2. What is the wavelength, in nm, of light with an energy content of 550 kj/mol? a nm b nm c. 157 nm d. 217 nm e.

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1 1. What is the frequency associated with radiation of 4.59 x 10-8 cm wavelength? a x s -1 b x s -1 c x 10-8 s -1 d s -1 e x 10 7 s What is the wavelength, in nm, of light with an energy content of 550 kj/mol? a nm b nm c. 157 nm d. 217 nm e nm 3. Select the correct statement The photoelectric effect: a. was discovered by Max Planck. b. describes the phenomenon of producing a beam of electrons by shining light on any metal surface. c. contradicted the view that light energy was dependent upon intensity only. d. was explained by classical physics wave theory e. results in a beam of electrons which increases in number, but not velocity, as the wavelength of incident light decreases. 4. In comparing UV and microwave electromagnetic radiation, which statement is correct? a. Photon energy for microwave > Photon energy for UV b. ν for UV > ν for microwave c. λ for UV > λ for microwave d. UV travels faster than microwave radiation in a vacuum e. two of these statements are correct 5. How many electrons would be found in the n=6 level if all possible orbitals were completely filled with electrons? a. 18 b. 32 c. 72 d The possible values of the orbital angular momentum quantum number of a 3p electron are: a. +1/2, -1/2 b. -1, 0, +1 c. 0, 1, 2 d. 1, 2, 3

2 7. The ratio of the radius of the 8 th orbit of He + to the radius of the 4 th orbit for H is: a. ¼ b. 2 c. 4 d. ½ e The ground state electron configuration of Au is: a. [Xe] 4f 13 5d 9 6s 2 b. [Xe] 5d 10 6s 1 c. [Xe] 5d 9 6s 2 d. [Xe] 4f 14 5d 10 6s 1 9. [Ar]3d 10 is the ground state electronic configuration of which species: a. Zn b. Cu 2+ c. Ge 2+ d. Ga The quantum numbers of the last electron of Antimony (Sb) could be: a. n = 5, l = 0, ml = 0, ms = 1/2 b. n = 4, l = 2, ml = -2, ms = 1/2 c. n = 5, l = 1, ml = 0, ms = 1/2 d. n = 5, l = 1, ml = -2, ms = 1/2 e. n = 4, l = 3, ml = 3, ms = 1/2 11. The ion represented as a. 22 electrons b. 48 neutrons c. 26 protons d. 4 3d electrons e. 0 4s electrons 48 22Ti 4+ has: 12. The orbital in which the last electron of Tantalum (Ta) is placed will have a total of how many nodes (both radial and angular)? a) 5 b) 3 c) 4 d) 6 e) none of these

3 3 13. Which species is the most paramagnetic? a) Cr + b) Mn + c) Ag d) Fe e) As 14. Which of the following electron transitions in the He + ion results in absorption of light of the longest wavelength? a) n = 8 to n = 7 b) n= 4 to n = 5 c) n = 1 to n = 8 d) n = 2 to n = 3 e) n = 1 to n = What would be the ionization energy for a B 4+ ion on another planet where a high surface temperature resulted in the third principle energy level being the ground state for the B 4+ ionic under these extreme extraterrestrial conditions? a) 25/9 hcr H b) -25/9 hcr H c) 5/9 hcr H d) -1/9 hcr H e) hcr H 16. The n th orbit of a hydrogen like species has a radius of 441 pm and an energy of x J. Identify the correct H-like species and electron orbit. a) He +, n=3 b) He +, n=4 c) Li 2+, n=4 d) Li 2+, n=5 e) Be 3+, n=5 17. For the ion Be 3+, an emission line is detected at nm. This line is due to an electron transition from the n th orbit to the ground state orbit of this ionic species. Identify the value of n for the initial orbit for this emission line. a) 1 b) 4 c) 5 d) 7 e) 9

