the empty circles are desorption points BILP-10 N 2 uptake at 77K 400 Uptake (cc/g) P/P 0 S13
14 Figure S8: BET plot for BILP-10 calculated from the N 2 adsorption isotherm at 77 K. The model was applied from P/P 0 = The correlation factor is indicated. (W= Weight of gas absorbed at a relative pressure P/P 0 ). 1/[W(P/P 0 )-1] BILP-10 N 2 sorption SA BET = 832 m 2 /g R 2 = P/P 0 S14
15 Figure S9: Ar adsorption isotherm for BILP-10 measured at 87 K. The filled circles are adsorption points and the empty circles are desorption points BILP-10 Ar uptake at 87 K Uptake (cc/g) P/P 0 S15
16 Figure S10: BET plot for BILP-10 calculated from the Ar adsorption isotherm at 87 K. The model was applied from P/P 0 = The correlation factor is indicated. (W= Weight of gas absorbed at a relative pressure P/P 0 ) /[W(P/P 0 )-1] BILP-10 Ar sorption SA BET = 787 m 2 /g R 2 = P/P 0 S16
17 Figure S11: The Pore Size Distribution of BILP-10 was calculated from the Ar adsorption isotherm using oxygen (zeolite) model, spherical/cylindrical pore, NLDFT adsorption model (A) and from N 2 isotherm (B) using silica as adsorbent and cylindr./sphere. pore, NLDFT adsorption model. The use of N 2 to probe porosity leads to PSD ~12.6 Å and to a broad distribution of mesopores in the range of ~20 to 50 Å that contributes ~23% of the the cumulative pore volume. Pore Width (Mode) = 7.55 Å V(W) (cc/å/g) (A) Pore size dstribution from Ar isotherm Spherical/cylinderical pore NLDFT ads. model PSD = 7.6 Å Actual Fitting Error = % Cumul. Pore Volume (cc/g) Pore Volume = cc/g at P/P o = Pore Width (Å) V(W) (cc/å/g) (C) Pore size dstribution from N 2 isotherm Cylindr./sphere.pore, NLDFT ads. Model PSD = 12.6 Å Actual Fitting Error = % Pore Width (Å) Cumul. Pore Volume (cc/g) Pore Width (Mode) = 12.6 Å Pore Volume = cc/g at P/P o = 0.95 S17
18 Figure S12: Experimental Ar adsorption isotherm for BILP-10 measured at 87 K is shown as filled circle. The calculated NLDFT isotherm is overlaid as open circle. Note that a fitting error of less than 1% indicates the validity of using this method for assessing the porosity of BILP-10. The fitting error is indicated BILP-10 Ar uptake at 87 K Uptake (cc/g) Fitting Error = % Original Fitted P/P 0 S18
19 Figure S13: gas adsorption for BILP-10 at 273 K (A), 288 K (B), and 298 K (C). The continuous solid line corresponds to a Tóth isotherm fit to the experimental data. uptake (mmol/g) (A), at 273 K Expt. Fitting P (bar) uptake (mmol/g) (B), at 288 K Expt. Fitting P (bar) (C), at 298 K uptake (mmol/g) Expt. Fitting P (bar) S19
20 Figure S14: CH 4 gas adsorption for BILP-10 at 273 K (A), 288 K (B), and 298 K (C). The continuous solid line corresponds to a Tóth isotherm fit to the experimental data. CH 4 uptake (mmol/g) (A) CH 4, at 273 K Expt. Fitting P (bar) CH 4 uptake (mmol/g) (B) CH 4, at 288 K Expt. Fitting P (bar) (C) CH 4, at 298 K CH 4 uptake (mmol/g) Expt. Fitting P (bar) S20
21 Figure S15: Virial analysis of adsorption data (A) (circles: 273 K, squares: 298 K) and isosteric heats of adsorption (Q st ) (B) for BILP-10. a0 = , a1= , a2 = , a3 = , b0 = , b1 = Q st (kj/mole) (B) Q st for Q st from Virial method Q st from Clausius-Clapeyron equation uptake (mg/g) Q st for from Clausius-Clapeyron Equation: kj/mol Q st for from virial method: ~ kj/mol (0 ~ mg/g) S21
22 Figure S16: Virial analysis of H 2 adsorption data (A) (circles: 77 K, squares: 87 K) and isosteric heats of adsorption (Q st ) (B) for BILP-10. a0 = , a1= , a2 = , a3 = , a4 = , b0 = , b1 = , b2 = Q st (kj/mol) (B) Q st for H H 2 Uptake (mg/g) Q st for H 2 from virial method: 9.3 ~ 3.7 (0 ~ 15.8 mg/g) S22
23 Figure S17: Virial analysis of CH 4 adsorption data (A) (circles: 273 K, squares: 298 K) and isosteric heats of adsorption (Q st ) (B) for BILP-10. a0 = , a1= , a2 = , a3 = , b0 = , b1 = (B) Q st for CH Q st (kj/mol) Q st from Virial method Q st from Clausius-Clapeyron equation CH 4 uptake (mg/g) Q st for CH 4 from Clausius-Clapeyron Equation: kj/mol Q st for CH 4 from virial method: ~ (0 ~ 16.7 mg/g) S23
24 Figure S18: Proposed interaction sites of with imidazole moieties BILP-10. S24
25 Figure S19: Analysis of adsorption isotherms at 273 K and 298 K for BILP-10 using virial method (Equation I). At 273 K: A 0 = and A 1 = ; at 298 K: A 0 = and A 1 = ln(n/p) (ln(mol g -1 Pa -1 )) Expt. at 273 K Fitted at 273 K Expt. at 298 K Fitted at 298 K N (mol g -1 ) S25
26 Figure S20: Selective adsorption of over CH 4 and N 2 at 273 K and 298 K. Uptake (mmol/g) uptake CH 4 uptake N 2 uptake BILP-10, 273 K P (bar) Uptake (mmol/g) uptake CH 4 uptake N 2 uptake BILP-10, 298 K P (bar) S26
