Quantitative analysis of GITT measurements of Li-S batteries
|
|
- Augusta Price
- 5 years ago
- Views:
Transcription
1 Quantitative analysis of GITT measurements of Li-S batteries James Dibden, Nina Meddings, Nuria Garcia-Araez, and John R. Owen Acknowledgements to Oxis and EPSRC for EP/M5066X/1 - CASE studentship, EP/P019099/1- MESS project co-funded by Innovate UK. 1
2 -voltage -current The Galvanostatic Intermittent Titration Technique - as applied to Li-ION Li e Li Host Constant current pulse + relaxation step time Li + c Li e - Cathode. thickness L depth 0 l L E PULSE IR u constant potential after relaxation IR u time E RELAX
3 - voltage - current The Galvanostatic Intermittent Titration Technique - as applied to Li-S Constant current pulse + relaxation step time Li + c(lis n ) S e - S n - S ne S Li + depth n 0 L O H A R A Li E PULSE IR u constant potential after relaxation IR u time E RELAX 3
4 GITT in Li-ion battery materials 4 Weppner and Huggins. J. Electrochem. Soc, 1977, 14, Chemical diffusion coefficient Equilibrium voltage profile 4 PULSE RELAX E E L D =
5 Thermodynamically enhanced diffusion Enhancement factor: dln a y F Li de d ln c RT d Li Enhancement of the chemical diffusion coefficient Weppner and Huggins. J. Electrochem. Soc, 1977, 14,
6 GITT in Li-S cells complications Redox reactions in the liquid state Multiple polysulfide species (not fully identified) Polysulfide shuttle can cause self discharge GITT in Li-S cells our approach Polysulfide shuttling avoided using a lithium selective membrane (Ohara) Equations derived for (complicated) solution redox reactions 6
7 Plan Validate our approach with a model redox system Apply it to cells containing dissolved sulfur Apply it to cells containing dissolved polysulfides Apply it to Li-S cells Aim Use GITT in Li-S cells to obtain quantitative information of: Mass transport rate (diffusion coefficient) Reaction rate (relaxation rate) Composition-dependent activity coefficients 7
8 Validation Chemical diffusion coefficient determined by: Cyclic voltammetry Square-wave voltammetry Chronopotentiometry GITT Model redox system: EtV + = 8
9 Cell design 9
10 Results: Summary 0.01 mm EtV + in 0.1 M LiTFSI in Pyr 14 TFSI Glassy carbon working electrode Method D / cm s -1 Cyclic voltammetry 6.3 x 10-8 Chronopotentiometry 7.7 x 10-8 Square wave voltammetry 7.5 x
11 Cyclic voltammetry mm EtV + in 0.1 M LiTFSI in Pyr 14 TFSI System is electrochemically reversible (~ 63 mv) D EtV+ = 6.3 x 10-8 cm s -1 11
12 Chronopotentiometry mm EtV + in 0.1 M LiTFSI in Pyr 14 TFSI Transition time: D EtV+ = 7.7 x 10-8 cm s -1 1
13 Square wave voltammetry 0.01 mm EtV + in 0.1 M LiTFSI in Pyr 14 TFSI mm D EtV+ = 7.5 x 10-8 cm s -1 13
14 GITT mm EtV + in 0.1 M LiTFSI in Pyr 14 TFSI D = 4 L E E RELAX PULSE c surface 30% (0.6 mm) c 0.00mM E bulk RELAX 0 mv Next: repeat the experiments with an smaller and thinner separator to decrease the electrolyte volume and thus increase c bulk. 14
15 Cell design 15
16 Results: Summary 5 mm EtV + in 1 M LiTFSI in DOL Method D / cm s -1 Cyclic voltammetry. x 10-6 Chronopotentiometry.4 x 10-6 GITT x
17 Cyclic voltammetry 5 mm EtV + in 1 M LiTFSI in DOL System is electrochemically reversible (~ 60 mv) D EtV+ =. x 10-6 cm s -1 17
18 Chronopotentiometry 5 mm EtV + in 1 M LiTFSI in DOL Glassy carbon C-coated Al foil Transition time: D EtV+ =.4 x 10-6 cm s -1 18
19 GITT (1) 19 5 mm EtV + in 1 M LiTFSI in DOL 4 PULSE RELAX E E L D = Unrealistic variation of the chemical diffusion coefficient
20 GITT () 5 mm EtV + in 1 M LiTFSI in DOL EtV + + e - EtV + D = 4 L E E RELAX PULSE E E 0 RT F c ln EtV c EtV Equilibrium voltage profile in agreement with Nernst equation Evolution of voltage change induced by pulses is unexpected 0
21 GITT analysis Fick s first law: I c nfd 0 A xx0 EtV e EtV Evolution of surface concentrations with time: I t c c c AnF D x0 initial 0 initial EtV EtV EtV c I t c x AnF D x0 0 EtV 0 Assumption: E PULSE is proportional to c(x=0) E kc( x 0) PULSE E kc and the proportionality constant is RELAX bulk Since c bulk I / 0 nf AL It is concluded that: L t EPULSE E D RELAX And for t=: D = 4 L E E RELAX PULSE 1
