3.012 Fund of Mat Sci: Bonding Lecture 10

General Chemistry. Contents. Chapter 12: Chemical Bonding II: Additional Aspects What a Bonding Theory Should Do. Potential Energy Diagram

General Chemistry Principles and Modern Applications Petrucci Harwood Herring 8 th Edition Chapter 12: Chemical Bonding II: Additional Aspects Philip Dutton University of Windsor, Canada N9B 3P4 Contents

Chapter 12: Chemical Bonding II: Additional Aspects

General Chemistry Principles and Modern Applications Petrucci Harwood Herring 8 th Edition Chapter 12: Chemical Bonding II: Additional Aspects Philip Dutton University of Windsor, Canada N9B 3P4 Prentice-Hall

3.012 Fund of Mat Sci: Bonding Lecture 13 THE DANCE OF SHIVA

3.012 Fund of Mat Sci: Bonding Lecture 13 THE DANCE OF SHIVA Source: Wikipedia Homework for Mon Oct 31 Study:18.1 (quantum oscillator), 28.1 and 28.2 (symmetry) Read 18.6 (classical harmonic oscillator)

would represent a 1s orbital centered on the H atom and φ 2px )+ 1 r 2 sinθ

Physical Chemistry for Engineers CHEM 4521 Homework: Molecular Structure (1) Consider the cation, HeH +. (a) Write the Hamiltonian for this system (there should be 10 terms). Indicate the physical meaning

Lecture 16 C1403 October 31, Molecular orbital theory: molecular orbitals and diatomic molecules

Lecture 16 C1403 October 31, 2005 18.1 Molecular orbital theory: molecular orbitals and diatomic molecules 18.2 Valence bond theory: hybridized orbitals and polyatomic molecules Bond order, bond lengths,

Contents. 1. Basic Concepts. 2. The Covalent Bond. 3. The Valence-Shell Electron-Pair Repulsion Models 4. Bond theories. 5. The Metallic Bond.

Chemical Bonding (II) Topic 4. Chemical Bonding (II) (II) 1 Contents 1. Basic Concepts. a) Molecular parameters b) Lewis Dot Symbols 2. The Covalent Bond a) Polar Covalent Bond b) Formal Charge c) Exceptions

σ u * 1s g - gerade u - ungerade * - antibonding σ g 1s

One of these two states is a repulsive (dissociative) state. Other excited states can be constructed using linear combinations of other orbitals. Some will be binding and others will be repulsive. Thus

ECE 535 Theory of Semiconductors and Semiconductor Devices Fall 2015 Homework # 5 Due Date: 11/17/2015

ECE 535 Theory of Semiconductors and Semiconductor Devices Fall 2015 Homework # 5 Due Date: 11/17/2015 Problem # 1 Two carbon atoms and four hydrogen atoms form and ethane molecule with the chemical formula

1s atomic orbital 2s atomic orbital 2s atomic orbital (with node) 2px orbital 2py orbital 2pz orbital

Atomic Orbitals 1s atomic orbital 2s atomic orbital 2s atomic orbital (with node) 2px orbital 2py orbital 2pz orbital Valence Bond Theory and ybridized Atomic Orbitals Bonding in 2 1s 1s Atomic Orbital

Molecular Structure. Valence Bond Theory Overlap of atomic orbitals is a covalent bond that joins atoms together to form a molecule

Molecular Structure Topics 3-D structure shape (location of atoms in space) Molecular Geometry Valence Bond Theory Hybrid Orbitals Multiple Bonds VSEPR (Valence Shell Electron Pair Repulsion) Valence Bond

Hybridization of Orbitals

Hybridization of Orbitals Structure & Properties of Matter 1 Atomic Orbitals and Bonding Previously: Electron configurations Lewis structures Bonding Shapes of molecules Now: How do atoms form covalent

Hybridisation 1. Hybridisation involves 1. Inter mixing of electron s 2. Inter mixing and redistribution of atomic orbitals of only one atom 3. Inter mixing and redistribution of atomic orbitals of different

