Turn your Ion Analyzer into a Titrator

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2 Sensing the Future Other Innovative Products Turn your Ion Analyzer into a Titrator Model 940 SAVE $ ROSS ph Electrodes Fastest, Accurate, Reproducible Results at Varying Temperatures Unique, Nonmetallic Reference Does Not Contaminate Samples ionplus Sure-Flow Combination ISE Electrodes Stable and Reproducible for Low-Levels and Small Samples Reduced Analysis Time and Maintenance Time Model 960 Purchase a 960 Module and Save $ Take Advantage of Untapped Potential Specialty Titration Electrodes For Karl Fischer Titrations For Redox and Surfactant Applications Increase Accuracy and Precision by Automating your Current Electrode Analysis Save Time by Letting the Instrument Automate the Analysis Expand your Current Measurement Capabilities to Do Automated Incremental ISE and Titration Techniques Have the Ability to Expand your Laboratory s Sample Throughput by Adding an AS3000 Autosampler New Turn-key ISE Application Kits ISE Meter, Electrode and Solutions Fluoride, Chloride and Sodium Measurements Register to Download our NEW On-Line Titration Catalog at Limited time offer, some restrictions apply

3 Table of Contents Introduction pg 5 Applications pg 6 Model 960 Titrator PLUS pg 7 AS3000 New Series Autosamplers pg 8 Model 950 Fast QC Titrator pg 9 Model 930 Ionalyzer System pg 10 Techniques pg 11 Endpoint Analysis, KAP Analysis, GAP Analysis, Assist Analysis Specifications pg 12 Model 960, 950 & 930 Accessories & Consumables pg 13 Description of Accessories, Consumables, Printers Printer Consumables, Cables, EPROMS & Software Electrodes & Solutions pg 15 ATC Probes, Ammonia Analysis, Calcium Analysis, Chloride/Chloride Analysis, Cupric Analysis, Fluoride Analysis Lead Analysis, Nitrate Analysis, ph Analysis, Potassium Analysis pg. 16 Reference Electrodes, Sodium Analysis, Surfactant Analysis, Special Tests & Analyses pg. 17 TURBO2 Blending Volumetric Karl Fischer Titrator pg 18 Model AF8 Volumetric Karl Fischer Titrator pg 19 Model AF7 Coulometric Karl Fischer Titrator pg 20 Model AF7LC Coulometric Karl Fischer Titrator pg 20 Accessories & Consumables pg Description of Instruments, Model AF7 Accessories & Consumables, Model AF7LC Accessories & Consumables Accessories & Cables pg Description of Karl Fischer Moisture Vaporizer Accessory, Balance & Printer Cables Specifications pg 23 Model TURBO2, AF8, AF7 & AF7LC Terms and Conditions pg 24 Warranty pg 25 Cross References pg 26

4 Introduction Table of Contents Applications 960 AS Turbo2 AF8 AF7/AF7LC 5 Thermo Orion offers a wide variety of innovative titration and automation products. Thermo Orion s expertise in titration began with the automation of Ion Selective Electrode (ISE) analyses. Over time, it expanded to include an entire product line dedicated to potentiometric analyses as well as a full line of Karl Fischer Moisture Analysis Titrators. Through continued research and development, Thermo Orion is always expanding into new technologies to Sense the Future Potentiometric workstations and titration systems make analyses quick, easy and reproducibly accurate. Whether the analysis is surfactants in shampoo, fluoride in drinking water, or Vitamin C in juices, Thermo Orion has the system to automate your measurements. Model 960 Thermo Orion has an automated Karl Fischer Titrator to accurately measure moisture in most any type of sample. Numerous applications have been developed for a variety of industries including the agricultural, chemical, pharmaceutical, cosmetic and food industries. A wide range of ph, ISE and Specialty titration electrodes are available, including the surfactant electrode to test for anionic, cationic and nonionic surfactants. The New AS3000 Series Autosampler is compatible with the Model 960 TitratorPLUS as well as Models 162A, 535A, 550A, 555A, and 862A benchtop meters. Increase lab productivity by automating sample preparation and analyses with an AS3000 Autosampler. TURBO2 ph and ISE Electrodes AS3000 Series Autosampler

