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1 Publications (i) Book 1. Moad G, Solomon DH In: The Chemistry of Radical Polymerization Second Edition. Elsevier, Oxford. 1 Introduction ( 2 Radical Reactions ( 3 Initiation ( 4 Propagation ( 5 Termination ( 6 Chain Transfer ( 7 Copolymerization ( 8 Controlling Polymerization ( 9 Living Radical Polymerization ( Abbreviations ( Index ( (ii) Book Chapters 2. Moad G, Rizzardo E History of nitroxide-mediated polymerization. In: Gigmes D, editor. Nitroxide Mediated Polymerization: From Fundamentals to Applications in Materials Cambridge, UK: The Royal Society of Chemistry. pp Moad G Radical Polymerization. Reference Module in Materials Science and Materials Engineering: Elsevier. 74 pp (update of 9) Moad G, Rizzardo E, Thang SH Radical Addition Fragmentation Chemistry and RAFT Polymerization. Reference Module in Materials Science and Materials Engineering: Elsevier. 54 pp (update of 10) Moad G RAFT Polymerization -Then and Now. In: Matyjaszewski, K.; Sumerlin, B. S.; Tsarevsky, N. V.; Chiefari, J. (eds) Controlled Radical Polymerization: Mechanisms. ACS Symposium Series. 1187: Rizzardo E, Moad G, Thang SH In: Reversible addition fragmentation chain transfer. In: Mark HF, (ed) Encyclopedia of Polymer Science and Technology, John Wiley & Sons, Inc. 11: (hardcopy edition of 14). 7. Moad G, Guerrero-Sanchez C, Haven JJ, Keddie DJ, Postma A, Rizzardo E, Thang SH RAFT for the control of monomer sequence distribution Single unit monomer insertion (SUMI) into dithiobenzoate RAFT agents. In: Lutz J-F, Ouchi M, Sawamoto M, Meyer T, (eds) Sequence-Controlled Polymers: Synthesis, Self-assembly and Properties. ACS Symposium Series : Moad G, Rizzardo E, Thang SH Fundamentals of RAFT polymerization. In: Tsarevsky NV, Sumerlin BS. (eds). In: Fundamentals of Controlled/Living Radical Polymerization. RSC Polymer Chemistry Series No. 4. Royal Society of Chemistry, Cambridge. pp Moad G. Radical polymerization In: Matyjaszewski K, Möller M. (eds). Polymer Science: A Comprehensive Reference. 2nd ed. Elsevier BV: Amsterdam. 3:
2 10. Moad G, Rizzardo E, Thang, SH In: Matyjaszewski K, Möller M. (eds). Radical addition-fragmentation chemistry and RAFT polymerization. In Polymer Science: A Comprehensive Reference, 2nd ed. Elsevier BV, Amsterdam. 3: Moad G, Bicciocchi E, Chen M, Chiefari J, Guerrero-Sanchez C, Haeussler M, Houshyar S, Keddie D, Rizzardo E, Thang SH, Tsanaktsidis, J Some recent developments in RAFT polymerization. In: Matyjaszewski K, Sumerlin BS, Tsarevsky NV, (eds). Progress in Controlled Radical Polymerization: Mechanisms and Techniques. ACS Symposium Series. 1100: Moad G, Benaglia M, Chen M, Chiefari J, Chong YK, Keddie DJ, Rizzardo E, Thang SH Block copolymer synthesis through the use of switchable RAFT agents. In: Theato P, Kilbinger AFM, Coughlin EB, (eds). Non-Conventional Functional Block Copolymers. ACS Symposium Series. 1066: Moad G, Chong YK, Mulder R, Rizzardo E, Thang SH New features of the mechanism of RAFT polymerization. In: Matyjaszewski K (ed.). Controlled/Living Radical Polymerization. Progress in RAFT, NMP & OMRP. ACS Symposium Series. 1024: Rizzardo E, Moad G, Thang SH Reversible addition fragmentation chain transfer. In: Encyclopedia of Polymer Science and Technology, John Wiley & Sons, Inc Moad G, Barner-Kowollik C The mechanism and kinetics of the RAFT process: overview, rates, stabilities, side reactions, product spectrum and outstanding challenges. In: Barner-Kowollik C (ed).. Handbook of RAFT Polymerization. Wiley-VCH, Weinheim, Germany. pp Rizzardo E, Moad G, Thang SH RAFT Polymerization in bulk monomer or in (organic) solution. In: Barner-Kowollik C (ed). Handbook of RAFT Polymerization. Wiley-VCH, Weinheim, Germany. pp Moad G, Li G, Pfaendner R, Postma A, Rizzardo E, Thang S, Wermter H RAFT copolymerization and its application to the synthesis of novel dispersants/intercalants/exfoliants for polymer-clay nanocomposites. Some interesting results from RAFT (co)polymerization. In: Matyjaszewski K (ed.). Controlled/Living Radical Polymerization: From Synthesis to Materials. ACS Symposium Series. 