Chapter 5 Molecular. removed are labeled in brackets as the chapter opener is below. [Chapter opener]

Chapter 5 Molecular Orbitals Figures and table removed are labeled in brackets as the chapter opener is below [Chapter opener] 5.1 Formation of Molecular Orbitals from Atomic Orbitals Molecular Orbitals

Lecture Notes D: Molecular Orbital Theory

Lecture Notes D: Molecular Orbital Theory Orbital plotting applet: http://www.mpcfaculty.net/mark_bishop/hybrid_frame.htm Images below from: http://employees.oneonta.edu/viningwj/chem111/hybrids%20and%20pi%20bonding.jpg

3.012 Fund of Mat Sci: Bonding Lecture 11. The future of electronics? A pentacene molecule deposited on SiO 2. Image removed for copyright reasons.

3.012 Fund of Mat Sci: Bonding Lectue 11 BONDING IN MOLECULES The futue of electonics? A pentacene molecule deposited on SiO 2 as a thin film Image emoved fo copyight easons. 3.012 Fundamentals of Mateials

Molecular Structure and Bonding- 2. Assis.Prof.Dr.Mohammed Hassan Lecture 3

Molecular Structure and Bonding- 2 Assis.Prof.Dr.Mohammed Hassan Lecture 3 Hybridization of atomic orbitals Orbital hybridization was proposed to explain the geometry of polyatomic molecules. Covalent

8.3 Bonding Theories > Chapter 8 Covalent Bonding. 8.3 Bonding Theories. 8.1 Molecular Compounds 8.2 The Nature of Covalent Bonding

Chapter 8 Covalent Bonding 8.1 Molecular Compounds 8.2 The Nature of Covalent Bonding 8.3 Bonding Theories 8.4 Polar Bonds and Molecules 1 Copyright Pearson Education, Inc., or its affiliates. All Rights

4 Copyright Pearson Education, Inc., or its affiliates. All Rights Reserved.

CHEMISTRY & YOU Chapter 8 Covalent Bonding 8.1 Molecular Compounds 8.2 The Nature of Covalent Bonding 8.3 Bonding Theories 8.4 Polar Bonds and Molecules 1 Copyright Pearson Education, Inc., or its affiliates.

Lecture 16 C1403 October 31, Molecular orbital theory: molecular orbitals and diatomic molecules

Lecture 16 C1403 October 31, 2005 18.1 Molecular orbital theory: molecular orbitals and diatomic molecules 18.2 Valence bond theory: hybridized orbitals and polyatomic molecules. From steric number to

Organic Chemistry. 2 nd Stage Pharmacy/ Undergraduate

Organic Chemistry 2 nd Stage Pharmacy/ Undergraduate Time of Lectures: Saturday; 8:30-11:30 am Instructor: Wrya O. Karim University email: wrya.karim@univsul.edu.iq Personal email: wrya.othman49@gmail.com

1. Which is the most electronegative atom in the compound below?

1. Which is the most electronegative atom in the compound below? A) Carbon C) Oxygen B) Nitrogen D) Bromine 2. Which of the following correctly describes the electrons of a carbon atom in its ground state?

Chemical Bonds, Orbital Shapes, and Orbital Hybridization

Chemical Bonds, Orbital Shapes, and Orbital Hybridization PRELAB ASSIGNMENT Read the entire laboratory write up. Write an objective and answer the following questions in your laboratory notebook before

Chapter 3. Orbitals and Bonding

Chapter 3. Orbitals and Bonding What to master Assigning Electrons to Atomic Orbitals Constructing Bonding and Antibonding Molecular Orbitals with Simple MO Theory Understanding Sigma and Pi Bonds Identifying

Bonding SL/HL Network/Metallic HL Topics Hybrid Orbitals. IB Chemistry Topic 04 - Bonding