5 Applications Table of Contents Applications 960 AS Turbo2 AF8 AF7/AF7LC 6 The Thermo Orion Applications Lab makes the difference when purchasing titration equipment! Thermo Orion has hundreds of application notes providing valuable methods and performance information for all of our titration equipment. In addition to the existing database of application notes, the Application Lab will analyze customer samples for either method development or test validation procedures. The Applications Lab is utilized in conjunction with the sale of a Thermo Orion titration unit. Application development may be performed on any of Thermo Orion s potentiometric or Karl Fischer Titrators. Listed below are just some of Thermo Orion's titration application notes. Examples of Applications: Potentiometric Analyses Log # Free Fatty Acid in Animal Fat/Refined Vegetable 638A Calcium Carbonate in Acid Relief Tablets 646A Sodium in Bacon 505 Sodium Chloride in Barbecue Sauce 296B Sodium in Beer 123 Anionic surfactant in bath soap 453 Chloride in Biscuit and Gravy mix 412C Chlorine in Bleach 468D Sodium in Butter 630B Chloride in Cat Food 541C Surfactant in Detergent 438 Fluoride in Ground Water 586 Hydrogen Peroxide in Hair Permanents 28 Vitamin C in Infant Formula 327A Zinc in Motor Oils 133 Anionic Surfactant in Shampoo 658A Nitrate in Soil 284A Karl Fischer Moisture Analyses Log # Advil Tablets by TURBO2 Blending Volumetric KF Chewing Gum by TURBO2 Blending Volumetric KF Face Lotion by TURBO2 Blending Volumetric KF Freeze-Dried Foods by TURBO2 Blending Volumetric KF Ink-Printing by TURBO2 Blending Volumetric KF Pasta by TURBO2 Blending Volumetric KF Sugar by TURBO2 Blending Volumetric KF Brake Fluid by AF8 Volumetric KF Cosmetics (Alcohol) by AF8 Volumetric KF Insulin Standard by AF8 Volumetric KF Kerosene by AF8 Volumetric KF Textiles Wool by AF8 Volumetric KF Toothpaste by AF8 Volumetric KF Antifreeze by AF7 Coulometric KF Moisture Titrator Oil-Mineral by AF7 Coulometric KF Moisture Titrator Diesel by AF7LC KF1523 KF1286 KF1193 KF09 KF1013 KF1039 KF1565 KF1088 KF1574 KF05 KF1059 KF1246 KF1095 KF66 KF14 KF1259 Food/Confectionaries Cosmetics/Pharmaceuticals Water/Waste Water * Register at to view the entire index of Thermo Orion Titration application notes.

6 Titrator PLUS Table of Contents Applications 960 AS Model 960 Highly Versatile - analytical instrument with complete automation capability 12 Preprogrammed Techniques - automate titrations, ph and direct ion measurement Potentiometric Titrations - including acid/base, redox, precipitation and complexometric Simple - YES and NO operating commands Method Memory - store up to 20 methods Data Collection Software - collect, view, store and print data AssuredAccuracy - titrant delivery with gravimetric calibration Karl Fischer Accessory - for low throughput moisture analysis Techniques Specifications Accessories & Consumables Electrodes & Solutions Ideally suited for dedicated, routine measurements, the Model 960 is intended for use in laboratories where automation is needed to overcome problems of sample throughput or analytical complexity. What differentiates the Model 960 from other single parameter analyzers or automatic titrators is its versatility. Not only can it be used for performing classical titrations, it can also automate the measurement of any species measurable by ion selective and ph electrodes. All of the operating procedures appear on the instrument s display in the form of easy-to-understand questions. Using the Model 960 improves precision and response time for electrode measurements. Because the analysis is automated, each step is carried out consistently time after time, operator to operator. Quick release fittings on the bottles make it easy to disconnect one bottle and connect another. There s no need to stock spare burettes for fast reagent changes. The dispenser is a rotary reciprocating pump. Unlike an automatic burette, the pump has no valves to switch for refilling. Also, there is no dead volume, making changing reagents easy and fast. Typical problems encountered when doing manual analyses are virtually eliminated, making ISE technology better suited for a busy day of testing. Higher levels of automation can be achieved by adding a Model 960AD Workstation as an auxiliary reagent dispenser. The Model 960AD is available in two versions for use with or without the AS3000 Series Autosampler. You can integrate up to eight workstations and an autosampler into one system for maximum versatility. For routine measurements, a short form printout is available. All pertinent GLP information is provided, including sample ID, electrode, time, date, and the result. The Model 960 can calculate results in units of measurement. In addition, diagnostic error messages may be printed to provide troubleshooting information such as excessive electrode drift or matrix effect. For method development a long form printout is available where raw data is printed, including volume of reagent, millivolts, time elapsed, a plot of the curves where appropriate and method parameters Description of Instruments 960 Titrator PLUS System, complete with EA 940 ph/ise Meter, Model 960 Titrator Plus Module. Includes: Base assembly, tower assembly, electrode holder, stirrer, two dispenser probes, anti-diffusion dispenser probe with six tips, tubing kit, calibration kit, cable (Models 960 and EA 940), reference tablet, two working solution bottles, two dip tubes and caps, line cords, and instruction manual. User selectable power requirement 100/115/0/240V ±10%. 960 Titrator PLUS Module (Module does not include EA 940). Includes: Base assembly, tower assembly, electrode holder, stirrer, two dispenser probes, one anti-diffusion dispenser probe with six tips, tubing kit, calibration kit, cable (Models 960 EA 940), reference tablet, three speed number note pads, two working solution bottles, two dip tubes and caps, PROM upgrade kit (to update software in EA 940), line cord, U.S. standard connector and instruction manual. User selectable power requirement 100/115/0/240 ±10%.

