9 - The Hot Corinos. Complex organic molecules in the inner 100 AU envelope of Solar type protostars

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1 9 - The Hot Corinos Complex organic molecules in the inner 100 AU envelope of Solar type protostars 1

2 THE COLLAPSING PROTOSTAR PHASE 2

3 THE INNER ENVELOPES OF LOW MASS PROTOSTARS Direct observations of iced molecules are possible only for abundances x>10-6 Less abundant species (x>10-11) can be observed only in the gas phase in the region where they sublimate 3

4 THE INNER ENVELOPES : SIZES Predicted sizes of Hot Corinos (Maret et al. 2004) Source R 100K (AU) Distance of the Solar System planets from the Sun: IRAS4A IRAS4B IRAS Planet Earth R (AU) 1 L1448-MM 20 Saturn ~10 L1448-N L1157-MM Uran ~20 L Neptun ~30 VLA1623 I Pluton ~50 4

5 WHAT DETERMINE THE HOT CORINO SIZES? SIMPLE MINDED THEORY : In first approximation, the corino sizes are determined by the LUMINOSITY of the protostar. This sets where the dust temperature reaches the sublimation temperature of the H 2 O-rich ices, and the molecules trapped in. During the Main Accretion Phase, the luminosity L bol of the protostar is given by the gravitational energy released during the collapes. L bol ~ M * M acc / G / R * Where M acc is the accretion rate, G is the gravitational constant, and R * is where the infalling matter releases its energy. Assuming in first approximation that M acc and R * are constant during this phase, the luminosity increases with the age of the protostar. 5

6 THE INNER ENVELOPES : ABUNDANCE JUMPS Formaldehyde & Methanol Source X OUT X IN X OUT X IN IRAS4A IRAS4B IRAS2 L1448-MM L1448-N L1157-MM L1527 (10-10 ) (10-7 ) (10-10 ) (10-7 ) <0.1 <~7 3 <~5 <4 <0.3 <0.1 (Maret et al. 2004,2005) VLA I ICES (1-4)x10-6 (2-20)x10-6 6

7 FORMALDEHYDE & METHANOL FORMATION ON THE GRAIN SURFACES The observed abundances in the hot corinos compare rather well with the theoretical model predictions of CO hydrogenation on the grains surfaces. 7

8 ABUNDANCE JUMPS OF OTHER MOLECULES A detailed study only carried out towards IRAS so far. 8

9 TH E AGE OF THE HOT CORINO The Suplhur chemistry in hot corinos allows to estimate their ages : the case of IRAS Comparing the abundances of SO, SO 2, H 2 S and CS with chemical model predictions, the estimate of the age of the IRAS16293 hot corino is ~10 3 yr. Wakelam et al

10 COMPLEX ORGANIC MOLECULES The first Hot Corino where complex organic molecules have been detected: IRAS (Cazaux et al. 2003) MOLECULE I16293 OMC-1 G CH 3 OH 1E-7 1E-7 2E-5 H 2 CO 1E-7 7E-9 CH 3 OCHO-A 2E-7 1E-8 2E-6 CH 3 OCHO-E 2E-7 1E-8 2E-6 CH 3 OCH 3 2E-7 8E-9 3E-8 CH 3 CHO-A 2E-8 6E-10 3E-9 CH 3 CHO-E 3E-8 6E-10 3E-9 Many other complex molecules are observed in IRAS in a deep unbiased survey covering the mm/submm bands observable from ground (Caux et al. 2005). HCOOH CH 3 CN C 2 H 5 CN CH 3 CCH 6E-8 1E-8 1E-8 3E-7 8E-10 4E-9 3E-9 1E-9 9E-10 7E-7 4E-7 10

11 THE HOT CORINO IMAGES High resolution images of the IRAS Hot Corino shows that the sizes are ~150AU, as predicted Bottinelli et al. 2004b and show a clear chemical differentiation in the two components of the binary system forming IRAS

12 IS IRAS A FREAK? HOT CORINOS EVERYWHERE! WHY & HOW COMPLEX MOLECULES FORM??? Detected methyl formate (HCOOCH 3 ), formic acid (HCOOH) and methyl cyanid (CH 3 CN) in another low mass protostar, NGC1333-IRAS4 (Bottinelli et al. 2004a). Note the methanol deficiency in low mass wrt high mass protostars. 12

13 THE FORMATION OF THE HOT CORINO MOLECULES Simple hydrogenated molecules like ammonia, methanol and formaldehyde are formed by grain surface reactions (during the Pre-Stellar Core phase), and are called PARENT molecules. Once injected into the gas phase (because of ice sublimation) they undergo gas phase reactions and form complex molecules, called DAUGTHER molecules. 13

14 THE FORMATION OF THE HOT CORINO MOLECULES Ion-neutral and neutralneutral reactions involving ammonia, formaldehyde and methanol lead to the formation of complex organic molecules in ~10 4 yr. Note that in low mass protostars this seems a too long time 14

15 MOLECULAR COMPLEXITY IN HOT CORES The most complex organic molecules so far detected in the ISM are glycolaldehyde (CH 2 OHCHO), propenal (CH 2 CHCHO ) and propanal (CH 3 CH 2 CHO). They are in absorption in the direction of the Giant Molecular Cloud SgrB2 (Hollis et al. 2000; 2004). 15

16 THE SEARCH OF THE HOLY GRAIL : GLYCINE DETECTION OF GLYCINE? (Kwan et al. 2003) VERY DEBATED DETECTION REACHED THE CONFUSION LIMIT (Combes et al. 1996) 16

17 WHAT ABOUT GLYCINE in HOT CORINOS? NO DETECTION SO FAR 17

18 8- Hot Corinos Summary Low mass protostars have Hot Corinos whose sizes vary between 10 and 150 AU; Formaldehyde and methanol have been observed to have abundance as high as 10-7 ; Complex organic molecules are also detected and seem to be a common propriety of hot corinos; Likely, grain surface reactions followed by gas phase reactions is the way these molecules are formed; Glycolaldehyde, propenal and propanal are the most complex molecules so far detected. 18