Cost Action CM1404. CHEMISTRY OF SMART ENERGY CARRIERS AND TECHNOLOGIES: SMARTCATs
|
|
- Annabella Hart
- 5 years ago
- Views:
Transcription
1 Cost Action CM144 CHEMISTRY OF SMART ENERGY CARRIERS AND TECHNOLOGIES: SMARTCATs Report of the STSM with code COST-STSM-ECOST-STSM-CM STSM Title "Adsorption tests as diagnostic tool for pollutants emissions control in SECs combustion" STSM duration 4 weeks STSM period 3-28 April 217 STSM applicant Valentina Gargiulo, Research fellow at the Istituto di Ricerche sulla Combustione IRC-CNR of Naples Host institution Institute of Conditions Extrêmes et Matériaux: Haute Température et Irradiation, CEMHTI, belonging to the Centre National de la Recherche Scientifique (CNRS) in Orléans, France. CEMHTI has a highly recognized international experience on the characterization of the physicochemical properties of materials under extreme conditions, through the understanding of the fundamentals of their structure at atomic scale with a special concern in the study of materials for energy applications and environmental remediation. Host group ADPOR Group under the coordination of Dr. Conchi O. Ania. The host group has a long-standing interest and a well-known experience on research activities related to exploring precursors and developing advanced nanostructured materials for their use in high-tech applications, covering energy storage and conversion and environmental protection. Working group WG3 Keywords Diagnostic, gaseous pollutants, CO 2, gas adsorption measurements
2 Motivation of the STSM Nowadays the interest in natural and renewable forms of energy, also referred as smart energy carriers (SECs), is progressively increasing over the classical fossil fuel sources which are severely diminishing. Such carriers include hydrogen and natural gas. At the same time great attention is focused in monitoring pollutants emissions in SECs combustion. Adsorption techniques are a reliable diagnostic tool from both the technological and economical points of view (high energy efficiency, ease of control, low capital investment costs) to face the issues involved in SECs combustion (i.e. the presence of CO, CO 2, SO 2, NH 3 and VOCs in combustion exhaust causes combustion chamber corrosion and overall environmental problems). Separation and quantification of pollutants from gas exhaust is thus inevitably demanded in order to minimize the impact of SECs combustion. In a view of exploiting adsorption on solid matrix as diagnostic tool to monitoring gaseous pollutants emission in SECs combustion, an ideal sorbent should exhibit high selectivity toward CO, CO 2, SO 2, NH 3 and light hydrocarbons (i.e. CH 4 ) with respect N 2, possibly acting as potential pollutant storage sink. Purpose (objectives) of the STSM The topic of the research developed by Dr Gargiulo during the STSM was focused on exploring the fate of gases emitted to the atmosphere in typical SECs combustion processes (i.e., CO 2, CH 4, CO, H 2 among others). The approach was based on studying the differences in affinity of these gases and their mixtures in meso-nanoporous materials used for monitoring their control and in the storage, as well as the interactions in the confined pore voids to maximize physisorption and/or separation. The goal of these adsorption tests on new materials based on carbon, ideally produced via inexpensive, low-energy consumption methods, using renewable resources as precursors, with flexible morphologies, pore structures and functionalities, was the identification of the optimal shape, size, geometry and chemistry of the pores as ought to be for a given application like those described above. Description of the work carried out during the STSM Samples A selection of chemically tailored materials prepared at IRC-CNR, differing in terms of textural, chemical and structural characteristics, was tested at the host institution where volumetric gas adsorption analyzers are available. The materials, prepared at IRC and analyzed at CEMHTI, are listed in the Table 1 along with the nomenclature used within the text to identify them. The materials object of the experimental campaign of measurements performed during the STSM can be gathered into four groups: i) reference carbonaceous material (carbon black), ii) inorganic materials (nfem, Ti-MIL125), iii) carbonaceous materials derived from biomass thermochemical conversions -carbonized rice husk (RH), biochars from cellulose (Char C), biochars from populus nigra wood (Char P)- and iv) chemical modified materials obtained by modifying carbonaceous materials derived from biomass thermochemical conversions (RH NaOH, Char P NaOH, Char P nfem and Char P NH 2 ). The selected biochars differ not only for the type of biomass used for their preparation (cellulose fibers and populus nigra wood) but also for 2
3 the pyrolysis temperature employed (53, 65, 7 C for cellulose fibers, 48 and 6 C for populus nigra wood). A so great variability of samples was chosen to cover a large range of chemical and textural properties. Table 1. List of samples and their nomenclature Group Sample Description Label i Carbon black Furnace black carbon, selected as reference material CB ii MIL-125 (Ti) Magnetite nanoparticles Metal organic framework made by Ti 4+ and 1,4-benzene dicarboxylic acid (BDC) [1] Ferric oxide nanoparticles prepared in presence of a surfactant in order to prevent agglomeration [2] Ti-MIL125 nfem Biochars from cellulose pyrolysis Biochars obtained by steam assisted slow pyrolysis of cellulose fibers [3]. The pyrolysis temperature was rise up to three different values: 53 C, 65 C and 7 C Char C 53 C Char C 65 C Char C 7 C iii Biochars from populus nigra wood pyrolysis Biochars obtained by steam assisted slow pyrolysis of populus nigra wood [4]. The pyrolysis temperature was rise up to two different values: 48 C, and 6 C Char P 48 C Char P 6 C Carbonized rice husk Rice husk carbonized in a auger furnace in the 5-8 C temperature range for 3 hours RH Biochar from populus Biochar obtained by steam assisted slow pyrolysis of nigra wood pyrolysis populus nigra wood at 6 C after base leaching with a Char P NaOH after base leaching NaOH 5 M solution iv nfem doped populus nigra biochar Biochar obtained by steam assisted slow pyrolysis of populus nigra wood at 6 C decorated with magnetite nanoparticle (15 wt%) Biochar obtained by steam assisted slow pyrolysis of Char P nfem Chemically modified populus nigra wood at 6 C decorated with NH 2 groups biochar introduced after a reaction with DETA on oxidized char Char P NH 2 sample [5] Carbonized rice husk after base leaching Carbonized rice husk after base leaching with a NaOH 5 M solution RH NaOH Methods The gas storage ability of the above reported materials was tested by using various probes (N 2, CO 2, CH 4,) and various temperatures (from cryogenic to near ambient conditions) and from vacuum up to ambient pressures (76 mmhg), under equilibrium conditions. High resolution N 2 adsorption/desorption isotherms were collected on a volumetric analyzer (Micrometrics Triflex) at 77 K, provided with three pressures transducers to allow high resolution in the low pressure range. The cryogenic temperature was maintained with liquid nitrogen bath. All the gas adsorption/desorption isotherms (i.e., CO 2 and CH 4 and N 2 ) at 273, 283, and 298 K were collected on a second volumetric analyzer 3
