izotermalna titracijskamikrokalorimetrija(itc)
|
|
- Erick Thomas
- 5 years ago
- Views:
Transcription
1 P / µw t / min Polielektroliti u otopini i na površini Prema IUPAC-u: Polielektroliti - makromolekule kod koje je prisutan znatan udjel konstitucijskih(gradivnih) jedinica koje sadrže ionske i/ili lako ionizirajuće skupine. suprotno nabijeni polielektroliti u otopini izotermalna titracijska mikrokalorimetrija Na + PSS M w = 7 g mol -1 izotermalna titracijskamikrokalorimetrija(itc) G. E. Boyd, D. P. Wilson, G. S Manning, J. Phys. Chem. 8 (1976) 88 mikrokalorimetrijska titracija vodene otopine Na + PSS vodenom otopinom CsNO 3 G. Vesnaver, Z. Kranjc, C. Pohar, J. Škerjanc, J. Phys. Chem. 91 (1987) 3845 mikrokalorimetrijska titracija vodene otopine Na + PSS - vodenim otopinama različitih soli H / µj 5 Li H / µj 5 Li Na n (M + ) / n m n (M + ) / n m H / µj 5 15 Li H / µj Li Na Na K n (M + ) / n m Rb K n (M + ) / n m 1
2 n (M + ) / n m n(m + ) / n m mikrokalorimetrijska titracija vodene otopine Na + PSS - vodenim otopinama različitih soli H / µj 3 Li a Rb 1-1 Na K potenciometrijska titracija Li Cs - -3 Rb Cs H /mj Na K Rb Cs Me 4N Et 4N hydrh/ kj mol 1 kompleksiranje polielektrolita (polikationa i polianiona) u otopini Nastajanje polielektrolitnih kompleksa elektrostatske interakcije polielektrolitni kompleksi (polyelectrolyte complexes) topljivi kompleksi izdvajanje faze (phase separation) istraživali Voorn, Bungeberg de Jong i Michaels u Colloid Science, H. R. Kruyt, Ed. (Elsevier Publishing Company, Amsterdam, 1949) vol. II, pp Polielektroliti u otopini Nastajanje polielektrolitnih kompleksa uz otpuštanje kationa i aniona koji se homogeno raspoređuju u otopini Miješanje suprotno nabijenih homopolimera, utjecaj količinskog udjela jedne komponente I c topljivi kompleksi topljivi kompleksi izdvajanje faze f + 1 Suvišak pozitivnog naboja - topljivi kompleksi Nastajanje netopljivih agregata količinski udjel PAA Suvišak negativnog naboja - topljivi kompleksi
3 .95.9 M n AMA = g/mol (13 monomera) M n PAA = 11 g/mol (158 monomera) bistra otopina Fizikalne kemije kompleksnih micela (Complex Micelles) miješanje blok-kopolimera različitih naboja polyion complex micelles c(nacl)/mol / l.85 razdvajanje faza A. Harada and K. Kataoka, Science, 83 (1999) 65. A. Harada and K. Kataoka, Macromolecules, 8 (1995) c(polimer)/g/l Diblok-kopolimer Neutralna, hidrofilna kruna P-AMA-(GMA) Poli(di-metil-Amino-etil-MetAkrilat)-(kopoli(Gliceril-MetAkrilat)) Nenabijeni, hidrofilni blok Kationski blok C CH C O n O C CH C O O m CH HC-OH CH HC-OH N H C-OH Različiti omjeri duljine blokova (M w,total = konst.) Neutralna hidrofobna jezgra Anionski homopolimer complex coacervation core micelles ph, ionska jakost, omjer mješanja, duljina blokova, itd... PAA PoliAcrylic Acid CH CH C OH O Različite molekulske mase PMA Poly Methacrylic Acid C CH C O OH Različite molekulske mase Smjesa homopolielektrolita i suprotno nabijenog diblok-kopolimera, utjecaj omjera miješanja 7 6 Utjecaj odnosa duljine blokova diblok-kopolimera Mutna otopina, makroskopsko razdvajanje faza Bistra otopina, stabilne micele Bistra otopina, nema interakcija 5 Size (nm) 4 3 Suvišak pozitivnog naboja, topljivi kompleksi Izoelektrična smjesa Množinski udjel PAA Suvišak negativnog naboja, topljivi kompleksi 1 PAA M w mm NaNO Množinski udjel GMA u diblok-kopolimeru 3
4 36 34 Množinski udjel PAA/AMA,877 5 mm NaNO 3 Mw PAA 1361 P-AMA-GMA 1:3 Janusove micele R (nm) Izoelektrična točka ph iep = 5.8 Scattering Intensity (a.u.) miješanje blok-kopolimera različitih naboja polyion complex micelles amfifilni diblok (triblok) kopolimeri Janusove micele ph ( - ) Janus Janusove micele hidrofobna PS polukruna (hemicorona) hidrofilna PMMA polukruna (hemicorona) rimski bog ulaza i vrata, početka i kraja R. Erhardt et al, Macromolecules, 34 (1) 169. R. Erhardt et al, J. Am. Chem. Soc., 15 (3) 36. Janusove micele cross-linking prekursor: polistiren-blok-polibutadien-blok-poli(metil metakrilat) (SBM) triblok kopolimer sintetiziran sekvencijalnom anionskom polimerizacijom cross-linking metoda - reaktant S Cl 4
