Enhancing Sodium Ion Battery Performance by. Strongly Binding Nanostructured Sb 2 S 3 on
|
|
- Paula Stewart
- 6 years ago
- Views:
Transcription
1 Enhancing Sodium Ion Battery Performance by Strongly Binding Nanostructured Sb 2 S 3 on Sulfur-Doped Graphene Sheets Xunhui Xiong, Guanhua Wang, Yuwei Lin, Ying Wang, Xing Ou, Fenghua Zheng, Chenghao Yang,*,a Jeng-Han Wang, and Meilin Liu*, New Energy Research Institute, School of Environment and Energy, South China University of Technology, Guangzhou , P. R. China School of Materials Science and Engineering, South China University of Technology, Guangzhou , P. R. China School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA , USA 1
2 Figure S1. Sb 3d spectrum of pure Sb 2 S 3 and Sb 2 S 3 /SGS. Figure S2. SEM images of the Sb 2 S 3 /SGS composite prepared at 300 o C (a) and 450 o C (b). 2
3 Figure S3. (a) SEM and (b) TEM images of Sb2S3/GS composite. Displayed in Figure S3 are typical SEM and TEM images of an interconnected, porous framework with random open pores constructed from graphene sheets. Numerous Sb2S3 nanoparticles with size of nm are encapsulated within the graphene sheets. The initial morphology of Sb2S3/SGS composite is similar to that of the Sb2S3/GS composite. Figure S4. (a-c) SEM, TEM images and SAED pattern of pure Sb2S3, and SEM image of pure Sb2S3 calcined at 450 oc. Pure Sb2S3 tends to have rod-like agglomerations, with a width of 100 nm and a length of 500 nm. TEM image shown in Fig. S3b confirms the rod-like morphology. High resolution TEM (HRTEM) (Figure S4b) and selected area electron diffraction (SAED) (inset of Figure 3
4 S4c) demonstrate the single-phase crystalline nature of rods. Higher processing temperature (450 o C) results in undesirable growth of Sb 2 S 3 grains (Figure S4d). Figure S5. Nitrogen sorption analysis: N 2 isotherms and calculated BET specific surface area of (a) Sb 2 S 3 /SGS composite, (b) Sb 2 S 3 /GS composite and (c) pure Sb 2 S 3. Figure S6. CV of the first five cycles at a scan rate of 0.1 mv s -1 for pure Sb 2 S 3. CV curves of pure Sb 2 S 3 are shown in Figure S6. As indicated in the figure, four peaks centered at around 0.76 V, 0.46 V and 0.23 V are observed in the sodiation process, which are 4
5 attributed to conversion reaction with sulfur atoms (Sb 2 S 3 +6Na + +6e - 2Sb+3Na 2 S) and the alloying reaction of Sb with Na (2Sb+6Na + +6e - 2Na 3 Sb). The broad peak at 1.20 V is ascribedto the formation reaction of solid electrolyte interface (SEI) layer. The anodic peaks centered at 0.74 V and 1.32 V are related to the dealloying reaction (2Na 3 Sb 2Sb+6Na + +6e - ) and the formation of Sb 2 S 3 (2Sb+3Na 2 S Sb 2 S 3 +6Na + +6e - ). Obviously, the polarization of pure Sb 2 S 3 is larger than that of the Sb 2 S 3 /SGS composite. Figure S7. The second charge/discharge curves of Sb 2 S 3 /SGS composite at various current densities. Figure S8. (a) The initial charge-discharge curves of at Sb 2 S 3 /SGS composite 50 ma g -1. (b) The charge-discharge curves at 50 ma g -1 after rate performance tests for Sb 2 S 3 /SGS composite. 5
6 As shown in Figure S8, the curves before and after rate performance tests are superimposable, suggesting good reversibility of Sb 2 S 3 /SGS composite. Furthermore, the capacity can be fully recovered at mah g -1 when the current density is reset to 0.05 A g -1, which is extremely important for high-power and long cycle life batteries. Figure S9. (a) The initial and second charge-discharge curves of GS and SGS at 50 ma g -1. (b) The corresponding cycle performance at 2 A g -1. Figure S10. The initial charge/discharge curves of Sb 2 S 3 /GS composite at various current densities. 6
7 Figure S11. Cycling performances of Sb 2 S 3 /SGS, Sb 2 S 3 /GS, Sb 2 S 3 /GS, pure Sb 2 S 3 and commercial Sb 2 S 3 in terms of area capacity of the electrode. Figure S12. Cycling performaces of pure Sb 2 S 3 and Sb 2 S 3 /SGS composites with different amount of SGS at 0.5 A g -1 (Insert is the initial charge-discharge curves of Sb 2 S 3 /SGS composites with 7.82 wt.% SGS and wt.%. Sb 2 S 3 /SGS composites with different amounts of SGS were also studied (shown in Figure S12). SGS/Sb 2 S 3 with 7.82 wt.% SGS shows the highest specific capacity, the best cyclability at 0.5 A g -1, as well as the highest initial coulombic efficiency. 7