22 GITT analysis Fick s first law: I c nfd 0 A xx0 EtV e EtV Evolution of surface concentrations with time: c c I x0 initial 0 EtV EtV AnF t D c I x0 0 EtV AnF t D Assumption: E PULSE is calculated with the Nernst equation E PULSE E 0 RT nf ln c c x0 EtV x0 EtV and E 0 is obtained from the equilibrium voltage profile (.44V) taking into account: c bulk I / 0 nf AL
23 GITT (3) 5 mm EtV + in 1 M LiTFSI in DOL Pulse 1 Pulse 5 Pulse 15 The evolution of the voltage change induced by the pulse is in agreement with the Nernst equation 3
24 Conclusions Theoretical framework to analyze GITT results of Li-S cells Validation of the evaluation of the diffusion coefficient by: Cyclic voltammetry Square wave voltammetry Chronopotentiometry GITT Next: GITT as diagnostic tool of Li-S cells 4
Protocols for studying intercalation electrodes materials: Part I: Galvanostatic cycling with potential limitation (GCPL)
Electrochemistry - Application note n 1 Protocols for studying intercalation electrodes materials: Part I: Galvanostatic cycling with potential limitation (GCPL) Available instruments for the GCPL protocol
More informationSupplemental Information. Lightweight Metallic MgB 2 Mediates. Polysulfide Redox and Promises High- Energy-Density Lithium-Sulfur Batteries
JOUL, Volume 3 Supplemental Information Lightweight Metallic MgB 2 Mediates Polysulfide Redox and Promises High- Energy-Density Lithium-Sulfur Batteries Quan Pang, Chun Yuen Kwok, Dipan Kundu, Xiao Liang,
More informationUnique Behaviour of Nonsolvents for Polysulphides in Lithium-Sulphur Batteries.
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 214 Supplementary Information Unique Behaviour of Nonsolvents for Polysulphides
More informationProtocols for studying intercalation electrodes materials: Part II: Potentiodynamic Cycling with Galvanostatic Acceleration (PCGA)
Electrochemistry - Application note n 2 Protocols for studying intercalation electrodes materials: Part II: Potentiodynamic Cycling with Galvanostatic Acceleration (PCGA) Available instruments for the
More informationEnhancing potassium-ion battery performance by defect and. interlayer engineering
Electronic Supplementary Material (ESI) for Nanoscale Horizons. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information for Enhancing potassium-ion battery performance
More informationCritical Role of Redox Mediator in Suppressing Charging Instabilities of Lithium-Oxygen Batteries
Supporting information Critical Role of Redox Mediator in Suppressing Charging Instabilities of Lithium-Oxygen Batteries Zhuojian Liang and Yi-Chun Lu * Electrochemical Energy and Interfaces Laboratory,
More informationi i ne. (1) i The potential difference, which is always defined to be the potential of the electrode minus the potential of the electrolyte, is ln( a
We re going to calculate the open circuit voltage of two types of electrochemical system: polymer electrolyte membrane (PEM) fuel cells and lead-acid batteries. To do this, we re going to make use of two
More informationElectrochemical Cell - Basics
Electrochemical Cell - Basics The electrochemical cell e - (a) Load (b) Load e - M + M + Negative electrode Positive electrode Negative electrode Positive electrode Cathode Anode Anode Cathode Anode Anode
More informationComponents of output signal in Chronoamperometry
Chronoamperometry Stationary electrode Unstirred = mass transport by diffusion Constant potential Measure current vs time Theory assume Ox + n e - Red - both Ox and Red are soluble - reversible reaction
More informationSupporting Information. Electrocatalytic polysulfide-traps for controlling redox shuttle process of Li-S battery
Supporting Information Electrocatalytic polysulfide-traps for controlling redox shuttle process of Li-S battery Hesham Al Salem, Ganguli Babu, Chitturi V. Rao and Leela Mohana Reddy Arava * Department
More informationBasic Concepts of Electrochemistry
ELECTROCHEMISTRY Electricity-driven Chemistry or Chemistry-driven Electricity Electricity: Chemistry (redox): charge flow (electrons, holes, ions) reduction = electron uptake oxidation = electron loss
More informationFixed surface concentration. t 1 < t 2 < t 3 C O. t 1 t 2 t 3. Concentration. Distance
Fixed surface concentration O * oncentration t 1 < t 2 < t 3 t 1 t 2 t 3 Distance Fixed surface concentration onsider the t 1 < t 2 < t 3 * O concentration profile t 3 when t 1 t the sample 2 t 3 length