5 Janusove micele Janusove micele karakterizacija: Transmission Electron Microscopy (TEM) Multi-Angle Laser Light Scattering Gel Permeation Cromatography (MALLS-GPC) Confocal Fluorescence Correlation Spectroscopy (FCS) na svaku PB jezgru vezano 13 ± 5 lanaca radijus procijenjen na 11,4 ±,8 nm Janusove micele nastajanje supermicela u otopini tvore superstrukture orijentirane prema površini priprava raznih supramolekularnih objekata iznad kritične agregacijske koncentracije (,3 g/l) nastaju u vodenoj otopini (uz NaCl) sferne superstrukture ( supermicele ) od oko 3 PS-PMAA micela radijusa 4-6 nm. primjena nosači lijekova (drug carriers) ugradnja hidrofobnih anti-tumorskih lijekova u jezgru i njihova dostava do tumora Block copolymer micelles for gene therapy Transfection of plasmid DNA using diblock copolymer. DNA is released inside the cytosol and appears in the nucleus to express a desired protein. Forster and M. Konrad, J. Mater. Chem., 3 5
6 Janus beads polimeri na površini; adsorpcija polimera parcijalna hidrofobna modifikacija staklenih sfernih čestica C. Casagrande and M. Veyssié, C. R. Acad. Sci (Paris) II 36 (1988) 143. višesloj (multilayer)? nastaju naizmjeničnom adsorpcijom polikationa i polianiona na čvrstu površinu najčešća metoda naizmjenično uranjanje u otopinu polielektrolita intenzivno istraživan posljednjih petnaestak godina (preko 1 radova godišnje) istražuju se uglavnom jaki polielektroliti polikationi i polianioni; ponašanje na površini adsorpcija polielektrolita na kovinskim oksidima izmjenično dodavanje pozitivno i negativno nabijenih polielektrolita nastajanje višesloja na površini metalnog oksida izrastanje višesloja je karakterizirano porastom adsorbirane mase metoda praćenja reflektometrija polyelectrolyte multilayers 6
7 otvorena pitanja eksperimentalne metode: ponašanje slabih polielektrolita mehanizam nastajanja višeslojeva polielektrolitni višeslojevisu ravnotežne strukture? eksponencijalni vs. linearni rast Elipsometrija Optička reflektometrija Quartz crystal microbalance(qcm) Optical vaweguide lightmode spectroscopy Surface plasmon resonance spectroscopy Neutron reflectometry FTIR-IR, AFM, itd, itd... optička reflektometrija P-AMA Poly(di-methyl-Amino-ethyl-MethAcrylate) C CH C O n O CH CH M w= kg/mol M s= 157 g/mol N PAA Poly Acrylic Acid CH CH C O OH M w= 1 kg/mol M s= 7 g/mol polielektrolitni višeslojevi (Polyelectrolyte Multilayers) 1..8 mm 3,5 3,.6,5, 1,5 polikation polianion.4 1,,5. AMA, -,
8 mm.8 mm PAA. AMA mm.8 mm PAA.4 AMA mm 4 mm PAA
9 mm 5 mm mm utjecaj ionske jakosti 5 mm 3. dva slučaja a) niska ionska jakost (e.g., mm) nastaju višeslojevi b) visoka ionska jakost (e.g. 5 mm, mm) ne nastaju višeslojevi što se dogadja ako se ionska jakost varira tijekom eksperimenta? mm 3. 5 mm
10 3.. 5 mm utjecaj ionske jakosti je li elektrolit odgovoran za destrukciju višeslojeva? M 1 M mm mm 5 mm 5 5 mm mm 5 mm 1 M 1 M1 M mm 5 mm mm mm mm mm mm mm mm mm
11 c s L L S L c cr AFM mjerenja usporedba između uzoraka pripremljenih pri mm i 5 mm contact mode AFM c G g f mm otvorena pitanja ponašanje slabih polielektrolita mehanizam nastajanja višeslojeva polielektrolitni višeslojevisu ravnotežne strukture? eksponencijalni vs. linearni rast 11
12 eksponencijalni vs. linearni rast eksponencijalni vs. linearni rast linearni rast 8 eksponencijalni rast eksponencijalni vs. linearni rast eksponencijalni vs. linearni rast Faktori koji utječu na tip rasta: kemijska priroda polielektrolitnog para 7 6 eksponencijalni vrsta dodanog elektrolita linearni ionska jakost 1 temperatura metoda priprave adsorpcija BSA na prethodno formirani polielektrolitni višesloj polielektrolitne četke (Polyelectrolyte Brushes). BSA. BSA 1. PSS PAH 1. PAH PSS PAH PAH t /s t/s. 1g/L,5g/L,75g/L BSA PAH 1. PSS PAH t/s 1