4 (Micrometrics Tristar 32) provided with one pressure transducer, in the pressure range of.1 9 Torr. During the analysis, the temperature near ambient conditions (ca. between K) was controlled and maintained using a water circulating- bath. Before the gas adsorption experiments, all the samples were outgassed under vacuum at 12 C for hours. Ultrapure gases were used for all the measurements. The reproducibility of the adsorption data was assessed by repeating twice selected measurements. Data analysis The adsorption data were analyzed and modeled in order to have a complete characterization of the textural properties of all the materials. The isosteric heats of adsorption and gas selectivity of a selection of them were also evaluated. The isotherm data were also used to predict the binary mixture adsorption from the experimental pure-gas isotherms of various gas mixtures of strategic impact (ca. CO 2 /CH 4, and CO 2 /N 2 ) by applying the Ideal Adsorbed Solution Theory (IAST) [6]. The isotherms were used to obtain various textural parameters such as: a) the specific surface area using the BET equation applied to the N 2 adsorption isotherms at 77 K; b) the total pore volume at p/p =.99 from the N 2 adsorption isotherms at 77 K; c) the micropore volumes by using the Dubinin-Radushkevich (DR) equation applied to the N 2 and CO 2 adsorption isotherms at 77 K and 273 K, respectively; d) the distribution of pore sizes by applying the NLDFT model to the N 2 adsorption data at 77 K. The CO 2 adsorption isotherms at 273, 283 and 298 K of a selection of samples were used to evaluate the isosteric heats of adsorption. The CO 2, N 2 and CH 4 adsorption isotherms at 298 K of a selection of samples were used to evaluate the gas uptake and selectivity. Timeline of activities carried out during STSM The timeline of the activities performed during the STSM is reported in the Table 2. Table 2. Timeline of the activities performed during the STSM Period Experiments and data analysis carried out 1 th week Adsorption tests with CO 2, and N 2 at cryogenic temperatures. 2 d week Adsorption tests with CO 2, and N 2 at cryogenic temperatures. Analysis of the data. 3 d week 4 th week Adsorption tests with CO 2, and N 2 at temperature near ambient conditions. Adsorption tests with N 2 at cryogenic temperatures. Analysis of the data. Adsorption tests with CO 2, CH 4 and N 2 at temperature near ambient conditions. Adsorption tests with N 2 at cryogenic temperatures. Analysis of the data, evaluation of isosteric heats of adsorption and CO 2 /N 2, CO 2 /CH 4 selectivities. High resolution nitrogen isotherms at 77 K were performed during the whole STSM period because they required very long acquisition times, being the samples under study microporous and showing constricted porosity. The first two weeks were devoted also to the complete characterization of the samples by acquiring CO 2 isotherms at 273 K. The analysis of these data then allowed the selection of six samples whose 4
5 adsorption capacities against CO 2, N 2 and CH 4 has been analyzed more in depth by acquiring, during the last two weeks, adsorption isotherms at different temperatures: 283 and 298 K. During the last week, the data acquired were then used for determining the isosteric heats of adsorption and CO 2 /N 2, CO 2 /CH 4 selectivities. Description of the main results obtained The N 2 adsorption/desorption isotherms collected at 77 K are reported in Figure 1. The shape of the N 2 isotherms of all the samples is different, pointing out to different porosity in all of them. For instance, all the chars, and the samples Ti-MIL125 and RH showed type I isotherms in the IUPAC classification, characteristic of microporous materials. At converse, sample CB and nfem showed type IV(a) isotherms, characteristic of samples with a well-developed mesoporosity, as seen in the high uptake at relative pressures above.5 and the presence of marked hysteresis loops [7]. Sample RH-NaOH displayed also a type IV(a) isotherm, with a marked adsorption at low relative pressures, indicating a well-developed microporosity along with the mesoporosity CB Ti-MIL125 nfem Group i & ii Char C 53 C Char C 7 C Char C 65 C Group iii,2,4,6,8 1,2,4,6, RH Char P 6 C Char P 48 C Group iii Char P NaOH Char P 6 C Char P NH2 Char P nfem RH NaOH Group iv,2,4,6,8 1,2,4,6,8 1 Figure 1. High resolution N 2 adsorption/desorption isotherms at 77 K of the studied samples. In contrast, samples char P 48 C and char P-NH 2 showed almost no porosity, as seen in the very low N 2 adsorption in the whole range of relative pressures, revealing the absence of pores accessible to nitrogen 5
6 probe at this temperature. It is interesting to point out that the char samples are characterized by irreversible nitrogen isotherms even at low relatives pressures (the desorption branch does not overlap the adsorption branch); this is a typical feature of char samples [8] and it is related to the presence of microporous samples with constricted porosity. The main textural features of the samples were calculated analyzing the N 2 adsorption isotherms, and are reported in Table 3. Data indicates that CB, selected as reference material, has quite a high surface area compared to other carbon black reported in literature [9], as well as a low volume of micropores, as expected from the isotherm depicted in Figure 1. On the other hand, the MOF sample presented a high surface area and a very high total pore volume, corroborating that it is a microporous material. This is in accordance with previous literature findings for this material [1]. As for sample nfem, the contribution of microporosity is also low, as in the case of the carbon black. Table 3. Main textural properties calculated from the N 2 adsorption isotherms at 77 K BET area V tot (p/p =.99) V micro (DR) Group Sample m 2 /g cm 3 liq/g cm 3 /g i CB ii nfem Ti-MIL Char C Char C iii Char C Char P Char P RH Char P NaOH iv Char P nfem Char P NH RH NaOH The char samples obtained by steam assisted slow pyrolysis of cellulose fibers at different temperatures are characterized by moderate surface areas, with increasing values as the pyrolysis temperature is raised. Accordingly, the volume of micropores grows with the increase of temperature, and in all the three samples the total pore volume roughly corresponds to that of micropores, which indicates a low contribution of mesoporosity to the overall porous structure of these samples. The char obtained by the pyrolysis of populus nigra wood is characterized by lower surface area and micropore volume compared to those of cellulose chars. This might be likely due to the presence of the other 6
7 two main wood components (lignin and hemicellulose) that during the pyrolysis process entrapped the cellulose fraction in a more compact matrix. When the Char P is treated with NaOH, an increase in the surface area was detected (ca. 3%), which is reasonable if one considers that the data is normalized per gram of sample and the treatment in NaOH removes the ash content (typically non porous matter). The doping of this char with magnetite nanoparticles was not followed by a decrease of the surface area, which we attribute to the low amount of magnetite added (~15 wt.