7 New Series Autosamplers Table of Contents Applications 960 AS AS3000 AS3000 Series Autosamplers - for use with the Model 960 TitratorPLUS Enhance Lab Productivity - automate Sample Preparation, Calibrations and Standardizations Increased Flexibility - interchangeable beaker racks and probe holders Three Rack Sizes - (45) 50 ml, (28) 150 ml or (18) 250 ml beakers Quality Control - up to five rinse beakers to clean the electrodes between analyses Accessories & Consumables The new AS3000 XYZ Autosamplers are designed for use with the Model 960 TitratorPLUS. Thermo Orion offers a choice in autosamplers with multiple rack configurations to provide flexibility for high sample throughput. Run titrations or other ph/ise techniques with the use of the new AS3000 series Autosampler overnight! Additionally, the probe arm assembly moves along the X, Y and Z-axes at speeds from 0 to 3.5 inches per second with full control of velocity and acceleration allowing for faster sampling and analyses. New Autosampler packages and upgrades from your existing Thermo Orion sample changer are available. Feature Description Feature Description Programmable Sample Access Area Foot Print Height to top of Z-axis Sample Capacity Model AS3050 Model AS3150 Model AS3250 Computer Interface Power Voltage 18.7 X 7.0 X 4.75 inches (W X D X H) 23.25X.5X15.75 inches (W X D X H) 59X37X40 cm 45, 50 ml glass or plastic beaker 28, 150 ml glass or plastic beaker 18, 250 ml glass or plastic beaker RS Vac, 50/60 Hz 50 ml beaker sold with autosampler 150 ml beaker sold with autosampler 250 ml beaker sold with autosampler Accuracy Agency Approvals Environmental Requirements Paint Color Polypropylene, Chemically resistant, 42 mm diameter Polypropylene, Chemically resistant, 57 mm diameter Polypropylene, Chemically resistant, 68 mm diameter ± 1.0 mm in all axes CE, UL, CSA 5 to 45 C and 20 to 80% Relative Humidity Carbide Black Description of Accessories AS3050 AS3150 AS A 96150A 96250A ASR050 ASR150 ASR250 ASB050 ASB150 ASB S Model AS3000 Autosampler, complete with 45-position rack, electrode holder, interface cable, line cord, pkg of (50) 50 ml plastic beakers and instruction manual. 115V/0V Model AS3000 Autosampler, complete with 28-position rack, electrode holder, interface cable, line cord, pkg of (50) 150 ml plastic beakers and instruction manual. 115V/0V Model AS3000 Autosampler, complete with 18-position rack, electrode holder, interface cable, line cord, pkg of (25) 250 ml plastic beakers and instruction manual. 115V/0V Model 960 with AutoSampler, 45-Position Rack Designed for 50 ml Beakers (Beakers Included) Model 960 with AutoSampler, 28-Position Rack Designed for 150 ml Beakers (Beakers Included) Model 960 with AutoSampler, 18-Position Rack Designed for 250 ml Beakers (Beakers Included) 45-Position Rack Designed for 50 ml Beakers 28-Position Rack Designed for 150 ml Beakers 18-Position Rack Designed for 250 ml Beakers Beakers, Plastic 50 ml, pkg of 50 Beakers, Plastic 150 ml, pkg of 50 (Replaces Cat No. 096S17) Beakers, Plastic 250 ml, pkg of 25 Beakers, Plastic 45 ml, pkg of 50