13 PARTICLE COATING SEM images of bacteria Pseudomonas aeruginosa adhered on a polyelectrolyte multilayer surface at x magnification. (A) Adhered bacteria on SiO plate, which is covered with five polyelectrolyte layers and the terminating layer has a positive electric charge (PAH) (B) Adhered bacteria on SiO plate, which is covered with six layers and the last adsorbed layer has a negative electric charge (PSS) SEM images of bacteria Pseudomonas aeruginosa adhered on a polyelectrolyte multilayer surface at 5x magnification. (A) Adhered bacteria on SiO plate, which is covered with five polyelectrolyte layers and the terminating layer has a positive electric charge (PAH) (B) Adhered bacteria on SiO plate, which is covered with six layers and the last adsorbed layer has a negative electric charge (PSS) PEMs can even be formed on colloidal particles as templates instead of planar substrates. In this case, the excess polyelectrolyte has to be removed by centrifugation or ultrafiltration. The development of PEM-coating procedures for particles is a major achievement, since it allows to prepare dispersions with a large surface area. In such samples, PEMs can be studied by volume techniques which require a sufficient amount of compound, such as for example NMR or DSC. After coating of colloidal particles the template itself can be removed employing suitable chemical procedures (for example a dissolution or degradation in acidic conditions). Provided that the PEM shell is stable against that treatment, a hollow polymeric capsule is remaining. Such hollow containers are interesting objects for applications such as encapsulation and the controlled release of active compounds. primjena šuplje sfere modifikacija površine inkapsulacija (encapsulation) šuplje sfere (hollow spheres) drug delivery 13
izotermalna titracijskamikrokalorimetrija(itc)
P / µw 7 5 3 1-1 5 1 15 2 25 t / min 25 2 15 1 5.5 1 1.5 2 2.5 3 25 2 15 1 5-5 -1.5 1 1.5 2 2.5 3 25 2 15 1 5 25 2 15 1 5-5 -1-15 -2-25.5 1 1.5 2 2.5 3.5 1 1.5 2 2.5 3 Polielektroliti u otopini i na površini
More informationSupporting Information
Block Copolymer Mimetic Self-Assembly of Inorganic Nanoparticles Yunyong Guo, Saman Harirchian-Saei, Celly M. S. Izumi and Matthew G. Moffitt* Department of Chemistry, University of Victoria, P.O. Box
More informationLayer-by-Layer (LBL) Self-Assembly
Layer-by-Layer (LBL) Self-Assembly 1 Layer-by-Layer (LBL) Self-Assembly No! Layers! Onions have layers! Ogres have Layers! Onions have Layers. You get it? We both have layers. Sherk 2001 Oh, you both have
More informationThin film techniques: the layer-by-layer self assembly technique
Thin film techniques: the layer-by-layer self assembly technique Carmelina Ruggiero University of Genoa Overview Thin films Thin film techniques Langmuir-Blodgett technique Chemical self-assembling Layer-by-Layer
More informationPolyelectrolyte hydrogels
Polyelectrolyte hydrogels Last Day: Physical hydrogels Structure and physical chemistry Today: polyelectrolyte hydrogels, complexes, and coacervates Polyelectrolyte multilayers theory of swelling in ionic
More informationDeposition of Gold Nanoparticles on Polystyrene Spheres by Electroless Metal Plating Technique
Journal of Physics: Conference Series Deposition of Gold Nanoparticles on Polystyrene Spheres by Electroless Metal Plating Technique To cite this article: Y Kobayashi et al 2007 J. Phys.: Conf. Ser. 61
More informationElectrostatic Self-assembly : A New Route Towards Nanostructures
1 Electrostatic Self-assembly : A New Route Towards Nanostructures J.-F. Berret, P. Hervé, M. Morvan Complex Fluids Laboratory, UMR CNRS - Rhodia n 166, Cranbury Research Center Rhodia 259 Prospect Plains
More informationph-triggered aggregation of responsive polymer-stabilized colloids and the reversible formation of porous scaffolds
Supporting Information: ph-triggered aggregation of responsive polymer-stabilized colloids and the reversible formation of porous scaffolds Robert T. Woodward, Christopher Hight, Ufuk Yildiz, Nicolas Schaeffer,
More informationSupracolloidal Polymer Chains of Diblock Copolymer Micelles
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2014 Supporting Information Supracolloidal Polymer Chains of Diblock Copolymer Micelles
More information6. Plasmon coupling between a flat gold interface and gold nanoparticles.
