Dr. Shanish Kumar, Education Profile. Fellowships/Honors. Teaching Experience

Transcription

1 Dr. Shanish Kumar, Assistant rofessor, Dept. of Chemistry M. D. College, aubatpur, atna Mobile: , Education rofile.d., Chemistry Department of Chemistry, ndian nstitute of Technology Kharagpur, Kharagpur , ndia Advisor: rof. Ganesan Mani Dissertation Topic: Group 10 and 11 Metal Complexes Bearing ew yrrole-based Diphosphine Ligands and Chromium() Complexes Containing 3,5-Dimethylpyrazolate Ligand. Master of Science, norganic Chemistry Department of Chemistry, University of Delhi, ndia, Bachelor of Science, Chemistry(H) Department of Chemistry, Kirori Mal College, University of Delhi, Delhi , ndia, Higher Secondary Education Jharkhand ntermediate Education Council, Ranchi Secondary Education 1999 Bihar School Examination Board, atna Fellowships/Honors Qualified for joint CSR-UGC ational Eligibility Test (ET) and was awarded Junior Research Fellowship (JRF) by Council for Scientific and ndustrial Research (CSR), ew Delhi, ndia (June, 2007). Qualified Joint CSR-UGC for Senior Research Fellowship (SRF), ndia (January 2010). Teaching Experience Four years (July, 2008 July, 2012) teaching experience in inorganic chemistry (tutorial and lab classes) for B. Tech 1st year students at ndian nstitute of Technology Kharagpur.

2 Mentored the four first year graduate student who rotated in the Lab in Guest faculty, Centre for anoscience and anotechnology, Aryabhatta Knowledge University, atna, Jan 15 to June 15. Assistant rofessor, Suraj Degree College, MDU, Mahendargarh, Haryana, July 15 to Jan'16 Teaching Assistantships, Feb 16-Oct 17 (tutorial and Lab) for UG and G courses at ndian nstitute of Technology Bombay during by my ost-doc tenure. Assistant rofessor, M D College, aubatpur, atna, ov 17 to till date. Research Experience ost Doctoral Fellow(DF), ndian nstitute of Technology Bombay Feb'16- Oct 17 Research Assistant, ndian nstitute of Technology Kharagpur Sep 13-Aug 14 ndian nstitute of Technology Kharagpur roject: Development of new yrrole-based phosphine ligands and their transition metal complexes to study the different organic transformation reaction and synthesis of Cr() complexes to study the olefin polymerization reaction. - Designed and developed a very simple synthetic method for the synthesis of new pyrrole based pincer and type diphosphine ligands. - Synthesized a series of d(), d(), i(), i(), (), and Ag() transition metal complexes bearing new pincer and -type diphosphine ligands. - Studied the catalytic activity for C C coupling, carrying out the Suzuki reaction in the aqueous medium using d(), pincer complex. - Synthesized a series of Cr() complexes by the reaction between [Cp*CrCl 2 ] 2 and 3,5-dimethyl pyrazole. - Synthesized novel Yb() complexes and structurally characterized. Research Skills More than seven years research experience in the field of phosphine ligands, transition and lanthanide metal chemistry at T Kharagpur and T Bombay. Highly skilled in handling air and moisture sensitive compounds and their purification by standard schlenk line technique or inside the Glove Box. Skillful in the execution of general purification, crystallization and separation techniques. roficient in experimental methodology and interpretation of data from techniques such as multinuclear MR, FT-R, UV-vis etc. Experienced in the handling of advanced experimental instruments like MR spectrometer (Bruker-200 and Bruker-400), FT-R (erkin-elmer Spectrometer), UV-vis