8 Figure S13. The charge capacities of the Sb 2 S 3 /SGS electrode with different active materials mass at 2 A g -1. Table S1 Cycling performance comparison of the as-prepared Sb nanorod arrays with previously reported Sb-based anodes. Materials Current density/a g -1 Cycles Retention Last cycle capacity/mah g -1 rgo/sb 2 S % Sb/C fibers % 350 Sb-C nanofibers % 450 Sn-Ge-Sb thin film % 662 alloys 4 Monodisperse Sb % 580 Nanocrystals 5 SnSb-porous carbon % 345 nanofibers 6 Bulk Sb % 576 3D interconnected NiSb hollow nanospheres Sb 2 S 3 /SGS % (this work) %
9 Figure S14. (a, b) SEM images of pure Sb 2 S 3 after 200 cycles at 2 A g -1. The pure Sb 2 S 3 experienced severe pulverization and rod-like morphology was totally destroyed, resulting in breakdown and reformation of SEI, and eventually a rapid deterioration of the cyclability. Figure S15. The optimized structure in DFT calculation, showing the interactions of Na 3 Sb with (a) pure graphene and (b) sulfur-doped graphene. The upper are top views, and the bottom are side views. The carbon (C), sulfur (S), antimony (Sb), and hydrogen (H) atoms are denoted by gray, yellow, celadon, and white spheres, respectively. 9
10 The adsorption energy between Na 3 Sb and SGS is ev, higher than that of graphene/sb 2 S 3 (-1.48 ev), which is benificial to preventing the discharge products from aggregation. REFERENCES 1. Yu, D. Y.; Prikhodchenko, P. V.; Mason, C. W.; Batabyal, S. K.; Gun, J.; Sladkevich, S.; Medvedev, A. G.; Lev, O., High-Capacity Antimony Sulphide Nanoparticle-Decorated Graphene Composite as Anode for Sodium-Ion Batteries. Nat. Commun. 2013, 4, Zhu, Y.; Han, X.; Xu, Y.; Liu, Y.; Zheng, S.; Xu, K.; Hu, L.; Wang, C., Electrospun Sb/C Fibers for a Stable and Fast Sodium-Ion Battery Anode. ACS Nano 2013, 7, Wu, L.; Hu, X.; Qian, J.; Pei, F.; Wu, F.; Mao, R.; Ai, X.; Yang, H.; Cao, Y., Sb-C Nanofibers with Long Cycle Life as An Anode Material for High-Performance Sodium-Ion Batteries. Energy Environ. Sci. 2014, 7, Farbod, B.; Cui, K.; Kalisvaart, W. P.; Kupsta, M.; Zahiri, B.; Kohandehghan, A.; Lotfabad, E. M.; Li, Z.; Luber, E. J.; Mitlin, D., Anodes for Sodium Ion Batteries Based on Tin-Germanium-Antimony Alloys. ACS Nano 2014, 8, He, M.; Kravchyk, K.; Walter, M.; Kovalenko, M. V., Monodisperse Antimony Nanocrystals for High-Rate Li-Ion and Na-Ion Battery Anodes: Nano versus Bulk. Nano Lett. 2014, 14, Ji, L.; Gu, M.; Shao, Y.; Li, X.; Engelhard, M. H.; Arey, B. W.; Wang, W.; Nie, Z.; Xiao, J.; Wang, C.; Zhang, J.-G.; Liu, J., Controlling SEI Formation on SnSb-Porous Carbon Nanofibers for Improved Na Ion Storage. Adv. Mater. 2014, 26, Darwiche, A.; Marino, C.; Sougrati, M. T.; Fraisse, B.; Stievano, L.; Monconduit, L., Better Cycling Performances of Bulk Sb in Na-Ion Batteries Compared to Li-Ion Systems: An Unexpected Electrochemical Mechanism. J. Am. Chem. Soc. 2012, 134,
11 8. Liu, J.; Yang, Z.; Wang, J.; Gu, L.; Maier, J.; Yu, Y., Three-Dimensionally Interconnected Nickel-Antimony Intermetallic Hollow Nanospheres as Anode Material for High-Rate Sodium-Ion Batteries. Nano Energy 2015, 16,
An Advanced Anode Material for Sodium Ion. Batteries
Layered-Structure SbPO 4 /Reduced Graphene Oxide: An Advanced Anode Material for Sodium Ion Batteries Jun Pan, Shulin Chen, # Qiang Fu, Yuanwei Sun, # Yuchen Zhang, Na Lin, Peng Gao,* # Jian Yang,* and
More informationSupporting Information for
Supporting Information for A Few-Layer SnS 2 /Reduced Graphene Oxide Sandwich Hybrid for Efficient Sodium Storage Fengzhang Tu,, Xin Xu, Pengzi Wang, Ling Si, Xiaosi Zhou,*, and Jianchun Bao*, Jiangsu
More informationInexpensive Colloidal SnSb Nanoalloys as Efficient Anode Materials for Lithium- and Sodium-Ion Batteries
