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1 W. Greiner B. Muller QUANTUM MECHANICS Symmetries Physics and Astronomy ONLINE LIBRARY Springer Berlin Heidelberg New York Barcelona Hong Kong London Milan Paris Tokyo

2 Greiner Quantum Mechanics An Introduction 4th Edition Greiner Quantum Mechanics Special Chapters Greiner Miiller Quantum Mechanics Symmetries 2nd Edition Greiner Relativistic Quantum Mechanics Wave Equations 3rd Edition Greiner Classical Mechanics I (in preparation) Greiner Classical Mechanics II (in preparation) Greiner Classical Electrodynamics Greiner Neise Stocker Thermodynamics and Statistical Mechanics Greiner Reinhardt Field Quantization Greiner Reinhardt Quantum Electrodynamics 2nd Edition Greiner Schramm Stein Quantum Chromodynamics 2nd Edition Greiner Marohn Nuclear Models Greiner Miiller Gauge Theory of Weak Interactions 3rd Edition

3 Walter Greiner Berndt MUller QUANTUM MECHANICS Symmetries With a Foreword by D. A. Bromley Second Revised Edition With 81 Figures, and 128 Worked Examples and Problems Springer

4 Professor Dr. Walter Greiner Institut fiir Theoretische Physik der Johann Wolfgang Goethe-Universitat Frankfurt Postfach I I Frankfurt am Main Germany Street address: Robert-Mayer-Strasse Frankfurt am Main Germany greiner@th.physik.uni-frankfurt.de Professor Dr. Berndt Muller Physics Department Duke University P.O. Box Durham, NC USA muller@phy.duke.edu Title of the original German edition: Theoretische Physik, Band 5: Quantenmechanik II, Symmetrien 3. Aujl. Verlag Harri Deutsch, Thun, I 984, I 992 Second Edition I 994 Second Printing I 997 Third Printing 200 I ISBN Auflage Springer-Verlag Berlin Heidelberg New York ISBN I. Autlage Springer-Verlag Berlin Heidelberg New York This volume originally appeared in the series "Theoretical Physics -Text and Exercise Books Vol. 2". This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilm or in any other way, and storage in data banks. Duplication of this publication or parts thereof is permitted only under the provisions of the German Copyright Law of September 9, 1965, in its current version, and permission for use must always be obtained from Springer-Verlag. Violations are liable for prosecution under the German Copyright Law. Springer-Verlag Berlin Heidelberg New York a member of BertelsmannSpringer Science+ Business Media GmbH Springer-Verlag Berlin Heidelberg 1989, 1994 Printed in Germany The use of general descriptive names, registered names, trademarks, etc. in this publication docs not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Typesetting: Data conversion by LE-TEX, Leipzig Cover design: Design Concept, Emil Smejkal, Heidelberg Copy Editor: V. Wicks, Heidelberg Production Editor: P. Treiber, Heidelberg Printed on acid-free paper SPIN /3141/tr I 0

5 Foreword to Earlier Series Editions More than a generation of German-speaking students around the world have worked their way to an understanding and appreciation of the power and beauty of modem theoretical physics - with mathematics, the most fundamental of sciences -using Walter Greiner's textbooks as their guide. The idea of developing a coherent, complete presentation of an entire field of science in a series of closely related textbooks is not a new one. Many older physicists remember with real pleasure their sense of adventure and discovery as they worked their ways through the classic series by Sommerfeld, by Planck and by Landau and Lifshitz. From the students' viewpoint, there are a great many obvious advantages to be gained through use of consistent notation, logical ordering of topics and coherence of presentation: beyond this, the complete coverage of the science provides a unique opportunity for the author to convey his personal enthusiasm and love for his subject. The present five volume set, Theoretical Physics, is in fact only that part of the complete set of textbooks developed by Greiner and his students that presents the quantum theory. I have long urged him to make the remaining volumes on classical mechanics and dynamics, on electromagnetism, on nuclear and particle physics, and on special topics available to an English-speaking audience as well, and we can hope for these companion volumes covering all of theoretical physics some time in the future. What makes Greiner's volumes of particular value to the student and professor alike is their completeness. Greiner avoids the all too common "it follows that... " which conceals several pages of mathematical manipulation and confounds the student. He does not hesitate to include experimental data to illuminate or illustrate a theoretical point and these data, like the theoretical content, have been kept up to date and topical through frequent revision and expansion of the lecture notes upon which these volumes are based. Moreover, Greiner greatly increases the value of his presentation by including something like one hundred completely worked examples in each volume. Nothing is of greater importance to the student than seeing, in detail, how the theoretical concepts and tools under study are applied to actual problems of interest to a working physicist. And, finally, Greiner adds brief biographical sketches to each chapter covering the people responsible for the development of the theoretical ideas and/ or the experimental data presented. It was Auguste Comte ( ) in his Positive Philosophy who noted, "To understand a science it is necessary to know its history". This is all too often forgotten in modern