Bonding SL/HL Network/Metallic HL Topics Hybrid Orbitals IB Chemistry Topic 04 - Bonding Bond Type Properties Hydrocarbon C 2 H 6 Ethane C 2 H 4 Ethene C 2 H 2 Ethyne Structural Formula H H H H H H H H

- H. Predicts linear structure. Above are all σ bonds

arbon sp hybrids: : Acetylene and the Triple bond 2 2 is - - Form sp on each leaving 2p x, 2p y unused - sp sp + + sp sp - Predicts linear structure. Above are all σ bonds --- Uses up 2 valence e - for

VSEPR Model. Valence-Shell Electron-Pair Repulsion Bonds (single or multiple) and lone pairs are thought of as charge clouds

Molecular Shapes VSEPR Model Valence-Shell Electron-Pair Repulsion Bonds (single or multiple) and lone pairs are thought of as charge clouds They repel each other and stay as far away from each other as

Unit3Day4-LaBrake. Important Information. Is the molecule CH 2 Cl 2? Vanden Bout/LaBrake/Crawford CH301

Unit3Day4-LaBrake Page 1 Unit3Day4-LaBrake Monday, October 21, 2013 11:32 AM Vanden Bout/LaBrake/Crawford CH301 WHY DOES A FROG FLOAT IN A MAGNETIC FIELS? MORE ON BONDING THEORIES UNIT 3 Day 4 Important

Chapter 10 Theories of Covalent Bonding

Chapter 10 Theories of Covalent Bonding 1 Atomic Orbitals Molecules Bonding and 2 Molecular Structure Questions How are molecules held together? Why is O 2 paramagnetic? And how is this property connected

Molecular Geometry and Bonding Theories. Chapter 9

Molecular Geometry and Bonding Theories Chapter 9 Molecular Shapes CCl 4 Lewis structures give atomic connectivity; The shape of a molecule is determined by its bond angles VSEPR Model Valence Shell Electron

Ch. 9 Practice Questions

Ch. 9 Practice Questions 1. The hybridization of the carbon atom in the cation CH + 3 is: A) sp 2 B) sp 3 C) dsp D) sp E) none of these 2. In the molecule C 2 H 4 the valence orbitals of the carbon atoms

Learning Check. Determine the VSEPRT geometry, bond angle, and hybridization of each indicated atom in the following molecule.

Learning Check Determine the VSEPRT geometry, bond angle, and hybridization of each indicated atom in the following molecule. 1 Types of Covalent Bonds 1. A sigma (σ) bond is formed by endto-end overlap

like carbon, has fewer than an octet. It is simply less likely but still imperative to draw.

Andrew Rosen Chapter 1: The Basics - Bonding and Molecular Structure 1.1 - We Are Stardust - Organic chemistry is simply the study of carbon-based compounds, hydrocarbons, and their derivatives, which

Physical Chemistry (II) CHEM Lecture 12 Molecular Structure. Lecturer: Hanning Chen, Ph.D. 02/28/2018

Physical Chemistry (II) CHEM 3172-80 Lecture 12 Molecular Structure Lecturer: Hanning Chen, Ph.D. 02/28/2018 Quiz 11 5 minutes Please stop writing when the timer stops! Three Types of Chemical Bonds What

MO theory is better for spectroscopy (Exited State Properties; Ionization)

CHEM 2060 Lecture 25: MO Theory L25-1 Molecular Orbital Theory (MO theory) VB theory treats bonds as electron pairs. o There is a real emphasis on this point (over-emphasis actually). VB theory is very

Chemistry 881 Lecture Topics Fall 2001

Chemistry 881 Lecture Topics Fall 2001 Texts PHYSICAL CHEMISTRY A Molecular Approach McQuarrie and Simon MATHEMATICS for PHYSICAL CHEMISTRY, Mortimer i. Mathematics Review (M, Chapters 1,2,3 & 4; M&S,

Chem 442 Review for Exam 2. Exact separation of the Hamiltonian of a hydrogenic atom into center-of-mass (3D) and relative (3D) components.