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Supplementary Information for Inexpensive Colloidal SnSb Nanoalloys as
More informationSpherical composite as high-rate and ultra-stable anode material for sodium ion batteries
Nano Research DOI 10.1007/s12274-015-0838-3 Nano Res 1 Spherical nano-sb@c composite as high-rate and ultra-stable anode material for sodium ion batteries Ning Zhang 1, Yongchang Liu 1, Yanying Lu 1, Xiaopeng
More informationEngineering of Hollow Core-Shell Interlinked Carbon Spheres for Highly Stable Lithium-Sulfur Batteries
SUPPLEMENTARY INFORMATION Engineering of Hollow Core-Shell Interlinked Carbon Spheres for Highly Stable Lithium-Sulfur Batteries Qiang Sun, Bin He, Xiang-Qian Zhang, and An-Hui Lu* State Key Laboratory
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Supporting Information Highly dispersed Zn nanoparticles confined in nanoporous
More informationHigh-Performance Flexible Asymmetric Supercapacitors Based on 3D. Electrodes
Supporting Information for: High-Performance Flexible Asymmetric Supercapacitors Based on 3D Porous Graphene/MnO 2 Nanorod and Graphene/Ag Hybrid Thin-Film Electrodes Yuanlong Shao, a Hongzhi Wang,* a
More informationSupporting Information
Supporting Information Fe 3 O 4 @Carbon Nanosheets for All-Solid-State Supercapacitor Electrodes Huailin Fan, Ruiting Niu, & Jiaqi Duan, Wei Liu and Wenzhong Shen * State Key Laboratory of Coal Conversion,
More informationHierarchical MoO 2 /Mo 2 C/C Hybrid Nanowires for High-Rate and. Long-Life Anodes for Lithium-Ion Batteries. Supporting Information
Supporting Information Hierarchical MoO 2 /Mo 2 C/C Hybrid Nanowires for High-Rate and Long-Life Anodes for Lithium-Ion Batteries Lichun Yang, a Xiang Li, a Yunpeng Ouyang, a Qingsheng Gao, b Liuzhang
More informationScience and Technology, Dalian University of Technology, Dalian , P. R. China b
Electronic Supplementary Information for Fabrication of Superior-Performance SnO 2 @C Composites for Lithium-Ion Anodes Using Tubular Mesoporous Carbons with Thin Carbon Wall and High Pore Volume Fei Han,
More informationHoneycomb-like Interconnected Network of Nickel Phosphide Hetero-nanoparticles
Supporting Information Honeycomb-like Interconnected Network of Nickel Phosphide Hetero-nanoparticles with Superior Electrochemical Performance for Supercapacitors Shude Liu a, Kalimuthu Vijaya Sankar
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Supporting Information Na3V2(PO4)2F3-SWCNT: A High Voltage Cathode for
More informationMulticomponent (Mo, Ni) metal sulfide and selenide microspheres with empty nanovoids as anode materials for Na-ion batteries
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Multicomponent (Mo, Ni) metal sulfide and selenide microspheres with empty
More informationHigh Voltage Magnesium-ion Battery Enabled by Nanocluster Mg3Bi2
Supporting Information High Voltage Magnesium-ion Battery Enabled by Nanocluster Mg3Bi2 Alloy Anode in Noncorrosive Electrolyte Yi-Hong Tan,, Wei-Tang Yao,*, Tianwen Zhang, Tao Ma, Lei-Lei Lu, Fei Zhou,
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Supporting Information Si/SiO x Hollow Nanospheres/Nitrogen-Doped Carbon
More informationMetal Organic Framework-Derived Metal Oxide Embedded in Nitrogen-Doped Graphene Network for High-Performance Lithium-Ion Batteries
Supporting Information for Metal Organic Framework-Derived Metal Oxide Embedded in Nitrogen-Doped Graphene Network for High-Performance Lithium-Ion Batteries Zhu-Yin Sui, Pei-Ying Zhang,, Meng-Ying Xu,
More informationSupporting Information. Metal-Organic Frameworks Mediated Synthesis of One-Dimensional Molybdenum-Based/Carbon Composites for Enhanced Lithium Storage
Supporting Information Metal-Organic Frameworks Mediated Synthesis of One-Dimensional Molybdenum-Based/Carbon Composites for Enhanced Lithium Storage Wei Tian a, Han Hu b, Yixian Wang a, Peng Li c, Jingyan
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Supporting Information Carbon Dots Supported upon N-doped TiO 2 Nanorod