6 VI Foreword to Earlier Series Editions physics teaching and the bridges that Greiner builds to the pioneering figures of our science upon whose work we build are welcome ones. Greiner's lectures, which underlie these volumes, are internationally noted for their clarity, their completeness and for the effort that he has devoted to making physics an integral whole; his enthusiasm for his science is contagious and shines through almost every page. These volumes represent only a part of a unique and Herculean effort to make all of theoretical physics accessible to the interested student. Beyond that, they are of enormous value to the professional physicist and to all others working with quantum phenomena. Again and again the reader will find that, after dipping into a particular volume to review a specific topic, he will end up browsing, caught up by often fascinating new insights and developments with which he had not previously been familiar. Having used a number of Greiner's volumes in their original German in my teaching and research at Yale, I welcome these new and revised English translations and would recommend them enthusiastically to anyone searching for a coherent overview of physics. Yale University New Haven, CT, USA 1989 D. Allan Bromley Henry Ford II Professor of Physics

7 Preface to the Second Edition We are pleased to note that our text Quantum Mechanics - Symmetries has found many friends among physics students and researchers so that the need for a second edition has arisen. We have taken this opportunity to make several amendments and improvements to the text. We have corrected a number of misprints and minor errors and have added explanatory remarks at various places. In addition to many other smaller changes the sections 8.6, 8.11, and 11.4 and the exercises 3.9, 7.8, and 9.5 have been expanded. Two new exercises on the Wigner-Eckart theorem (Ex. 5.8) and on the completeness relation for the SU(N) generators (Ex. 11.3) have been added. Finally, the Mathematical Supplement on Lie groups (Chap. 12) has been carefully checked and received a new introductory section. We thank several colleagues for helpful comments, especially Prof. L. Wilets (Seattle) for providing a list of errors and misprints. We are greatly indebted to Prof. P.O. Hess (University of Mexico) for making available corrections and valuable material for Chap. 12. We also thank Dr. R. Mattiello who has supervised the preparation of the second edition of the book. Finally we acknowledge the agreeable collaboration with Dr. H.J. Ktilsch and his team at Springer-Verlag, Heidelberg. Frankfurt am Main and Durham, NC, USA July 1994 Walter Greiner Berndt Miiller Preface to the Third Printing We are pleased to note that our Quantum Mechanics: Symmetries has found many friends among physics students and researchers so that the need for a third printing has arisen. We have taken this opportunity to make amendments and improvements to the text. A number of misprints and minor errors have been corrected and explanatory remarks have been given at various places. Several new examples and exercises and, in particular, a short chapter (Chap. 16) on the proof of Racah's theorem have been added.