27 Figure S21: Adsorption selectivity of BILP-10 for over CH 4 and N 2 at 273 K and at 298 K from low-pressure data. Selectivity at 273 K: From initial slopes: S(CO /N ) 107 ; S CO / CH ) ( 2 4 From equation S = [q 1 /q 2 ]/[p 1 /p 2 ]: uptake at 0.15 bar = mmol/g N 2 uptake at 0.75 bar = mmol/g S CO / N ) 128 ( 2 2 uptake at 0.1 bar = mmol/g; CH 4 uptake at 1.9 bar = mmol/g S(CO 2/CH 4 ) 18 (It should be noted that CH 4 uptake at 1.9 bar was selected from high pressure experiment at 275 C and it was assumed that the data at 273 K and 275 K are very similar. Uptake (mmol/g) 0.24 BILP-10, Selectivity at 273 K , y = x CH 4, y = x N 2, y = x E P (bar) Selectivity at 298 K: From initial slopes: S CO / N ) 59 ; S CO / CH ) 7 ( 2 2 ( 2 4 From equation S = [q 1 /q 2 ]/[p 1 /p 2 ]: uptake at 0.15 bar = mmol/g N 2 uptake at 0.75 bar = mmol/g S CO / N ) 107 ( 2 2 Uptake (mmol/g) BILP-10, Selectivity at 298 K, y = x CH 4, y = x N 2, y = x E-5 uptake at 0.1 bar = mmol/g CH 4 uptake at 1.9 bar = mmol/g S(CO /CH ) P (bar) S27
28 Section S4: High-Pressure (0 40 bar) Gas Adsorption Measurements for BILP- 10. High pressure sorption isotherms were run using a VTI HPVA-100 volumetric analyzer. Ultrahigh purity helium (99.999%) was used to calibrate the free volume in the sample cell before each measurement. The skeletal density (d sk ) of BILP-10 was found in the course of analysis for appropriate density correction factorization. 5 High pressure data was collected using ultrahigh purity H 2 (99.999%), (99.99%) and CH 4 (99.999%) obtained from Airgas Inc. (Radnor, PA). Free space measurements were performed prior to data collection utilizing ultrahigh purity helium to establish the appropriate cold zone compensation factors. Absolute gas uptakes were calculated according to literature methods 6 using NIST Thermochemical Properties of Fluid Systems. 7 Bulk phase gas densities up to 40 bar were fit using a sixth-order polynomial, then multiplied by the pore volume obtained from the Ar isotherm. Although the surface excess adsorption and absolute adsorption are nearly identical under low pressure up to 1 bar, they are different under high pressure conditions because the void space of the pores of adsorbent can hold significant amount of compressed gas under high pressure. The absolute amount of adsorbed gas is then expressed as N abs = N exc + d gas V p Where N abs is the absolute adsorption in mg g -1 ; N exc is the excess adsorption which is experimentally measured; d gas is the density of the compressed gas at a given temperature and pressure in cm 3 g -1, 7 and V p is the pore volume in cm 3 g -1. The V p can be calculated from d sk and d bulk using the following expression 5 V p dsk d d d sk bulk bulk Where d sk is the skeletal density of the material obtained from He experiment and d bulk is the bulk density of the sample which is, typically, obtained from available crystallographic model. S28
29 Ideally, above calculated pore volume should be comparable to the pore volume obtained from low-pressure Ar or N 2 isotherms. However, they deviate each other in many cases even for crystalline materials due to the partial decomposition of crystals or the presence of any other impurities. 8 Consequently, it is more relevant to recalculate the d bulk, particularly for noncrystalline amorphous materials, using the experimental obtained V p and d sk. The volumetric density of adsorbed gas inside the sample can be obtained simply by multiplying the adsorbed quantity with the bulk density of the sample. N v = N g d bulk Where N v is the volumetric uptake in g L -1, and N g is the gravimetric uptake in mg g -1, and d bulk is the bulk density of the sample in g cm -3. S29
30 Figure S22: H 2 isotherms for BILP-10 measured at 77 (black) and 87 K (red). Circles and squares represent surface excess (N Exc ) and absolute adsorbed (N Abs ) amounts, respectively BILP-10, H 2 uptake at 77 K and 87 K 300 H 2 uptake (mg/g) N Exx at 77 K N Exc at 87 K N Abs at 77K N Abs at 87 K P (bar) H 2 uptake (v/v) S30
31 Figure S23: isotherms for BILP-10 measured at 275 (black) and 298 K (red). Circles and squares represent surface excess (N Exc ) and absolute adsorbed (N Abs ) amounts, respectively. uptake (mg/g) 1000 BILP-10, CO uptake at 275 K and 298 K N Exc at 275 K N Exc at 298 K 100 N Abs at 275K N Abs at 298 K P (bar) uptake (v/v) S31
32 Figure S24: CH 4 isotherms for BILP-10 measured at 275 (black) and 298 K (red). Circles and squares represent surface excess (N Exc ) and absolute adsorbed (N Abs ) amounts, respectively. CH 4 uptake (mg/g) 100 BILP-10, CH 90 4 uptake at 275 K and 298 K N Exc at 275 K N Exc at 298 K 10 N Abs at 275K N Abs at 298 K P (bar) CH 4 uptake (v/v) S32