More informationLithium-ion Batteries Based on Vertically-Aligned Carbon Nanotubes and Ionic Liquid
Electronic Supplementary Information Lithium-ion Batteries Based on Vertically-Aligned Carbon Nanotubes and Ionic Liquid Electrolytes Wen Lu, * Adam Goering, Liangti Qu, and Liming Dai * 1. Synthesis of
More informationCHM 213 (INORGANIC CHEMISTRY): Applications of Standard Reduction Potentials. Compiled by. Dr. A.O. Oladebeye
CHM 213 (INORGANIC CHEMISTRY): Applications of Standard Reduction Potentials Compiled by Dr. A.O. Oladebeye Department of Chemistry University of Medical Sciences, Ondo, Nigeria Electrochemical Cell Electrochemical
More informationCapacity fade studies of Lithium Ion cells
Capacity fade studies of Lithium Ion cells by Branko N. Popov, P.Ramadass, Bala S. Haran, Ralph E. White Center for Electrochemical Engineering, Department of Chemical Engineering, University of South
More informationModeling the next battery generation: Lithium-sulfur and lithium-air cells
Modeling the next battery generation: Lithium-sulfur and lithium-air cells D. N. Fronczek, T. Danner, B. Horstmann, Wolfgang G. Bessler German Aerospace Center (DLR) University Stuttgart (ITW) Helmholtz
More informationThermodynamic study of WO 3 and WO 3 :Li + thin films
Materials Science and Engineering B 138 (2007) 123 127 Thermodynamic study of WO 3 and WO 3 :Li + thin films César O. Avellaneda Laboratório Interdisciplinar de Eletroquímica e Cerâmica-LIEC, Departamento
More informationEMA4303/5305 Electrochemical Engineering Lecture 03 Electrochemical Kinetics
EMA4303/5305 Electrochemical Engineering Lecture 03 Electrochemical Kinetics Dr. Junheng Xing, Prof. Zhe Cheng Mechanical & Materials Engineering Florida International University 2 Electrochemical Kinetics
More informationCovalent-Organic Frameworks: Potential Host Materials for Sulfur Impregnation in Lithium-Sulfur Batteries
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 Covalent-Organic Frameworks: Potential Host Materials for Sulfur Impregnation
More informationOptimization of MnO2 Electrodeposits using Graphenated Carbon Nanotube Electrodes for Supercapacitors
Optimization of MnO2 Electrodeposits using Graphenated Carbon Nanotube Electrodes for Supercapacitors Waleed Nusrat, 100425398 PHY 3090U Material Science Thursday April 9 th 2015 Researchers optimize the
More informationElectrochemical behavior of graphite anode at elevated temperatures in organic carbonate solutions
Journal of Power Sources 119 121 (2003) 538 542 Electrochemical behavior of graphite anode at elevated temperatures in organic carbonate solutions M.D. Levi *, C. Wang, J.S. Gnanaraj, D. Aurbach Department
More informationVoltammetry. Voltammetry and Polarograph. Chapter 23. Polarographic curves -- Voltammograms
Chapter 23 Voltammetry Voltammetry and Polarograph Electrochemistry techniques based on current (i) measurement as function of voltage (E appl ) Voltammetry Usually when the working electrode is solid,
More informationRedox Titration. Properties of Umass Boston
Redox Titration Redox Titration Ce 4+ + Fe 2+ Ce 3+ + Fe 3+ Redox titration is based on the redox reaction (oxidation-reduction) between analyte and titrant. Position of the end point Determine the end
More informationSUPPLEMENTARY INFORMATION. Lamuel David, Romil Bhandavat and Gurpreet Singh*
SUPPLEMENTARY INFORMATION MoS 2 /graphene Composite Paper For Sodium-Ion Battery Electrodes Lamuel David, Romil Bhandavat and Gurpreet Singh* Mechanical and Nuclear Engineering Department, Kansas State
More informationSupplementary Material. Improving cycling performance of LiMn 2 O 4 battery by. adding an ester functionalized ionic liquid to electrolyte
10.1071/CH15154_AC CSIRO 2015 Australian Journal of Chemistry 2015, 68 (12), 1911-1917 Supplementary Material Improving cycling performance of LiMn 2 O 4 battery by adding an ester functionalized ionic
More informationHigh-Energy Secondary Metal-Sulfur Batteries Cathode and Anode Solutions
High-Energy Secondary Metal-Sulfur Batteries Cathode and Anode Solutions Lynden A. Archer (laa25@cornell.edu) October 20, 2016 Acknowledgements: NSF-DMR1609125, ARPAE-DE-AR0000750 & DOE-BESC00016082 Pros
More informationElectrochemical System