8 Fast QC Titrator Table of Contents Applications 960 AS Model 950 Economical Automatic Titrator - fits any budget! Automates - routine titrations can be done easily Modular Design the compact design allows flexibility and versatility Superior Features - incorporates premium ROSS ph electrode technology Printer Options - provide comprehensive record of results and methods Techniques Specifications Accessories & Consumables Electrodes & Solutions The Model 950 incorporates the superior features of the patented ROSS ph technology into an economical yet versatile potentiometric titrator. The Model 950 performs Acid/Base titrations, including non-aqueous samples, oxidation-reduction, precipitation and complexometric titrations using ion selective electrodes. Automate all routine manual color end-point titrations with the Model 950 preset end-point technique. The Model 950 preset technique can titrate to one or two preset ph or millivolt values to measure P & M alkalinity of water or acidity of carbonated beverages. The Model 950 first derivative technique offers titration to one or multiple inflection points for many analyses, for example: chloride in food ingredients, copper in a plating bath, or TAN and TBN of the petroleum products. The Titrant and the entire system can be standardized automatically against an accurately weighed known NIST or other national standards using the standardize system technique. This basic titrator is extremely simple to use; just press a single button to start the titration. Automatic ph calibration menu leads you to perform one or two point calibration. On-board memory stores up to 10 methods that can be recalled at the push of a button. Methods can be locked to safeguard accidental deletion! Unique to Thermo Orion titrators, the AssuredAccuracy feature allows the gravimetric calibration of the entire dispensing system, making it easy to meet ISO 9000 and GLP requirements. Simply add a second workstation to expand your Model 950 titration capabilities and enhance your lab s productivity Description of Instruments 950 FAST QC Titrator with printer, Includes workstation, control unit, printer, printer paper, ROSS Sure-Flow ph Combination electrode (8172BN), cables, tubing instructional manual and line cords, 110V 60Hz. 950 FAST QC Titrator with printer, Includes workstation, control unit, printer, printer paper, ROSS Sure-Flow ph Combination electrode (8172BN), cables, tubing instructional manual and line cords, 0V 60Hz. 950 FAST QC Titrator without line cord, Includes workstation, control unit, printer, printer paper, ROSS Sure-Flow ph Combination electrode (8172BN), cables, tubing instructional and manual. 950 FAST QC Titrator without printer, Includes workstation, control unit, ROSS Sure-Flow ph Combination electrode (8172BN), cables, tubing instructional manual and line cords, 110V 60Hz. 950 FAST QC Titrator without printer, Includes workstation, control unit, ROSS Sure-Flow ph Combination electrode (8172BN), cables, tubing instructional manual and line cords, 0V 60Hz. Note: To use with an external printer order 950DPU OR 950EPN splitter cables.

9 Ionalyzer System Table of Contents Applications 960 AS Model 930 Ion Measurement - made easier through automation Simple - self-calibrating one beaker analysis Workstation Design - reduces chemical usage and reagent handling KAP Analysis one Beaker Analysis! Customize - with any ionplus combination ion selective electrode Techniques Specifications Accessories & Consumables Electrodes & Solutions The Model 930 Ionalyzer System and ionplus electrodes provide fast, reliable ion measurement with an easy-to-use, precise analysis technique. The exclusive KAP Analysis techniques ensure dependable performance, even with the most difficult samples. Design features provide a saving in time and cost per analysis. Automated reagent handling reduces time spent preparing samples and produces less reagent waste. The Model 930 Ionalyzer workstation also holds electrodes and stirs the sample during analysis. Using advanced ionplus electrodes (with Sure-Flow references) measure even the dirtiest samples, without additional filtration or distillation steps. Save time and money measuring such species as cyanide in plating solutions and sulfide in pulping liquors. Customize to meet your specialized needs, calculate results in your choice of concentration units and report all results on the integrated or external printer. With dual channel inputs, you can add an additional workstation to expand your analysis capacity. Store up to ten different methods for maximum productivity. The Model 930 Ionalyzer also measures ph providing additional measurement choice. For example, the Model 930 is ideal for both ammonia and ph measurements in effluent. KAP Analysis techniques improve performance by adding small aliquots of a standard to the sample. This self-calibrating technique performs both electrode calibration and sample measurement in one beaker. KAP Analysis minimizes errors due to complexing agents or complicated sample backgrounds. Choose between single known addition, for simple measurements, or double or multiple known addition, for samples with complex backgrounds. Quickly measure compounds such as chloride in food in one beaker without hazardous metal titration. Verify analysis with spike recovery, automatically performed in the multiple known addition technique. Also automate other direct measurements with the ACCUread or serial calibration techniques, performing an entire multipoint calibration in one beaker. Providing calibration, measurement and validation of results automatically, the Model 930 Ionalyzer improves speed and accuracy, and lowers cost per analysis Description of Instruments 930 Ionalyzer with printer, Includes workstation, control unit, printer, printer paper, cables, tubing instructional manual and line cords, 110V 60Hz. 930 Ionalyzer with printer, Includes workstation, control unit, printer, printer paper, cables, tubing instructional manual and line cords, 0V 60Hz. 930 Ionalyzer without line cord, Includes workstation, control unit, printer, printer paper, cables, tubing instructional and manual. 930 Ionalyzer without printer, Includes workstation, control unit, cables, tubing instructional manual and line cords, 110V 60Hz. 930 Ionalyzer without printer, Includes workstation, control unit, cables, tubing instructional manual and line cords, 0V 60Hz. Note: To use with an external printer order 950DPU OR 950EPN splitter cables.