33 High Pressure Gas Selectivity Studies Selectivity prediction using ideal adsorbed solution theory (IAST): Ideal adsorbed solution theory calculations were performed as has been previously reported. 9,10,11 According to Myers and Prausnitz, 9 the ideal adsorbed solution theory can be reduced to the mathematical integration: Py x 1 1 t0 2 x 2 Py F 1( t ) d lnt F ( t) d lnt In this equation, P is the total pressure, y i is the bulk phase molar ratio of gas i, x i is the adsorbed phase molar ratio of gas i, and the function, F i (t), is a fitting function for the pure component i based on the Langmuir-Freundlich model: t0 2 n a * b * p 1 b * p 1/c 1/c d * e * p 1 d * p 1/f 1/f In this equation, n is the gas uptake in mmol/g, p is the pressure in bar, and a, b, c, d, e, and f are the fitting parameters. Since x 1 = 1 x 2 and y 1 = 1 y 2, the integrated equation nets only three unknowns. Therefore, by specifying one value and varying a second, the third value can be calculated. Selectivity can then be calculated as: S 1,2 x1/y x /y S33
34 Figure S25: Pure component isotherms for (black circle), CH 4 (red square) and N 2 (blue diamond) at 298 K. The solid lines are the dual-site Langmuir-Freundlich fits for (black) CH 4 (red) and N 2 (blue). Gas uptake (mmol/g) expt CH 4 expt N 2 expt model CH 4 model N 2 model P (bar) S34
35 Figure S26: IAST selectivities of over CH 4 at 298 K, the low pressure region is expanded in the bottom figure. Selectivity ( /CH 4 ) Selectivity /CH 4, 298 K 8 Gas phase mole fraction ratios 6 for and CH : : : : : : P (bar) Selectvity ( /CH 4 ) 16 Selectivity 14 /CH 4, 298 K : : : : : : P (bar) S35
36 Figure S27: IAST selectivities of over N 2 at 298 K, low pressure region is expanded in the bottom figure. Selectivity ( /N 2 ) Selectivity /N 2, 298 K Gas phase mole fraction ratios for :N 2 0.5: : : : : : P (bar) Selectvity ( /N 2 ) Selectivity /N 2, 298 K 30 Gas phase mole fraction ratios for :N : : : : : : P (bar) S36
37 References 1. X. Zhao, S. Villar-Rodil, A. J. Fletcher and K. M. Thomas, J. Phys. Chem. B 2006, 110, J. L. C. Rowsell and O. M. Yaghi, J. Am. Chem. Soc., 2006, 128, P. Huanhua, J. A. Ritter and P. B. Balbuena, Langmuir 1998, 14, S. Tedds, A. Walton, D. P. Broom, and D. Book, Faraday Discuss., 2011, 151, M. Dincă, A. Dailly, Y. Liu, C. M. Brown, D. A. Neumann and J. Long, J. Am. Chem. Soc., 2006, 128, H. Furukawa, M. A. Miller and O. M. Yaghi, J. Mater. Chem., 2007, 17, NIST Chemistry WebBook (Thermophysical Properties of Fluid Systems): 8. H. Furukawa and O. M. Yaghi, J. Am. Chem. Soc., 2009, 131, A. L. Myers and J. M. Prausnitz, AIChE J., 1965, 11, Z. R. Herm, J. A. Swisher, B. Smit, R. Krishna and J. R. Long, J. Am. Chem. Soc., 2011, 133, T. E. Reich, S. Behera, K. T. Jackson, P. Jena and H. M. El-Kaderi, J. Mater. Chem., 2012, 22, S37
Characterisation of Porous Hydrogen Storage Materials: Carbons, Zeolites, MOFs and PIMs
Characterisation of Porous Hydrogen Storage Materials: Carbons, Zeolites, MOFs and PIMs Steven Tedds, a * Allan Walton, a Darren P. Broom, b and David Book a DOI:.39/c0fd00022a Electronic Supplementary
More informationSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Supporting Information Novel Nanoporous Ferrocenyl Framework for Clean Energy Application Qingquan
More informationSupporting Information
Supporting Information Nitrogen-Rich Porous Polymers for Carbon Dioxide and Iodine Sequestration for Environmental Remediation Yomna H. Abdelmoaty, Tsemre-Dingel Tessema, Fatema Akthar Choudhury, Oussama
More informationLocal Deprotonation Enables Cation Exchange, Porosity. Modulation and Tunable Adsorption Selectivity in a. Metal-Organic Framework
Supporting Information for Local Deprotonation Enables Cation Exchange, Porosity Modulation and Tunable Adsorption Selectivity in a Metal-Organic Framework Jun-Hao Wang,, Dong Luo, Mian Li, and Dan Li
More informationStorage of Hydrogen, Methane and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications
Storage of Hydrogen, Methane and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications (Supporting Information: 33 pages) Hiroyasu Furukawa and Omar M. Yaghi Center
More informationDepartment of Materials and Environmental Chemistry, Berzelii Center EXSELENT on
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information Adsorption of CO 2 on a micro-/mesoporous
More informationSilver-Decorated Hafnium Metal-Organic Framework for. Ethylene/Ethane Separation
Supporting Information Silver-Decorated Hafnium Metal-Organic Framework for Ethylene/Ethane Separation Yuxiang Wang, Zhigang Hu, Youdong Cheng, and Dan Zhao * Department of Chemical & Biomolecular Engineering,
More informationElectronic Supplementary Information. Selective Sorption of Light Hydrocarbons on a Family of
Electronic Supplementary Information Selective Sorption of Light Hydrocarbons on a Family of Metal-Organic Frameworks with different Imidazolate Pillars Hong-Ru Fu and Jian Zhang* State Key Laboratory