Electrochemical System Topic Outcomes Week Topic Topic Outcomes 8-10 Electrochemical systems It is expected that students are able to: Electrochemical system and its thermodynamics Chemical reactions in
More informationElectrochemistry objectives
Electrochemistry objectives 1) Understand how a voltaic and electrolytic cell work 2) Be able to tell which substance is being oxidized and reduced and where it is occuring the anode or cathode 3) Students
More informationElectronic Supplementary Information. Polysulfide Speciation and Electrolyte Interactions in Lithium-Sulfur Batteries with In Situ
Electronic Supplementary Information Polysulfide Speciation and Electrolyte Interactions in Lithium-Sulfur Batteries with In Situ Infrared Spectroelectrochemistry Caitlin Dillard, Arvinder Singh and Vibha
More informationSulfur-Infiltrated Porous Carbon Microspheres with Controllable. Multi-Modal Pore Size Distribution for High Energy Lithium-
Electronic Supplementary Information Sulfur-Infiltrated Porous Carbon Microspheres with Controllable Multi-Modal Pore Size Distribution for High Energy Lithium- Sulfur Batteries Cunyu Zhao, a Lianjun Liu,
More informationPlease do not adjust margins. Electronic supplementary information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry Please do 2017 not adjust margins Journal of Materials Chemistry A Electronic
More informationSupporting Information for Atomic layer deposited TiO 2 on nitrogen-doped graphene/sulfur electrode for high performance lithiumsulfur
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2016 Supporting Information for Atomic layer deposited TiO 2 on nitrogen-doped
More informationLecture 12: Electroanalytical Chemistry (I)
Lecture 12: Electroanalytical Chemistry (I) 1 Electrochemistry Electrochemical processes are oxidation-reduction reactions in which: Chemical energy of a spontaneous reaction is converted to electricity
More informationElectronic Supplementary Information. Concentrated Electrolytes Stabilize Bismuth-Potassium Batteries
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information Concentrated Electrolytes Stabilize Bismuth-Potassium
More informationn. log a ox a red
Amperometry &Voltammetry Non-equilibrium electrochemistry! Based on Electrolytic Cells---apply external voltage to pair of electrodes to force rxn to occur--get current flow---current α [conc] o E elect
More informationElectrochemical Cells at Non-Standard Conditions
Electrochemical Cells at Non-Standard Conditions Oxidation-reduction reactions in the real world rarely occur under standard conditions. Even if the cell started out with all dissolved species at 1M concentration,
More informationPowering Lithium Sulfur Battery Performance by Propelling. Polysulfide Redox at Sulfiphilic Hosts
Supporting Information Powering Lithium Sulfur Battery Performance by Propelling Polysulfide Redox at Sulfiphilic Hosts Zhe Yuan,, Hong-Jie Peng,, Ting-Zheng Hou,, Jia-Qi Huang, Cheng-Meng Chen, Dai-Wei
More informationLecture Presentation. Chapter 20. Electrochemistry. James F. Kirby Quinnipiac University Hamden, CT Pearson Education, Inc.
Lecture Presentation Chapter 20 James F. Kirby Quinnipiac University Hamden, CT is the study of the relationships between electricity and chemical reactions. It includes the study of both spontaneous and
More informationLecture Presentation. Chapter 20. Electrochemistry. James F. Kirby Quinnipiac University Hamden, CT Pearson Education
Lecture Presentation Chapter 20 James F. Kirby Quinnipiac University Hamden, CT is the study of the relationships between electricity and chemical reactions. It includes the study of both spontaneous and
More informationChapter 7 Electrochemistry
Chapter 7 Electrochemistry Outside class reading Levine: pp. 417 14.4 Galvanic cells: pp. 423 14.5 types of reversible electrodes 7.6.1 Basic concepts of electrochemical apparatus (1) Electrochemical apparatus
More informationBasic Concepts in Electrochemistry
Basic Concepts in Electrochemistry 1 Electrochemical Cell Electrons Current + - Voltage Source ANODE Current CATHODE 2 Fuel Cell Electrons (2 e) Current - + Electrical Load ANODE Current CATHODE H 2 2H
More informationElectrochemistry. Goal: Understand basic electrochemical reactions. Half Cell Reactions Nernst Equation Pourbaix Diagrams.