%) and the fact that magnetite itself shows some porosity. In contrast, the impregnation with amine caused a dramatic decrease in the textural properties of the char P, leading to an almost complete blockage of the pores by the amine molecules, as seen in the surface area near to zero. RH exhibited a low surface area and a quite low total pore volume; after the treatment with NaOH 5 M to remove most of the inorganic component (sample RH NaOH), the surface area grew considerably as well as both the total pore volume and the volume of micropores. The textural characterization of the samples was completed by the CO 2 adsorption isotherms at 273 K, that in carbon-based samples allow to evaluate the narrow microporosity [8]. The corresponding isotherms are reported in Figure 2, and the data about narrow microporosity, calculated from the DR equation applied to the CO 2 adsorption isotherms at 273 K are reported in Table 4. As seen, CB and nfem are the samples with the lowest amount of adsorbed CO 2 at a relative pressures of p/p =.35, while the char obtained after the pyrolysis of cellulose fibers at 7 C is the sample with the highest amount of adsorbed CO 2. At converse, Ti-MIL125 exhibited the highest amount of CO 2 adsorbed at p/p =.35, but a different isotherm shape (almost a straight line) compared to that of char isotherms (concave curves); overall this behavior agreed with previous literature findings [1], and indicates a lower interaction of the framework with CO 2 molecules, compared to the carbon-based materials. The comparison between the CO 2 isotherms of the chars from cellulose and populus nigra wood collected at different pyrolysis temperatures revealed that the CO 2 uptake of the chars increased with pyrolysis temperature, indicating that a higher pyrolysis temperature allowed the development of a narrower microporosity. The chemical modification of char from populus nigra wood, as expected, affected the CO 2 sorption capacity; as already observed in the case of nitrogen adsorption, the treatment with NaOH increased the gas uptake due to the effect of ash removal in the mass of the sample. The doping with magnetite nanoparticles did not bring about an increase in the CO 2 uptake, whereas the impregnation with amine resulted in a decrease of the CO 2 uptake. Also in the case of RH, the treatment with NaOH leads to an increase of the gas uptake. 7
8 Group i & ii Group iii CB nfem Ti-MIL125,5,1,15,2,25,3, Char C 65 C Char C 7 C Char C 53 C,5,1,15,2,25,3,35 Group iii Group iv Char P 48 C Char P 6 C RH,5,1,15,2,25,3, RH NaOH Char P nfem Char P NH2 Char P NaOH,5,1,15,2,25,3,35 Figure 2. CO 2 isotherms at 273 K The CO 2 isotherms at 273 K were analyzed to evaluate also the narrow micropore volume (Wo) using the Dubinin-Radushkevich (DR) equation. Also, an average micropore diameter (L) was obtained by the application of Stoeckli Ballerini equation [1]. Data are reported in Table 4. It is important to remark that for some samples, the shape of the CO 2 adsorption isotherms a marked knee in the isotherm at low p/p -, suggested the presence of specific interactions between CO 2 and the samples (for instance in the case of Char P NH 2 ), for which the use of Dubinin-Radushkevich (DR) equation to obtain the micropore volume is not advisable. The CO 2 data collected at 273 K confirmed the trend highlighted by the analysis of N 2 isotherms at 77 K: the CB and the nfem resulted the samples with the lowest narrow micropore volume -in agreement with their classification as mesopourous materials made on the basis of N 2 isotherms at 77 K-, while the Ti-MIL125 and the chars from cellulose fibers were the samples with the highest narrow micropore volumes. For char samples prepared from the same precursor, the volume of narrow micropores grows with the pyrolysis temperature. The NaOH treatment of Char P resulted in a higher narrow micropore volume while, as expected, the impregnation with amine caused a decrease. Also in the case of RH a higher narrow micropore volume was evaluated for RH NaOH compared to RH. 8
9 Table 4. Main textural parameters of the studied samples calculated from the CO 2 adsorption isotherms at 273 K Group Sample Wo micro L cm 3 liq/g i CB.2.72 ii nfem.3.35 Ti-MIL Char C Char C iii Char C Char P Char P RH.1.47 Char P NaOH iv Char P nfem Char P NH RH NaOH nm On the basis of CO 2 sorption capacities at 273 K, six samples were selected to perform a deeper characterization of the sorption capacities: Char C 65 C, Char C 7 C, Char P 6 C, Char P NaOH, CharP NH 2 and RH NaOH. The gas uptake and the CO 2 /N 2 and CO 2 /CH 4 selectivities of these six samples were evaluated by comparing the adsorption isotherms of CO 2, N 2 and CH 4 at 298 K. As seen in the isotherms, in all the cases the adsorbents exhibited a good affinity toward the adsorption of CO 2 and low affinities toward the adsorption of CH 4 and N 2. The CO 2, CH 4 and N 2 adsorption isotherms at 298 K of Char C 7 C and Char P 6 C are shown in Figure 3, as an example of this behavior. Char C 7 C Char P 6 C Quantity Adsorbed, mmol/g 3 2,5 2 1,5 1,5 CH4 CO2 N2 Quantity Adsorbed, mmol/g 1,4 1,2 1,8,6,4,2 N2 CH4 CO2,5 1 Absolute Pressure, atm,5 1 Absolute Pressure, atm Figure 3. Comparison of the CO 2, N 2 and CH 4 isotherms at 298 K for char C 7 C (left) and Char P 6 C (right) 9
10 The prediction of the CO 2 /N 2 and CO 2 /CH 4 selectivities of selected samples were calculated from the single component experimental adsorption data, using the Ideal Adsorbed Solution Theory (IAST) [6]. The selectivity of a gas X over Y (S x/y ) was calculated as the ratio: S x/y = qx/qy p x/p y where q x and q y are IAST predicted uptakes (cm 3 /g) and p x and p y are the partial pressures of gas X and Y respectively. Data for various gas mixtures (i.e., CO 2 :N 2 15:85 for a typical post-combustion application and CO 2 :CH 4 3:7 for natural gas upgrading) at 1 bar are reported in Table 5. Table 5. CO 2 /N 2 and CO 2 /CH 4 selectivities at 1 bar for binary mixtures, evaluated from the single component experimental adsorption isotherms applying the IAST approach. CO 2 /N 2 CO 2 /CH 4 15:85 3:7 Char C Char C Char P Char P NaOH Char P NH RH NaOH All the selected samples exhibited good CO 2 /N 2 and CO 2 /CH 4 selectivities; for the cellulose derived chars, the sample prepared at 7 ºC has a higher selectivity CO 2 /N 2 in a mixture with a typical post-combustion fuel gas composition (ca. 15:85 of CO 2 :N 2 ), than the one obtained at 65 ºC. In the case of the PN-derived chars, the sample modified with amine moieties exhibited the largest selectivity. When a typical natural gas composition is considered (ca. 3:7 of CO 2 :CH 4 ) the selectivity CO 2 /CH 4 is good for all the samples as well, but the values are slightly lower than those over nitrogen. Among all, Char C 65 C, Char P and Char P NH 2 are the samples with the highest selectivity CO 2 /CH 4. To understand the results about gas selectivity the main parameters governing both the CO 2 uptake capacity and selectivity (micropore volume and size and chemical functionalization of the pores) must be taken into account. In general, high CO 2 uptakes correspond to samples with high micropore volumes. On the other hand, selectivity depends on the presence specific interactions between the adsorbent surface and the CO 2 molecules, which explains the higher values for the samples decorated with the amine groups [11]. 1
11 The CO 2 adsorption isotherms of the six samples listed above acquired at 273, 283 and 298 K were used to calculate the CO 2 isosteric heats of adsorption using the Clausius Clapeyron equation. The adsorption isotherms of Char C 7 C and Char P 6 C at 273, 283 and 298 K are shown in Figure 4, as an example. Char C 7 C Char P 6 C Volume Adsorbed, mmol/g 4 3,5 3 2,5 2 1,5 1,5 283 K 298 K 273 K Volume Adsorbed, mmol/g 2,5 2 1,5 1,5 283 K 298 K 273 K Absolute Pressure, mmhg Absolute Pressure, mmhg Figure 4. Comparison among CO 2 isotherms at 273, K for char C 7 C (left) and Char P 6 C (right) The calculated values of the isosteric heat of adsorption ranged between 25 and 35 kj/mol for all six investigated samples. The highest value was found for Char P NH 2 (ca. 35 kj/mol), while the lowest one was obtained for Char C 7 (ca. 28 kj/mol). Overall, the CO 2 isosteric heats of adsorption estimated are in line with those evaluated for other biochars obtained by slow pyrolyis experiments [12] and indicated, for the most of the samples, a non-specific interactions with the gas. Furthermore, the trend of the heats of adsorption agrees with the gas selectivity evaluation: the higher heat of adsorption corresponds to Char P- NH 2, namely the only material bearing specific functional groups selective to carbon dioxide molecules. References [1] Se-Na Kim, Jun Kim, Hee-Young Kim, Hye-Young Cho, Wha-Seung Ahn "Adsorption/catalytic properties of MIL-125 and NH 2 -MIL-125" Catalysis Today 24 (213):85 93; [2] Utkan GG, Sayar F, Batat P, Ide S, Kriechbaum M, Pişkin E. " Synthesis and characterization of nanomagnetite particles and their polymer coated forms" Journal of Colloid and Interface Science 353(211): ; [3] Raffaele Ragucci, Paola Giudicianni, Antonio Cavaliere "Cellulose slow pyrolysis products in a pressurized steam flow reactor" Fuel 17(213): ; [4] Paola Giudicianni, Stefania Pindozzi, Corinna Maria Grottola, Fernando Stanzione, Salvatore Faugno, Massimo Fagnano, Nunzio Fiorentino, Raffaele Ragucci "Pyrolysis for exploitation of biomasses selected for soil phytoremediation: Characterization of gaseous and solid products" Waste Management 61(217): ; 11