More informationElectronic Supplementary Information. Materials
Electronic Supplementary Information S1 Enhancement of H 2 Adsorption in Li + -Exchanged Co-ordination Framework Materials Sihai Yang, 1 Xiang Lin, 1 Alexander J. Blake, 1 K. Mark Thomas, 2 Peter Hubberstey,
More informationNew Journal of Chemistry Electronic Supplementary Information
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2018 New Journal of Chemistry Electronic
More informationEthers in a Porous Metal-Organic Framework
Supporting Information Enhanced Isosteric Heat of H 2 Adsorption by Inclusion of Crown Ethers in a Porous Metal-Organic Framework Hye Jeong Park and Myunghyun Paik Suh* Department of Chemistry, Seoul National
More informationQuantifying hydrogen uptake by porous materials
Quantifying hydrogen uptake by porous materials Nuno Bimbo Postdoctoral Research Officer Department of Chemical Engineering University of Bath N.M.M.Bimbo@bath.ac.uk http://www.bath.ac.uk/chem-eng/people/bimbo
More informationQingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Science,
Supporting information A rht type Metal-Organic Framework based on Small Cubicuboctahedron Supermolecular Building Blocks and Adsorption Properties Liangjun Li a,b, Sifu Tang a, Xiaoxia Lv a,b, Min Jiang
More informationSupporting Information
Supporting Information Nitrogen-doped coal tar pitch based microporous carbons with superior CO 2 capture performance Dai Yu, Jun Hu, Lihui Zhou *, Jinxia Li, Jing Tang, Changjun Peng, and Honglai Liu
More information1. Materials All chemicals and solvents were purchased from Sigma Aldrich or SAMCHUN and used without further purification.
1. Materials All chemicals and solvents were purchased from Sigma Aldrich or SAMCHUN and used without further purification. 2. Experimental procedures Benzo[1,2-c:3,4-c':5,6-c'']trifuran, 1: The synthesis
More informationSupplementary Information
Supplementary Information Co-doping of MOF-5 framework and its effect on gas adsorption behaviour J.A. Botas a,*, G. Calleja a, M. Sánchez-Sánchez,b, M.G. Orcajo a a Department of Chemical and Energy Technology,
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Cation exchange MOF-derived nitrogen-doped
More informationA flexible zinc tetrazolate framework with breathing behaviour on xenon adsorption and selective adsorption of xenon over other noble gases
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Material (ESI) for J. Mater. Chem. A. Supporting
More informationElectronic supplementary information (ESI) Temperature dependent selective gas sorption of unprecedented
Electronic supplementary information (ESI) Temperature dependent selective gas sorption of unprecedented stable microporous metal-imidazolate framework Shui-Sheng Chen, a,c Min Chen, a Satoshi Takamizawa,
More informationSUPPLEMENTARY INFORMATION
doi:10.1038/nature14327 Supplementary Text Structure solution and Rietveld refinement of mmen-mn 2 (dobpdc) Initially, the previously reported crystal structure of the isostructural Zn 2 (dobpdc) 13, with
More informationSupplementary Information
Supplementary Information Stable aluminum metal-organic frameworks (Al-MOFs) for balanced CO 2 and water selectivity Haiwei Li, Xiao Feng, * Dou Ma, Mengxi Zhang, Yuanyuan Zhang, Yi Liu, Jinwei Zhang,
More informationMetal-Organic Frameworks and Porous Polymer Networks for Carbon Capture
Carbon Capture Workshop, Tuesday, April 3 rd, Texas A&M, Qatar Metal-Organic Frameworks and Porous Polymer Networks for Carbon Capture J. P. Sculley, J.-R. Li, J. Park, W. Lu, and H.-C. Zhou Texas A&M
More informationSuperacid-Promoted Synthesis of Highly Porous Hypercrosslinked Polycarbazoles for Efficient CO 2 Capture
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 [Supporting Information] Superacid-Promoted Synthesis of Highly Porous Hypercrosslinked Polycarbazoles
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 204 Supporting Information Efficient CO 2 Capture by a Task-Specific Porous Organic Polymer Bifunctionalized
More informationSupporting Information
Supporting Information Hexafluorogermanate (GeFSIX) Anion-Functionalized Hybrid Ultramicroporous Materials for Efficiently Trapping of Acetylene from Ethylene Zhaoqiang Zhang, Xili Cui, Lifeng Yang, Jiyu
More informationHydrogen Adsorption and Storage on Porous Materials. School of Chemical Engineering and Advanced Materials. Newcastle University United Kingdom
Hydrogen Adsorption and Storage on Porous Materials K. M. Thomas. School of Chemical Engineering and Advanced Materials H2FC SUPERGEN Conference Birmingham University, 16-18 th December 2013 Newcastle
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) Rational Design and Synthesis of a Porous, Task-Specific
More informationSupporting Information. Table of Contents