Electrochemistry Goal: Understand basic electrochemical reactions Concepts: Electrochemical Cell Half Cell Reactions Nernst Equation Pourbaix Diagrams Homework: Applications Battery potential calculation
More informationElectrochemistry. The study of the interchange of chemical and electrical energy.
Electrochemistry The study of the interchange of chemical and electrical energy. Oxidation-reduction (redox) reaction: involves a transfer of electrons from the reducing agent to the oxidizing agent. oxidation:
More informationAmperometric biosensors
Electrochemical biosensors II: Amperometric biosensors Lecture 2 Amperometric Sensors: Problem formulation amperometric techniques have some selectivity as every RedOx reaction has it s own characteristic
More informationChapter - 8. Summary and Conclusion
Chapter - 8 Summary and Conclusion The present research explains the synthesis process of two transition metal oxide semiconductors SnO 2 and V 2 O 5 thin films with different morphologies and studies
More informationSpecial Lecture Series Biosensors and Instrumentation
!1 Special Lecture Series Biosensors and Instrumentation Lecture 2: Introduction to Electrochemistry Electrochemistry Basics Electrochemistry is the study of electron transfer processes that normally occur
More information) and is known as the halfwave potential (E1/2); it is an intrinsic property of an ion at a particular temperature and can be used to identify the ion
Lesson 1 1) Electrochemical Cells There are two types of electrochemical cell: - Galvanic cells convert chemical energy into electrical energy; a spontaneous (ΔG = -ve) reaction is allowed to take place,
More informationFunctionalization of reduced graphene oxides by redox-active ionic liquids for energy storage
Supplementary Material (ESI) for Chemical Communications Functionalization of reduced graphene oxides by redox-active ionic liquids for energy storage Sung Dae Cho, a Jin Kyu Im, b Han-Ki Kim, c Hoon Sik
More informationOxidation-reduction (redox) reactions
Oxidation-reduction (redox) reactions Reactions in which there are changes in oxidation state (oxidation number) between reactants and products 2 MnO 4- + 10 Br - + 16 H + 2 Mn 2+ + 5 Br 2 + 8 H 2 O One
More informationCHEM J-12 June 2013
CHEM1101 2013-J-12 June 2013 In concentration cells no net chemical conversion occurs, however a measurable voltage is present between the two half-cells. Explain how the voltage is produced. 2 In concentration
More informationGermanium Anode with Excellent Lithium Storage Performance in a Ge/Lithium-
Supporting Information Germanium Anode with Excellent Lithium Storage Performance in a Ge/Lithium- Cobalt-Oxide Lithium-Ion Battery Xiuwan Li, Zhibo Yang, Yujun Fu, Li Qiao, Dan Li, Hongwei Yue, and Deyan
More informationChem 4501 Introduction to Thermodynamics, 3 Credits Kinetics, and Statistical Mechanics. Fall Semester Homework Problem Set Number 12 Solutions
Chem 4501 Introduction to Thermodynamics, 3 Credits Kinetics, and Statistical Mechanics Fall Semester 017 Homework Problem Set Number 1 Solutions 1. (Based on McQuarrie and Simon, 13-1.) Write balanced
More informationIn all electrochemical methods, the rate of oxidation & reduction depend on: 1) rate & means by which soluble species reach electrode surface (mass
Voltammetry Methods based on an electrolytic cell Apply potential or current to electrochemical cell & concentrations change at electrode surface due to oxidation & reduction reactions Can have 2 or 3
More informationQuinone electrochemistry in acidic and alkaline solutions & its application in large scale energy storage
Quinone electrochemistry in acidic and alkaline solutions & its application in large scale energy storage Michael R. Gerhardt 1, Kaixiang Lin 2, Qing Chen 1, Michael P. Marshak 1,3, Liuchuan Tong 2, Roy
More informationA Highly Efficient Double-Hierarchical Sulfur Host for Advanced Lithium-Sulfur Batteries
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2017 Supporting Information A Highly Efficient Double-Hierarchical Sulfur Host for Advanced
More informationOverview of electrochemistry
Overview of electrochemistry 1 Homogeneous Heterogeneous Equilibrium electrochemistry (no current flows) Thermodynamics of electrolyte solutions: electrolytic dissociation thermodynamics and activities
More information17.1 Redox Chemistry Revisited
Chapter Outline 17.1 Redox Chemistry Revisited 17.2 Electrochemical Cells 17.3 Standard Potentials 17.4 Chemical Energy and Electrical Work 17.5 A Reference Point: The Standard Hydrogen Electrode 17.6
More informationELECTROCHEMICAL CELLS
