Stereochemistry is EZ! Thanks to Jonah H. for the title.
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1 Stereochemistry is EZ! Thanks to Jonah. for the title. rganic Chemistry CE 310, Exam #3 100 painless points! November 17, 2017 Rules of the road: 1. There are 9 questions on 5 pages, plus a couple of extra credit questions for your amusement. 2. No Notes. 3. No electronic devices of any kind. This includes, but is not limited to the following: PDAs, cell phones, pagers, calculators, mp3 players and multifunctional watches. Students found with these devises at their desk or on their person will fail the exam and be reported to the Dean of Students. w 4. This exam is for the sole use of the student whose name appears below. This exam may not be reproduced in any form without written consent of the instructor. 5. Read the agreement and sign below before you begin. 6. Good Luck! K.C. Russell I have read and agree to follow the above rules. Furthermore, I hereby recognize that I am subject to and agree to abide by the onor Code, which provides standards that encourage ethical academic behavior and imposes penalties for violations of such standards. Printed Name : Student ID# Last eight of IS or last four of SSN Signature :
2 Exam 3: Stereochemistry is EZ CE Fill in the blank. Classify each reaction as either an addition, elimination, rearrangement, or substitution. (4 points) a. Cl N C N Cl b. Cl C 3 Na C 3 NaCl 2. The compound below was recently isolated from a plant fungus and showed potent activity against colon cancer cell lines. Assign the absolute configuration (R, S, E, Z) to the indicated sites by filling in the blanks. (12 pts) a. b. c. d. e. f. f a b c e d 3. Rank the compounds below in the order of decreasing stability (8 points) A B C D Most stable > > > Least stable 1
3 Exam 3: Stereochemistry is EZ CE For each pair below: (20 points) a. Circle the molecule that best fits the description on the right. If both molecules fit the description equally circle them both. If neither fits, write neither. (2 points) b. Provide a brief explanation regarding the fundamental physical property behind the trait. Typically one sentence will do. (2 points) a) A:B A + B vs. A:B A + B Reaction best describing bond disassociation energy b) vs. N 2 N 2 Compound that could be used to resolve a racemic carboxylic acid c) vs. Energy diagram that best represents the formation of a carbocation d) vs. has more total stereoisomers e) vs. 2 more electrophilic carbon 2
4 Exam 3: Stereochemistry is EZ CE Provide the major product(s), missing reagent(s) or starting material(s) for the reactions below. Clearly indicate the stereochemistry in your structures where appropriate. Where more than one stereoisomer is formed you only need to draw one of the stereoisomeric products. ther stereoisomers should be indicated by writing, + enantiomer or + diastereomer, as appropriate. Check the boxes on the right to indicate whether the reaction product solution would be optically active ([a] D 0) or not optically active ([a] D = 0). (12 points; product(s) and starting material(s) = 2, stereochem = 1) a) C 3 + C 3 b) K c) 2 Cl d) Cl 2 ether 6. Rank the carbocations below in order of increasing stability. (8 pts) C 3 C 2 C C 3 C C 3 CC 2 C C 3 C 2 C C 3 C C 3 A B C D C F C 3 Least stable < < < Most stable 3
5 Exam 3: Stereochemistry is EZ CE Provide the complete mechanism for the reactions below to give the product(s) shown. (20 pts) For full credit each mechanism must include the following: Proper arrows to show all electron motion. The structure of all reactive intermediates including stereochemistry where appropriate. a. This mechanism only needs the major pathway necessary to produce the product shown. 2 hν b
6 Exam 3: Stereochemistry is EZ CE For each pair of molecules below fill in the blank with their relationship. Choices are identical, enantiomers, diastereomers, conformational isomers, resonance contributors, constitutional isomers, and non-isomeric. (12 points) C 3 C 3 C 3 C 3 N 2 N 2 C 3 C 2 C 3 C 2 9. Enter in the blanks the number of peaks that would be observed in the 1 and 13 C NMR spectra of the compounds below. You must consider diastereotopic / enantiotopic groups when solving this problem. (4 points) N 2 1 = 13 C = 1 = 13 C = Extra Credit. 1. In what year did your Laureate win his/her prize? (2 points) 2. Which Nobel Laureate received the award for experiments that allowed the examination of transition states? Circle your answer (2 points) Richard Ernst George lah Vadimir Prelog Amhed Zewail 5
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