Supporting Information Polyamine-Cladded 18-Ring-Channel Gallium Phosphites with High-Capacity Hydrogen Adsorption and Carbon Dioxide Capture Ming-Jhe Sie, 1 Chia-Her Lin, 2, * and Sue-Lein Wang, 1, *
More informationSupple. KBr. C N) cm (s, p-phenenylene
Supple ementary Information Supplementary Figures Supplementary Figure S1. FTIR spectra of azo-cops. The spectra were recorded as KBr pellets. 3400 (s, free N H), 32000 (s, hydrogen bonded N H), 1610 (s,
More informationElectronic Supplementary Information
Electronic Supplementary Information The directing effect of linking unit on building microporous architecture in tetraphenyladmantane-based poly(schiffbase) networks Guiyang Li, Biao Zhang, Jun Yan and
More informationMetal organic Frameworks as Adsorbents for Hydrogen Purification and Pre-Combustion Carbon Dioxide Capture
Supporting Information for: Metal organic Frameworks as Adsorbents for Hydrogen Purification and Pre-Combustion Carbon Dioxide Capture Zoey R. Herm, Joseph A. Swisher, Berend Smit, Rajamani Krishna, Jeffrey
More informationHigh H2 Adsorption by Coordination Framework Materials
Arianna Marchioro Florian Degueldre High H2 Adsorption by Coordination Framework Materials Xiang Lin, Junhua Jia, Xuebo Zhao, K. Mark Thomas, Alexender J. Black, Gavin S. Walker, Neil R. Champness, Peter
More informationA new tetrazolate zeolite-like framework for highly selective CO 2 /CH 4 and CO 2 /N 2 separation
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Material (ESI) for ChemComm. Supporting Information A new tetrazolate
More informationSupporting Information
Supporting Information Highly selective carbon dioxide adsorption in a water-stable Indium-organic framework material Jin-Jie Qian, a,bi Fei-Long Jiang, a Da-Qiang Yuan, a Ming-Yan Wu, a Shu-Quan Zhang,
More informationPhosphonium Salt & ZnX 2 -PPh 3 Integrated Hierarchical POPs: Tailorable Synthesis and Highly Efficient Cooperative Catalysis in CO 2 Utilization
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Supporting Information: Phosphonium Salt & ZnX 2 -PPh 3 Integrated Hierarchical
More informationSupporting Information
Supporting Information Hydrogen Storage in the Dehydrated Prussian Blue Analogues M 3 [Co(CN) 6 ] 2 (M = Mn, Fe, Co, Ni, Cu, Zn) Steven S. Kaye and Jeffrey R. Long* Dept. of Chemistry, University of California,
More informationBuilding multiple adsorption sites in porous polymer networks for carbon capture applications
Electronic Supplementary Information Building multiple adsorption sites in porous polymer networks for carbon capture applications Weigang Lu, a Wolfgang M. Verdegaal, a Jiamei Yu, b Perla B. Balbuena,
More informationSUPPORTING INFORMATION
SUPPORTING INFORMATION Unusual pore structure and sorption behaviour in a hexanodal zinc-organic framework material Jinjie Qian a,b Feilong Jiang, a Linjie Zhang, a,b Kongzhao Su, a,b Jie Pan, a,b Qipeng
More informationCovalent Organic Frameworks in 2013
2014 Super Literature Club@JIANG Lab, IMS Covalent Organic Frameworks in 2013 Presented by Dr. Shangbin Jin Feb. 7, 2014 1 Covalent Organic Frameworks Covalent-bond linked (B-O, C=N,...) Light-weight element
More informationElectronic Supplementary Information (ESI) Framework
Electronic Supplementary Information (ESI) Exceptionally High H 2 Storage by a Metal Organic Polyhedral Framework Yong Yan, Xiang Lin, Sihai Yang, Alexander J. Blake, Anne Dailly, Neil R. Champness, Peter
More informationSupporting Information
Supporting Information Highly Selective Carbon Dioxide Sorption in an Organic Molecular Porous Material Hyunuk Kim, Yonghwi Kim, Minyoung Yoon, Soyoung Lim, Se Min Park, Gon Seo, Kimoon Kim*, National
More informationSimultaneously High Gravimetric and Volumetric Gas Uptake Characteristics of the Metal Organic Framework NU-111
Simultaneously High Gravimetric and Volumetric Gas Uptake Characteristics of the Metal Organic Framework NU-111 Yang Peng, a,b Gadipelli Srinivas a,b, Christopher E. Wilmer, c Ibrahim Eryazici, d Randall
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supporting Information Cyclic Molecule Aerogels: A Robust Cyclodextrin
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information A Highly stable Metal- and Nitrogen-doped Nanocomposite derived from Zn/Ni-ZIF-8
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 15 Supporting Information Co-MOF as sacrificial template: Manifesting new Co
More informationSupporting Information
A Calcium Coordination Framework Having Permanent Porosity and High CO 2 /N 2 Selectivity Debasis Banerjee, a, * Zhijuan Zhang, b Anna M. Plonka, c Jing Li, b, * and John B. Parise a, c, d, * (a) Department
More informationSupplementary figure 1 Molecular electrostatic potential surface of CF 3 X. Reprinted with permission from Supplementary Reference #4.