ELECTROCHEMICAL CELLS Electrochemistry 1. Redox reactions involve the transfer of electrons from one reactant to another 2. Electric current is a flow of electrons in a circuit Many reduction-oxidation
More informationEnhanced Lithium-Ion Mobility Induced by the Local Piezoelectric
Supporting Information to Silicon/Carbon Nanotube/BaTiO 3 Nanocomposite Anode: Evidence for Enhanced Lithium-Ion Mobility Induced by the Local Piezoelectric Potential Byoung-Sun Lee a, Jihyun Yoon b, Changhoon
More informationMikaël Cugnet, Issam Baghdadi, and Marion Perrin OCTOBER 10, Excerpt from the Proceedings of the 2012 COMSOL Conference in Milan
Mikaël Cugnet, Issam Baghdadi, and Marion Perrin OCTOBER 0, 202 Comsol Conference Europe 202, Milan, CEA Italy 0 AVRIL 202 PAGE Excerpt from the Proceedings of the 202 COMSOL Conference in Milan SUMMARY
More informationHalf-Cell, Steady-State Flow-Battery Experiments. Robert M. Darling and Mike L. Perry
Half-Cell, Steady-State Flow-Battery Experiments Robert M. Darling and Mike L. Perry United Technologies Research Center, East Hartford, Connecticut, 06108, USA An experimental approach designed to separately
More informationNanostructured Li 2 MnO 3 : a Disordered Rock Salt type structure for High Energy Density Li ion batteries
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 217 Supporting Information Nanostructured Li 2 : a Disordered Rock Salt type
More informationOxidation number. The charge the atom would have in a molecule (or an ionic compound) if electrons were completely transferred.
Oxidation number The charge the atom would have in a molecule (or an ionic compound) if electrons were completely transferred. 1. Free elements (uncombined state) have an oxidation number of zero. Na,
More informationChapter 20 Electrochemistry
Chapter 20 Electrochemistry Learning goals and key skills: Identify oxidation, reduction, oxidizing agent, and reducing agent in a chemical equation Complete and balance redox equations using the method
More informationMembrane Electrodes. Several types
Membrane Electrodes Electrical connection Several types - Glass membrane electrode - Liquid membrane electrode - Solid State membrane electrode - Permeable membrane electrode seal 0.1 M HCl Filling solution
More informationChemistry 2000 (Spring 2014) Problem Set #7: Redox Reactions and Electrochemistry Solutions
Chemistry 2000 (Spring 2014) Problem Set #7: Redox Reactions and Electrochemistry Solutions Answers to Questions in Silberberg (only those w/out answers at the back of the book) 192 An electrochemical
More informationMathematical Modeling All Solid State Batteries
Katharina Becker-Steinberger, Stefan Funken, Manuel Landsdorfer, Karsten Urban Institute of Numerical Mathematics Konstanz, 04.03.2010 Mathematical Modeling All Solid State Batteries Page 1/31 Mathematical
More informationHelis. High energy lithium sulphur cells and batteries. Dr. Marian Cristian Stan a, Prof. Dr. Martin Winter a,b
Helis High energy lithium sulphur cells and batteries Dr. Marian Cristian Stan a, Prof. Dr. Martin Winter a,b a MEET Battery Research Center, University of Muenster b Helmholtz-Institute Muenster (HI MS),
More informationELECTROCHEMISTRY Chapter 19, 4.9
ELECTROCHEMISTRY Chapter 19, 4.9 Overview of an Electrochemical Process at Constant T and P ΔG = ΔG o + RT ln Q = welec (maximum) Note: I below stands for current measured in amperes = qecell = ItEcell
More informationSupporting Information
Supporting Information Multielectron Cycling of a Low Potential Anolyte in Alkali Metal Electrolytes for Non-Aqueous Redox Flow Batteries Koen H. Hendriks, ab Christo S. Sevov, ab Monique E. Cook, ab and
More informationAP CHEMISTRY NOTES 12-1 ELECTROCHEMISTRY: ELECTROCHEMICAL CELLS
AP CHEMISTRY NOTES 12-1 ELECTROCHEMISTRY: ELECTROCHEMICAL CELLS Review: OXIDATION-REDUCTION REACTIONS the changes that occur when electrons are transferred between reactants (also known as a redox reaction)
More informationSupporting information. Alkali Metal Ion Templated Transition Metal Formate. Framework Materials: Synthesis, Crystal Structures,
Supporting information Alkali Metal Ion Templated Transition Metal Formate Framework Materials: Synthesis, Crystal Structures, Ion Migration and Magnetism Espen Eikeland, 1 Nina Lock, 2 Mette Filsø, 1
More informationContents. Publisher s Foreword. Glossary of Symbols and Abbreviations
Publisher s Foreword Glossary of Symbols and Abbreviations v xiii 1 Equilibrium Electrochemistry and the Nernst Equation 1 1.1 Cell Thermodynamics....................... 1 1.2 The Nernst Equation........................