6. Plasmon coupling between a flat gold interface and gold nanoparticles. 6.1. Introduction In this outlook oriented chapter the applicability of the multilayered system used in chapter 4.1., for the study
More informationInteraction of Gold Nanoparticle with Proteins
Chapter 7 Interaction of Gold Nanoparticle with Proteins 7.1. Introduction The interfacing of nanoparticle with biomolecules such as protein is useful for applications ranging from nano-biotechnology (molecular
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information Nanoparticle-to-vesicle and nanoparticle-to-toroid transitions of ph-sensitive
More informationDefense Technical Information Center Compilation Part Notice
UNCLASSIFIED Defense Technical Information Center Compilation Part Notice ADP012179 TITLE: Salt-Induced Block Copolymer Micelles as Nanoreactors for the Formation of CdS Nanoparticles DISTRIBUTION: Approved
More informationInteraction of Proteins with Nanostructured Latex Particles in Aqueous Solution
Interaction of Proteins with Nanostructured Latex Particles in Aqueous Solution A. Wittemann, B. Haupt, University of Bayreuth E. Breininger, T. Neumann, M. Rastätter, N. Dingenouts, University of Karlsruhe
More informationSupplementary Information
Supplementary Information Facile preparation of superhydrophobic coating by spraying a fluorinated acrylic random copolymer micelle solution Hui Li, a,b Yunhui Zhao a and Xiaoyan Yuan* a a School of Materials
More informationMolecular weight of polymers. Molecular weight of polymers. Molecular weight of polymers. Molecular weight of polymers. H i
Gel Permeation Chromatography (GPC) : Size Exclusion Chromatography GPC : 1. Chromatogram (V R vs H) H i Detector response Baseline N i M i 130 135 140 145 150 155 160 165 Elution volume (V R ) (counts)
More informationSynthesis and characterization of poly(amino acid methacrylate)-stabilized diblock copolymer nanoobjects
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2014 Supporting Information for Polymer Chemistry manuscript: Synthesis and characterization
More informationElectronic Supplementary Information. Direct synthesis of H 2 O 2 catalyzed by Pd nanoparticles encapsulated in multi-layered
Electronic Supplementary Information Direct synthesis of H 2 O 2 catalyzed by Pd nanoparticles encapsulated in multi-layered polyelectrolyte nanoreactors on a charged sphere Young-Min Chung,* a Yong-Tak
More informationHairy Uniform Permanently-Ligated Hollow Nanoparticles with. Precise Dimension Control and Tunable Optical Properties
Supporting Information Hairy Uniform Permanently-Ligated Hollow Nanoparticles with Precise Dimension Control and Tunable Optical Properties Yihuang Chen, 1,2 Di Yang, 3 Young Jun Yoon, 1 Xinchang Pang,
More informationSupporting information
Supporting information Polymer-Single-Crystal@Nanoparticle Nanosandwich for Surface Enhanced Raman Spectroscopy Bin Dong, Wenda Wang, David L. Miller, Christopher Y. Li* Department of Material Science
More informationSupplementary Figure 1. Temperature profile of self-seeding method for polymer single crystal preparation in dilute solution.
Supplementary Figure 1. Temperature profile of self-seeding method for polymer single crystal preparation in dilute solution. Supplementary Figure 2. 1 H nuclear magnetic resonance (NMR) spectra (a) and
More informationPHENOLIC POLYMERIZATION USING Fe III -TAML
PHENOLIC POLYMERIZATION USING Fe III -TAML K. Entwistle*, D. Tshudy*, and T. Collins** *Gordon College, Department of Chemistry, Wenham, MA 01984 **Institute for Green Science, Carnegie Mellon University,
More informationSelf-Assembly of Coated Colloidal Particles for Optical Applications
Self-Assembly of Coated Colloidal Particles for Optical Applications Introduction Nearly two decades ago, theoretical predictions indicated the possibility of creating omnidirectional photonic-band-gap
More informationSupporting Information
Supporting Information Structural Engineering of Biodegradable PCL Block Copolymer Nano-assemblies for Enzyme-Controlled Drug Delivery in Cancer Cells Bapurao Surnar and Manickam Jayakannan* 1 Department
More informationMoscow Institute of Physics and Technology, Institutsky 9, Dolgoprudny , Russia 2
Graphene oxide linking layers: a versatile platform for biosensing Yu.V. Stebunov 1, O.A. Aftenieva 1, A.V. Arsenin 1, and V.S. Volkov 1,2 1 Moscow Institute of Physics and Technology, Institutsky 9, Dolgoprudny
More informationElectronic Supplementary Information
Electronic Supplementary Information Surfactant-free single-nano-sized colloidal Cu nanoparticles for use as an active catalyst of Ullmann-coupling reaction Yuto Isomura, a Takashi Narushima, b Hideya
More informationESI. Core-Shell Polymer Nanoparticles for Prevention of GSH Drug Detoxification and Cisplatin Delivery to Breast Cancer Cells
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2015 ESI Core-Shell Polymer Nanoparticles for Prevention of GSH Drug Detoxification and Cisplatin Delivery