Chem 44 Review for Exam Hydrogenic atoms: The Coulomb energy between two point charges Ze and e: V r Ze r Exact separation of the Hamiltonian of a hydrogenic atom into center-of-mass (3D) and relative

Covalent Bonding - Orbitals

Covalent Bonding - Orbitals ybridization - The Blending of Orbitals + = Poodle + Cocker Spaniel = Cockapoo + = s orbital + p orbital = sp orbital What Proof Exists for ybridization? We have studied electron

14.1 Shapes of molecules and ions (HL)

14.1 Shapes of molecules and ions (HL) The octet is the most common electron arrangement because of its stability. Exceptions: a) Fewer electrons (incomplete octet) if the central atom is a small atoms,

CHEMISTRY Topic #1: Bonding What Holds Atoms Together? Spring 2012 Dr. Susan Lait

CHEMISTRY 2000 Topic #1: Bonding What Holds Atoms Together? Spring 2012 Dr. Susan Lait Why Do Bonds Form? An energy diagram shows that a bond forms between two atoms if the overall energy of the system

Carbon Compounds. Electronegativity. Chemical Bonding Part 1c. Bond Polarity. Bond Polarity

Electronegativity Carbon Compounds Electronegativity is a relative measure on the pull of electrons by an atom in a bond. Most bonds fall somewhere in between and these bonds are considered polar. Chemical

What are we going to learn today?

UNIT3DAY4-LaB Page 1 UNIT3DAY4-LaB Tuesday, October 23, 2012 8:29 AM Vanden Bout/LaBrake CH301 WHY IS EVERYTHING SO DIFFERENT? MORE ON BONDING THEORIES UNIT 3 Day 4 Important Information LM22 DUE Th 9AM

Chemistry 2000 Lecture 1: Introduction to the molecular orbital theory

Chemistry 2000 Lecture 1: Introduction to the molecular orbital theory Marc R. Roussel January 5, 2018 Marc R. Roussel Introduction to molecular orbitals January 5, 2018 1 / 24 Review: quantum mechanics

Molecular Orbitals. Based on Inorganic Chemistry, Miessler and Tarr, 4 th edition, 2011, Pearson Prentice Hall

Molecular Orbitals Based on Inorganic Chemistry, Miessler and Tarr, 4 th edition, 2011, Pearson Prentice Hall Images from Miessler and Tarr Inorganic Chemistry 2011 obtained from Pearson Education, Inc.

Organic Chemistry. an introduction. Dr.Anandhi Sridharan

1 Organic Chemistry an introduction Dr.Anandhi Sridharan 2 Introduction Organic chemistry is the study of carbon compounds. These organic compounds constitute essential compounds of our blood, muscles

QUANTUM MECHANICS AND MOLECULAR STRUCTURE

6 QUANTUM MECHANICS AND MOLECULAR STRUCTURE 6.1 Quantum Picture of the Chemical Bond 6.2 Exact Molecular Orbital for the Simplest Molecule: H + 2 6.3 Molecular Orbital Theory and the Linear Combination

Covalent Bonding: Orbitals

Hybridization and the Localized Electron Model Covalent Bonding: Orbitals A. Hybridization 1. The mixing of two or more atomic orbitals of similar energies on the same atom to produce new orbitals of equal

Study flashcards. Elements Polyatomic ions: be sure to learn the chemical. Slide 1of 29

Study flashcards Elements Polyatomic ions: be sure to learn the chemical formula AND the charge 1of 29 Write the formula for: 1. Phosphate PO 4 3 2. Nitrate NO 3 3. Carbonate CO 3 2 4. Sulfate SO 4 2 5.

Lecture B6 Molecular Orbital Theory. Sometimes it's good to be alone.