More informationHg2 2+ (aq) + H2(g) 2 Hg(l) + 2H + (aq)
The potential difference between two electrodes in a cell is called the electromotive force, or The EMF of a voltaic cell is called the The cell voltage of a voltaic cell will be a Note: We are used to
More informationProbing into the Electrical Double Layer Using a Potential Nano-Probe
A3 Foresight Program, 2. 27-3. 1, 26 Probing into the Electrical Double Layer Using a Potential Nano-Probe Heon Kang ( 姜憲 ) Department of Chemistry, Seoul National University, Republic of Korea (E-mail:
More informationIntroduction to Dualfoil 5.0
Introduction to Dualfoil 5.0 Paul Albertus and John Newman August 14, 2007 Contents 1 Introduction 2 Description of what an average user should be able to do 2 Notes on operating dualfoil5.f 3 Input file
More informationELECTROCHEMISTRY Chapter 14
ELECTROCHEMISTRY Chapter 14 Basic Concepts: Overview of Electrochemical Process at Constant T, P (14-1) ΔG = ΔG o + RT ln Q = w elec (maximum) = qe = ItE (exp) (E intensive parameter, q extensive) = nfe
More informationElectrochemical Measurements
1 Electrochemical Measurements 1. Performance metrics vs. performance- and life-limiting mechanisms 2. General approach a. Reference electrodes b. Types of cells c. Inert electrodes 3. AC impedance 1.
More informationCh. 13 Fundamentals of Electrochemistry
Ch. 13 Fundamentals of Electrochemistry 13.1 13-1. Basic Concepts of electrochemistry redox reaction : reactions with electron transfer oxidized : loses electrons reduced : gains electrons Fe 3+ + V 2+
More informationAnalysis of Hydroquinone/Quinone Redox Couple Through the Use of Cyclic Voltammetry
Analysis of Hydroquinone/Quinone Redox Couple Through the Use of Cyclic Voltammetry Adam Woodard and Katrin Henry Ta: Jie Ding Abstract: The hydroquinone/quinone redox couple was studied under various
More informationFUEL CELLS in energy technology (4)
Fuel Cells 1 FUEL CELLS in energy technology (4) Werner Schindler Department of Physics Nonequilibrium Chemical Physics TU Munich summer term 213 Fuel Cells 2 Nernst equation and its application to fuel
More information3. Potentials and thermodynamics
Electrochemical Energy Engineering, 2012 3. Potentials and thermodynamics Learning subject 1. Electrochemical reaction 2. Thermodynamics and potential 3. Nernst equation Learning objective 1. To set up
More informationElectronic Supplementary Information
Electronic Supplementary Information Stable cycling of lithium sulfide cathodes through strong affinity with a bifunctional binder Zhi Wei Seh, Qianfan Zhang, Weiyang Li, Guangyuan Zheng, Hongbin Yao,
More informationElectrogravimetry. All Cu is plated out Nothing else plates out
Electrogravimetry Apply potential to cause a soluble species to reduce or deposit on a solid electrode e.g., reduce Cu 2+ onto Pt cathode Cu 2+ (aq) + 2 e - Cu (metal on Pt) Change in weight of dried cathode
More informationLithium Bis(fluorosulfonyl)imide/Poly(ethylene oxide) Polymer Electrolyte for All Solid-State Li-S Cell
Supporting Information Lithium Bis(fluorosulfonyl)imide/Poly(ethylene oxide) Polymer Electrolyte for All Solid-State Li-S Cell Xabier Judez, Heng Zhang,*, Chunmei Li,*, José A. González-Marcos, Zhibin
More informationFUEL CELLS: INTRODUCTION
FUEL CELLS: INTRODUCTION M. OLIVIER marjorie.olivier@fpms.ac.be 19/5/8 A SIMPLE FUEL CELL Two electrochemical half reactions : H 1 O H + + H + e + + e H O These reactions are spatially separated: Electrons:
More informationSupplemental Information. Crumpled Graphene Balls Stabilized. Dendrite-free Lithium Metal Anodes
JOUL, Volume 2 Supplemental Information Crumpled Graphene Balls Stabilized Dendrite-free Lithium Metal Anodes Shan Liu, Aoxuan Wang, Qianqian Li, Jinsong Wu, Kevin Chiou, Jiaxing Huang, and Jiayan Luo
More informationpossesses negative potential & undergoes oxidation preferably act as ANODE
ELECTROCHEMISTRY Introduction: Electrochemistry is the area of Chemistry dealing with the interconversion of electrical energy and chemical energy. There are many applications of this in every day life.