More informationNanocontainers with controlled permeability for feedback active coatings
Nanocontainers with controlled permeability for feedback active coatings Contents: 1. Self-healing coatings based on nanocontainers for corrosion protection: - with ph-triggered release, - triggered by
More informationAqueous Self-Assembly of Fp Derivatives: Multifunctional Metal-Carbonyl Nanovesicles (MCsomes)
Aqueous Self-Assembly of Fp Derivatives: Multifunctional Metal-Carbonyl Nanovesicles (MCsomes) 38 th IPR Symposium-May 4 th 2016 Nimer Murshid and Xiaosong Wang Nimer Murshid Department of Chemistry Waterloo
More informationRational design of light-directed dynamic spheres
Electronic Supplementary Information (ESI) Rational design of light-directed dynamic spheres Yumi Okui a and Mina Han* a,b a Department of Chemistry and Department of Electronic Chemistry Tokyo Institute
More informationSupporting Information. Near Infrared-modulated Propulsion of Catalytic Janus Polymer. Multilayer Capsule Motors
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information Near Infrared-modulated Propulsion of Catalytic Janus Polymer Multilayer
More informationDi-Stimuli Responsive Diblock and Triblock Copolymer Particles
Di-Stimuli Responsive Diblock and Triblock Copolymer Particles Nancy Weber, John Texter *, and Klaus Tauer Max Planck Institute for Colloids and Interfaces Department of Colloid Chemistry 14476 Golm, Germany
More informationJulien Schmitt, postdoc in the Physical Chemistry department. Internship 2010: Study of the SAXS scattering pattern of mesoporous materials
Before starting Julien Schmitt, postdoc in the Physical Chemistry department Internship 2010: Study of the SAXS scattering pattern of mesoporous materials PhD 2011-2014: Self-assembly mechanism of mesoporous
More informationSupplementary Information
Supplementary Information Self-assembly of Metal-Polymer Analogues of Amphiphilic Triblock Copolymers 1 Zhihong Nie, 1 Daniele Fava, 1, 2, 3 Eugenia Kumacheva 1 Department of Chemistry, University of Toronto,
More informationHierarchically Structured Nanoporous Poly(Ionic Liquid) Membranes: Facile Preparation and Application in Fiber-optic ph Sensing
Supporting Information Hierarchically Structured Nanoporous Poly(Ionic Liquid) Membranes: Facile Preparation and Application in Fiber-optic ph Sensing Qiang Zhao, a Mingjie Yin, b A. Ping Zhang, b Simon
More informationAnomalous phase behavior in blends of -SO 3 H terminated polystyrene with poly(n-butyl acrylate) containing a small amount of tertiary amino groups
e-polymers 2008, no. 078 http://www.e-polymers.org ISSN 1618-7229 Anomalous phase behavior in blends of -SO 3 H terminated polystyrene with poly(n-butyl acrylate) containing a small amount of tertiary
More informationIn Situ Gelation-Induced Death of Cancer Cells Based on Proteinosomes
Supporting information for In Situ Gelation-Induced Death of Cancer Cells Based on Proteinosomes Yuting Zhou, Jianmin Song, Lei Wang*, Xuting Xue, Xiaoman Liu, Hui Xie*, and Xin Huang* MIIT Key Laboratory
More informationControlling Multicompartment Morphologies Using Solvent Conditions and Chemical Modification
Supporting Information to Controlling Multicompartment Morphologies Using Solvent Conditions and Chemical Modification by Tina I. Löbling, Olli Ikkala, André H. Gröschel *, Axel H. E. Müller * Materials
More informationNANOTECHNOLOGIES AND NANOSCIENCES, KNOWLEDGE-BASED MULTIFUNCTIONAL MATERIALS, AND NEW PRODUCTION PROCESSES AND DEVICES
NANOCAPS 001428 Nano-capsules for Targeted Controlled Delivery of Chemicals SPECIFIC TARGETED RESEARCH OR INNOVATION PROJECT NANOTECHNOLOGIES AND NANOSCIENCES, KNOWLEDGE-BASED MULTIFUNCTIONAL MATERIALS,
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Information (ESI) A thin-layered chromatography plate prepared from naphthalimide-based receptor immobilized SiO 2 nanoparticles as a portable chemosensor and adsorbent for Pb
More informationShell-isolated nanoparticle-enhanced Raman spectroscopy
Shell-isolated nanoparticle-enhanced Raman spectroscopy Jian Feng Li, Yi Fan Huang, Yong Ding, Zhi Lin Yang, Song Bo Li, Xiao Shun Zhou, Feng Ru Fan, Wei Zhang, Zhi You Zhou, De Yin Wu, Bin Ren, Zhong
More informationSupporting Information for:
Supporting Information for: Preparation and Cross-linking of All-Acrylamide Diblock Copolymer Nano-objects via Polymerization-Induced Self-Assembly in Aqueous Solution Sarah J. Byard, Mark Williams, Beulah
More informationA Hydrophilic/Hydrophobic Janus Inverse-Opal
Supporting information A Hydrophilic/Hydrophobic Janus Inverse-Opal Actuator via Gradient Infiltration Dajie Zhang #, Jie Liu //#, Bo Chen *, Yong Zhao, Jingxia Wang * //, Tomiki Ikeda, Lei Jiang //. CAS
More informationRadical Polymerization and Click Chemistry. Surfaces using Gamma Irradiation. Supporting Information*
Synthesis of Block Copolymers via Atom Transfer Radical Polymerization and Click Chemistry grafted from Pre-functionalized Polypropylene Surfaces using Gamma Irradiation Supporting Information* Ollie Foster,