12 [5] Valentina Gargiulo. Michela Alfè. Paola Ammendola, Federica Raganati, Riccardo Chirone "CO 2 sorption on surface-modified carbonaceous support: Probing the influence of the carbon black microporosity and surface polarity" Applied Surface Science 36 (Part A)(216): ; [6] A. L. Myers and J. M. Prausnitz "Thermodynamics of mixed-gas adsorption" AIChE Journal 11(1965): ; [7] Thommes M., Kaneko K., Neimark A.V., Olivier J. P., Rodrigez-Reinoso F., Rouquerol J., Sing K. S. W. "Physorption of gases, with special reference to the evaluation of surface area and pore size distribution" (IUPAC technical report) Pure Applied Chemistry 215 (DOI /pac ); [8] Harry Marsh, Francisco Rodriguez-Reinoso "Activated Carbon" Elsevier Science & Technology Books (ISBN: ), August 26; [9] Dana Pantea, Hans Darmstadt, Serge Kaliaguine, Christian Roy " Electrical conductivity of conductive carbon blacks: influence of surface chemistry and topology" Applied Surface Science 217 (23) ; [1] F. Rouquerol, J. Rouquerol, K.S.W. Sing, P. Llewellyn and G. Maurin "Adsorption by Powders and Porous Solids Principles, Methodology and Applications" Elsevier Science & Technology Books (ISBN: ), Second edition 214; [11] J. Patiño, MC. Gutiérrez, D. Carriazo, C. O. Ania, JLG. Fierro, ML. Ferrera, F. del Monte "DES assisted synthesis of hierarchical nitrogen-doped carbon molecular sieves for selective CO 2 versus N 2 adsorption" Journal of Materials Chemistry A, 2 (214): ; [12] Anne Elise Creamer, Bin Gao, Ming Zhang "Carbon dioxide capture using biochar produced from sugarcane bagasse and hickory wood" Chemical Engineering Journal 249 (214) Confirmation of the Host Institution of the successful execution of the STSM See attached documents. How the STSM has contributed to the action s aim The STSM of Dr Gargiulo within the COST action Smartcats was devoted to the collection of new data and the development of diagnostic protocols and methods. The funding of this STSM has contributed to strengthen the competences of the young researcher involved in monitoring pollutants emissions in SECs combustion and also in the fields of engineering and material science. A fundamental value-added was the knowledge transfer between ADPOR Group in the host institution CEMHTI and the young researcher involved: competences in the measurements of gas adsorption isotherms with high resolution instruments, data elaboration and modelling to identify possible applications of materials with tailored chemical and textural as gas storage systems. Moreover, the funding of this STSM has contributed to start a new fruitful collaboration between CNR and CNRS. 12
13 Future collaboration with host institution A new fruitful collaboration between CNR and CNRS on the study of carbonaceous materials for environmental applications stemmed from the funding of this STSM. The first outcome of this new collaboration will be in the next feature the publication of some joint papers aimed to disseminate the results of the STSM research activity. Both parts are intentioned to keep alive this collaboration through continuous discussion and exchange about the data, and overall the possibility to submit joint proposals to national and European founding agencies will be considered surely. Foreseen publications/articles resulting from the STSM The dissemination of the results as communications at national and international meetings will be achieved in the next future as follows: Presentation of oral and WIP contributes at: Tenth Mediterranean Combustion Symposium, September 217, Napoli, Italy 3rd General Meeting and Workshop on SECs in Industry of SMARTCATs Action, Prague, October 25-27, 217 Submission of one or more papers to international peer reviewed journals will be accomplished in the next future. Other comment Dr. Valentina Gargiulo sincerely acknowledges the COST action CM144 and the chair Dr. Mara de Joannon for the opportunity to join the ADPOR group activities at the CEMHTI institute at CNRS campus of Orleans, and to start a fruitful collaboration between CNR and CNRS. VG thanks go to Dr. Conchi O. Ania and all the members of ADPOR groups, Dr. Alicia Gomis Berenguer, Miss. María Cocina Fernández de Córdoba and Miss. Ana Casanova Martinez for their availability and support, for the experimental training and for the fruitful discussions. VG acknowledges also Dr. Michela Alfè for her constant support and Dr. Paola Giudicianni for the help in the production of char samples. 13
High-Pressure Volumetric Analyzer
High-Pressure Volumetric Analyzer High-Pressure Volumetric Analysis HPVA II Benefits Dual free-space measurement for accurate isotherm data Free space can be measured or entered Correction for non-ideality
More informationCO 2 Adsorption Properties of Activated Carbon Fibres under Ambient Conditions
621 CO 2 Adsorption Properties of Activated Carbon Fibres under Ambient Conditions Yoshitaka Nakahigashi 1, Hirofumi Kanoh 1,*, Tomonori Ohba 1, Masumi Baba 1, Yoshiyuki Hattori 2, Naoya Inoue 3 and Masafumi
More informationMetal-Organic Frameworks and Porous Polymer Networks for Carbon Capture
Carbon Capture Workshop, Tuesday, April 3 rd, Texas A&M, Qatar Metal-Organic Frameworks and Porous Polymer Networks for Carbon Capture J. P. Sculley, J.-R. Li, J. Park, W. Lu, and H.-C. Zhou Texas A&M
More informationCARBONIZATION KINETICS OF COCONUT SHELL AND PLUM STONE
CARBONIZATION KINETICS OF COCONUT SHELL AND PLUM STONE Benoît CAGNON, Xavier PY, André GUILLOT I.M.P.-C.N.R.S., Institut de Science et Génie des Matériaux et Procédés, Rambla de la Thermodynamique, Tecnosud,
More informationMOLECULAR SIEVE EFFECTS IN THE ADSORPTION OF ORGANIC VAPORS ON POLYARAMIDE-DERIVED ACTIVATED CARBON FIBERS
MOLECULAR SIEVE EFFECTS IN THE ADSORPTION OF ORGANIC VAPORS ON POLYARAMIDE-DERIVED ACTIVATED CARBON FIBERS M.C. Almazán-Almazán 1, I. Fernández-Morales 1, M. Domingo-García 1, F.J. López- Garzón 1, M.
More informationPREPARATION OF ACTIVATED CARBON FROM PULP AND PAPER MILL WASTES TO BE TESTED FOR THE ADSORPTION OF VOCS
PREPARATION OF ACTIVATED CARBON FROM PULP AND PAPER MILL WASTES TO BE TESTED FOR THE ADSORPTION OF VOCS A. GREGÓRIO *, A. GARCIA-GARCIA #, D. BOAVIDA *, I. GULYURTLU * AND I. CABRITA * * Department of
More informationAdsorption Processes. Ali Ahmadpour Chemical Eng. Dept. Ferdowsi University of Mashhad
Adsorption Processes Ali Ahmadpour Chemical Eng. Dept. Ferdowsi University of Mashhad Contents Introduction Principles of adsorption Types of adsorption Definitions Brief history Adsorption isotherms Mechanism
More informationCO 2 ADSORPTION BY SURFACE MODIFIED CARBON SORBENTS
CO 2 ADSORPTION BY SURFACE MODIFIED CARBON SORBENTS Mercedes Maroto-Valer*, Zhong Tang and Yinzhi Zhang The Energy Institute and The Department of Energy and Geo-Environmental Engineering, The Pennsylvania
More informationAvailable online at ScienceDirect. Energy Procedia 63 (2014 ) GHGT-12
Available online at www.sciencedirect.com ScienceDirect Energy Procedia 63 (2014 ) 6527 6533 GHGT-12 Towards bio-upgrading of biogas: biomass waste-based adsorbents N. Álvarez-Gutiérrez, S. García, M.V.