944: (iii) Journal Papers 18. Moad G. RAFT Polymerization to form Stimuli-Responsive Polymers Polym Chem. 8(1), Xu J, Fu C, Shanmugam S, Hawker CJ, Moad G, Boyer C Synthesis of Discrete Oligomers by Sequential PET-RAFT Single Unit Monomer Insertion. Angew Chem: Early View, Danial M, Telwatte S, Tyssen D, Cosson S, Tachedjian G, Moad G, Postma A Combination anti-hiv therapy via tandem release of prodrugs from macromolecular carriers. Polym Chem. 7(48), Moad G RAFT (co)polymerization of the conjugated diene monomers: butadiene, isoprene and chloroprene. Polym Int. 66(1):
3 22. Danial M, Andersen AHF, Żuwała K, Cosson S, Riber CF, Smith AAA, Tolstrup M, Moad G, Zelikin AN, Postma A Triple Activity of Lamivudine Releasing Sulfonated Polymers against HIV-1. Molecular Pharmaceutics. 13(7): Gardiner J, Martinez-Botella I, Tsanaktsidis J, Moad G Dithiocarbamate RAFT agents with broad applicability - the 3,5-dimethyl-1H-pyrazole-1-carbodithioates. Polym Chem.7(2): Stace SJ, Moad G, Fellows CM, Keddie DJ The effect of the Z-group on RAFT polymerization of N-vinylpyrrolidone mediated by switchable N- pyridyldithiocarbamates Polym Chem. 6(40): Barlow KJ, Bernabeu V, Hao X, Hughes TC, Hutt OE, Polyzos A, Turner, KA, Moad, G Triphenylphosphine-grafted, RAFT-synthesised, porous monoliths as catalysts for Michael addition in flow synthesis. React Funct Polym. 96: Moad G, Dagley IJ, Habsuda J, Garvey CJ, Li G, Nichols L, Simon GP, Nobile MR Aqueous hydrogen peroxide-induced degradation of polyolefins: a greener process for controlled-rheology polypropylene. Polymer Degradation and Stability. 117: Moad G, Keddie D, Guerrero-Sanchez C, Rizzardo E, Thang SH Advances in Switchable RAFT Polymerization. Macromolecular Symposia. 350(1): Wilson JT, Postma A, Keller S, Convertine AJ, Moad G, Rizzardo E, Meagher L, Chiefari J, Stayton PS Enhancement of MHC-I antigen presentation via architectural control of ph-responsive, endosomolytic polymer nanoparticles. AAPS Journal. 17(2): Williams EGL, Thang S, Mulder RJ, Moad G, Fairbanks BD, Rizzardo E Preparation of 1:1 alternating, nucleobase-containing copolymers for use in sequencecontrolled polymerisation. Polymer Chemistry. 6(2): Moad G RAFT-Crosslinking (Co)polymerization of Multi-Olefinic Monomers to form Polymer Networks. Polymer International. 64(1): Wei X, Gunatillake PA, Moad G, Rizzardo E, Rosselgong J, Yang W, Thang SH Synthesis of cleavable multi-functional mikto-arm star polymer by RAFT polymerization: example of an anti-cancer drug 7-ethyl-10-hydroxycamptothecin (SN- 38) as functional moiety. Science China Chemistry. 57(7): Haven JJ, Guerrero-Sanchez C, Keddie DJ, Moad G, Thang SH, Schubert US One pot synthesis of higher order quasi-block copolymer libraries via sequential RAFT polymerization in an automated synthesizer. Polymer Chemistry 5(18): López-Domínguez P, Hernández-Ortiz JC, Barlow KJ, Vivaldo-Lima E, Moad G Modeling the Kinetics of Monolith Formation by RAFT Copolymerization of Styrene and Divinylbenzene. Macromolecular Reaction Engineering. 8(10): Wei, X., Moad, G., Muir, B. W., Rizzardo, E., Rosselgong, J., Yang, W., Thang, S. H An Arm-First Approach to Cleavable Mikto-Arm Star Polymers by RAFT Polymerization. Macromolecular Rapid Communications. 35(8):
4 35. Moad G. Mechanism and kinetics of dithiobenzoate-mediated RAFT polymerization status of the dilemma Macromolecular Chemistry and Physics. 215(1): Barlow KJ, Hao X, Hughes TC, Hutt OE, Polyzos A, Turner KA, Moad G Porous, functional, poly(styrene-co-divinylbenzene) monoliths by RAFT polymerization. Polymer Chemistry 5(3): Haven JJ, Guerrero-Sanchez C, Keddie DJ, Moad G Rapid and systematic access to quasi-diblock copolymer libraries covering a comprehensive composition range by sequential RAFT polymerization in an automated synthesizer. Macromolecular Rapid Communications. 35(4): Moad G, Rizzardo E, Thang SH RAFT Polymerization and some of its applications. Chemistry Asian Journal. 