Syllabus for CHEM 1312 (Spring 2016)

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1 College of Science, Technology, Engineering and Mathematics Syllabus for CHEM 1312 (Spring 2016) Class: General Chemistry II ( 3 sch) Room: SCIT 306 Time: MW 11:00a-12:30p Instructor: Md Abul Kalam Office: SCIT 318B Office Hrs: TR 9:00am-12:00pm md.kalam@tamut.edu Office Phone: (903) COURSE DESCRIPTION This course is the second course of the general chemistry sequence. Topics include chemical equilibrium, phase diagrams and spectrometry, acid-base concepts, thermodynamics, kinetics, electrochemistry, nuclear chemistry, and an introduction to organic chemistry and descriptive organic chemistry. Prerequisite: CHEM COURSE DELIVERY METHODS Face-to-face lecture Class discussion Web-enhanced/based multimedia TEXTBOOKS/RESOURCES: Required: 1. Chemistry: The Central Science (with Mastering Chemistry) by Brown, T. E. (12 th Edition), Prentice Hall, (ISBN-10: , ISBN-13: ) 2. A scientific calculator will be needed for this course. (The library will have some calculators available for use on a first-come, first-served basis.) STUDENT LEARNING OUTCOMES (SLO) A student graduating with the chemistry minor is expected to demonstrate that (s)he is able to: 1. Explain atomic & molecular structures, bonding, stoichiometry, and periodic properties of representative elements 2. Apply the concepts and fundamental principles of thermodynamics, chemical equilibria, and chemical kinetics. 3. Write and explain organic reactions, stereochemistry, and processes in biological and environmental systems

2 4. Use essential instruments/equipment to perform selected chemistry experiments in the laboratory STUDENT LEARNING OBJECTIVES At the end of this course, a student should be able to A. Explain the basic concepts of intermolecular forces B. Interpret physical properties of solutions C. Apply the basic concepts of chemical kinetics and equilibrium D. Understand the concepts of acid and bases E. Use the laws of thermodynamics in solving chemical problems F. Analyze redox reactions This course is designed to fulfill SLO 2 COURSE OUTLINE General Chemistry II is the second semester of a one-year course. The second semester covers the following topics and subtopics: 1. Intermolecular Forces: Intermolecular Forces, Some Properties of Liquids, Some Properties of Solids, Phase Diagrams, Network Covalent Solids and Ionic Solids, Crystal Structures; 2. Solutions and Their Physical Properties: Types of Solutions, Solution Concentration, Intermolecular Forces and the Solution Process, Solution Formation and Equilibrium, Solubilities of Gases, Vapor Pressures of Solutions, Osmotic Pressure, Freezing-Point Depression and Boiling Point Elevation, Solutions of Electrolytes and Colloidal Mixtures; 3. Acids and Bases: Arrhenius Theory, Brönsted-Lowry Theory of Acids and Bases, Self- Ionization of Water and the ph Scale, Strong Acids and Strong Bases, Weak Acids and Weak Bases, Polyprotic Acids, Lewis Acids and Bases; 4. Chemical Kinetics: The Rate of a Chemical Reaction, Measuring Reaction Rates, Effect of Concentration on Reaction Rates, Reaction Order, The Effect of Temperature on Reaction Rates, Reaction Mechanisms, Catalysis; 5. Principles of Chemical Equilibrium: Dynamic Equilibrium, The Equilibrium Constant Expression, Relationships Involving Equilibrium Constants, The Magnitude of an Equilibrium Constant, Le Châtelier s Principle, Equilibrium Calculations;

3 6. Solubility and Complex-Ion Equilibria: Solubility Product Constant, Ksp, Relationship Between Solubility and Ksp, Limitations of the Ksp Concept, Criteria for Precipitation and Its Completeness, Fractional Precipitation, Solubility and ph, Qualitative Cation Analysis; 7. Entropy and Gibbs Energy: The Concept of Entropy, Evaluating Entropy and Entropy K as Functions of Temperature,Coupled Reactions; 8. Electrochemistry: Electrode Potentials and Their Measurement, Standard Electrode Potentials, Ecellas a Function of Concentrations, Batteries and Corrosion, Electrolysis; 9. Nuclear Chemistry: Radioactivity, Radioactive Isotopes, Rate of Radioactive Decay, Energetics of Nuclear Reactions, Nuclear Stability, Nuclear Fission, Nuclear Fusion, Applications of Radioisotopes; 10. Complex Ions and Coordination Compounds: Ligands, Nomenclature, Isomerism, Crystal Field Theory, Color and the Colors of Complexes, Aspects of Complex-Ion Equilibria, Acid- Base Reactions of Complex Ions, Application of Coordination Chemistry; 11. Structures of Organic Compounds: Alkanes, Cycloalkanes, Stereoisomerism in Organic Compounds, Alkenes and Alkynes, Aromatic Hydrocarbons, Functional Groups, Introduction to Organic Reactions. Course Calendar Lecture 1 (January 20): Discussion on Syllabus, Intermolecular Forces, Properties of Liquids, and Properties of Solids Lecture 2 (January 25): Phase Diagrams, Network Covalent Solids and Ionic Solids, Crystal Structures Lecture 3 (January 27): Types of Solutions, Solution Concentration, Intermolecular Forces and the Solution Process, Solution Formation and Equilibrium, Solubility of Gases; Homework 1 due Lecture 4 (February 01): Vapor Pressures of Solutions, Osmotic Pressure, Freezing-Point Depression and Boiling Point Elevation, Solutions of Electrolytes and Colloidal Mixtures Lecture 5 (February 03): Discussion on selective questions and problems on chapter 11 and 13 Lecture 6 (February 08): The Rate of a Chemical Reaction, Measuring Reaction Rates, Effect of Concentration on Reaction Rates; Homework 2 due Lecture 7 (February 10): Reaction Order, the Effect of Temperature on Reaction Rates, Reaction Mechanisms, and Catalysis Lecture 8 (February 15): Review on chapters 11, 13 and 14; Homework 3 due Lecture 9 (February 17): Exam I, Syllabus- Chapters 11, 13, and 14