More informationComparison of the Diffusion Coefficients Obtained for Latex Film Formation Studied by FRET and Pyrene Excimer Formation
Comparison of the Diffusion Coefficients Obtained for Latex Film Formation Studied by FRT and Pyrene xcimer Formation Remi Casier, Jean Duhamel, Mario Gauthier Institute for Polymer Research, Department
More informationUtilization of star-shaped polymer architecture in the creation of high-density polymer
Electronic Supplementary Material (ESI) for Biomaterials Science. This journal is The Royal Society of Chemistry 2014 Supplementary Information Utilization of star-shaped polymer architecture in the creation
More informationLipid functionalised Polyelectrolyte Multilayers Studied by Neutron Reflectometry
Lipid functionalised Polyelectrolyte Multilayers Studied by Neutron Reflectometry R. Krastev, N. Ch. Mishra, Chr. Delajon, H. Möhwald Max-Planck Institute of Colloids and Interfaces, Golm/Potsdam Th. Gutberlet
More informationChapter - 9 CORE-SHELL NANOPARTICLES
Chapter - 9 CORE-SHELL NANOPARTICLES Fig. 9.1: Transmission electron micrographs of silica coated gold nanoparticles. The shell thicknesses are (a) 10 nm, (b) 23 nm, (c) 58 nm, and (d) 83 nm. Reprinted
More informationSamuel Dodoo, Anna Burmistrova, Kornelia Gawlitza, Adrian Carl, Marcel Richter, Regine v. Klitzing
2) Stimuli responsive polyelectrolyte coatings Samuel Dodoo, Anna Burmistrova, Kornelia Gawlitza, Adrian Carl, Marcel Richter, Regine v. Klitzing Stranski-Laboratorium Technical University of Berlin, Germany
More informationSUPPORTING INFORMATION
SUPPORTING INFORMATION Non-Plasmonic SERS with Silicon: Is It Really Safe? New Insights into the Opto-Thermal Properties of Core/Shell Microbeads Nicolò Bontempi, a,d Irene Vassalini, a,b Stefano Danesi,
More informationFrom Polymer Gel Nanoparticles to Nanostructured Bulk Gels
From Polymer Gel Nanoparticles to Nanostructured Bulk Gels Zhibing Hu Departments of Physics and Chemistry, University of North Texas Denton, TX 76203, U. S. A. Phone: 940-565 -4583, FAX: 940-565-4824,
More informationSUPPLEMENTARY INFORMATION
SUPPLEMENTARY INFORMATION Facile Synthesis of High Quality Graphene Nanoribbons Liying Jiao, Xinran Wang, Georgi Diankov, Hailiang Wang & Hongjie Dai* Supplementary Information 1. Photograph of graphene
More informationSupplementary Information
Supplementary Information 1. Experimental 1.1.1 Synthesis of hollow silica nanoparticles NPs. The precursor of sol-gel silica is fresh made 1.0 M Si(OH) 4 solution which was made by adding tetramethyl
More informationA novel modification of superhydrophobic surfaces using supercritical carbon dioxide 1 H NMR
A novel modification of superhydrophobic surfaces using supercritical carbon dioxide 1 H NMR 164 171.5 96.5 Superhydrophobic surfaces were obtained by coating with spherical particles formed by the self-assembly
More informationSUPPORTING INFORMATION. Preparation of colloidal photonic crystal containing CuO nanoparticles with. tunable structural colors
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 215 SUPPORTING INFORMATION Preparation of colloidal photonic crystal containing CuO nanoparticles
More informationBreakthrough in Nanoparticle Tracking Analysis (NTA)
Breakthrough in Nanoparticle Tracking Analysis (NTA) April 2017 Rick Cooper, CEO rick.cooper@mantainc.com 858.449.5801 Outline Background Technology overview Validation results Product details Established
More informationSupplementary Materials
Supplementary Materials Sample characterization The presence of Si-QDs is established by Transmission Electron Microscopy (TEM), by which the average QD diameter of d QD 2.2 ± 0.5 nm has been determined
More informationElectronic Supplementary Information. Facile synthesis of polypyrrole coated copper nanowire: new concept to engineered core-shell structures
Electronic Supplementary Information Facile synthesis of polypyrrole coated copper nanowire: new concept to engineered core-shell structures Yang Liu, a Zhen Liu, a Ning Lu, b Elisabeth Preiss, a Selcuk
More informationNano fabrication and optical characterization of nanostructures
Introduction to nanooptics, Summer Term 2012, Abbe School of Photonics, FSU Jena, Prof. Thomas Pertsch Nano fabrication and optical characterization of nanostructures Lecture 12 1 Optical characterization
More informationChapter 2 Overview. ! all matter, whether liquid, solid, or gas,consists of atoms, which form molecules
Chapter 2 Overview! all matter, whether liquid, solid, or gas,consists of atoms, which form molecules! the identity of an atom and its chemical behavior is strictly defined by the number of electrons in
More informationCorrelative Raman Imaging of Polymeric Materials
APPLICATION NOTE Correlative Raman Imaging of Polymeric Materials WITec GmbH, Lise-Meitner-Str. 6, 89081 Ulm, Germany phone+49 (0) 731 140 700, fax +49 (0) 731 140 70 200 info@witec.de, www.witec.de Characterization
More informationChapter 3: Stoichiometry
