uco.es/grados TEACHING GUIDE DETAILS OF THE SUBJECT TEACHER INFORMATION REQUIREMENTS AND RECOMMENDATIONS

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1 17/ Year DETAILS OF THE SUBJECT Title (of the subject): TÉCNICAS ANALÍTICAS DE SEPARACIÓN Code: 14 Degree/Master: GRADO DE QUÍMICA Year: Name of the module to which it belongs: FUNDAMENTAL Field: QUÍMICA ANALÍTICA Character: OBLIGATORIA ECTS Credits: 6 Face-to-face classroom percentage: 4% Online platform: Duration: SECOND TERM Classroom hours: 6 Non-contact hours: TEACHER INFORMATION Name: LUCENA RODRÍGUEZ, RAFAEL (Coordinador) Office location: Edificio Marie Curie (aneo) q6luror@uco.es Phone: Name: ARCE JIMENEZ, LOURDES Office location: Edificio Marie Curie (aneo) qa1arjil@uco.es Phone: 76 Name: BALLESTEROS GÓMEZ, ANA MARÍA Office location: Edificio Marie Curie (aneo) abagoa@uco.es Phone: 7644 Name: DELGADO POVEDANO, MARÍA DEL MAR Office location: Edificio Marie Curie (aneo) q8depom@uco.es Phone: 761 Name: LÓPEZ LORENTE, ÁNGELA INMACULADA Office location: Edificio Marie Curie (aneo) q3loloa@uco.es Phone: 7616 REQUIREMENTS AND RECOMMENDATIONS Prerequisites established in the study plan Students can matriculate in optative subjects once they have passed the 6 credits of basic formation and, at least, other 3 credits corresponding to obligatory subjects. Recommendations PAGE 1/6 17/ Year

2 17/ Year Students should certify at least B1 English level. SKILLS CB CE3 CE16 CE CE1 CE CE3 CE8 CE3 CE31 The capacity for data management and to generate information / understanding principles and proceedures used in chemical analysis and in the characterisation of chemical compounds. study of the technical instruments and their application. Metrology of chemical processes, including quality control The ability to show knowledge and understanding of the essential facts, concepts, principles, and theories relating to chemistry The ability to apply knowledge to solve qualitative and quantitative problems according to previously developed models competency to evaluate, interpret and summarise Chemical data and information. Ability to carry out standard laboratory procedures involved in analytical and concise work in relation with organic and inorganic systems. The ability to handle standard chemistry equipment used in structural studies and seperations interpretation of data from previous observations and measurements in the laboratory in terms of their significance and the theories that support them OBJECTIVES The student will be able to: 1. Understand the principles and features of chromatographic and non chromatographic separation techniques and their application in chemical analysis.. Demonstrate competence in selecting the most suitable separation technique for solution-oriented problem solving. 3. Demonstrate competence in the application of quantitative methods in chemical analysis. 4. Recognize Analytical Chemistry as a metrological science that develop, optimize and apply measurement processes intended to get high quality chemical information CONTENT 1. Theory contents 1. INTRODUCTION TO ANALYTICAL SEPARATION TECHNIQUES. General considerations. Role of separation techniques in analytical processes. Fundamentals of separation processes: Distribution ratio and separation factor.. LIQUID-LIQUID EXTRACTION. Introduction. Thermodynamic aspects: equilibrium distribution, recovery factors, etraction selectivity, distribution ratio. Kinetic aspects. Etraction techniques. Applications. 3. SOLID PHASE EXTRACTION. Description. Formats. Sorbents: types and interactions. SPE characteristics. Matri components influence in SPE. Applications. ción. Formatos. Adsorbentes: tipos e interacciones. Características de la SPE. Influencia de la matriz de la muestra en SPE. Aplicaciones. 4. SOLID-LIQUID EXTRACTION. Sohlet etraction. Ultrasound-assisted etraction. Accelerated solvent etraction. Microwave-assisted etraction. Supercritical fluid etraction.. ELECTROPHORESIS. Fundamentals. Transport processes. Factors influencing electrophoretic separations. Electrophoretic modes. Capillary electrophoresis. Applications. 6. CHROMATOGRAPHIC TECHNIQUES. The chromatographic process. Migration rate of solutes. Band-broadening. Resolution. Sample size effects. The general elution problem PAGE /6 17/ Year