8(8): Hess M, Allegra G, He J, Hori K, Kim J.S, Meille SV, Metanomski V, Moad G, Stepto RFT, Vert M, Vohlídal J Glossary of terms relating to thermal and thermomechanical properties of polymers (IUPAC Recommendations 2013). Pure and Applied Chemistry. 85(5): Jones R G, Ober CK, Hodge P, Kratochvíl P, Moad G, Vert M Terminology for aggregation and self-assembly in polymer science (IUPAC Recommendations 2013). Pure and Applied Chemistry. 85(2): Keddie D J, Guerrero-Sanchez C, Moad G The reactivity of N-vinylcarbazole in RAFT polymerization: trithiocarbonates deliver optimal control for the synthesis of homopolymers and block copolymers. Polymer Chemistry. 4(12): Hiorns RC, Boucher RJ, Duhlev R, Hellwich KH, Hodge P, Jenkins A D, Jones RG, Kahovec J, Moad G, Ober CK, Smith D W, Stepto RFT, Vairon JP, Vohlídal J A brief guide to polymer nomenclature (IUPAC Technical Report). Pure and Applied Chemistry. 84(10): Houshyar S, Keddie D, Moad G, Mulder R, Saubern S, Tsanaktsidis J The scope for synthesis of macro-raft agents by sequential insertion of single monomer units. Polymer Chemistry. 3(7): Keddie DJ, Guerrero-Sanchez C, Moad G, Mulder R, Rizzardo E, Thang SH Chain transfer kinetics of acid/base switchable N-aryl-N-pyridyl dithiocarbamate RAFT agents in methyl acrylate, N-vinylcarbazole and vinyl acetate polymerization. Macromolecules. 45(10): Keddie DJ, Moad G, Rizzardo E, Thang SH. RAFT agent design and synthesis. Macromolecules (13): Moad G, Rizzardo E, Thang SH. Living radical polymerization by the RAFT Process - A third update. Australian Journal of Chemistry (8): Keddie DJ, Guerrero-Sanchez C, Moad G, Rizzardo E, Thang SH Switchable RAFT polymerization in aqueous solution - N,N-dimethylacrylamide. Macromolecules. 44: Chen M, Haeussler M, Moad G, Rizzardo E Block polymers containing organic semiconductor segments by RAFT polymerization. Organic & Biomolecular Chemistry. 9: Hornung CH, Guerrero-Sanchez C, Brasholz M, Saubern S, Chiefari J, Moad G, Rizzardo E, Thang SH Controlled RAFT polymerization in a continuous flow
5 microreactor. Organic Process Research & Development. 15: Moad G, Rizzardo E, Thang SH A RAFT tutorial. Strem Chemiker, 25: Chen M, Moad G, Rizzardo E A potential new RAFT-click reaction or a cautionary note on the use of diazomethane to methylate RAFT-synthesized polymers. Australian Journal of Chemistry. 64: Moad G, Chen M, Haussler, M, Postma A, Rizzardo E, Thang S Functional polymers for optoelectronic applications by RAFT polymerization. Polymer Chemistry. 2: Moad G Chemical modification of starch by reactive extrusion. Progress in Polymer Science. 36: Moad G, Rizzardo E, Thang SH End-functional polymers, thiocarbonylthio group removal/transformation and reversible addition-fragmentation-chain transfer (RAFT) polymerization. Polymer International. 60: Moad G, Rizzardo E, Thang SH Reversible addition-fragmentation chain transfer (RAFT) polymerization. Material Matters Jenkins AD, Jones RG, Moad G Terminology for reversible-deactivation radical polymerization previously called controlled radical or living radical polymerization. Pure and Applied Chemistry. 82: Bicciocchi E, Chong YK, Giorgini L, Moad G, Rizzardo E, Thang SH Substituent effects on raft polymerization with benzyl aryl trithiocarbonates. Macromolecular Chemistry and Physics. 211: Moad G, Thang SH RAFT Polymerization: Materials of the future, science of today: radical polymerization the next stage. Australian Journal of Chemistry. 62: Moad G, Rizzardo E, Thang SH Living radical polymerization by the RAFT process a second update. Australian Journal of Chemistry. 62: Benaglia, M, Chen M, Chong YK, Moad G, Rizzardo E, Thang SH Polystyreneblock-poly(vinyl acetate) through the use of a switchable RAFT agent. Macromolecules. 42: Chen M, Moad G, Rizzardo E Thiocarbonylthio end group removal from RAFTsynthesized polymers by a radical-induced process. Journal of Polymer Science, Part A: Polymer Chemistry. 