4 Lecture 10 (February 22): Dynamic Equilibrium, the Equilibrium Constant Expression, and Relationships Involving Equilibrium Constants Lecture 11 (February 24): The Magnitude of an Equilibrium Constant, Le Châtelier s Principle, and Equilibrium Calculations Lecture 12 (February 29): Arrhenius Theory, Brönsted-Lowry Theory of Acids and Bases, Self-Ionization of Water and the ph Scale, Strong Acids and Strong Bases; Homework 4 due Lecture 13 (March 02): Weak Acids and Weak Bases, Polyprotic Acids, Lewis Acids and Bases Lecture 14 (March 07): Solubility Product Constant, Ksp, Relationship between Solubility and Ksp, Limitations of the Ksp Concept; Homework 5 due Lecture 15 (March 09): Criteria for Precipitation and Its Completeness, Fractional Precipitation, Solubility and ph, Qualitative Cation Analysis Lecture 16 (March 21): Review on chapters 15, 16, and 17; Homework 6 due Lecture 17 (March 23): Exam II; Syllabus- Chapters Lecture 18 (March 28): The Concept of Entropy, Evaluating Entropy and Entropy Changes, the Second Law of Thermodynamics, Lecture 19 (March 30): Temperature, Coupled Reactions Lecture 20 (April 04): Electrode Potentials and Their Measurement, Standard Electrode Potentials; Homework 7 due Lecture 21 (April 06): E cell as a Function of Concentrations, Batteries and Corrosion, Electrolysis Lecture 22 (April 11): Review on chapters 19 and 20; Homework 8 due Lecture 23 (April 13): Exam III; Syllabus- Chapters 19 and 20 Lecture 24 (April 18): Radioactivity, Radioactive Isotopes, Rate of Radioactive Decay, and Energetics of Nuclear Reactions Lecture 25 (April 20): Nuclear Stability, Nuclear Fission, Nuclear Fusion, Applications of Radioisotopes Lecture 26 (April 25): Ligands, Nomenclature, Isomerism, Crystal Field Theory, Color and the Colors of Complexes Lecture 27 (April 27): Aspects of Complex-Ion Equilibria, Acid-Base Reactions of Complex Ions, Application of Coordination Chemistry

5 Lecture 28 (May 02): Alkanes, Cycloalkanes, Stereoisomerism in Organic Compounds, Alkenes and Alkynes Lecture 29 (May 04): Aromatic Hydrocarbons, Functional Groups, Introduction to Organic Reactions Final Exam (May 07): At 08:00 am; Syllabus- chapters 11-17, 19-21, N.B.: This course calendar is subject to change. Changes will be announced via blackboard Homework Assignments There will be a total 8 problem sets. NO LATE HOMEWORK WILL BE ACCEPTED. METHODS OF EVALUATION Examinations Assignments Examinations There will three in-course examinations and a final examination. NO MAKE-UP EXAMS WILL BE GIVEN (with some exceptions). The final is mandatory and comprehensive. It will be used for the assessment of SLO 2. Each in-course exam is worth 20% and the final will be worth 25% of the final grade.. Exam I: (20%) Wednesday, February 17 Exam II: (20%) Wednesday, March 23 Exam III: (20%) Wednesday, April 13 Final Exam: (25%) Saturday, May 07 (8:00 am) Homework/Class activities: (15%) Eight graded problem sets Total Points: 100% GRADING SCALE A = %, B = 80-89%, C = 70-79%, D = 60-69%, F = 0-59%