8 VIII Preface to the Third Printing We thank several colleagues and students for helpful comments, particularly Prof. Dr. Peter Hess (Instituto de Ciencias Nucleares, UNAM, Mexico City) and Dr. Ulrich Eichmann who helped to improve some exercises and examples and to prepare this third printing. Finally we acknowledge the agreeable collaboration with Dr. H.J. KO!sch and his team at Springer-Verlag, Heidelberg. Frankfurt am Main July 2001 Walter Greiner

9 Preface to the First Edition Theoretical physics has become a many-faceted science. For the young student it is difficult enough to cope with the overwhelming amount of new scientific material that has to be learned, let alone obtain an overview of the entire field, which ranges from mechanics through electrodynamics, quantum mechanics, field theory, nuclear and heavy-ion science, statistical mechanics, thermodynamics, and solid-state theory to elementary-particle physics. And this knowledge should be acquired in just 8-10 semesters, during which, in addition, a Diploma or Master's thesis has to be worked on or examinations prepared for. All this can be achieved only if the university teachers help to introduce the student to the new disciplines as early on as possible, in order to create interest and excitement that in turn set free essential, new energy. Naturally, all inessential material must simply be eliminated. At the Johann Wolfgang Goethe University in Frankfurt we therefore confront the student with theoretical physics immediately, in the first semester. Theoretical Mechanics I and II, Electrodynamics, and Quantum Mechanics I - An Introduction are the basic courses during the first two years. These lectures are supplemented with many mathematical explanations and much support material. After the fourth semester of studies, graduate work begins, and Quantum Mechanics II - Symmetries, Statistical Mechanics and Thermodynamics, Relativistic Quantum Mechanics, Quantum Electrodynamics, the Gauge Theory of Weak Interactions, and Quantum Chromodynamics are obligatory. Apart from these, a number of supplementary courses on special topics are offered, such as Hydrodynamics, Classical Field Theory, Special and General Relativity, Many Body Theories, Nuclear Models, Models and Elementary Particles, and Solid State Theory. Some of them, for example the two-semester courses Theoretical Nuclear Physics and Theoretical Solid-State Physics, are also obligatory. The form of the lectures that comprise Quantum Mechanics- Symmetries follows that of all the others: together with a broad presentation of the necessary mathematical tools, many examples and exercises are worked through. We try to offer science in a way as interesting as possible. With symmetries in quantum mechanics we are dealing with a particularly beautiful theme. The selected material is perhaps unconventional, but corresponds, in our opinion, to the importance of this field in modem physics. After a short reminder of some symmetries in classical mechanics, the great importance of symmetries in quantum mechanics is outlined. In particular, the consequences of rotational symmetry are described in detail, and we are soon led to the general theory of Lie groups. The isospin group, hypercharge, and

10 X Preface to the First Edition SU(3) symmetry and its application in modem elementary-particle physics are broadly outlined. Essential mathematical theorems are first quoted without proof and heuristically illustrated to show their importance and meaning. The proof can then be found in detailed examples and worked-out exercises. A mathematical supplement on root vectors and classical Lie algebras deepens the material, the Young-tableaux technique is broadly outlined, and, by way of a chapter on group characters and another on charm, we lead up to very modem questions of physics. Chapters on special discrete symmetries and dynamical symmetries round off these lectures. These are all themes which fascinate young physicists, because they show them that as early as the fifth semester they can properly address and discuss questions of frontier research. Many students and collaborators have helped during the years to work out examples and exercises. For this first English edition we enjoyed the help of Maria Berenguer, Snjezana Butorac, Christian Derreth, Dr. Klaus Geiger, Dr. Matthias Grabiak, Carsten Greiner, Christoph Hartnack, Dr. Richard Herrmann, Raffaele Mattiello, Dieter Neubauer, Jochen Rau, Wolfgang Renner, Dirk Rischke, Thomas SchOnfeld, and Dr. Stefan Schramm. Miss. Astrid Steidi drew the graphs and prepared the figures. To all of them we express our sincere thanks. We are also grateful to Dr. K. Langanke and Mr. R. Konning of the Physics Department of the University in Munster for their valuable comments on the German edition. We would especially like to thank Mr. Bela Waldhauser, Dipl.-Phys., for his overall assistance. His organizational talent and his advice in technical matters are very much appreciated. Finally, we wish to thank Springer-Verlag; in particular, Dr. H.-U. Daniel, for his encouragement and patience, and Mr. Michael Edmeades, for expertly copyediting the English edition. Frankfurt am Main July 1989 Walter Greiner Berndt Muller