Lecture B6 Molecular Orbital Theory Sometimes it's good to be alone. Covalent Bond Theories 1. VSEPR (valence shell electron pair repulsion model). A set of empirical rules for predicting a molecular geometry

Chapter 10 Chemical Bonding II

Chapter 10 Chemical Bonding II Valence Bond Theory Valence Bond Theory: A quantum mechanical model which shows how electron pairs are shared in a covalent bond. Bond forms between two atoms when the following

Chapter 10: Chemical Bonding II. Bonding Theories

Chapter 10: Chemical Bonding II Dr. Chris Kozak Memorial University of Newfoundland, Canada Bonding Theories Previously, we saw how the shapes of molecules can be predicted from the orientation of electron

CHEMISTRY. Chapter 8 ADVANCED THEORIES OF COVALENT BONDING Kevin Kolack, Ph.D. The Cooper Union HW problems: 6, 7, 12, 21, 27, 29, 41, 47, 49

CHEMISTRY Chapter 8 ADVANCED THEORIES OF COVALENT BONDING Kevin Kolack, Ph.D. The Cooper Union HW problems: 6, 7, 12, 21, 27, 29, 41, 47, 49 2 CH. 8 OUTLINE 8.1 Valence Bond Theory 8.2 Hybrid Atomic Orbitals

ANNOUNCEMENTS. If you have questions about your exam 2 grade, write to me or Chapter 8 homework due April. 13 th.

ANNOUNCEMENTS If you have questions about your exam 2 grade, write to me or Chem200@mail.sdsu.edu. Chapter 8 homework due April. 13 th. Chapter 9 home work due April. 20th. Exam 3 is 4/14 at 2 pm. LECTURE

Chemical Bonding II: Molecular Geometry and Hybridization of Atomic Orbitals Chapter 10

Chemical Bonding II: Molecular Geometry and Hybridization of Atomic Orbitals Chapter 10 Linear Trigonal 180 o planar 120 o Tetrahedral 109.5 o Trigonal Bipyramidal 120 and 90 o Octahedral 90 o linear Linear

Chemistry 483 Lecture Topics Fall 2009

Chemistry 483 Lecture Topics Fall 2009 Text PHYSICAL CHEMISTRY A Molecular Approach McQuarrie and Simon A. Background (M&S,Chapter 1) Blackbody Radiation Photoelectric effect DeBroglie Wavelength Atomic

Lecture 9: Molecular Orbital theory for hydrogen molecule ion

Lecture 9: Molecular Orbital theory for hydrogen molecule ion Molecular Orbital Theory for Hydrogen Molecule Ion We have seen that the Schrödinger equation cannot be solved for many electron systems. The

1. Know which elements correspond to metals, non-metals, and semi-conductors

Chemistry 106 Lectures 2 & 3: Chemical Foundations II: Atomic Structure and the Periodic Table; Properties of Important Elements; Ionic vs. Covalent Bonding; Lewis Structures; Drawing Molecules 9/26/18,

:C O: σorbitals of CO. πorbitals of CO. Assumed knowledge. Chemistry 2. Learning outcomes. Lecture 2 Particle in a box approximation. C 2p.

Chemistry 2 Lecture 2 Particle in a bo approimation Assumed knowledge Be able to predict the geometry of a hydrocarbon from its structure and account for each valence electron. Predict the hybridization

Chapter 9 - Covalent Bonding: Orbitals

Chapter 9 - Covalent Bonding: Orbitals 9.1 Hybridization and the Localized Electron Model A. Hybridization 1. The mixing of two or more atomic orbitals of similar energies on the same atom to produce new

CLASSICAL OR QUANTUM?

3.012 Fund of Mat Sci: Bonding Lecture 1 CLASSICAL OR QUANTUM? Reading Material (Bonding) Textbook: Engel and Reid, Physical Chemistry, Pearson (2006) Further readings for the first half of the course

Essential Organic Chemistry. Chapter 1

Essential Organic Chemistry Paula Yurkanis Bruice Chapter 1 Electronic Structure and Covalent Bonding Periodic Table of the Elements 1.1 The Structure of an Atom Atoms have an internal structure consisting

Chemical Bonding & Structure

Chemical Bonding & Structure Further aspects of covalent bonding and structure Hybridization Ms. Thompson - HL Chemistry Wooster High School Topic 14.2 Hybridization A hybrid orbital results from the mixing