More informationADSORPTION AND DESORPTION OF CO ON SOLID SORBENTS
ADSORPTION AND DESORPTION OF CO ON SOLID SORBENTS Ranjani Siriwardane (rsiiw@netl.doe.gov; 34-85-4513) Ming Shen (mshen@netl.doe.gov; 34-85-411) Edward Fisher (efishe@netl.doe.gov; 34-85-411) James Poston
More informationACTIVATION OF BIOMASS FIBRES USING ALKALI METAL SALTS
SUMMARY ACTIVATION OF BIOMASS FIBRES USING ALKALI METAL SALTS James Illingworth, Aidan Westwood*, Brian Rand and Paul Williams School of Process Environmental and Materials Engineering University of Leeds,
More informationSTATE-OF-THE-ART ZEOLITE CHARACTERIZATION: ARGON ADSORPTION AT 87.3 K AND NONLOCAL DENSITY FUNCTIONAL THEORY (NLDFT)
STATE-OF-THE-ART ZEOLITE CHARACTERIZATION: ARGON ADSORPTION AT 87.3 K AND NONLOCAL DENSITY FUNCTIONAL THEORY (NLDFT) Physical adsorption in materials consisting of micropores, as for instance in zeolites
More informationPREPARATION OF NITROGEN ENRICHED HIERARCHICALLY NANOPOROUS CARBON FROM POLYBENZOXAZINE FOR METHANE STORAGE
PREPARATION OF NITROGEN ENRICHED HIERARCHICALLY NANOPOROUS CARBON FROM POLYBENZOXAZINE FOR METHANE STORAGE Norawit Kaewpornmongkol a and Thanyalak Chaisuwan *,a,b a The Petroleum and Petrochemical College,
More informationPreparation of biomass derived porous carbon: Application for methane energy storage
Edith Cowan University Research Online ECU Publications Post 013 016 Preparation of biomass derived porous carbon: Application for methane energy storage Yong Sun Edith Cowan University, y.sun@ecu.edu.au
More informationNon-porous reference carbon for N 2 (77.4 K) and Ar (87.3 K) adsorption
Non-porous reference carbon for N 2 (77.4 K) and Ar (87.3 K) adsorption A. Silvestre-Albero a, J. Silvestre-Albero a,*, M. Martínez-Escandell a, Ryusuke Futamura b, Tsutomu Itoh c, K. Kaneko b, F. Rodríguez-Reinoso
More informationEXECUTIVE SUMMARY. especially in last 50 years. Industries, especially power industry, are the large anthropogenic
EXECUTIVE SUMMARY Introduction The concentration of CO 2 in atmosphere has increased considerably in last 100 years, especially in last 50 years. Industries, especially power industry, are the large anthropogenic
More informationThis is a repository copy of Optimised PEI impregnation of activated carbons - Enhancement of CO2 capture under post-combustion conditions.
This is a repository copy of Optimised PEI impregnation of activated carbons - Enhancement of CO2 capture under post-combustion conditions. White Rose Research Online URL for this paper: http://eprints.whiterose.ac.uk/89498/
More informationApplication Challenges for Nanostructured Porous Materials
Application Challenges for Nanostructured Porous Materials Dr Liz Rowsell Director, Johnson Matthey Technology Centre 1 Paradigm Shift in Automotive NOx Control Catalysts A paradigm shift describes a fundamental
More informationIUPAC Technical Report
Pure Appl. Chem. 2015; aop IUPAC Technical Report Matthias Thommes*, Katsumi Kaneko, Alexander V. Neimark, James P. Olivier, Francisco Rodriguez-Reinoso, Jean Rouquerol and Kenneth S.W. Sing Physisorption
More informationSOPHISTICATED DESIGN, INTUITIVE OPERATION, RESEARCH-GRADE RESULTS
SOPHISTICATED DESIGN, INTUITIVE OPERATION, RESEARCH-GRADE RESULTS ASAP 2020 Plus: Accelerated Surface Area and Porosimetry System The Micromeritics ASAP 2020 Plus integrates a variety of automated gas
More informationACTIVATED CARBON FOR GAS ADSORPTION
IV International Seminar Heat Pipes, Heat Pumps, Refrigerators Minsk,Belarus, September 4-7, 2000 ACTIVATED CARBON FOR GAS ADSORPTION A.M. Safonova, N. K.Luneva * L.L. Vasiliev, D.A. Mishkinis ** * Institute
More informationGas content evaluation in unconventional reservoir
Gas content evaluation in unconventional reservoir Priyank Srivastava Unconventional reservoirs 1 Average monthly prod. (mscf) The Problem Gas in-place calculation Prediction of production decline Total
More informationS BET vs. S DFT. Supporting Information
Supporting Information Naturally Nitrogen and Calcium-doped Nanoporous Carbon Derived from Pine Cone with Superior CO 2 Capture Capacities Bingjun Zhu, Congxiao Shang and Zhengxiao Guo S BET vs. S DFT
More informationSpecific Surface Area and Porosity Measurements of Aluminosilicate Adsorbents
ORIENTAL JOURNAL OF CHEMISTRY An International Open Free Access, Peer Reviewed Research Journal www.orientjchem.org ISSN: 0970-020 X CODEN: OJCHEG 2016, Vol. 32, No. (5): Pg. 2401-2406 Specific Surface
More informationInvestigation of Mixed Gas Sorption in Lab-Scale. Dr. Andreas Möller
Investigation of Mixed Gas Sorption in Lab-Scale Dr. Andreas Möller 1 Technical Necessity: Application of porous Materials as Adsorbents Fine cleaning of Gases (i.e. purification of H 2, natural gas, bio
More informationHigh H2 Adsorption by Coordination Framework Materials
Arianna Marchioro Florian Degueldre High H2 Adsorption by Coordination Framework Materials Xiang Lin, Junhua Jia, Xuebo Zhao, K. Mark Thomas, Alexender J. Black, Gavin S. Walker, Neil R. Champness, Peter
More informationMicroporous Carbon adsorbents with high CO 2 capacities for industrial applications
Microporous Carbon adsorbents with high CO 2 capacities for industrial applications Santiago Builes, a,b Thomas Roussel,* b Camelia Matei Ghimbeu, c Julien Parmentier, c Roger Gadiou, c Cathie Vix-Guterl
More informationPorous Solids for Biogas Upgrading
WASTES: Solutions, Treatments and Opportunities 2 nd International Conference September 11 th 13 th 2013 Porous Solids for Biogas Upgrading J.A.C. Silva 1 and A.E. Rodrigues 2 1 Escola Superior de Tecnologia
More informationADSORPTION. Briefly, adsorption is the surface accumulation of material.
ADSORPTION Briefly, adsorption is the surface accumulation of material. Adsorption is a unit operation in which dissolved constituents are removed from the solvent (water) by transfer to the surfaces of
More informationMECHANISM OF ENHANCED HYDROGEN ADSORPTION ON PALLADIUM-DOPED NANOPOROUS CARBON FIBERS. Abstract. Introduction
MECHANISM OF ENHANCED HYDROGEN ADSORPTION ON PALLADIUM-DOPED NANOPOROUS CARBON FIBERS Cristian I. Contescu 1, Nidia C. Gallego 1, Xianxian Wu 1, Halil Tekinalp 2, Dan D. Edie 2, and Frederick S. Baker
More informationHiden Isochema. Gravimetric Gas & Vapor Sorption Analyzers. Hiden Isochema IGA Series. Advancing Sorption Analysis
Technical Specifications The IGA-1 is designed for gravimetric mixed gas sorption, as well as single component vapor sorption analysis, and powerfully combines the features of the IGA-1, IGA-2 and IGA-3.