11 Contents 1. Symmetries in Quantum Mechanics Symmetries in Classical Physics Spatial Translations in Quantum Mechanics The Unitary Translation Operator The Equation of Motion for States Shifted in Space Symmetry and Degeneracy of States Time Displacements in Quantum Mechanics Mathematical Supplement: Definition of a Group Mathematical Supplement: Rotations and their Group Theoretical Properties An Isomorphism of the Rotation Group Infinitesimal and Finite Rotations Isotropy of Space The Rotation Operator for Many-Particle States Biographical Notes Angular Momentum Algebra Representation of Angular Momentum Operators: Generators of S0(3) Irreducible Representations of the Rotation Group Matrix Representations of Angular Momentum Operators Addition of Two Angular Momenta Evaluation of Clebsch-Gordan Coefficients Recursion Relations for Clebsch-Gordan Coefficients Explicit Calculation of Clebsch-Gordan Coefficients Biographical Notes Mathematical Supplement: Fundamental Properties of Lie Groups General Structure of Lie Groups Interpretation of Commutators as Generalized Vector Products, Lie's Theorem, Rank of Lie Group Invariant Subgroups, Simple and Semisimple Lie Groups, Ideals Compact Lie Groups and Lie Algebras Invariant Operators (Casimir Operators) Theorem of Racah Comments on Multiplets Invariance Under a Symmetry Group

12 XII Contents 3.9 Construction of the Invariant Operators Remark on Casimir Operators of Abelian Lie Groups Completeness Relation for Casimir Operators Review of Some Groups and Their Properties The Connection Between Coordinate Transformations and Transformations of Functions Biographical Notes Symmetry Groups and Their Physical Meaning: General Considerations Biographical Notes The Isospin Group (Isobaric Spin) Isospin Operators for a Multi-Nucleon System General Properties of Representations of a Lie Algebra Regular (or Adjoint) Representation of a Lie Algebra Transformation Law for Isospin Vectors Experimental Test of Isospin lnvariance Biographical Notes The Hypercharge Biographical Notes The SU(3) Symmetry The Groups U(n) and SU(n) The Generators ofu(n) and SU(n) The Generators of SU(3) The Lie Algebra of SU(3) The Subalgebras of the SU (3) Lie Algebra and the Shift Operators Coupling oft, U and V Multiplets Quantitative Analysis of Our Reasoning Further Remarks About the Geometric Form of an SU(3) Multiplet The Number of States on Mesh Points on Inner Shells Quarks and SU (3) Searching for Quarks The Transformation Properties of Quark States Construction of all SU(3) Multiplets from the Elementary Representations [3] and [3] Construction of the Representation D(p, q) from Quarks and Antiquarks The Smallest SU (3) Representations Meson Multiplets Rules for the Reduction of Direct Products of SU(3) Multiplets U-Spin Invariance Test of U -Spin Invariance

13 Contents XIII 8.9 The Gell-Mann-Okubo Mass Formula The Clebsch-Gordan Coefficients of the SU(3) Quark Models with Inner Degrees of Freedom The Mass Formula in SU(6) Magnetic Moments in the Quark Model Excited Meson and Baryon States Combinations of More Than Three Quarks Excited States with Orbital Angular Momentum Representations of the Permutation Group and Young Tableaux The Permutation Group and Identical Particles The Standard Form of Young Diagrams Standard Form and Dimension of Irreducible Representations of the Permutation Group SN The Connection Between SU(2) and S The Irreducible Representations of SU(n) Determination of the Dimension The SU(n -1) Subgroups of SU(n) Decomposition of the Tensor Product of Two Multiplets Mathematical Excursion. Group Characters Definition of Group Characters Schur's Lemmas Schur's First Lemma Schur's Second Lemma Orthogonality Relations of Representations and Discrete Groups Equivalence Classes Orthogonality Relations of the Group Characters for Discrete Groups and Other Relations Orthogonality Relations of the Group Characters for the Example of the Group D(3) Reduction of a Representation Criterion for Irreducibility Direct Product of Representations Extension to Continuous, Compact Groups Mathematical Excursion: Group Integration Unitary Groups The Transition from U(N) to SU(N) for the example SU(3) Integration over Unitary Groups Group Characters of Unitary Groups Charm and SU(4) Particles with Charm and the SU(4) The Group Properties of SU(4) Tables of the Structure Constants fijk and the Coefficients d;jk for SU(N) Multiplet Structure of SU(4)