Ch 125a Problem Set 1

Ch 5a Problem Set Due Monday, Oct 5, 05, am Problem : Bra-ket notation (Dirac notation) Bra-ket notation is a standard and convenient way to describe quantum state vectors For example, φ is an abstract

Lecture 10. Born-Oppenheimer approximation LCAO-MO application to H + The potential energy surface MOs for diatomic molecules. NC State University

Chemistry 431 Lecture 10 Diatomic molecules Born-Oppenheimer approximation LCAO-MO application to H + 2 The potential energy surface MOs for diatomic molecules NC State University Born-Oppenheimer approximation

Chapter 1 Carbon Compounds and Chemical Bonds

Chapter 1 Carbon Compounds and Chemical Bonds Introduction Organic Chemistry The chemistry of the compounds of carbon The human body is largely composed of organic compounds Organic chemistry plays a central

Molecular Structure and Orbitals

CHEM 1411 General Chemistry Chemistry: An Atoms First Approach by Zumdahl 2 5 Molecular Structure and Orbitals Chapter Objectives: Learn the basics of Valence Bond Theory and Molecular Orbital Theory and

HYBRIDIZATION THEORY

HYBRIDIZATION THEORY According to carbon's orbital diagram, it should only be able to form two bonds... 1s 2s 2p But we know carbon forms 4 bonds, not 2!!! Dec 5 8:19 PM HYBRIDIZATION THEORY Scientists

Chapter 9 Molecular Geometry Valence Bond and Molecular Orbital Theory

Chapter 9 Molecular Geometry Valence Bond and Molecular Orbital Theory Chapter Objectives: Learn the basics of Valence Bond Theory and Molecular Orbital Theory and how they are used to model covalent bonding.

We can model covalent bonding in molecules in essentially two ways:

CHEM 2060 Lecture 22: VB Theory L22-1 PART FIVE: The Covalent Bond We can model covalent bonding in molecules in essentially two ways: 1. Localized Bonds (retains electron pair concept of Lewis Structures)

5.111 Principles of Chemical Science

MIT OpenCourseWare http://ocw.mit.edu 5.111 Principles of Chemical Science Fall 2008 For information about citing these materials or our Terms of Use, visit: http://ocw.mit.edu/terms. 5.111 Lecture Summary

Chemistry 2000 Lecture 8: Valence bond theory

Chemistry 000 Lecture 8: Valence bond theory Marc R. Roussel January 9, 08 Marc R. Roussel Valence bond theory January 9, 08 / 5 MO theory: a recap A molecular orbital is a one-electron wavefunction which,

Downloaded from

I.I.T.Foundation - XI Chemistry MCQ #4 Time: 45 min Student's Name: Roll No.: Full Marks: 90 Chemical Bonding I. MCQ - Choose Appropriate Alternative 1. The energy required to break a chemical bond to

3.012 Quiz Fall points total (50 in thermo + 50 in bonding)

3.012 Quiz 2 3.012 11.14.05 Fall 2005 100 points total (50 in thermo + 50 in bonding) Give as much written explanation as possible of your reasoning, and write clearly and legibly. There is plenty of space

CURIOSITY KILLED THE CAT

3.012 Fund of Mat Sci: Bonding Lecture 4 CURIOSITY KILLED THE CAT Last Time Expectation values of the energy in an infinite well (particle-in-a-box) Absorption lines (linear conjugated molecules) Particles

Hybridization of Atomic Orbitals. (Chapter 1 in the Klein text)

Hybridization of Atomic Orbitals (Chapter 1 in the Klein text) Basic Ideas The atomic structures, from the Periodic Table, of atoms such as C, N, and O do not adequately explain how these atoms use orbitals

Chapter 9. Covalent Bonding: Orbitals

Chapter 9 Covalent Bonding: Orbitals Chapter 9 Table of Contents 9.1 Hybridization and the Localized Electron Model 9.2 The Molecular Orbital Model 9.3 Bonding in Homonuclear Diatomic Molecules 9.4 Bonding

