Unit 4 Review Chemical Change
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1 1. Balance the following equations: Name Unit 4 Review Chemical Change a. NO + H2O NH3 + O2 b. (NH4)2Cr2O7 + AlCl3 Al2(Cr2O7)3 + NH4Cl c. C17H36 + O2 CO2 + H2O d. Co + H2SO4 Co2(SO4)3 + H2 e. P4 + Cl2 PCl3 f. H3PO4 + Ba(OH)2 Ba3(PO4)2 + H2O g. Al(CH3COO)3 Al + C + H2 + O2 2. Complete, balance and classify the following equations as synthesis, decomposition, single replacement, double replacement, neutralization or combustion. a. Al + Zn(NO3)2 b. C6H14 + O2 c. Na3PO4 + Ca(NO3)2 d. Mg(H2PO4)2 e. Cl2 + KI f. Al + F2 Page 1 of 9
2 g. Zn + Cu(ClO3)2 h. Co(NO3)3 + (NH4)2C2O4 i. C12H25OH + O2 j. Sr(OH)2 + HNO3 k. V + O2 (Assume combining capacity of V is 5+) l. Rb3AsO4 m. CsOH + H3PO4 n. Ni(NO3)2 + (NH4)3PO4 o. Al + H2CO3 p. MgSO4 + AgNO3 Page 2 of 9
3 3. State whether each of the following are exothermic or endothermic. a. HCl kj H + Cl Answer b. C12H22O O2 12CO2 + 11H2O kj Answer c. H2O(l) H2O(g) Answer d. Energy (kj) A + B AB Reaction Proceeding Answer e. C + D CD H= kj Answer f. E + F G + H= kj Answer 4. In an exothermic reaction, the surroundings get (warmer/cooler). 5. Define enthalpy 6. Why does a light stick glow brighter when it is heated? 7. Which reaction will be faster? 6M HCl with zinc or 3 M HCl with zinc WHY? Page 3 of 9
4 8. Use the following Potential Energy Diagram to answer the questions below: ABC 60 AB + C A + BC 0 Progress of Reaction a) Determine the Activation Energy for the forward reaction... kj b) Determine the Activation Energy for the reverse reaction... kj c) What is the Enthalpy Change ( H) forward the reaction?.. kj d) What is the Enthalpy Change ( H) reverse for reaction?.. kj the e) The forward reaction is thermic. f) The reverse reaction is thermic. g) Which species or set of species forms the Activated Complex? h) What is the formula for the activated complex? 9. State the meaning of Activation Energy Page 4 of 9
5 10. Use the following Potential Energy Diagram to answer the questions below: Potential Energy 300 ABC A + BC AB + C Progress of Reaction a) Determine the Activation Energy for the forward reaction... kj b) Determine the Activation Energy for the reverse reaction... kj c) What is the Enthalpy Change ( H) forward the reaction?.. kj d) What is the Enthalpy Change ( H) reverse for reaction?.. the kj e) The forward reaction is thermic. f) The reverse reaction is thermic. g) Which species or set of species forms the Activated Complex? 11. Given the balanced equation: 2 Si4H10 (l) + 13 O2 (g) 8 SiO2 (aq) + 10 H2O (g) a) What volume of oxygen (STP) is required to react with g of Si4H10? Page 5 of 9
6 Chemistry 11 b) What mass of SiO2 is formed when g of H20 are formed? c) How many molecules of H2O are formed when L of O2 are used at STP? d) What is the concentration of 25.0 ml SiO2 if ml of 1.78M Si4H10 is reacted? 12. Given the balanced equation: Al2C6 + 6 H2O 2 Al(OH)3 + 3CH4 (g) a) If 34.5 grams of Al2C6 is mixed with 72.0 grams of water, which reactant is in excess? Show by calculations. b) If 34.5 grams of Al2C6 is mixed with 72.0 grams of water, what mass of Al(OH)3 is formed? Page 6 of 9
7 c) If 34.5 grams of Al2C6 is mixed with 72.0 grams of water, what volume of CH4 is formed at STP? 13. Given the equation: 4 NH3 + 5 O2 4 NO + 6 H2O When 51.0 grams of NH3 is burned in an excess of oxygen, g of water are produced. a) Calculate the theoretical yield of H2O. b) Calculate the % yield of H2O. 14. Given the equation: N2 + 3 H2 2 NH3 When 4.0 grams of hydrogen is combined with an excess of nitrogen, a 92% yield of NH3 is obtained. a) Calculate the theoretical yield of NH3 b) Calculate the actual yield of NH3 Page 7 of 9
8 15. Given the balanced equation: 3 HCl(aq) + Fe(OH)3 (aq) 3 H2O(l) + FeCl3 (aq) a) It takes ml of 0.50 M HCl to titrate a 25.0 ml sample of a solution of Fe(OH)3. Calculate the [Fe(OH)3 ] b) What mass of Fe(OH)3 is needed to completely react with 10.0 ml of 0.50M HCl solution? c) What volume of 0.50M HCl is required to titrate a gram sample of iron (III) hydroxide? Page 8 of 9
9 16. Given the following balanced equation, answer the questions below it. 2C6H14(l) + 19O2(g) 12CO2(g) + 14H2O(l) a. If g of C6H14 is mixed with grams of oxygen gas, which reactant is limiting? (2 marks) b. How much is the other reactant in excess? Answer Answer Page 9 of 9
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