Experiment 10 Organic Molecules: Description, Nomenclature and Modeling
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1 Experiment 10 Organic Molecules: Description, Nomenclature and Modeling Objectives The objectives for this lab are: Part I: To learn the structures of and construct models for simple organic molecules, to draw their projection and perspective formulae, and to learn their nomenclature. Part II: To classify, recognize, construct and name models of different types of isomers of organic compounds. Background Almost all compounds that contain carbon are known as organic compounds. Most organic compounds also contain hydrogen. Organic compounds that contain only carbon and hydrogen atoms are classified as hydrocarbons. The four classes of hydrocarbons are alkanes, alkenes, alkynes and aromatic hydrocarbons. Alkanes and alkenes and alkynes are further classified as aliphatic hydrocarbons. Structures and simple physical properties of hydrocarbons will be discussed in Part I. Different arrangements of atoms in a set of molecules that cannot be interconverted by simple rotation around a single bond are called isomers. To convert one isomer to another requires enough energy to break and reform one or more π or σ bonds. Therefore, they are different compounds and exhibit different properties. There are two main classes of isomers called constitutional (structural) isomers and stereoisomers. Structural isomers have the same molecular formula, but the atoms are bonded in a different order, or bonding connectivity. Stereoisomers have the same bonding connectivity, but have a different three dimensional arrangement. Geometric isomers have different orientations of atoms or groups across a double bond or a ring. Enatiomers are mirror images of each other, and therefore are not superimposable on their mirror image Summary of Isomers isomers structural isomers (different connectivity) stereoisomers (same connectivity, different spatial arrangement) geometric isomers enantiomers (cis-trans isomers) (mirror images, not superimposable) Baggett Page 1 of 10 rev.05/09
2 Molecular Models Molecular models will be used to illustrate the three-dimensional structures of simple hydrocarbons and different types of isomers. The model kits contain different colored balls and different size sticks. Three-dimensional models will be constructed from these balls and sticks. Molecular models will be constructed for each molecule. Different colored balls represent different atoms. The usual designation is: Black carbon White hydrogen Red oxygen Green chlorine Orange bromine Purple - iodine Blue nitrogen Yellow sulfur The plastic sticks in the kits represent bonds. There are two different sized sticks. The short, stiff sticks are used to represent single bonds and the long flexible sticks are used for double and triple bonds. In order to make one double bond two flexible sticks are needed to connect the two adjacent atoms and to make a triple bond three flexible sticks are used to connect the two adjacent atoms. Lewis structure and three dimensional perspective diagrams will be drawn. Three dimensional drawings can be either done as ball and stick or projection drawings. Projection drawings require a different drawing technique to identify bond orientation. A solid straight lines ( ) represent bonds lying in the plane of the paper, a wedgeshaped line constructed of hatch marks ( ) represents bonds that project down into the paper, and solid wedge-shaped line ( ) represents bonds that project up out of the paper, toward the viewer. Lewis and 3D diagram of C 4 C Lewis Structure 3D ball and stick projection It is important to be able to visualize these three-dimensional structures in your mind without the aid of molecular models. If you need further practice with these models you can purchase them or you can you be creative and make home made models using materials that are available in your home. Baggett Page 2 of 10 rev.05/09
3 Name: Lab Partner: Date: Lab Section: Pre Lab for Introduction to the Structures and Isomerism of Simple Organic Molecules: Description and Modeling Carbon had five distinct bonding patterns, which are shown in the table below. In preparation for the modeling lab, complete the table. Bonding Pattern of Carbon Shape Around Carbon Bond Angle of Carbon ybridization of Carbon C \ C= / =C= C Baggett Page 3 of 10 rev.05/09
4 Lab Report for Introduction to the Structures and Isomerism of Simple Organic Molecules: Description and Modeling Part I: ydrocarbons Alkanes 1. Construct a model of C 4 name: ybridization: Shape: Bond angle: C bond 2. Construct a model of C 3 -C 3 name: ybridization: Shape: Bond angle: C bond Bond angle: CC bond Baggett Page 4 of 10 rev.05/09
5 Alkenes 3. Construct a model of C 2 =C 2 name: ybridization: Shape: Bond angle: C bond Bond angle: CC bond 4. Construct a model of C 2 =C-C 3 name: ybridization, first C: ybridization, third C: Bond angle: C bond, first C Bond angle: CC bond, first and second C Bond angle: C bond, third C Baggett Page 5 of 10 rev.05/09
6 Alkynes 5. Construct a model of C C name: ybridization: Shape: Bond angle: CC bond 6. Construct a model of C C-C 3 name: Bond angle: CC bond (first C) ybridization: (first C) ybridization: (second C) ybridization: (third C) Shape: first C Shape: second C Shape: third C Baggett Page 6 of 10 rev.05/09
7 Aromatic hydrocarbons 7. Construct a model of C 6 6 name: ybridization: Shape: Bond angle: CC bond Bond angle: CCC bond 8. Construct a model of o-c 6 4 Cl 2 (1,2-dichlorobenzene). Bond angle: CCC bond Bond angle: ClCC bond Baggett Page 7 of 10 rev.05/09
8 Part II: Isomers 9. Construct models for the isomers of o-c 6 4 Cl 2 (1,2-dichlorobenzene). Lewis structures of all isomers of C 6 4 Cl 2 (dichlorobenzene); name each. a. ow many isomers exist? b. Can you convert one into another without breaking any bonds? c. What type isomerism do these represent? 10. Construct models for all the isomers of the alkane C Lewis structures of all isomers of C 4 10 ; name each. a. ow many possible isomers exist? b. What type of isomerism do they represent? Baggett Page 8 of 10 rev.05/09
9 11. Construct models for all the isomers of the alkane C Lewis structures of all isomers of C 5 12 ; name each. a. ow many possible isomers exist? b. What type of isomerism do they represent? 12. Construct models of the isomers of ClC = CCl (1,2-dichloroethene) Lewis structures of both isomers; name each. a. Make two models that have different spatial arrangement of the substitutions (the two Cl atoms) across the double bond. b. What type of isomerism do these represent? Baggett Page 9 of 10 rev.05/09
10 13. Construct models of all the structural isomers of the hydrocarbon C 4 8. Lewis structures of all isomers of C 4 8 ; name each. ow many possible isomers exist? 14. There are geometric isomers for one of the isomers drawn in problem 13. Construct models of the geometric isomers of C 4 8. Lewis structures of both isomers; name each. 15. Construct models of the enantiomers of CBrClI 3D drawings of both enantiomers (make one model then make its mirror image): a. Can the two models be superimposed? b. What type of isomerism do these models represent? Baggett Page 10 of 10 rev.05/09
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Chemistry 110 Bettelheim, Brown, Campbell & Farrell Ninth Edition Introduction to General, Organic and Biochemistry Chapter 12 Alkenes & Alkynes Chapter 12 Alkenes are hydrocarbons which have one or more