DAMIETTA UNIVERSITY CHEM-103: BASIC ORGANIC CHEMISTRY LECTURES 1-2. Dr Ali El-Agamey LEARNING OUTCOMES LECTURES 1-2

DAMIETTA UNIVERSITY EM-103: BASI RGANI EMISTRY LETURES 1-2 Dr Ali El-Agamey ١ LEARNING UTMES LETURES 1-2 Appreciate the importance of organic chemistry. Draw the structures of organic compounds using Lewis,

Carbon Compounds and Chemical Bonds

Carbon Compounds and Chemical Bonds Introduction Organic Chemistry The chemistry of the compounds of carbon The human body is largely composed of organic compounds Organic chemistry plays a central role

Molecular Orbital Theory

Molecular Orbital Theory Paramagnetic properties of O 2 pranjoto utomo Covalent Bonding Theory Valence Bond Theory useful for deriving shapes/polarity simple but inaccurate/deficient Molecular Orbital

Covalent Bonding and Molecular Structures

CHAPTERS 9 AND 10 Covalent Bonding and Molecular Structures Objectives You will be able to: 1. Write a description of the formation of the covalent bond between two hydrogen atoms to form a hydrogen molecule.

Localized Electron Model

Localized Electron Model Models for Chemical Bonding Localized electron model (Valence bond model) Molecular orbital model Localized Electron Model Useful for explaining the structure of molecules especially

Chapter Molecules are 3D. Shapes and Bonds. Chapter 9 1. Chemical Bonding and Molecular Structure

Chapter 9 Chemical Bonding and Molecular Structure 1 Shape 9.1 Molecules are 3D Angle Linear 180 Planar triangular (trigonal planar) 120 Tetrahedral 109.5 2 Shapes and Bonds Imagine a molecule where the

LOBs covered during tutorials: 7. Solve exercises related to atomic structure, electronic configurations, and periodic properties.

Course Code Course Title ECTS Credits MED-102 General Chemistry 6 School Semester Prerequisites Medical School Fall (Semester 1) None Type of Course Field Language of Instruction Required Medicine English

Chapter 9 Molecular Geometry and Bonding Theories

Chapter 9 Molecular Geometry and Bonding Theories 9.1 Molecular Shapes Lewis structures give atomic connectivity (which atoms are physically connected). By noting the number of bonding and nonbonding electron

Organic Chemistry (1)

Organic Chemistry (1) Course Number and Symbol: Credit hours: (2+0) 240 Chem 1 What is Organic Chemistry? Organic chemistry is the chemistry of compounds that contain the element carbon. Carbon compounds

ON Chemical Bonding-I & II

CET ON Chemical Bonding-I & II 1.The number of π - electrons present in 2.6 g of ethyne is 1) 0.1 mol 2) 0.2 mol 3) 0.3 mol 4) 0.4 mol π - electrons in one molecule of ethyne =4 π - electron in 2.6 g (=

Valence Bond Theory. Localized Electron Model. Hybridize the Orbitals! Overlap and Bonding. Atomic Orbitals are. mmmkay. Overlap and Bonding

Valence Bond Theory Atomic Orbitals are bad mmmkay Overlap and Bonding Lewis taught us to think of covalent bonds forming through the sharing of electrons by adjacent atoms. In such an approach this can

Chapter 9. Molecular Geometries and Bonding Theories. Lecture Presentation. John D. Bookstaver St. Charles Community College Cottleville, MO

Lecture Presentation Chapter 9 Theories John D. Bookstaver St. Charles Community College Cottleville, MO Shapes The shape of a molecule plays an important role in its reactivity. By noting the number of

16. NO 3, 5 + 3(6) + 1 = 24 e. 22. HCN, = 10 valence electrons

Solution to Chapts 9 & 10 Problems: 16. N 3, 5 + 3(6) + 1 = 24 e 22. HCN, 1 + 4 + 5 = 10 valence electrons Assuming N is hybridized, both C and N atoms are sp hybridized. The C H bond is formed from overlap