More informationPhytic Acid-Assisted Formation of Hierarchical Porous CoP/C Nanoboxes for Enhanced Lithium Storage and Hydrogen Generation
Phytic Acid-Assisted Formation of Hierarchical Porous CoP/C Nanoboxes for Enhanced Lithium Storage and Hydrogen Generation Xuxu Wang, ab Zhaolin Na, a Dongming Yin, a Chunli Wang, ab Yaoming Wu, a Gang
More informationSupporting Information for
Supporting Information for Multilayer CuO@NiO Hollow Spheres: Microwave-Assisted Metal-Organic-Framework Derivation and Highly Reversible Structure-Matched Stepwise Lithium Storage Wenxiang Guo, Weiwei
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Supporting Information Directly anchoring 2D NiCo metal-organic frameworks
More informationSupplementary Figures
Supplementary Figures Supplementary Figure 1: Microstructure, morphology and chemical composition of the carbon microspheres: (a) A SEM image of the CM-NFs; and EDS spectra of CM-NFs (b), CM-Ns (d) and
More informationIn-Situ Fabrication of CoS and NiS Nanomaterials Anchored on. Reduced Graphene Oxide for Reversible Lithium Storage
Supporting Information In-Situ Fabrication of CoS and NiS Nanomaterials Anchored on Reduced Graphene Oxide for Reversible Lithium Storage Yingbin Tan, [a] Ming Liang, [b, c] Peili Lou, [a] Zhonghui Cui,
More informationMetal-Organic Framework Derived Iron Sulfide-Carbon Core-Shell Nanorods as a Conversion-Type Battery Material
Supporting Information Metal-Organic Framework Derived Iron Sulfide-Carbon Core-Shell Nanorods as a Conversion-Type Battery Material Wei Huang,, Shuo Li, Xianyi Cao, Chengyi Hou, Zhen Zhang, Jinkui Feng,
More informationSupporting Information
Supporting Information MoSe2 embedded CNT-Reduced Graphene Oxide (rgo) Composite Microsphere with Superior Sodium Ion Storage and Electrocatalytic Hydrogen Evolution Performances Gi Dae Park, Jung Hyun
More informationSupporting Information
Supporting Information Hierarchical Porous N-doped Graphene Monoliths for Flexible Solid-State Supercapacitors with Excellent Cycle Stability Xiaoqian Wang, Yujia Ding, Fang Chen, Han Lu, Ning Zhang*,
More informationSelf-assembled pancake-like hexagonal tungsten oxide with ordered mesopores for supercapacitors
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Electronic Supporting Information Self-assembled pancake-like hexagonal
More informationGeneral Synthesis of Graphene-Supported. Bicomponent Metal Monoxides as Alternative High- Performance Li-Ion Anodes to Binary Spinel Oxides
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) General Synthesis of Graphene-Supported
More informationSupporting Information. Co 4 N Nanosheets Assembled Mesoporous Sphere as a Matrix for Ultrahigh Sulfur Content Lithium Sulfur Batteries
Supporting Information Co 4 N Nanosheets Assembled Mesoporous Sphere as a Matrix for Ultrahigh Sulfur Content Lithium Sulfur Batteries Ding-Rong Deng, Fei Xue, Yue-Ju Jia, Jian-Chuan Ye, Cheng-Dong Bai,
More informationSupporting Information
Copyright WILEY-VCH Verlag GmbH & Co. KGaA, 69469 Weinheim, Germany, 2016. Supporting Information for Adv. Mater., DOI: 10.1002/adma.201604015 High Performance Graphene/Ni 2 P Hybrid Anodes for Lithium
More informationSupporting information
a Supporting information Core-Shell Nanocomposites Based on Gold Nanoparticle@Zinc-Iron- Embedded Porous Carbons Derived from Metal Organic Frameworks as Efficient Dual Catalysts for Oxygen Reduction and
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Mesoporous C-coated SnO x nanosheets
More informationSupplementary Figure 1. (a-b) EDX of Mo 2 and Mo 2
Supplementary Figure 1. (a-b) EDX of Mo 2 C@NPC/NPRGO and Mo 2 C@NPC. Supplementary Figure 2. (a) SEM image of PMo 12 2-PPy, (b) TEM, (c) HRTEM, (d) STEM image and EDX elemental mapping of C, N, P, and
More informationSupplementary Figure 1 XPS, Raman and TGA characterizations on GO and freeze-dried HGF and GF. (a) XPS survey spectra and (b) C1s spectra.