3 spectrometer, CH Analyzer (erkin-elmer 2400-), Single crystal -ray diffractometer etc. Capable in solving crystal structures (Single crystal -ray) of organic and inorganic compounds. ublications and atent Shanish Kumar, Ganesan Mani, Debodyuti Dutta, Sabyashachi Mishra Structural Diversity of Copper() Complexes Formed by yrrole- and Dipyrrolylmethane-based Diphosphine Ligands with H Hydrogen Bonds. norg. Chem.2014, 53, Shanish Kumar, Ganesan Mani. Synthesis and Structural Characterization of Chromium() Complexes Bearing 3,5-dimethylpyrazolate Ligand. olyhedron, 2015, 99, Shanish Kumar, Ganesan Mani, SukantoMondol, ratimkumarchattaraj. yrrole-based ew Diphosphines: d and i Complexes Bearing the incer Ligand. norg. Chem.2012,51, DebasishGhorai, Shanish Kumar, Ganesan Mani. Mononuclear, helical binuclear palladium and lithium complexes bearing a new pyrrole-based -pincer ligand: fluxional property. Dalton Trans. 2012, 41, Ganesan Mani, Tapas Guchhait, Rajnish Kumar, Shanish Kumar. Macrocyclic and Acyclic molecules synthesiszed from dipyrrolylmethanes: Receptors for Anoins. Org. Lett. 2010, 12, Shanish Kumar, Oishi Jana, Vasudevan Subramaniyam. The Reverse Transmetalation Reaction of the yrrole-based incer i() Complexes: -ray Structures of Binuclear Silver() and Thiocyanate ickel() complexes. norganica Chimica Acta, atent: Shanish Kumar and Ganesan Mani. yrrole-based Diphosphines and their Oxidized roducts filed Ref. o.508/kol/2013, dated- 3/5/2013. Scientific Meeting/ resentation/ Workshop Sixth One Day ational Symposium in Chemistry held in the department of Chemistry, ndian nstitute of Technology Kharagpur, ndia (8 th ovember, 2008). Graduate student registration seminar given Oral presentation Synthesis and Structural Characterization of Yb() and Cr() Complexes (28 th January 2010). articipated in First Three Day nternational Symposium (DJSRTC) in Chemistry held in the department of Chemistry, ndian nstitute of Technology Kharagpur, ndia (21st - 23rd October, 2011).

4 Symposium on Modern Trends in norganic Chemistry (MTC V) held in the school of Chemistry, University of Hyderabad, Hyderabad, ndia. Represented poster entitled Synthesis and Structural Characterization of 3,5-Dimethylpyrazolate Cr() Complexes.(10th - 13th December, 2011). Fourth One Day Research Scholar Day Symposium held in the department of Chemistry, ndian nstitute of Technology Kharagpur, ndia (1st March, 2013). Represented poster on the topic entitled d and i Complexes Bearing ew incer Ligand. Symposium organized by American Chemical Society as ACS on Campus at the Department of chemistry, T Kharagpur, ndia. Represented poster entitled yrrole Based incer and Type Diphosphines: Transition Metal Complexes and Catalysis. (25th ovember, 2013). articipated in Three day nternational workshop organized by Department of Chemistry, ndian nstitute of Technology Bombay, in 'Workshop on Electronic Structure of Coordination Complexes' (WESCC). (16th-18th May 2016) articipated in Three day nternational Conference organized by Department of Chemistry, ndian nstitute of Technology Bombay, in 'Modern Trends in Molecular Magnets' (MTMM). (19th-21th May 2016). articipated in nternational Seminar on Green Chemistry: Synthesis, rocessing and Devices (SGCSD-2018) and given Oral resentation (Solvent Free Synthesis of - incer Ligand: d() Complex and Suzuki Coupling in Water) held in the department of Chemistry, Veer Kunwar Singh University, Ara, ndia (6th -7th April, 2018).

5 Brief Research Work of My Thesis H 2Me 2 H. HCl/ 2HCHO/aOH EtOH Me 2 H Me H 150 o C/22 h 2 H 2 2, 90% 2 CO/H + EtOH 2Me 2 H. HCl/ 2HCHO/aOH 2 2 H H H H H H H EtOH toluene/ Me 2 Me o C/20 h 5, 92% MeLi toluene 2 2 LiCl or LiBr or K i RT, 20 h 2 i i 2 acetone/h 2 O 2 i o C/24 h = Cl, 16, 89 % OAc = Br, 17, 80 % 15 =, 18, 85 % 19, 15% CH 3 C 25 o C/24 h [i(oac) 2 ]. 4H 2 O 2 H [dcl [d 2 (dba) 3 ]. CHCl 3 d Cl d Cl 2 (C) 2 ] Cl d Cl 2 d H H 2 toluene, 95% 2 toluene, 23% 11 CH 3 C 87% 2 [dcl 2 (C) 2 ] Et 3 -Et 3. HCl d Cl 2 10 CDCl 3 12 Catalytic study for C-C coupling reaction in aqueous medium norg. Chem.2012,51, H 2 2, THF, RT, 20 h or Ag 2 O, DCM, RT, 48 h H 2 2 M M 2 H 2 M=, = Cl, 21 M=, = Br, 22 M=, =, 23 M=Ag, = Cl, % 2 H H 2 2 H H 68% 2 H THF, RT, 48 h 2 2 H 2 5 THF, RT, 20 h abf 4,Cl CH 3 C = Cl, 25 H H = Br, 26 =, % 16 h, RT H H 2 2 BF Cl 4 29, 57% norg. Chem.2014, 53,