Chapter 3: Stoichiometry Chem 6A Michael J. Sailor, UC San Diego 1 Announcements: Thursday (Sep 29) quiz: Bring student ID or we cannot accept your quiz! No notes, no calculators Covers chapters 1 and
More informationScheme 1: Reaction scheme for the synthesis of p(an-co-mma) copolymer
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Design and Development of Poly (acrylonitrile-co-methyl methacrylate) Copolymer to Improve
More informationSupporting information
Supporting information Temperature and ph-dual Responsive AIE-Active Core Crosslinked Polyethylene Poly(methacrylic acid) Multimiktoarm Star Copolymers ` Zhen Zhang,*,, and Nikos Hadjichristidis*, School
More informationCharacterization of Monoliths. Mateja Simonič
Characterization of Monoliths Mateja Simonič Index Introduction to chromatography Characterization Ionic capacity DBC - dynamic binding capacity Scanning Electron Microscopy Mercury Intrusion Porosimetry
More informationBlock Copolymer Based Hybrid Nanostructured Materials As Key Elements In Green Nanotechnology
The 7 th Korea-U.S. Nano Forum Block Copolymer Based Hybrid Nanostructured Materials As Key Elements In Green Nanotechnology Dong Ha Kim Department of Chemistry and Nano Science, Ewha Womans University
More informationRational design of a biomimetic glue with tunable strength and ductility
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2017 Supporting Information Rational design of a biomimetic glue with tunable strength and
More informationMeasuring nanoparticle properties: experiences from NPL Caterina Minelli
Measuring nanoparticle properties: experiences from NPL Caterina Minelli Measurement of Particles Types of materials: Metal Examples: Silver Gold Palladium Platinum Semiconductor Examples: Quantum Dots
More informationELECTRONIC SUPPLMENTARY INFORMATION (ESI) Doubly crosslinked microgel-colloidosomes: a versatile
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 1 ELECTRONIC SUPPLMENTARY INFORMATION (ESI) Doubly crosslinked microgel-colloidosomes: a versatile
More informationOrdered, porous and multifaceted polymer films
Ordered, porous and multifaceted polymer films Essay Submission for the 2008 IUPAC Prize for Young Chemists Dr. Luke A. Connal Department of Chemical and Biomolecular Engineering, The University of Melbourne,
More informationMath Without a Calculator for AP Chemistry
Math Without a Calculator for AP Chemistry Number Sense 6.02 1000 6.02 0.01 0.1 1000 0.02 1000 0.3 1000 0. 1000 Let fractions be your friends! Fraction Decimal Percent 3/ 0.80 Example: 3.00 1.2 3.00 6
More informationLecture 12: Biomaterials Characterization in Aqueous Environments
3.051J/20.340J 1 Lecture 12: Biomaterials Characterization in Aqueous Environments High vacuum techniques are important tools for characterizing surface composition, but do not yield information on surface
More informationSupporting Information
Supporting Information Synthesis, Anion Exchange, and Delamination of Co-Al Layered Double Hydroxide. Assembly of the Exfoliated Nanosheet/Polyanion Composite Films and Magneto-optical Studies Zhaoping
More informationMicelles-Encapsulated Microcapsules for Sequential Loading of Hydrophobic and Water-Soluble Drugs
Communication Micelles-Encapsulated Microcapsules for Sequential Loading of Hydrophobic and Water-Soluble Drugs Weijun Tong, Yi Zhu, Zhipeng Wang, Changyou Gao,* Helmuth Möhwald Layer-by-layer (LbL) assembly
More informationParticles 2009, Berlin. using AFM force spectroscopy. Andreas Fery
Particles 2009, Berlin Mechanical characterization of microcapsules using AFM force spectroscopy Andreas Fery University of Bayreuth Faculty of Biology, Chemistry and Geosciences Department Physical Chemistry
More informationSupplementary Information. Omnidispersible Hedgehog Particles with Multilayer Coatings for. Multiplexed Biosensing
Supplementary Information Omnidispersible Hedgehog Particles with Multilayer Coatings for Multiplexed Biosensing Douglas G. Montjoy 1, Joong Hwan Bahng 1,2, Aydin Eskafi 1, Harrison Hou 1, Nicholas A.
More informationSupporting Information. Reduction- and Thermo-Sensitive Star Polypeptide Micelles. and Hydrogels for On-Demand Drug Delivery
Supporting Information Reduction- and Thermo-Sensitive Star Polypeptide Micelles and ydrogels for n-demand Drug Delivery Dong-Lin Liu, Xiao Chang, Chang-Ming Dong* Department of Polymer Science & Engineering,
More informationTip-Enhanced Raman Spectroscopy: Developments and Application to the study of double-stranded DNA bundles and polymer-wrapped carbon nanotubes
Tip-Enhanced Raman Spectroscopy: Developments and Application to the study of double-stranded DNA bundles and polymer-wrapped carbon nanotubes Sébastien Bonhommeau Groupe Spectroscopie Moléculaire, ISM,
More informationIn-situ ellipsometry studies of thin swollen films, a review
In-situ ellipsometry studies of thin swollen films, a review Wojciech Ogiegło, Herbert Wormeester, Klaus-Jochen Eichhorn, Matthias Wessling, Nieck E. Benes 1 Thin polymer films Why are they important?