Supplementary Figure 1 XPS, Raman and TGA characterizations on GO and freeze-dried HGF and GF. (a) XPS survey spectra and (b) C1s spectra. (c) Raman spectra. (d) TGA curves. All results confirm efficient
More informationState Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing , China
Electronic Supplementary Material A Co-N/C hollow-sphere electrocatalyst derived from a metanilic CoAl layered double hydroxide for the oxygen reduction reaction, and its active sites in various ph media
More informationJournal of Materials Chemistry A ELECTRONIC SUPPLEMENTARY INFORMATION (ESI )
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 218 Journal of Materials Chemistry A ELECTRONIC SUPPLEMENTARY INFORMATION (ESI
More informationSupporting Information
Supporting Information Zeolite-Templated Mesoporous Silicon Particles for Advanced Lithium-Ion Battery Anodes Nahyeon Kim, Hyejung Park, Naeun Yoon, and Jung Kyoo Lee * Department of Chemical Engineering,
More informationSupplemental Information. Lightweight Metallic MgB 2 Mediates. Polysulfide Redox and Promises High- Energy-Density Lithium-Sulfur Batteries
JOUL, Volume 3 Supplemental Information Lightweight Metallic MgB 2 Mediates Polysulfide Redox and Promises High- Energy-Density Lithium-Sulfur Batteries Quan Pang, Chun Yuen Kwok, Dipan Kundu, Xiao Liang,
More informationTailorable and Wearable Textile Devices for Solar Energy Harvesting and Simultaneous Storage
Supporting Information Tailorable and Wearable Textile Devices for Solar Energy Harvesting and Simultaneous Storage Zhisheng Chai,, Nannan Zhang,, Peng Sun, Yi Huang, Chuanxi Zhao, Hong Jin Fan, Xing Fan,*,
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information In situ growth of heterostructured Sn/SnO nanospheres
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supporting Information Experimental section Synthesis of Ni-Co Prussian
More informationSupporting Information
Supporting Information A General Strategy for the Synthesis of Transition-Metal Phosphide/N-doped Carbon Frameworks for Hydrogen and Oxygen Evolution Zonghua Pu, Chengtian Zhang, Ibrahim Saana Amiinu,
More informationSupporting Information
Supporting Information Heterostructured Bi 2 S 3 -Bi 2 O 3 Nanosheets with a Built-In Electric Field for Improved Sodium Storage Wen Luo, a,b Feng Li, a Qidong Li, a Xuanpeng Wang, a Wei Yang, a Liang
More informationSupporting Information. Carbon nanofibers by pyrolysis of self-assembled perylene diimide derivative gels as supercapacitor electrode materials
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Supporting Information Carbon nanofibers by pyrolysis of self-assembled
More informationConversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin , PR China
Supporting information for Assembly of flexible CoMoO 4 @NiMoO 4 xh 2 O and Fe 2 O 3 electrodes for solid-state asymmetric supercapacitors Jing Wang a, Leipeng Zhang b, Xusong Liu a, Xiang Zhang b, Yanlong
More informationFlexible Asymmetrical Solid-state Supercapacitors Based on Laboratory Filter Paper
SUPPORTING INFORMATION Flexible Asymmetrical Solid-state Supercapacitors Based on Laboratory Filter Paper Leicong Zhang,,,# Pengli Zhu,,,#, * Fengrui Zhou, Wenjin Zeng, Haibo Su, Gang Li, Jihua Gao, Rong
More informationCo-vacancy-rich Co 1 x S nanosheets anchored on rgo for high-efficiency oxygen evolution
Electronic Supplementary Material Co-vacancy-rich Co 1 x S nanosheets anchored on rgo for high-efficiency oxygen evolution Jiaqing Zhu 1, Zhiyu Ren 1 ( ), Shichao Du 1, Ying Xie 1, Jun Wu 1,2, Huiyuan
More informationFacile synthesis of accordion-like Ni-MOF superstructure for highperformance
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Supplementary Information Facile synthesis of accordion-like Ni-MOF superstructure
More informationA Scalable Synthesis of Few-layer MoS2. Incorporated into Hierarchical Porous Carbon. Nanosheets for High-performance Li and Na Ion
Supporting Information A Scalable Synthesis of Few-layer MoS2 Incorporated into Hierarchical Porous Carbon Nanosheets for High-performance Li and Na Ion Battery Anodes Seung-Keun Park, a,b Jeongyeon Lee,
More informationHydrothermally Activated Graphene Fiber Fabrics for Textile. Electrodes of Supercapacitors
Supporting Information for Hydrothermally Activated Graphene Fiber Fabrics for Textile Electrodes of Supercapacitors Zheng Li, Tieqi Huang, Weiwei Gao*, Zhen Xu, Dan Chang, Chunxiao Zhang, and Chao Gao*