4 4 18. The energy of a laser beam that excites a two-photon absorption in a particular element is 1.22x10 5 J/(mol of photons). What would be the wavelength of light that would excite a one-photon absorption between the same states in the material? a) 980 nm b) 1960 nm c) 490 nm d) 8.11 x m e) none of these 19. What would be the atomic number for the undiscovered element which would have four electrons in its 6f orbitals? a) 120 b) 122 c) 125 d) 157 e) Assume the Laws of Nature were different and Hund s rule required that unpaired electrons fill empty degenerate orbitals singly with all electrons in a spin up configuration for every atom, before a second electron with opposite spin could be added to each orbital. What would be the outcome of the Stern Gerlach type experiment where a beam of vanadium (V) atoms are passed through a magnetic field? a) The V atoms would pass through the magnetic field undeflected and produce one spot on the detector. b) The V atoms would be deflected in two separate directions by the magnetic field and produce two spots on the detector. c) The V atoms would be deflected in three separate directions by the magnetic field and would produce three spots on the detector. d) The V atoms would be deflected backwards by the magnetic field would not reach the detector. e) The V atoms would be deflected in one direction by the magnetic field producing one spot on the detector. 21. A US car company lists the mass of a particular model as 3142 pounds. If the velocity of the car is measured to be u = 1.20 x 10 2 km/hour using a radar speed gun with a 2 % uncertainty, what is the uncertainty ( x) in the position of the car? (1 pound = g) a) 5.55 x m b) 3.08 x m c) 1.54 x m d) 5.55 x m e) none of these

5 5 22. If light of a frequency of 1.50 x s -1 is directed at a copper surface, electrons are ejected from the copper and are measured to have a velocity of 7.40 x 10 5 m s -1. What is the work function of copper in units of ev? (1eV = x J) a) 9.94 x ev b) 4.65 ev c) 6.20 ev d) 1.19 x ev e) 1.50 ev 23. The measured values for the work function of some metals are Al =4.19 ev, Zn=4.33 ev, Mg= 3.66 ev, Na= 2.7 ev and Cs If light having a wavelength of 414 nm is directed on samples of these metals, what would you expect to observe experimentally? (KE means Kinetic Energy in the answers; 1eV = x J) a) electrons would be ejected by Na and Cs with KE e - Cs > KE e - Na b) electrons would be ejected from Al, Zn, and Mg with KE e - Zn > KE e - Al > KE e - Mg c) electrons would be ejected from Al, Zn with KE e - Al > KE e - Zn d) electrons would be ejected from Mg, Na, and Cs with KE e - Cs > KE e - Na > KE e - Mg e) none of these would occur 24. Which is not a valid set of quantum numbers for an electron? a. n = 5, l = 2, ml = -2, ms = 1/2 b. n = 3, l = 0, ml = 0, ms = 1/2 c. n = 10, l = 2, ml = 2, ms = 1/2 d. n = 5, l = 4, ml = 4, ms = -1/2 e. n = 6, l = 3, ml = -4, ms = -1/2 25. What would be the ground state electronic configuration for In +? a. [Kr]4d 9 5s 2 5p 1 b. [Kr]4d 10 5s 1 5p 1 c. [Kr]4d 10 5s 2 5p 2 d. [Kr]4d 10 5s 2 5p What would be the wavelength of an electron that is moving at 1.5% of the speed of light? a) 74 pm b) 162 pm c) 52.9 pm d) 1.62 pm e) 7.4 pm

6 27. How many of the following species would you expect to be diamagnetic? Be, Cd, Cl -, Y +, Ti 2+ Ag + 6 a) one diamagnetic species b) two diamagnetic species c) three diamagnetic species d) four of them e) all of them 28. What ionic species with a 3+ charge would you expect to have the following electronic configuration: [Kr]4d 5 a) Ru 3+ b) Fe 3+ c) Pd 3+ d) Ni 3+ e) Zr 3+

7 INFORMATION SHEET 7 CONSTANTS: h = x Js c = x 10 8 ms -1 N = x10 23 mol -1 R H =1.097x10 7 m -1 m e =9.109x10-31 kg e=1.602x10-19 C a o =52.9 pm

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9 Answers 9 1. a 2. d 3. c 4. b 5. c 6. e 7. d 8. d 9. d 10. c 11. e 12. c 13. b 14. b 15. a 16. d 17. d 18. c 19. c 20. e 21. a 22. b 23. a 24. e 25. e 26. b 27. d 28. a