3 17/ Year 7. LIQUID CHROMATOGRAPHY. Basic concepts and modes in LC. Instrumentation: Solvent reservoirs and degassing. Pumps. Inlet systems. The column. Detectors. Ultra performance liquid chromatography 8. GAS CHROMATOGRAPHY. Introduction. Instrumentation. Carrier gas. Inlet systems. Columns and stationary phases. Detectors. Comprehensive two-dimensional GC. Quantification. Practical contents 1. Determination of anionic surfactants in environmental waters by liquid chromatography coupled to ultraviolet detection.. Determination of food additives in soft drinks by gas chromatography coupled to flame ionization detector. 3. Etraction of astaanthine in fish followed by photometric quantitation. METHODOLOGY Methodological adaptations for part-time students and students with disabilities and special educational needs Adaptations for part-time students will be in agreement with the Science Faculty normative. The methodologies will be adapted to the difficulties faced by students with any disability. Face-to-face activities Activity Assessment activities Laboratory Lectures Seminar Total hours: Large group 8 33 Medium group Small group Total 8 6 Not on-site activities Activity Bibliographic consultations Eercises Problems Self-study Total hours: Total WORK MATERIALS FOR STUDENTS Internship notebook Dossier Eercises and problems Manual of the subject PAGE 3/6 17/ Year

4 17/ Year EVALUATION Tools Internship reports Short answer tests Final eam Skills CB CE16 CE CE1 CE CE3 CE8 CE3 CE3 CE31 Total (1%) Minimum grade.(*) 7% 1% % (*) Minimum grade necessary to pass the subject Valora la asistencia?: No General clarifications on instruments for evaluation: The evaluation of this subject consists of three parts: 1. THEORETICAL CONTENTS: They will be evaluated by a written eam consisting of short questions. The aim of this eam is to check the knowledge of students about the contents eplained in lessons 1-8. The weighting of this part represents 7% of the global mark.. SEMINARS. The eam will consist of 1- practical questions. The aim of this eam is to check the ability of the student to solve practical problems related to the use of separation techniques in quantitative chemical analysis. The weighting of this part represents % of the global mark. 3. LAB PRACTICES. The eam will consists of 6 questions on the methods and contents involved in the 3 lab practices that will be developed. The weighting of lab practices is 1% of the global mark (% for the eam and % for student attendance to the lab practices). RULES TO PASS THE SUBJECT A mark representing the % of each evaluation part (i.e. Theoretical contents, Seminars and Lab Practices) will be required to pass the subject. Student attendance to lab practices is mandatory to pass this part. Marks above % corresponding to Lab Practices and Seminars will be kept until passing the Theoretical Contents. Clarifications on the methodology for part-time students and students with disabilities and special educational needs: Evaluation and methodological adaptation for part-time students will be carried out according the general rules established by the Faculty of Science. The methodologies will be adapted to the difficulties faced by students with any disability. Qualifying criteria for obtaining honors: Conforme la artículo 4c del Reglamento de régimen académico. Para calificaciones finales similares, prevalecerá la mayor puntuación en el eamen final de la asignatura PAGE 4/6 17/ Year

5 17/ Year General clarifications on the partial evaluations: Se realizará un eamen parcial referente al contenido de las lecciones 1-4. Se requerirá una nota mínima de para eliminar la materia en el eamen final. BIBLIOGRAPHY 1. Basic Bibliography: - Fundamentos de Química Analítica. D.A. Skoog, D.M. West y F.J. Holler. Ed. Reverté, Barcelona,. - Química Analítica. D.A. Skoog, D.M. West, F.J. Holler, R.S. Crouch. Ed. McGraw-Hill, Méico, 3. - Principios de análisis instrumental. D.A. Skoog, F.J. Holler y T.A. Nieman. Ed. McGraw-Hill, Interamericana, España, Madrid, 1 Específica: - Técnicas Analíticas de Separación. M. Valcárcel y A. Gómez Hens. Ed. Reverté, ª edición, Técnicas Analíticas de separación en Química Analítica. R. Cela, R.A. Lorenzo y C. Casais. Ed. Sintesis, Madrid,. - Teoría y Práctica de la Etracción Líquido-Líquido. M Valcárcel y M. Silva. Ed. Alhambra, Etracción con fluidos supercríticos en el proceso analítico. M.D. Luque, M. Valcárcel, T.Tena. Ed Reverté, 13 - Electroforesis capilar. C. Cruces. Servicio Publicaciones Universidad Almería, 18. Further reading: None. COORDINATION CRITERIA - Joint activities: lectures, seminars, visits... PAGE /6 17/ Year

6 17/ Year SCHEDULE Activity Assessment activities Laboratory Lectures Seminar Period 1# Week # Week 3# Week 4# Week # Week 6# Week 7# Week 8# Week # Week 1# Week 11# Week 1# Week 13# Week 14# Week Total hours: The methodological strategies and the evaluation system contemplated in this Teaching Guide will be adapted according to the needs presented by students with disabilities and special educational needs in the cases that are required. PAGE 6/6 17/ Year