Chapter 01 Covalent Bonding and Shapes of Molecules. Atomic Structure. Chapter 01 Topics. Structure. Atomic Structure. Subatomic Particles

hapter 01 ovalent Bonding and Shapes of Molecules EM 240: Fall 2016 Prof. Greg ook hapter 01 Topics Mostly a review of general chemistry Atomic Structure Lewis Models and Bonding Bonding and Shapes of

Molecular Geometry and intermolecular forces. Unit 4 Chapter 9 and 11.2

1 Molecular Geometry and intermolecular forces Unit 4 Chapter 9 and 11.2 2 Unit 4.1 Chapter 9.1-9.3 3 Review of bonding Ionic compound (metal/nonmetal) creates a lattice Formula doesn t tell the exact

Homework #2. Chapter 14. Covalent Bonding Orbitals

Homework # Chapter 14 Covalent Bonding Orbitals 1. Single bonds have their electron density concentrated between the two atoms (on the internuclear axis). Therefore an atom can rotate freely on the internuclear

7.014 Lecture 17: Carbon and Energy Metabolism

MIT Department of Biology 7.014 Introductory Biology, Spring 2005 7.014 Lecture 17: Carbon and Energy Metabolism March 14, 2005 Summary of the options for Life (the simplified view see also Freeman Ch

PHYSICAL CHEMISTRY I. Chemical Bonds

PHYSICAL CHEMISTRY I Chemical Bonds Review The QM description of bonds is quite good Capable of correctly calculating bond energies and reaction enthalpies However it is quite complicated and sometime

Shapes of Molecules VSEPR

Shapes of Molecules In this section we will use Lewis structures as an introduction to the shapes of molecules. The key concepts are: Electron pairs repel each other. Electron pairs assume orientations

MOLECULAR ORBITAL THEORY Chapter 10.8, Morrison and Boyd

MOLECULAR ORBITAL THEORY Chapter 10.8, Morrison and Boyd more understanding: why oxygen is paramagnetic, why H2 + exists; explanation of excited electronic states (e.g., visible spectra) eliminates need

5.61 Physical Chemistry Exam III 11/29/12. MASSACHUSETTS INSTITUTE OF TECHNOLOGY Department of Chemistry Chemistry Physical Chemistry.

MASSACHUSETTS INSTITUTE OF TECHNOLOGY Department of Chemistry Chemistry - 5.61 Physical Chemistry Exam III (1) PRINT your name on the cover page. (2) It is suggested that you READ THE ENTIRE EXAM before

Homework Problem Set 5 Solutions. E e + H corr (a.u.) a.) Determine the bond dissociation enthalpy of ethane in kcal/mol (1 a.u. = kcal/mol).

Chemistry 380.37 Dr. Jean M. Standard Homework Problem Set 5 Solutions 1. Given below are the sum of electronic and thermal enthalpies, E e + H corr, from Hartree-Fock calculations using a 6-31G(d) basis

Chemistry 2. Lecture 1 Quantum Mechanics in Chemistry

Chemistry 2 Lecture 1 Quantum Mechanics in Chemistry Your lecturers 8am Assoc. Prof Timothy Schmidt Room 315 timothy.schmidt@sydney.edu.au 93512781 12pm Assoc. Prof. Adam J Bridgeman Room 222 adam.bridgeman@sydney.edu.au

Work hard. Be nice. Name: Period: Date: UNIT 6: Organic Chemistry Lesson 5: Organic Reactions

Name: Period: Date: UNIT 6: Organic Chemistry Lesson 5: Organic Reactions By the end of today, you will have an answer to: What are the different organic reactions? Do Now: Circle the functional group

1) For molecules A and B, list the symmetry operations and point groups.

Problem 1 (2 points) The MO diagrams of complicated molecules can be constructed from the interactions of molecular fragments. The point groups of isolated fragments are often of higher symmetry that the