More informationNANOCOMPOSITE THIN FILMS:
NANOCOMPOSITE THIN FILMS: Assembly, Characterizations, & Applications Chaoyang Jiang Department of Chemistry The University of South Dakota St. Louis, June 26, 2008 Forest Products &Nanocomposite P. Monteiro@UC
More informationSemiconductor Quantum Dots with Environmentally Responsive Mixed Polystyrene/Poly(methyl methacrylate) Brush Layers
5868 Macromolecules 2007, 40, 5868-5878 Semiconductor Quantum Dots with Environmentally Responsive Mixed Polystyrene/Poly(methyl methacrylate) Brush Layers Yunyong Guo and Matthew G. Moffitt* Department
More informationIntroduction to Dynamic Light Scattering for Particle Size Determination
www.horiba.com/us/particle Jeffrey Bodycomb, Ph.D. Introduction to Dynamic Light Scattering for Particle Size Determination 2016 HORIBA, Ltd. All rights reserved. 1 Sizing Techniques 0.001 0.01 0.1 1 10
More informationFundamentals of nanoscience
Fundamentals of nanoscience Spectroscopy of nano-objects Mika Pettersson 1. Non-spatially resolved spectroscopy Traditionally, in spectroscopy, one is interested in obtaining information on the energy
More informationScattering-type near-field microscopy for nanoscale optical imaging
Scattering-type near-field microscopy for nanoscale optical imaging Rainer Hillenbrand Nano-Photonics Group Max-Planck-Institut für Biochemie 82152 Martinsried, Germany Infrared light enables label-free
More informationDouble Mesoporous Silica Shelled Spherical/Ellipsoidal Nanostructures: Synthesis and Hydrophilic/Hydrophobic Anticancer Drug Delivery
Supporting information for Supplementary Material (ESI) for Journal of Materials Chemistry Double Mesoporous Silica Shelled Spherical/Ellipsoidal Nanostructures: Synthesis and Hydrophilic/Hydrophobic Anticancer
More informationElectronic Supplementary Information. for
Electronic Supplementary Information for A Facile and Highly Efficient Strategy for Esterification of Poly (Meth) Acrylic Acid with halogenated compounds at Room Temperature Promoted by 1, 1, 3, 3-Tetramethylguanidine
More informationImaging Polymer Morphology Using Atomic Force Microscopy
Imaging Polymer Morphology Using Atomic Force Microscopy Russell J. Composto Materials Science and Engineering, and the Laboratory for Research on the Structure of Matter, University of Pennsylvania Agilent
More informationSupporting Information for
Supporting Information for Encapsulation and Controlled Release of L-Leuprolide from Poly(βhydroxyalkanoate)s: Impact of Microstructure and Chemical Functionalities Noureddine Ajellal, Christophe M. Thomas,*
More informationSurface Modification of PTMS Particles with Organosilanes: TEOS-, VTMS-, and MTMS-Modified Particles
Journal of Sol-Gel Science and Technology 31, 117 121, 2004 c 2004 Kluwer Academic Publishers. Manufactured in The United States. Surface Modification of PTMS Particles with Organosilanes: TEOS-, VTMS-,
More informationPreparation of Fe 3 O 2 Nanostructures via Inverse Micelle Method and Study of Their Magnetic Properties for Biological Applications
International Journal of Bio-Inorganic Hybrid Nanomaterials Preparation of Fe 3 O 4 @SiO 2 Nanostructures via Inverse Micelle Method and Study of Their Magnetic Properties for Biological Applications Afsaneh
More informationHighly corrosion resistant organic-inorganic hybrid coatings prepared using the sol-gel process
SÃO PAULO STATE UNIVERSITY- UNESP INSTITUTE OF CHEMISTRY - ARARAQUARA, BRAZIL Highly corrosion resistant organic-inorganic hybrid coatings prepared using the sol-gel process P. Hammer*, F. C. dos Santos,
More informationMichael KC Tam Department of Chemical Engineering University of Waterloo. Waterloo, Ontario, CANADA N2L 3G1
Design of Polymeric Nanostructures for Chemical and Biomedical Applications Michael KC Tam Department of Chemical Engineering University of Waterloo 200 University Avenue West Waterloo, ntario, CANADA
More informationSupporting Information for manuscript: Synthesis and ph-responsive Dissociation of Framboidal ABC Triblock Copolymer Vesicles in Aqueous Solution
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2017 Supporting Information for manuscript: Synthesis and ph-responsive Dissociation of Framboidal
More informationContents. Foreword by Darrell H. Reneker
Table of Foreword by Darrell H. Reneker Preface page xi xiii 1 Introduction 1 1.1 How big is a nanometer? 1 1.2 What is nanotechnology? 1 1.3 Historical development of nanotechnology 2 1.4 Classification
More informationNanoscale Chemical Imaging with Photo-induced Force Microscopy
OG2 BCP39nm_0062 PiFM (LIA1R)Fwd 500 279.1 µv 375 250 nm 500 375 250 125 0 nm 125 219.0 µv Nanoscale Chemical Imaging with Photo-induced Force Microscopy 0 Thomas R. Albrecht, Derek Nowak, Will Morrison,
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information Synthesis of Poly(dihydroxystyrene-block-styrene) (PDHSt-b-PSt) by the RAFT
More informationChemistry Section Review 7.3
Chemistry Section Review 7.3 Multiple Choice Identify the choice that best completes the statement or answers the question. Put the LETTER of the correct answer in the blank. 1. The molar mass of an element
More informationEnhanced Photonic Properties of Thin Opaline Films as a Consequence of Embedded Nanoparticles.
Enhanced Photonic Properties of Thin Opaline Films as a Consequence of Embedded Nanoparticles. D E Whitehead, M Bardosova and M E Pemble Tyndall National Institute, University College Cork Ireland Introduction:
More informationHeteroagglomeration of nanosilver with colloidal SiO2 and clay
, 14, 1 8 Supplementary material Heteroagglomeration of nanosilver with colloidal SiO2 and clay Sébastien Maillette, A Caroline Peyrot, A Tapas Purkait, B Muhammad Iqbal, B Jonathan G. C. Veinot B and
More informationStyrene-divinylbenzene copolymer grafted with phosphonic acid dialkylesters
J. Serb. Che. Soc. 69 (12) 43 51 (2004) UDC 547.538+678 13+547.315.2:543.216.185 JSCS-3232 Original scientific paper Styrene-divinylbenzene copolymer grafted with phosphonic acid dialkylesters GHEORGHE
More information