More informationYiping Zhao and Yuping He
Yiping Zhao and Yuping He Department of Physics and Astronomy Nanoscale Science and Engineering Center The University of Georgia, Athens, GA 30602 April 29, 2010 Outline: Introduction Hydrogenation behaviors
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Cation exchange MOF-derived nitrogen-doped
More informationTechnology offer: Highly Microporous Activated Carbon from an Spanish Anthracite with Homogeneous Pore Size Distribution
Technology offer: Highly Microporous Activated Carbon from an Spanish Anthracite with Homogeneous Pore Size Distribution Technology offer Highly Microporous Activated Carbon from an Spanish Anthracite
More informationPhosphonium Salt & ZnX 2 -PPh 3 Integrated Hierarchical POPs: Tailorable Synthesis and Highly Efficient Cooperative Catalysis in CO 2 Utilization
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Supporting Information: Phosphonium Salt & ZnX 2 -PPh 3 Integrated Hierarchical
More informationQuantifying hydrogen uptake by porous materials
Quantifying hydrogen uptake by porous materials Nuno Bimbo Postdoctoral Research Officer Department of Chemical Engineering University of Bath N.M.M.Bimbo@bath.ac.uk http://www.bath.ac.uk/chem-eng/people/bimbo
More informationLocal Deprotonation Enables Cation Exchange, Porosity. Modulation and Tunable Adsorption Selectivity in a. Metal-Organic Framework
Supporting Information for Local Deprotonation Enables Cation Exchange, Porosity Modulation and Tunable Adsorption Selectivity in a Metal-Organic Framework Jun-Hao Wang,, Dong Luo, Mian Li, and Dan Li
More informationDesign and testing of sorbents for CO2 separation of post-combustion and natural gas sweetening applications
Engineering Conferences International ECI Digital Archives CO2 Summit II: Technologies and Opportunities Proceedings Spring 4-13-2016 Design and testing of sorbents for CO2 separation of post-combustion
More informationPorous systems for high performance CO 2 capture: The MATESA selective CO 2 capture materials
Porous systems for high performance CO 2 capture: The MATESA selective CO 2 capture materials Alessio Masala Ph.D. student Prof. Silvia Bordiga Supervisor MATESA Dissemination Day, Jun. 16 th, 2016, OSLO,
More informationBAE 820 Physical Principles of Environmental Systems
BAE 820 Physical Principles of Environmental Systems Catalysis of environmental reactions Dr. Zifei Liu Catalysis and catalysts Catalysis is the increase in the rate of a chemical reaction due to the participation
More informationWater & Vapor Sorption
Water & Vapor Sorption Material Science Building Material Pharmaceuticals Food Processing www.quantachrome.com 2018 Quantachrome Corporation 07171 Rev C 05/18 Introduction The Vstar is the star of the
More informationDry-gel conversion synthesis of Cr-MIL-101 aided by grinding: High surface area high yield synthesis with minimum purification
Electronic Supporting Informations (ESI): Dry-gel conversion synthesis of Cr-MIL-101 aided by grinding: High surface area high yield synthesis with minimum purification Jun Kim, Yu-Ri Lee and Wha-Seung
More informationAmine-impregnated silica monolith with a hierarchical pore structure: enhancement of CO 2 capture capacity
1 Electronic Supplementary Information (ESI) Amine-impregnated silica monolith with a hierarchical pore structure: enhancement of CO 2 capture capacity for Chao Chen, Seung-Tae Yang, Wha-Seung Ahn* and
More informationSustainable Hydrogen and Electrical Energy Storage 6. F.M. Mulder & M. Wagemaker
Sustainable Hydrogen and Electrical Energy Storage 6 F.M. Mulder & M. Wagemaker 1 Comparison liquid and gaseous H 2 with other liquid fuels Natural gas gasoline Volumetric energy density H 2 is lower than
More informationInfluence of Nickel Electroplating on Hydrogen Chloride Removal of Activated Carbon Fibers
Carbon Science Vol. 5, No. 4 December 2004 pp. 186-190 Influence of Nickel Electroplating on Hydrogen Chloride Removal of Activated Carbon Fibers Soo-Jin Park, Sung-Yeol Jin and Seung-Kon Ryu 1 Advanced
More informationSupporting Information
Supporting Information Controllable Adsorption of CO2 on Smart Adsorbents: An Interplay between Amines and Photoresponsive Molecules Lei Cheng, Yao Jiang, Shi-Chao Qi, Wei Liu, Shu-Feng Shan, Peng Tan,
More informationDesign and Synthesis of Nitrogen-Doped Porous Carbon Materials for CO 2 Capture and Investigation of CO 2 Sorption Kinetics
Design and Synthesis of Nitrogen-Doped Porous Carbon Materials for CO 2 Capture and Investigation of CO 2 Sorption Kinetics Investigators Jennifer Wilcox, Assistant Professor, Energy Resources Engineering;
More informationNetwork of Excellence
Network of Excellence IN SItu study and DEvelopment of processes involving nano PORous Solids Priority 3 NMP research area3.4.1.1 www. pores.gr Goals of the inside-pores The goal of the INSIDE-PORES is
More informationMultilayer Adsorption Equations. Ali Ahmadpour Chemical Eng. Dept. Ferdowsi University of Mashhad
Multilayer Adsorption Equations Ali Ahmadpour Chemical Eng. Dept. Ferdowsi University of Mashhad Contents Empirical isotherm equations BET Surface area determination Limitation Measurement method BDDT
More informationElectronic Supporting information (ESI) for
Electronic Supporting information (ESI) for Experimental assessment of physical upper limit for hydrogen storage capacity at 20 K in densified MIL-101 monoliths Hyunchul Oh a, Dan Lupu b, Gabriela Blanita
More informationAdsorption Equilibrium and Kinetics of H 2 O on Zeolite 13X
Korean J. Chem. Eng., 8(4), 55-530 (00) Adsorption Equilibrium and Kinetics of H O on Zeolite 3X Young Ki Ryu*, Seung Ju Lee, Jong Wha Kim and Chang-Ha Lee *External Relations Department, Procter & Gamble
More informationBACKGROUND GOALS AND OBJECTIVES
Padmavathi Iyengar has earned a M.Sc. in civil and environmental engineering and is now studying for her M.Sc. in geology at the University of Missouri in Kansas City. Her advisor is Dr. Jejung Lee and
More informationProduction of Activated Carbon from Residue of Liquorices Chemical Activation
Abstract: Production of Activated Carbon from Residue of Liquorices Chemical Activation T.Kaghazchi *, M.Soleimani, M.Madadi Yeganeh, Department of Chemical Engineering, AmirKabir University of Technology,
More informationCeramic Processing Research
Journal of Ceramic Processing Research. Vol. 7, No. 1, pp. 37~48 (2006) J O U R N A L O F Ceramic Processing Research Electro-chemical removal effects for the pollutants with K-ACFs Won-Chun Oh a, *, Choung-Sung
More informationHierarchical Nanocomposite by Integrating Reduced Graphene Oxide and Amorphous Carbon with Ultrafine MgO Nanocrystallites for Enhanced CO 2 Capture
Supporting Information Hierarchical Nanocomposite by Integrating Reduced Graphene Oxide and Amorphous Carbon with Ultrafine MgO Nanocrystallites for Enhanced CO 2 Capture Ping Li, and Hua Chun Zeng* Department
More informationUPGRADING OF PETROLEUM RESIDUE BY NITROGEN DOPING FOR CO 2 ADSORPTION
UPGRADING OF PETROLEUM RESIDUE BY NITROGEN DOPING FOR CO 2 ADSORPTION Nattha Chalermwat a,b, Thanyalak Chaisuwan a,b, Uthaiporn Suriyapraphadilok*,a,b a The Petroleum and Petrochemical College, Chulalongkorn
More informationFull GAED Characterization with Aqueous-phase comparisons for Sample EE-541 February 22, 2015
1 Full GAED Characterization with Aqueous- comparisons for Sample February 22, 2015 Executive Summary One sample of granular activated carbon (GAC) was fully characterized for aqueous comparison using
More informationGHGT-11. A Moisture Swing Sorbent for Direct Air Capture of Carbon Dioxide: Thermodynamic and kinetic. analysis
Available online at www.sciencedirect.com Energy Procedia 37 (2013 ) 6096 6104 GHGT-11 A Moisture Swing Sorbent for Direct Air Capture of Carbon Dioxide: Thermodynamic and kinetic analysis Tao Wang a,b,
More informationGravimetric Analysers for the Characterisation of the Sorption Properties of Materials.