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Trifunctional NiO Ag NiO Electrodes
More informationSupporting Information. Electronic Modulation of Electrocatalytically Active. Highly Efficient Oxygen Evolution Reaction
Supporting Information Electronic Modulation of Electrocatalytically Active Center of Cu 7 S 4 Nanodisks by Cobalt-Doping for Highly Efficient Oxygen Evolution Reaction Qun Li, Xianfu Wang*, Kai Tang,
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Two-dimensional CoNi nanoparticles@s,n-doped
More informationSupporting Information
Supporting Information MoS 2 Nanosheets Vertically Grown on Graphene Sheets for Lithium Ion Battery Anodes Yongqiang Teng 1, Hailei Zhao 1, 2,*, Zijia Zhang 1, Zhaolin Li 1, Qing Xia 1, Yang Zhang 1, Lina
More informationSupporting Information
Supporting Information Surfactant-Free Assembly of Mesoporous Carbon Hollow Spheres with Large Tunable Pore Sizes Hongwei Zhang, Owen Noonan, Xiaodan Huang, Yannan Yang, Chun Xu, Liang Zhou, and Chengzhong
More informationSupporting Information. Supercapacitors
Supporting Information Ni(OH) 2 Nanoflower/Graphene Hydrogels: A New Assembly for Supercapacitors Ronghua Wang ab, Anjali Jayakumar a, Chaohe Xu* c and Jong-Min Lee* a [a] School of Chemical and Biomedical
More informationHigh Salt Removal Capacity of Metal-Organic Gel Derived. Porous Carbon for Capacitive Deionization
Supporting Information High Salt Removal Capacity of Metal-Organic Gel Derived Porous Carbon for Capacitive Deionization Zhuo Wang, Tingting Yan, Guorong Chen, Liyi Shi and Dengsong Zhang* Research Center
More informationSupporting Information
Electronic Supplementary Material (ESI) for Sustainable Energy & Fuels. This journal is The Royal Society of Chemistry 2017 Supporting Information Asymmetric hybrid energy storage of battery-type nickel
More informationSupporting Information for: Atomic Substitution Enabled Synthesis of Vacancy-Rich Two- Rechargeable Magnesium Batteries
Supporting Information for: Atomic Substitution Enabled Synthesis of Vacancy-Rich Two- Dimensional Black TiO 2-x Nanoflakes for High-Performance Rechargeable Magnesium Batteries Authors: Yanrong Wang,
More informationSupporting Information
Supporting Information N,P-co-doped Meso-/microporous Carbon Derived from Biomass Materials via a Dual-activation Strategy as High-performance Electrodes for Deionization Capacitors Dong Xu,, Ying Tong,,
More informationSupporting Information. Facile electrospinning formation of carbon-confined metal oxide cube-intube. nanostructures for stable lithium storage
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Supporting Information Facile electrospinning formation of carbon-confined metal oxide cube-intube
More informationTuning the Shell Number of Multi-Shelled Metal Oxide. Hollow Fibers for Optimized Lithium Ion Storage
Supporting Information Tuning the Shell Number of Multi-Shelled Metal Oxide Hollow Fibers for Optimized Lithium Ion Storage Jin Sun, Chunxiao Lv, Fan Lv, ǁ Shuai Chen, Daohao Li, Ziqi Guo, Wei Han, Dongjiang
More informationPomegranate-Like N, P-Doped Nanospheres as Highly Active Electrocatalysts for Alkaline Hydrogen Evolution
Supporting Information Pomegranate-Like N, P-Doped Mo2C@C Nanospheres as Highly Active Electrocatalysts for Alkaline Hydrogen Evolution Yu-Yun Chen,,,# Yun Zhang,,# Wen-Jie Jiang,, Xing Zhang,, Zhihui
More informationSupporting Information
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2015 Supporting Information Synthesis and electrochemical properties of spherical and hollow-structured
More informationDominating Role of Aligned MoS 2 /Ni 3 S 2. Nanoarrays Supported on 3D Ni Foam with. Hydrophilic Interface for Highly Enhanced
Supporting Information Dominating Role of Aligned MoS 2 /Ni 3 S 2 Nanoarrays Supported on 3D Ni Foam with Hydrophilic Interface for Highly Enhanced Hydrogen Evolution Reaction Jiamu Cao a, Jing Zhou a,
More informationSupplementary Figure 1 Supplementary Figure 2
Supplementary Figure 1 XRD pattern of pure 3D PGC framework. The pure 3D PGC was obtained by immersing NaCl Na 2 S@GC in water to remove the NaCl and Na 2 S. The broad reflection peak in the range of 15
More informationSustainable Li/Na-Ion Batteries