14 XIV Contents 11.5 Advanced Considerations Decay of Mesons with Hidden Charm Decay of Mesons with Open Charm Baryon Multiplets The Potential Model of Charmonium The SU(4) [SU(8)] Mass Formula The I Resonances Mathematical Supplement Introduction Root Vectors and Classical Lie Algebras Scalar Products of Eigenvalues Cartan-Weyl Normalization Graphical Representation of the Root Vectors Lie Algebra of Rank l Lie Algebras of Rank Lie Algebras of Rimk l > The Exceptional Lie Algebras Simple Roots and Dynkin Diagrams Dynkin' s Prescription The Cartan Matrix Determination of all Roots from the Simple Roots Two Simple Lie Algebras Representations of the Classical Lie Algebras Special Discrete Symmetries Space Reflection (Parity Transformation) Reflected States and Operators Time Reversal Antiunitary Operators Many-Particle Systems Real Eigenfunctions Dynamical Symmetries The Hydrogen Atom The Group S0(4) The Energy Levels of the Hydrogen Atom The Classical Isotropic Oscillator The Quantum Mechanical Isotropic Oscillator Mathematical Excursion: Non-compact Lie Groups Definition and Examples of Non-compact Lie Groups The Lie Group S0(2, 1) Application to Scattering Problems Proof of Racah's Theorem Subject Index

15 Contents of Examples and Exercises Angular Momenta in Different Reference Frames Conserved Quantities of Specified Fields Noether's Theorem (for Improved Insight) Time-Invariant Equations of Motion: The Lagrange Function and Conserved Quantities Conditions for Translational, Rotational and Galilean Invariance. 12 Conservation Laws in Homogeneous Electromagnetic Fields Matrix Elements of Spatially Displaced States The Relation (ifj/n)n B(x) and Transformation Operators Translation of an Operator A(x) Generators for Translations in a Homogeneous Field Transformation of Vector Fields Under Rotations Transformation of Two-Component Spinors Under Rotations Measuring the Direction of Electron Spins Special Representation of the Spin-1 Operators Calculation of the Clebsch-Gordan Coefficients for Spin-Orbit Coupling Lie Algebra of S0(3) Calculation with Complex n x n Matrices Proof of a Commutation Relation Generators and Structure Constants of Proper Lorentz Transformations Algebra of Pv and fv Translation-Rotation Group Simple_ and Semisimf.le Li~ Groups ReductiOn of exp{- 211/m u} Cartan's Criterion for Semisimplicity Semisimplicity of S0(3) An Invariant Subspace to the Rotation Group Reduction of an Invariant Subspace Casimir Operator of the Rotation Group Some Groups with Rank 1 or Construction of the Hamiltonian from the Casimir Operators Transformations with r Parameters of ann-dimensional Space Generators and Infinitesimal Operators of SO(n) Matrix Representation for the Lie Algebra of Spin l