Supplementary figure 1 Molecular electrostatic potential surface of CF 3 X. Reprinted with permission from Supplementary Reference #4. Copyright 2007 Springer. S1 Supplementary figure 2 Stability tests
More informationA Pyrene-based, Fluorescent Three-dimensional Covalent Organic Framework
Supporting Information A Pyrene-based, Fluorescent Three-dimensional Covalent Organic Framework Guiqing Lin, Huimin Ding, Daqiang Yuan, Baoshan Wang *, and Cheng Wang *, Key Laboratory of Biomedical Polymers
More informationSupporting Information for
1 Supporting Information for 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 Efficient and Selective Uptake of TcO 4 - by a Cationic Metal-Organic Framework Material with Open
More informationSUPPLEMENTARY INFORMATION
doi:10.1038/nature23674 Supplementary Discussion Definitions of compounds Fe 2 Cl 2 (bbta), 1 (H 2 bbta = 1H,5H-benzo(1,2-d:4,5-d )bistriazole) Fe 2 Cl 2 (btdd), 2 (H 2 btdd = bis(1h-1,2,3-triazolo[4,5-b],[4,5
More informationin a Porous Metal-Organic Framework [Zn 2 (BPnDC) 2 (bpy)]
Supporting Information Stepwise and Hysteretic Sorption N 2, O 2, CO 2, and H 2 Gases in a Porous Metal-Organic Framework [Zn 2 (BPnDC) 2 (bpy)] Hye Jeong Park and Myunghyun Paik Suh Contribution from
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) A photoluminescent covalent
More informationSUPPORTING INFORMATION. Enhanced gas-sorption properties of a high surface area, ultramicroporous magnesium formate
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2014 SUPPORTING INFORMATION Enhanced gas-sorption properties of a high surface area, ultramicroporous
More informationLecture 5. Solid surface: Adsorption and Catalysis
Lecture 5 Solid surface: Adsorption and Catalysis Adsorbtion G = H T S DG ads should be negative (spontaneous process) DS ads is negative (reduced freedom) DH should be negative for adsorption processes
More informationElectronic Supporting Information
Electronic Supporting Information Fluorescent Microporous Polyimides based on Perylene and Triazine for Highly CO 2 -Selective Carbon Materials Yaozu Liao, a Jens Weber b and Charl F.J. Faul a* a School
More informationHigh-Connected Mesoporous Metal Organic Framework
Supporting Information High-Connected Mesoporous Metal Organic Framework Xiaojun Gu, a Zhang-Hui Lu a,b and Qiang Xu* a,b a National Institute of Advanced Industrial Science and Technology (AIST), Ikeda,
More informationSupporting Information. Directing the Breathing Behavior of Pillared-Layered. Metal Organic Frameworks via a Systematic Library of
Supporting Information Directing the Breathing Behavior of Pillared-Layered Metal Organic Frameworks via a Systematic Library of Functionalized Linkers Bearing Flexible Substituents Sebastian Henke, Andreas
More informationSupplementary Information. Supplementary Figure 1 Synthetic routes to the organic linker H 2 ATBDC.
Supplementary Information Supplementary Figure 1 Synthetic routes to the organic linker H 2 ATBDC. S1 Supplementary Figure 2 1 H NMR (D 2 O, 500MHz) spectrum of H 2 ATBDC. S2 Supplementary Figure 3 13
More informationExperimental Methods and Analysis
Chapter 3 28 Experimental Methods and Analysis 1. Equipment The fundamental basis of quantitative adsorption analysis is the measurement of excess adsorption isotherms. Each isotherm comprises a series
More information3.5. Kinetic Approach for Isotherms
We have arrived isotherm equations which describe adsorption from the two dimensional equation of state via the Gibbs equation (with a saturation limit usually associated with monolayer coverage). The
More informationElectronic Supporting information (ESI) for
Electronic Supporting information (ESI) for Experimental assessment of physical upper limit for hydrogen storage capacity at 20 K in densified MIL-101 monoliths Hyunchul Oh a, Dan Lupu b, Gabriela Blanita
More informationSupporting Information. Adsorption of Aromatic Chemicals by Carbonaceous Adsorbents: A
Supporting Information Adsorption of Aromatic Chemicals by Carbonaceous Adsorbents: A Comparative Study on Granular Activated Carbon, Activated Carbon Fiber and Carbon Nanotubes Shujuan Zhang, Ting Shao,
More informationSupporting Information
S1 Submitted to J. Am. Chem. Soc. Supporting Information A porous coordination copolymer with over 5000 m 2 /g BET surface area Kyoungmoo Koh, Antek G. Wong-Foy, and Adam J. Matzger* Department of Chemistry,
More informationADSORPTION IN MICROPOROUS MATERIALS: ANALYTICAL EQUATIONS FOR TYPE I ISOTHERMS AT HIGH PRESSURE
ADSORPTION IN MICROPOROUS MATERIALS: ANALYTICAL EQUATIONS FOR TYPE I ISOTHERMS AT HIGH PRESSURE A. L. MYERS Department of Chemical and Biomolecular Engineering University of Pennsylvania, Philadelphia
More informationSupporting Information for. Linker-Directed Vertex Desymmetrization for the Production of Coordination Polymers. with High Porosity
Supporting Information for Linker-Directed Vertex Desymmetrization for the Production of Coordination Polymers with High Porosity Jennifer K. Schnobrich, Olivier Lebel,, Katie A. Cychosz, Anne Dailly,
More informationHigh-Pressure Volumetric Analyzer
High-Pressure Volumetric Analyzer High-Pressure Volumetric Analysis HPVA II Benefits Dual free-space measurement for accurate isotherm data Free space can be measured or entered Correction for non-ideality
More informationPreparation of biomass derived porous carbon: Application for methane energy storage