Sustainable Li/Na-Ion Batteries Chunsheng Wang 1223C Chemical and Nuclear Engineering Department of Chemical & Biomolecular Engineering Email: cswang@umd.edu Phone: (301) 405-0352 Application of Li-ion
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information (ESI) LiTi 2 (PO 4 ) 3 /reduced graphene oxide nanocomposite
More informationSupporting Information. Cobalt Molybdenum Oxide Derived High-Performance Electrocatalyst
Supporting Information Cobalt Molybdenum Oxide Derived High-Performance Electrocatalyst for the Hydrogen Evolution Reaction Mingjie Zang, [a] Ning Xu, [a] Guoxuan Cao, [a] Zhengjun Chen, [a] Jie Cui, [b]
More informationElectronic Supplementary Information. Composite Gel Polymer Electrolyte for Lithium-sulfur
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information Nano-SiO 2 Embedded Poly (propylene
More informationSupplementary Figure 1 A schematic representation of the different reaction mechanisms
Supplementary Figure 1 A schematic representation of the different reaction mechanisms observed in electrode materials for lithium batteries. Black circles: voids in the crystal structure, blue circles:
More informationLotus root-like porous carbon nanofiber anchored with CoP nanoparticles as all-ph hydrogen evolution electrocatalysts
Electronic Supplementary Material Lotus root-like porous carbon nanofiber anchored with CoP nanoparticles as all-ph hydrogen evolution electrocatalysts Hengyi Lu 1, Wei Fan 2 ( ), Yunpeng Huang 1, and
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supporting Information Ultrathin Petal-like NiAl Layered Double oxide/sulfide
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Supporting Information Adding refractory 5d transition metal W into PtCo
More informationSupporting Information. Bi-functional Catalyst with Enhanced Activity and Cycle Stability for. Rechargeable Lithium Oxygen Batteries
Supporting Information Hierarchical Mesoporous/Macroporous Perovskite La 0.5 Sr 0.5 CoO 3-x Nanotubes: a Bi-functional Catalyst with Enhanced Activity and Cycle Stability for Rechargeable Lithium Oxygen
More informationScalable Preparation of Hierarchical Porous Activated Carbon/graphene composite for High-Performance Supercapacitors
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2019 Supplementary Information Scalable Preparation of Hierarchical Porous Activated
More informationSupplementary Information for. Red Phosphorus as High-Performance Anode Materials for Naion. Batteries
Supplementary Information for Inexpensive Antimony Nanocrystals and Their Composites with Red Phosphorus as High-Performance Anode Materials for Naion Batteries Marc Walter, 1, 2 Rolf Erni, 3 and Maksym
More informationSupporting Information
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2015 Supporting Information Pyrite FeS 2 for High-rate and Long-life Rechargeable
More informationTwo Dimensional Graphene/SnS 2 Hybrids with Superior Rate Capability for Lithium ion Storage
Electronic Supplementary Information Two Dimensional Graphene/SnS 2 Hybrids with Superior Rate Capability for Lithium ion Storage Bin Luo, a Yan Fang, a Bin Wang, a Jisheng Zhou, b Huaihe Song, b and Linjie
More informationKinetically-Enhanced Polysulfide Redox Reactions by Nb2O5. Nanocrystal for High-Rate Lithium Sulfur Battery
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) Kinetically-Enhanced Polysulfide
More informationSupporting information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Supporting information Effect of cation substitution on pseudocapacitive
More informationHighly ordered mesoporous carbon nanofiber arrays from a crab shell biological template and its application in supercapacitors and fuel cells
Supporting Information Highly ordered mesoporous carbon nanofiber arrays from a crab shell biological template and its application in supercapacitors and fuel cells Hai-Jing Liu, Xiao-Ming Wang, Wang-Jun
More informationMagnesiothermic synthesis of sulfur-doped graphene as an efficient. metal-free electrocatalyst for oxygen reduction
Supporting Information: Magnesiothermic synthesis of sulfur-doped as an efficient metal-free electrocatalyst for oxygen reduction Jiacheng Wang, 1,2,3, * Ruguang Ma, 1,2,3 Zhenzhen Zhou, 1,2,3 Guanghui
More informationSupporting information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Supporting information Layered Nickel metal-organic framework for high