Gravimetric Analysers for the Characterisation of the Sorption Properties of Materials. + - IGA - The Intelligent Gravimetric Analyser The IGA range from Hiden Isochema provides the ultimate tool for sorption
More informationSYNTHESIS AND CHARACTERIZATION OF NITROGEN-CONTAINING MICROPOROUS CARBON WITH A THREE-DIMENSIONAL NANO-ARRAY STRUCTURE
SYNTHESIS AND CHARACTERIZATION OF NITROGEN-CONTAINING MICROPOROUS CARBON WITH A THREE-DIMENSIONAL NANO-ARRAY STRUCTURE Peng-Xiang Hou 1, Takashi Kyotani 1, Koich Matsuoka 1, Akira Tomita 1, Norihiko Setoyama
More informationCharacteristics of Hydrogen Adsorption on Chemical Activated Electrospun Carbon Nanofibers
Characteristics of Hydrogen dsorption on Chemical ctivated Electrospun Carbon Nanofibers Ji Sun Im 1, Ju Wan Kim 1, Jeen Seok Jang 2, Ji Sook Hong 3 and Jeong Kwon Suh 3,, Young-Seak Lee 1 1 Chungnam Nat
More informationInfluence of Amine Grafting on Carbon Dioxide Adsorption Behaviors of Activated Carbons
Influence of Amine Grafting on Carbon Dioxide Adsorption Behaviors Bull. Korean Chem. Soc. 2011, Vol. 32, No. 9 3377 http://dx.doi.org/10.5012/bkcs.2011.32.9.3377 Influence of Amine Grafting on Carbon
More informationFull GAED Characterization with Aqueous-phase comparisons for Sample EE-541 February 22, 2015
1 Full GAED Characterization with Aqueous- comparisons for Sample February 22, 2015 Executive Summary One sample of granular activated carbon (GAC) was fully characterized for aqueous comparison using
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) A photoluminescent covalent
More informationNew Journal of Chemistry Electronic Supplementary Information
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2018 New Journal of Chemistry Electronic
More informationHydrogen Adsorption and Storage on Porous Materials. School of Chemical Engineering and Advanced Materials. Newcastle University United Kingdom
Hydrogen Adsorption and Storage on Porous Materials K. M. Thomas. School of Chemical Engineering and Advanced Materials H2FC SUPERGEN Conference Birmingham University, 16-18 th December 2013 Newcastle
More informationADSORPTION IN MICROPOROUS MATERIALS: ANALYTICAL EQUATIONS FOR TYPE I ISOTHERMS AT HIGH PRESSURE
ADSORPTION IN MICROPOROUS MATERIALS: ANALYTICAL EQUATIONS FOR TYPE I ISOTHERMS AT HIGH PRESSURE A. L. MYERS Department of Chemical and Biomolecular Engineering University of Pennsylvania, Philadelphia
More informationAdsorption of Methylene Blue on Mesoporous SBA 15 in Ethanol water Solution with Different Proportions
2015 2 nd International Conference on Material Engineering and Application (ICMEA 2015) ISBN: 978-1-60595-323-6 Adsorption of Methylene Blue on Mesoporous SBA 15 in Ethanol water Solution with Different
More informationHYDROGEN PRODUCTION THROUGH SORPTION ENHANCED REFORMING
HYDROGEN PRODUCTION THROUGH SORPTION ENHANCED REFORMING H.T.J. Reijers, D.F. Roskam-Bakker, J.W. Dijkstra, R.P. de Smidt, A. de Groot, R.W. van den Brink Address: Energy research Centre of the Netherlands,
More informationTechnology offer: Development of novel adsorbents and catalysts based on activated carbon
Technology offer: Development of novel adsorbents and catalysts based on activated carbon Technology offer: Development of novel adsorbents and catalysts based on activated carbon SUMMARY The Advanced
More informationDESIGNED SYNTHESIS OF NANOPOROUS ORGANIC POLYMERS FOR SELECTIVE GAS UPTAKE AND CATALYTIC APPLICATIONS
Virginia Commonwealth University VCU Scholars Compass Theses and Dissertations Graduate School 2015 DESIGNED SYNTHESIS OF NANOPOROUS ORGANIC POLYMERS FOR SELECTIVE GAS UPTAKE AND CATALYTIC APPLICATIONS
More informationInfluence of Nonionic Surfactant Concentration on Physical Characteristics of Resorcinol-Formaldehyde Carbon Cryogel Microspheres
Influence of Nonionic Surfactant Concentration on Physical Characteristics of Resorcinol-Formaldehyde Carbon Cryogel Microspheres Seong-Ick Kim, Takuji Yamamoto, Akira Endo, Takao Ohmori, and Masaru Nakaiwa
More informationMONTEVIDEO. URUGUAY MÁLAGA. SPAIN
This article was downloaded by:[universidad De Malaga] [Universidad De Malaga] On: 11 June 2007 Access Details: [subscription number 770489852] Publisher: Taylor & Francis Informa Ltd Registered in England
More informationUnderstanding Importance of Water Sorption Isotherm Shape, Hysteresis, and Models on Pharmaceutical Materials
Understanding Importance of Water Sorption Isotherm Shape, Hysteresis, and Models on Pharmaceutical Materials Dr. Daniel J. Burnett Surface Measurement Systems, Ltd. Dburnett@surfacemeasurementsystems.com
More informationProf. Em. E.F. Vansant
EASTERN MACEDONIA AND THRACE INSTITUTE OF TECHNOLOGY HEPHAESTUS ADVANCED LABORATORY Prof. Em. E.F. Vansant University of Antwerp Department of Chemistry Material Science Lab Director Hephaestus Adv. Lab.