6 N.B.: A student may request for an incomplete grade, ONLY if (s)he completes all the course requirements except final exam due to extra-ordinary circumstance(s). If you are in such situations, you are advised to contact me as soon as possible. STUDENT PARTICIPATION a. Participation Policy: Students are always encouraged to participate in class discussion in lecture sessions and form group to solve assigned problems. Students will participate in team work by conducting lab experiments and discussing the findings in groups. b. Course Etiquette: Use of cell phones (for any purpose) is prohibited. Please turn the cell phone off or keep it in airport mode. Observing safety rules is a MUST for all present in the class. c. Discussion Board Standards: Students are encouraged to use discussion board (on blackboard) for discussions on topics relevant to the course. DISABILITY ACCOMMODATIONS Students with disabilities may request reasonable accommodations through the A&M-Texarkana Disability Services Office by calling ACADEMIC INTEGRITY Academic honesty is expected of students enrolled in this course. Cheating on examinations, unauthorized collaboration, falsification of research data, plagiarism, and undocumented use of materials from any source constitute academic dishonesty and may be grounds for a grade of F in the course and/or disciplinary actions. For additional information, see the university catalog. A&M-TEXARKANA ADDRESS Upon application to Texas A&M University-Texarkana an individual will be assigned an A&M- Texarkana account. This account will be used to deliver official university correspondence. Each individual is responsible for information sent and received via the university account and is expected to check the official A&M-Texarkana account on a frequent and consistent basis. Faculty and students are required to utilize the university account when communicating about coursework. DROP POLICY To drop this course after the census date (see semester calendar), a student must complete the Drop/Withdrawal Request Form, located on the University website ( or obtained in the Registrar s Office. The student must submit the signed and completed form to the instructor of

7 each course indicated on the form to be dropped for his/her signature. The signature is not an approval to drop, but rather confirmation that the student has discussed the drop/withdrawal with the faculty member. The form must be submitted to the Registrar s office for processing in person, Registrar@tamut.edu, mail (7101 University Ave., Texarkana, TX 75503) or fax ( ). Drop/withdraw forms missing any of the required information will not be accepted by the Registrar s Office for processing. It is the student s responsibility to ensure that the form is completed properly before submission. If a student stops participating in class (attending and submitting assignments) but does not complete and submit the drop/withdrawal form, a final grade based on work completed as outlined in the syllabus will be assigned. CLASS PARTICIPATION Students are responsible for beginning their participation on the FIRST CLASS DAY by logging on and completing assignments according to the COURSE CALENDAR. Failure to submit online assignments between the first day of classes and the University census date (according to the University schedule) will result in an ADMINISTRATIVE DROP from the course. STUDENT TECHNICAL ASSISTANCE Solutions to common problems and FAQ s for your web-enhanced and web courses are found at this link: If you cannot find your resolution there, you can send in a support request detailing your specific problem here: Blackboard Helpdesk contacts (office hours are: Monday - Friday, 8:00a to 5:00p) Julia Allen (main contact) julia.allen@tamut.edu Nikki Thomson (alternate) nikki.thomson@tamut.edu Jayson Ferguson (alternate) jayson.ferguson@tamut.edu Minimum Windows PC Requirements: TECHNICAL REQUIREMENTS Pentium IV 1.5GHz+ (preferred: Core Duo) 1 GB RAM minimum (preferred: 2 GB) 128MB Video Card minimum - Sound Card is required for some courses 56K modem minimum (Cable or DSL required for some courses) Windows 2000, XP, Vista or 7 Web browser (Internet Explorer 7.0+; Firefox 3.0+) Microsoft Word, minimum Office 97 Some courses will need plug-ins such as Flash player 10 +, QuickTime player 7.0+, Adobe Reader 9.0+, Java Runtime Environment (Java 1.6.0_15), Windows Media Player 10+, RealPlayer, and Macromedia/Adobe Shockwave.

8 Some online courses may also require a CD ROM (8x minimum, higher recommended) Blackboard has certified the following browsers for computers running Windows Operating Systems: Internet Explorer 8 or 9 (IE is not supported on Windows XP) Mozilla Firefox 3.6+ Google Chrome Minimum Apple Macintosh Requirements: Intel Core 2.0GHz+ 1 GB RAM (preferred: 2 GB) 128MB Video Card minimum - Sound Card is required for some courses 56K modem minimum (Cable or DSL required for some courses) Web browser (Firefox 3.0+ ; Safari 3.0+) Microsoft Word, minimum Office 97 Some courses will need plug-ins such as Flash player 10+, QuickTime player 7.0+, Adobe Reader 9.0+, Java Runtime Environment, RealPlayer, and Macromedia/Adobe Shockwave. Some online courses may also require a CD ROM (8x minimum, higher recommended) Blackboard has certified the following browsers for computers running Macintosh Operating Systems: Mac OS 10.2 (Jaguar): (Safari 1 is compatible) Mac OS 10.3 (Panther): Safari 1.2 (Firefox 1.5 is compatible) Mac OS 10.4 (Tiger): Safari 2 and Firefox 1.5 Mac OS 10.5 (Leopard): (Firefox 2.0 is compatible) I-OS and Android Devices These devices are currently supported using the Blackboard Mobile App, available for free from your App Store or scan the code below:

9 To access Texas A&M University - Texarkana, there is an individual license fee of $1.99 per year or $5.99 lifetime. This fee gives you access to the university from all your (same platform) devices; it is not necessary to pay the fee for each device you own.

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