More informationELEMENTS OF ELEC TROCHEMIS TRY. A. A number of analytical techniques are based upon oxidation-reduction reactions.
Page 1 of 8 Chem 201 Winter 2006 I. Introduction ELEMENTS OF ELEC TROCHEMIS TRY A. A number of analytical techniques are based upon oxidationreduction reactions. B. Examples of these techniques would include:
More informationBattery Design Studio Update
Advanced Thermal Modeling of Batteries Battery Design Studio Update March 20, 2012 13:30 13:55 New Features Covered Today 3D models Voltage dependent diffusion Let s start with brief introduction to Battery
More informationElectrode Potentials and Their Measurement
Electrochemistry Electrode Potentials and Their Measurement Cu(s) + 2Ag + (aq) Cu(s) + Zn 2+ (aq) Cu 2+ (aq) + 2 Ag(s) No reaction Zn(s) + Cu 2+ (aq) Cu(s) + Zn 2+ (aq) In this reaction: Zn (s) g Zn 2+
More informationPolysulfide-Scission Reagents for the Suppression of the Shuttle Effect in Lithium-Sulfur Batteries
Polysulfide-Scission Reagents for the Suppression of the Shuttle Effect in Lithium-Sulfur Batteries Wuxing Hua, Zhi Yang*, Huagui Nie, Zhongyu Li, Jizhang Yang, Zeqing Guo, Chunping Ruan, Xi an Chen and
More informationANALYSIS OF LEAD IN SEAWATER
ANALYSIS OF LEAD IN SEAWATER BY DIFFERENTIAL PULSE POLAROGRAPHY Introduction Electrochemical methods of analysis can be used for the quantitative analysis of any electroactive species any species that
More informationElectron Transfer Reactions
ELECTROCHEMISTRY 1 Electron Transfer Reactions 2 Electron transfer reactions are oxidation- reduction or redox reactions. Results in the generation of an electric current (electricity) or be caused by
More informationPart II: Self Potential Method and Induced Polarization (IP)
Part II: Self Potential Method and Induced Polarization (IP) Self-potential method (passive) Self-potential mechanism Measurement of self potentials and interpretation Induced polarization method (active)
More informationElectrochemical Impedance Spectroscopy of a LiFePO 4 /Li Half-Cell
Electrochemical Impedance Spectroscopy of a ifepo 4 /i Half-Cell Mikael Cugnet*, Issam Baghdadi and Marion Perrin French Institute of Solar Energy (INES), CEA / ITEN *Corresponding author: 50 Avenue du
More informationMitoSeminar II: Some calculations in bioenergetics
MitoSeminar II: Some calculations in bioenergetics MUDr. Jan Pláteník, PhD. Ústav lékařské biochemie 1.LF UK Helpful comments of Prof. MUDr. Jiří Kraml, DrSc., are acknowledged. 1 Respiratory chain and
More informationSolid State electrochemistry
Solid State electrochemistry edited by Peter G. Bruce Department of Chemistry, University of St Andrews, Scotland IH CAMBRIDGE ^pf UNIVERSITY PRESS 1 1.1 1.2 1.3 1.4 1.5 1.6 Preface Introduction P. G.
More informationSupplemental Information. An In Vivo Formed Solid. Electrolyte Surface Layer Enables. Stable Plating of Li Metal
JOUL, Volume 1 Supplemental Information An In Vivo Formed Solid Electrolyte Surface Layer Enables Stable Plating of Li Metal Quan Pang, Xiao Liang, Abhinandan Shyamsunder, and Linda F. Nazar Supplemental
More informationProton-Coupled Electron Transfer Kinetics for the Hydrogen Evolution Reaction of Hangman Porphyrins
Electronic Supplementary Information Proton-Coupled Electron Transfer Kinetics for the Hydrogen Evolution Reaction of Hangman Porphyrins Manolis M. Roubelakis, D. Kwabena Bediako, Dilek K. Dogutan and
More information