47: Benaglia M; Chiefari J, Chong YK, Moad G, Rizzardo E, Thang SH Universal (switchable) RAFT agents. Journal of the American Chemical Society. 131: Penczek S, Moad G Glossary of terms related to kinetics, thermodynamics, and mechanisms of polymerization. Pure and Applied Chemistry. 80: Moad G, Rizzardo E, Thang SH Toward living radical polymerization. Accounts of Chemical Research. 41: Moad G, Rizzardo E, Thang SH Radical addition-fragmentation chemistry in polymer synthesis. Polymer. 49: Chong YK, Moad G, Rizzardo E, Skidmore MA, Thang SH Reversible addition fragmentation chain transfer polymerization of methyl methacrylate in the presence of
6 lewis acids: an approach to stereocontrolled living radical polymerization. Macromolecules. 40: Aleman J, Chadwick AV, He J, Hess M, Horie K, Jones RG, Kratochvil P, Meisel I, Mita I, Moad G, Penczek S, Stepto RFT Definitions of terms relating to the structure and processing of sols, gels, networks, and inorganic-organic hybrid materials. Pure and Applied Chemistry. 79: Chong YK, Moad G, Rizzardo E, Thang SH Thiocarbonylthio end group removal from RAFT-synthesized polymers by radical-induced reduction. Macromolecules. 40: Hanley T, Sutton D, Heeley E, Moad G, Knott R A small-angle X-ray scattering study of the effect of chain architecture on the shear-induced crystallization of branched and linear poly(ethylene terephthalate). Journal of Applied Crystallography. 40(S1), s599 s Rizzardo E, Chen M, Chong B, Moad G, Skidmore MA, Thang SH RAFT polymerization: adding to the picture. Macromolecular Symposia. 248: Hanley TL, Forsythe JS, Sutton D, Moad G, Burford RP, Knott RB Crystallisation kinetics of novel branched poly(ethylene terephthalate): a small-angle X-ray scattering study. Polymer International. 55: Moad G The emergence of RAFT polymerization. Australian Journal of Chemistry. 59: Moad G, Rizzardo E, Thang SH Living radical polymerization by the RAFT process A first update. Australian Journal of Chemistry. 59: Chong B, Moad G, Rizzardo E, Skidmore MA, Thang SH Thermolysis of RAFT- Synthesized Poly(Methyl Methacrylate). Australian Journal of Chemistry. 59: Barner-Kowollik C, Buback M, Charleux B, Coote ML, Drache M, Fukuda T, Goto A, Klumperman B, Lowe AB, Mcleary JB, Moad G, Monteiro MJ, Sanderson RD, Tonge MP, Vana P Mechanism and kinetics of dithiobenzoate-mediated RAFT polymerization. I. The current situation. Journal of Polymer Science, Part A: Polymer Chemistry. 44: Postma A, Davis TP, Li G, Moad G, O'Shea MS RAFT polymerization with phthalimidomethyl trithiocarbonates or xanthates. On the origin of bimodal molecular weight distributions in living radical polymerization. Macromolecules. 39: Postma A, Davis TP, Evans RA, Li G, Moad G, O'Shea MS Synthesis of welldefined polystyrene with primary amine end groups through the use of phthalimidofunctional RAFT agents. Macromolecules. 39: Moad G, Dean K, Edmond L, Kukaleva N, Li G, Mayadunne RTA, Pfaendner R, Schneider A, Simon G, Wermter H Novel copolymers as dispersants/intercalants/exfoliants for polypropylene-clay nanocomposites. Macromolecular Symposia. 233: Forsythe JS, Cheah K, Nisbet DR, Gupta RK, Lau A, Donovan AR, O'Shea MS, Moad G Rheological properties of high melt strength poly(ethylene terephthalate) formed by reactive extrusion. Journal of Applied Polymer Science. 100:
7 80. Postma A, Davis TP, Donovan AR, Li GX, Moad G, Mulder R, O'Shea MS A simple method for determining protic end-groups of synthetic polymers by H-1 NMR spectroscopy. Polymer. 47: Moad G, Dean K, Edmond L, Kukaleva N, Li G, Mayadunne RTA, Pfaendner R, Schneider A, Simon G, Wermter H Non-ionic, poly(ethylene oxide)-based, surfactants as intercalants/dispersants/exfoliants for polypropylene-clay nanocomposites. Macromolecular Materials and Engineering. 291: Postma A, Davis TP, Moad G, O'Shea MS Approaches to phthalimido and amino end-functional polystyrene by atom transfer radical polymerisation (ATRP). Reactive and Functional Polymers. 66:
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