Edith Cowan University Research Online ECU Publications Post 013 016 Preparation of biomass derived porous carbon: Application for methane energy storage Yong Sun Edith Cowan University, y.sun@ecu.edu.au
More informationMicroporous Carbon adsorbents with high CO 2 capacities for industrial applications
Microporous Carbon adsorbents with high CO 2 capacities for industrial applications Santiago Builes, a,b Thomas Roussel,* b Camelia Matei Ghimbeu, c Julien Parmentier, c Roger Gadiou, c Cathie Vix-Guterl
More informationSupporting Information
Supporting Information Diamine-functionalized metal-organic framework: Exceptionally high capacities from ambient air and flue gas, ultrafast uptake rate, and adsorption mechanism Woo Ram Lee, Sang Yeon
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supporting Information Hyperbranched Poly(ether amine)@poly (vinylidenene
More informationHydrogen Storage in the Expanded Pore Metal-Organic Frameworks M 2 (dobpdc) (M = Mg, Mn, Fe, Co, Ni, Zn)
Supporting Information for: Hydrogen Storage in the Expanded Pore Metal-Organic Frameworks M 2 (dobpdc) (M = Mg, Mn, Fe, Co, Ni, Zn) David Gygi, Eric D. Bloch, Jarad A. Mason, Matthew R. Hudson, Miguel
More informationOptimized Separation of Acetylene from Carbon Dioxide. and Ethylene in a Microporous Material
Supporting Information Optimized Separation of Acetylene from Carbon Dioxide and Ethylene in a Microporous Material Rui-Biao Lin, 1 Libo Li, 1,3 Hui Wu, 2 Hadi Arman, 1 Bin Li, 1 Rong-Guang Lin, 1,4 Wei
More informationSupporting Information for the manuscript. Metastable interwoven mesoporous metal-organic frameworks
S1 Supporting Information for the manuscript Metastable interwoven mesoporous metal-organic frameworks Yabing He, ab Zhiyong Guo, b Shengchang Xiang, c Zhangjing Zhang, c Wei Zhou, d,e Frank R. Fronczek,
More informationCross-Linking Amine-Rich Compounds into High Performing Selective CO 2 Absorbents
Supplementary Information for Cross-Linking Amine-Rich Compounds into High Performing Selective CO 2 Absorbents Enrico Andreoli, Eoghan P. Dillon, Laurie Cullum, Lawrence B. Alemany, Andrew R. Barron*
More informationSupporting Information
Supporting Information Mixed-linker MOFs with CAU-10 structure: synthesis and gas sorption characteristics Helge Reinsch, Steve Waitschat and Norbert Stock S1: 1 H-NMR-spectra of dissolved CAU-10-X samples
More informationDepartment of Chemistry, Pohang University of Science and Technology, Pohang ,
Highly stable CO 2 /N 2 and CO 2 /CH 4 selectivity in hypercrosslinked heterocyclic porous polymers Muhammad Saleh,, Han Myoung Lee, K. Christian Kemp and Kwang S. Kim*, Department of Chemistry, Pohang
More informationDESIGNED SYNTHESIS OF NANOPOROUS ORGANIC POLYMERS FOR SELECTIVE GAS UPTAKE AND CATALYTIC APPLICATIONS
Virginia Commonwealth University VCU Scholars Compass Theses and Dissertations Graduate School 2015 DESIGNED SYNTHESIS OF NANOPOROUS ORGANIC POLYMERS FOR SELECTIVE GAS UPTAKE AND CATALYTIC APPLICATIONS
More informationSupporting Information
Copyright WILEY-VCH Verlag GmbH & Co. KGaA, 69469 Weinheim, Germany, 2012. Supporting Information for Adv. Mater., DOI: 10.1002/adma.201202447 Hypercrosslinked Aromatic Heterocyclic Microporous Polymers:
More informationElectronic Supplementary Information. Noninvasive Functionalization of Polymers of Intrinsic Microporosity for Enhanced CO 2 Capture
Electronic Supplementary Information Noninvasive Functionalization of Polymers of Intrinsic Microporosity for Enhanced CO 2 Capture Hasmukh A. Patel and Cafer T. Yavuz* Oxide and Organic Nanomaterials
More informationSupplementary Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Supplementary Information Rendering Non-Energetic Microporous Coordination Polymers Explosive Kyle
More informationElectronic supplementary information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Electronic supplementary information Heterogeneous nucleation and growth of highly crystalline
More informationSustainable Hydrogen and Electrical Energy Storage 6. F.M. Mulder & M. Wagemaker
Sustainable Hydrogen and Electrical Energy Storage 6 F.M. Mulder & M. Wagemaker 1 Comparison liquid and gaseous H 2 with other liquid fuels Natural gas gasoline Volumetric energy density H 2 is lower than
More informationAdsorption of Methylene Blue on Mesoporous SBA 15 in Ethanol water Solution with Different Proportions
2015 2 nd International Conference on Material Engineering and Application (ICMEA 2015) ISBN: 978-1-60595-323-6 Adsorption of Methylene Blue on Mesoporous SBA 15 in Ethanol water Solution with Different
More informationDepartment of Chemistry, University of California, Berkeley, California, , USA. b
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information for: Structural characterization of framework gas
More informationElectronic Supplementary Information for. Non-interpenetrated IRMOF-8: synthesis, activation, and gas sorption
S1 Electronic Supplementary Information for Non-interpenetrated IRMOF-8: synthesis, activation, and gas sorption Jeremy I. Feldblyum, a,b Antek G. Wong-Foy, b and Adam J. Matzger a,b a Macromolecular Science
More informationSchwarzites for Natural Gas Storage: A Grand- Canonical Monte Carlo Study
Schwarzites for Natural Gas Storage: A Grand- Canonical Monte Carlo Study Daiane Damasceno Borges 1, Douglas S. Galvao 1 1 Applied Physics Department and Center of Computational Engineering and Science,
More informationDistinguish quantitatively between the adsorption isotherms of Gibbs, Freundlich and Langmuir.