16 XVI Contents of Examples and Exercises 3.19 Translations in One-dimensional Space; the Euclidean Group E(3) in Three Dimensions Homomorphism and Isomorphism of Groups and Algebra Transformations of the Structure Constants Conservation Laws with Rotation Symmetry and Charge Independent Forces Energy Degeneracy for Various Symmetries Degeneracy and Parity of More Symmetries Addition Law for Infinitesimal SU(2) Transformations The Deuteron The Charge Independence of Nuclear Forces The Pion Triplet Normalization of the Group Generators The G Parity Representation of a Lie Algebra, Regular Representation of the Algebra of Orbital Angular Momentum Operators The Wigner-Eckart Theorem Pion Production in Proton-Deuteron Scattering Production of Neutral Pions in Deuteron-Deuteron Scattering Pion-Nucleon Scattering The Decay of the Neutral Rho Meson Hypercharge of Nuclei The Hypercharge of the~ Resonances The Baryons Antibaryons Isospin and Hypercharge of Baryon Resonances The Lie Algebra of SU(2) Linear Independence of the Generators 5..; I 7.3 Symmetry of the Coefficients d;jk Antisymmetry of the Structure Constants fijk Calculation of some dijk Coefficients and Structure Constants Relations Between the Structure Constants and the Coefficients d;jk Casimir Operators of SU(3) Useful Relations for SU(3) Casimir Operators The Increase of the Multiplicity of States on the Inner Shells of SU(3) Multiplets Particle States at the Centre of the Baryon Octet Calculation of the Dimension of the Representation D(p, q) The Casimir Operator C 1 = L; f? in terms of p and q The Generators of SU(3) in the Representation [3] Transformation Properties of the States of the Anti triplet [3] Non-equivalence of the Two Fundamental Representations of SU(3) The Weight of a State

17 Contents of Examples and Exercises XVII 8.5 The Maximum Weight of the Quark Triplet [3] and Antiquark Triplet (3] The Pseudoscalar Mesons Example (for Deeper Insight): The K0 and K0 Mesons and Their Decays The Scalar Mesons The Vector Mesons The Tensor Mesons Other Resonances Reduction of SU(2) Multiplets Construction of the Neutron Wave Function Construction of the Wave Functions of the Baryon Decuplet Construction of the Spin-Flavour Wave Functions of the Baryon Octet Basis Functions of S Irreducible Representations of S Multiplets of a System of Three Spin-! Particles Multiplets of a Two-Particle System in the Group SU(3) Multiplets of the SU(3) Constructed from Three Particles Dimension Formula for the SU(3) Decomposition of a Tensor Product Representations of the SU(2) and Spin Triality and Quark Confinement The Group D The Rotation Group 0(3) I 0.3 Application of Group Characters: Partition Function for the Colour Singlet Quark-Gluon Plasma with Exact SU(3) Symmetry Proof of the Recursion Formula for the Dimensions of the SU(n) Representations Anticommutators of the Generators of SU (N) Trace of a Generator Product in the SU (N) The Completeness Relation for Fa Eigenvalue of the Casimir Operator C 1 of a Fundamental Representation of the SU(N) SU(3) Content of the SU(4) Meson Multiplet Decomposition of the Product [4] 0 [4] 0 [4] SU(3) Content of the SU(4) Baryon Multiplet Decomposition and Dimension of Higher SU ( 4) Multiplets Mathematical Supplement. Airy Functions Weight Operators of the SU(4) Algebra Proof of a Relation for the Structure Constants Cikl Dynkin Diagrams for B The Cartan Matrices for SU(3), SU(4) and G

18 XVIII Contents of Examples and Exercises 12.5 Determination of the Roots ofg2 Using the Corresponding Simple Roots Analysis of SU(3) Effect of an Antiunitary Operator on Matrix Elements of Wavefunctions Commutation Relations Between{; and S Energy and Radial Angular Momentum of the Hydrogen Atom The Runge-Lenz Vector Properties of the Runge-Lenz Vector M The Commutator Between M and ii The Scalar Product L M Determination of Ml Proof of the Commutation Relation for [ M;, L j l Proof of the Commutation Relation for [M;, Hj l Representation of SU(2) Matrices Representation of SU(l, 1) Matrices Non-compactness of the Lorentz Group Generators of SO(p, q) Casimir Operator of S0(2, 1) Coordinate Representation of S0(2, 1) Operators The Eigenvalue of the Second-Order Casimir Operator of SU(3). 518