More informationSupporting Information
Supporting Information Towards rational design of Cu/SSZ-13 selective catalytic reduction catalysts: implications from atomic-level understanding of hydrothermal stability James Song, a,c Yilin Wang, a
More informationPowder Surface Area and Porosity
Powder Surface Area and Porosity Powder Technology Series Edited by B. Scarlett Department of Chemical Engineering University of Technology Loughborough Powder Surface Area and Porosity S. Lowell PhD Quantachrome
More informationPREPARATION OF ACTIVATED CARBON FROM THE BY-PRODUCTS OF AGRICULTURAL INDUSTRY
PREPARATION OF ACTIVATED CARBON FROM THE BY-PRODUCTS OF AGRICULTURAL INDUSTRY L. H. NOSZKO, A. BOTA, A. SIMAY and L. Gy. NAGY Department for Applied Chemistry, Technical University, H-1521 Budapest Received
More informationConductive Activation Carbon Monoliths Prepared Directly from Brown Coal Applications in Gas and Liquid Adsorption
Conductive Activation Carbon Monoliths Prepared Directly from Brown Coal Applications in Gas and Liquid Adsorption Mehrdad Parsa, Emma Qi, Alan. L. Chaffee School of Chemistry 12 th ECCRIA 5-7 Sept, Cardiff
More informationBuilding multiple adsorption sites in porous polymer networks for carbon capture applications
Electronic Supplementary Information Building multiple adsorption sites in porous polymer networks for carbon capture applications Weigang Lu, a Wolfgang M. Verdegaal, a Jiamei Yu, b Perla B. Balbuena,
More information1. Materials All chemicals and solvents were purchased from Sigma Aldrich or SAMCHUN and used without further purification.
1. Materials All chemicals and solvents were purchased from Sigma Aldrich or SAMCHUN and used without further purification. 2. Experimental procedures Benzo[1,2-c:3,4-c':5,6-c'']trifuran, 1: The synthesis
More informationPRODUCING ACTIVED CARBONS FROM PINECONES VIA CHEMICAL ACTIVATION. Abstract. Introduction. Experimental
PRODUCING ACTIVED CARBONS FROM PINECONES VIA CHEMICAL ACTIVATION Esin Apaydın Varol, Dept. of Chemical Engineering, Anadolu University, Eskisehir, Turkey Ersan Pütün, Dept. of Material Science and Engineering,
More informationReport on Preparation of Nanotemplates for mab Crystallization
Deliverable number D2.1 Due date 30/09/2017 Deliverable title Report on Preparation of Nanotemplates for mab Crystallization Issue date 21/09/2017 WP number WP2 Author(s) J. Heng, W. Chen, H. Yang Lead
More informationMetal-Organic Frameworks for Adsorbed Natural Gas Fuel Systems. Hong-Cai Joe Zhou Department of Chemistry Texas A&M University
Metal-Organic Frameworks for Adsorbed Natural Gas Fuel Systems Hong-Cai Joe Zhou Department of Chemistry Texas A&M University 2 US primary energy consumption by fuel, 1980-2035 (quadrillion Btu per year)
More information1 Supplemetary information. 3 Immobilization of hydrous iron oxides into porous alginate beads for. 4 arsenic removal from water
Electronic Supplementary Material (ESI) for Environmental Science: Water Research & Technology. This journal is The Royal Society of Chemistry 2018 1 Supplemetary information 2 3 Immobilization of hydrous
More informationAdsorption and Desorption of Emerging Water Contaminants on Activated Carbon Fabrics
Proceedings of the World Congress on New Technologies (NewTech 2015) Barcelona, Spain July 15-17, 2015 Paper No. 184 Adsorption and Desorption of Emerging Water Contaminants on Activated Carbon Fabrics
More informationEXPLORING ADSORPTION OF NATURAL ORGANIC MATTER FROM NATURAL WATERS BY SURFACE-MODIFIED ACTIVATED CARBONS
EXPLORING ADSORPTION OF NATURAL ORGANIC MATTER FROM NATURAL WATERS BY SURFACE-MODIFIED ACTIVATED CARBONS Wei Cheng, Seyed A. Dastgheib, and Tanju Karanfil * Clemson University, Department of Environmental
More informationTemplate-Free Synthesis of Highly Porous Boron. Nitride: Insights into Pore Network Design and Impact
Template-Free Synthesis of Highly Porous Boron Nitride: Insights into Pore Network Design and Impact on Gas Sorption Sofia Marchesini a, Catriona M. McGilvery b, Josh Bailey c and Camille Petit a, * a
More informationIntroduction. Monday, January 6, 14
Introduction 1 Introduction Why to use a simulation Some examples of questions we can address 2 Molecular Simulations Molecular dynamics: solve equations of motion Monte Carlo: importance sampling Calculate
More informationSupplementary Material (ESI) for Nanoscale This journal is the Royal Society of Chemistry 2011
Experimental details Supplementary Material (ESI) for Nanoscale Characterization For the elemental analysis (C, H, O), a Perkin Elmer 2400 analyzer was used. XRD patterns were recorded on a Siemens XD-500
More informationStudy of Adsorption Properties on Lithium Doped Activated Carbon Materials
Vol. 108 (2005) ACTA PHYSICA POLONICA A No. 2 Proceedings of the XXI International Meeting on Radio and Microwave Spectroscopy RAMIS 2005, Poznań-Bȩdlewo, Poland, April 24 28, 2005 Study of Adsorption
More informationProduction of Mesoporous Carbon from Waste Tire
Production of Mesoporous Carbon from Waste Tire E.L.K. Mui and G. M c Kay Department of Chemical Engineering Hong Kong University of Science and Technology Clear Water Bay, Kowloon, Hong Kong Corresponding
More informationDynamic cyclic performance of phenol-formaldehyde resinderived carbons for pre-combustion CO 2 capture: An experimental study
Available online at www.sciencedirect.com Energy Procedia 37 (213 ) 127 133 GHGT-11 Dynamic cyclic performance of phenol-formaldehyde resinderived carbons for pre-combustion CO 2 capture: An experimental
More informationModification In Charging Composition In Order To Arrive At Desired Circulation Composition In The Context Of Sorption Compressor Based J-T Cooler
Modification In Charging Composition In Order To Arrive At Desired Circulation Composition In The Context Of Sorption Compressor Based J-T Cooler R. N. Mehta, S. L. Bapat, M. D. Atrey Department of Mechanical
More informationAdsorption Equilibrium of Solvent Vapors on Activated Carbons
Korean J. Chem. Eng., 18(4), 518-524 (2001) Adsorption Equilibrium of Solvent Vapors on Activated Carbons Dae Jung Kim*, Wang Geun Shim and Hee Moon *Neophotech Inc., 633-1 Goan-Ri, Backam-Myun, Yongin
More informationExperimental Methods and Analysis
Chapter 3 28 Experimental Methods and Analysis 1. Equipment The fundamental basis of quantitative adsorption analysis is the measurement of excess adsorption isotherms. Each isotherm comprises a series
More informationEffect of pore size and surface chemistry of porous silica on CO 2
Songklanakarin J. Sci. Technol. 34 (4), 3-7, Jul. - Aug. 12 http://www.sjst.psu.ac.th Original Article Effect of pore size and surface chemistry of porous silica on Thongthai Witoon 1,2* and Metta Chareonpanich
More informationSchwarzites for Natural Gas Storage: A Grand- Canonical Monte Carlo Study
Schwarzites for Natural Gas Storage: A Grand- Canonical Monte Carlo Study Daiane Damasceno Borges 1, Douglas S. Galvao 1 1 Applied Physics Department and Center of Computational Engineering and Science,
More informationNITROGEN ENRICHED ACTIVATED CARBONS AS ADSORBENTS AND CATALYSTS IN DESULFURIZATION TECHNOLOGIES
NITROGEN ENRICHED ACTIVATED CARBONS AS ADSORBENTS AND CATALYSTS IN DESULFURIZATION TECHNOLOGIES Andrey Bagreev 1, Svetlana Bashkova 2, Teresa Bandosz 1,2, Angel Menendez 3, Irina Dukhno 4, Yuriy Tarasenko
More informationBy Rogéria Amaral and Sébastien Thomas
Kinetics of CO 2 methanation over a Ni/alumina industrial catalyst By Rogéria Amaral and Sébastien Thomas Laboratoire de Matériaux, Surfaces et Procédés pour la Catalyse, Groupe Energie et Carburants pour
More information