Module 8 : Surface Chemistry Lecture 36 : Adsorption Objectives After studying this lecture, you will be able to Distinguish between physisorption and chemisorption. Distinguish between monolayer adsorption
More informationSUPPORTING INFORMATION. and Mark E. Davis*
SUPPORTING INFORMATION Active Sites in Sn-Beta for Glucose Isomerization to Fructose and Epimerization to Mannose Ricardo Bermejo-Deval, Marat Orazov, Rajamani Gounder** Son-Jong Hwang and Mark E. Davis*
More informationSorption, Transport and Gas Separation Properties of Zn-Based Metal. Organic Frameworks (MOFs) and their Application in CO 2 Capture.
Sorption, Transport and Gas Separation Properties of Zn-Based Metal Organic Frameworks (MOFs) and their Application in CO 2 Capture. Carlos José Landaverde Alvarado Dissertation submitted to the faculty
More informationGrant agreement No ShaleXenvironmenT. Maximizing the EU shale gas potential by minimizing its environmental footprint
Grant agreement No. 640979 ShaleXenvironmenT Maximizing the EU shale gas potential by minimizing its environmental footprint H2020-LCE-2014-1 Competitive low-carbon energy D7.2 Full experimental materials
More informationPermanently Porous Single Molecule H-Bonded Organic Framework for Selective CO 2 Capture
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Supporting information for Permanently Porous Single Molecule H-Bonded Organic Framework for Selective
More informationA flexible MMOF exhibiting high selectivity for CO 2 over N 2, CH 4 and other small gases. Supporting Information
A flexible MMOF exhibiting high selectivity for CO 2 over N 2, CH 4 and other small gases Jingming Zhang, a Haohan Wu, a Thomas J. Emge, a and Jing Li* a a Department of Chemistry and Chemical Biology,
More informationElectronic Supporting Information (ESI) Porous Carbon Materials with Controllable Surface Area Synthsized from Metal-Organic Frameworks
Electronic Supporting Information (ESI) Porous Carbon Materials with Controllable Surface Area Synthsized from Metal-Organic Frameworks Seunghoon Lim, Kyungwon Suh, Yelin Kim, Minyoung Yoon, Hyeran Park,
More informationA triazine-based covalent organic polymer for efficient CO 2 adsorption
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2015 Supporting Information A triazine-based covalent organic polymer for efficient CO
More informationSUPPLEMENTARY INFORMATION
A partially interpenetrated metal organic framework for selective hysteretic sorption of carbon dioxide Sihai Yang, 1 * Xiang Lin, 1 William Lewis, 1 Mikhail Suyetin, 1 Elena Bichoutskaia, 1 Mikhail Suyetin,
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Micro- and mesoporous poly(schiff-base)s
More informationDry-gel conversion synthesis of Cr-MIL-101 aided by grinding: High surface area high yield synthesis with minimum purification
Electronic Supporting Informations (ESI): Dry-gel conversion synthesis of Cr-MIL-101 aided by grinding: High surface area high yield synthesis with minimum purification Jun Kim, Yu-Ri Lee and Wha-Seung
More informationConductive Activation Carbon Monoliths Prepared Directly from Brown Coal Applications in Gas and Liquid Adsorption
Conductive Activation Carbon Monoliths Prepared Directly from Brown Coal Applications in Gas and Liquid Adsorption Mehrdad Parsa, Emma Qi, Alan. L. Chaffee School of Chemistry 12 th ECCRIA 5-7 Sept, Cardiff
More informationA Third Generation Breathing MOF with Selective, Stepwise, Reversible and Hysteretic Adsorption properties
Supporting information for A Third Generation Breathing MOF with Selective, Stepwise, Reversible and Hysteretic Adsorption properties Suresh Sanda, Srinivasulu Parshamoni and SanjitKonar* Department of
More informationDMOF-1 as a Representative MOF for SO 2 Adsorption in both Humid and Dry Conditions
DMOF-1 as a Representative MOF for SO 2 Adsorption in both Humid and Dry Conditions Julian Hungerford, Souryadeep Bhattacharyya, Uma Tumuluri, Sankar Nair, Zili Wu, and Krista S. Walton* School of Chemical
More information