More informationPerovskite Solar Cells Powered Electrochromic Batteries for Smart. Windows
Electronic Supplementary Material (ESI) for Materials Horizons. This journal is The Royal Society of Chemistry 2016 Supporting Information for Perovskite Solar Cells Powered Electrochromic Batteries for
More informationGermanium Anode with Excellent Lithium Storage Performance in a Ge/Lithium-
Supporting Information Germanium Anode with Excellent Lithium Storage Performance in a Ge/Lithium- Cobalt-Oxide Lithium-Ion Battery Xiuwan Li, Zhibo Yang, Yujun Fu, Li Qiao, Dan Li, Hongwei Yue, and Deyan
More informationEngineering NiS/Ni 2 P Heterostructures for Efficient Electrocatalytic Water Splitting
Supporting Information Engineering NiS/Ni 2 P Heterostructures for Efficient Electrocatalytic Water Splitting Xin Xiao, Dekang Huang, Yongqing Fu, Ming Wen, Xingxing Jiang, Xiaowei Lv, Man Li, Lin Gao,
More informationSupporting Information. Engineering Two-Dimensional Mass-Transport Channels
Supporting Information Engineering Two-Dimensional Mass-Transport Channels of MoS 2 Nanocatalyst towards Improved Hydrogen Evolution Performance Ge Wang a, Jingying Tao a, Yijie Zhang a, Shengping Wang
More informationSupporting Information
Copyright WILEY-VCH Verlag GmbH & Co. KGaA, 69469 Weinheim, Germany, 2015. Supporting Information for Adv. Energy Mater., DOI: 10.1002/aenm.201500060 Interconnected Nanorods Nanoflakes Li 2 Co 2 (MoO 4
More informationMetal organic framework-based separator for lithium sulfur batteries
ARTICLE NUMBER: 16094 DOI: 10.1038/NENERGY.2016.94 Metal organic framework-based separator for lithium sulfur batteries 4 5 Songyan Bai 1,2, Xizheng Liu 1, Kai Zhu 1, Shichao Wu 1,2 Haoshen Zhou 1,2,3*
More informationSupporting Information
Supporting Information Iron Telluride Decorated Reduced Graphene Oxide Hybrid Microspheres as Anode Materials with Improved Na-Ion Storage Properties Jung Sang Cho 1, Seung Yeon Lee 1, Jung-Kul Lee 2,
More informationBoosting the hydrogen evolution performance of ruthenium clusters. through synergistic coupling with cobalt phosphide
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information for Boosting the hydrogen evolution
More informationSupporting Information
Supporting Information The Design of Hierarchical Ternary Hybrid for Fiber-Shaped Asymmetric Supercapacitor with High Volumetric Energy Density Xunliang Cheng, Jing Zhang, Jing Ren, Ning Liu, Peining Chen,
More informationFacile synthesis of porous nitrogen-doped holey graphene as an efficient metal-free catalyst for the oxygen reduction reaction
Electronic Supplementary Material Facile synthesis of porous nitrogen-doped holey graphene as an efficient metal-free catalyst for the oxygen reduction reaction Li Qin 1,2,5, Ruimin Ding 1,2, Huixiang
More informationSupplementary Information for
Supplementary Information for Facile transformation of low cost thiourea into nitrogen-rich graphitic carbon nitride nanocatalyst with high visible light photocatalytic performance Fan Dong *a, Yanjuan
More informationSupporting Information
Supporting Information Nest-like NiCoP for Highly Efficient Overall Water Splitting Cheng Du, a Lan Yang, a Fulin Yang, a Gongzhen Cheng a and Wei Luo a,b* a College of Chemistry and Molecular Sciences,
More informationSupporting Information. sulfurization of a bi-metal-organic framework for highperformance. supercapacitor and its photocurrent
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Supporting Information One-step synthesis of MnS/MoS 2 /C through calcination and sulfurization
More informationHighly doped and exposed Cu(I)-N active sites within graphene towards. efficient oxygen reduction for zinc-air battery
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) for Energy & Environmental Science.
More informationSynthesis and electrochemical performance of hierarchical Sb 2 S 3 nanorod-bundles for lithium-ion batteries
J. Electrochem. Sci. Eng. 4(2) (2014) 45-53; doi: 10.5599/jese.2014.0045 Original scientific paper Open Access : : ISSN 1847-9286 www.jese-online.org Synthesis and electrochemical performance of hierarchical
More informationSupporting Information
Copyright WILEY-VCH Verlag GmbH & Co. KGaA, 69469 Weinheim, Germany, 213. Supporting Information for Adv. Energy Mater., DOI: 1.12/aenm.2131565 Reduction of Graphene Oxide by Hydrogen Sulfide: A Promising
More information