10 Techniques Table of Contents Applications 960 AS The chart below describes the various techniques available on Thermo Orion s titrators and dispensing workstations and when they are recommended. Description When Recommended Advantage Endpoint Analysis First Derivative (For Model 960, and Model 950) Second Derivative (For Model 960) Present Endpoint (For Model 960,950) Automated titration technique which calculates endpoints from the first derivative of the titration curve Similar to first derivative but, endpoints are calculated from second derivative Allows titration to proceed to one or two preset mv or ph values Routine potentiometric titrations Determine poorly defined and multiple endpoints When required by industry standards Eliminates false endpoint detection P& M alkalinity of water and wastewater Titrations with no clearly defined endpoint When required by industry standards Precision No ambiguity in location of endpoints Precision No interference from color or turbidity KAP Analysis Multiple Known Addition (For Model 960, and Model 930) Multiple Known Subtraction (For Model 960) Multiple Analate Addition (For Model 960) Serial Calibration (For Model 960, 930) Performs calibration and calculates sample concentration by adding aliquots of standard to sample Performs calibration and calculates sample concentration by adding aliquots of reagent which reacts with sample species Performs calibration and calculates sample concentration by adding aliquots of sample to a standard solution Generates calibration curve by adding aliquots of standard to a beaker of water and ISA Measure nontitratable species, i.e., NA +, K +, NO 3-, NH 3 Complex sample matrix More precision required than Standard calibration No stable standard solution for ion of interest, i.e., sulfide Use for direct read of ions (calibrate and read series of samples) Concentrated sample Viscous samples Low level measurements Checking electrode performance No need for independent calibration or recalibration Matrix effects minimized Recovery test performed with every sample Faster than conventional titration Uses less reagent than conventional titration Sample automatically diluted as part of analysis Sample can be added from automatic pipet Defines non-linear portion of calibration curve Eliminates need to prepare standards GAP Analysis Gran Function (For Model 960) Gran Predict (For Model 960) Similar to first derivative but Gran Functions applied to determine equivalence points Similar to Gran Function but looks at data on one side of equivalence point only Titrations with poor endpoint Titrations with two endpoints Titrations with asymmetric curves Slow reactions Speed required Low level titrations, i.e., Cl - Accuracy Speed Less reagent consumption Assist Analysis Standardize System (For Model 960) HELP Analysis (For Model 960) ph Read (For Model 960) Standardizes entire system (electrodes, electronics, dispenser, titrant) Recommends the best method by adding aliquots of reagent to sample and analyzing data For accurate ph measurements and direct ion read Highest system accuracy required When unsure of what technique or measurement parameters to use Automation of ph or direct ion read Can be used on autosampler One-step standardization of all system components Optimizes method Automation, accuracy

11 Specifications Table of Contents Applications 960 AS Model 960 Model 950 Model 930 Output mv Concentration ph Range Temperature Power Requirement: Voltage Frequency Titration Modes Methods Saved Display Variable Speed Stirring Paddle Input Dimensions: Height Width Depth Case: Splash and Chemical Resistant Environmental Requirements: 5 to 45 C and 5 to 85% relative humidity Autosampler Option Agency Approvals Ordering Information: 110 V 0 V Without Line Cord Without Printer 110 V Without Printer 0 V 960 Module EA 940: RS232; recorder; Karl Fischer: 4 RS232 ports for connection to EA 940, printer, computer and balance; one 15-pin parallel port to mv to to to C 110/120/0/240 VAC 50/60 Hz All 930 and 950 Options Second Derivative Titration Single Known Subtraction Double Known Subtraction Multiple Known Subtraction Multiple Analate Addition Gran Function Gran Predict Standardize System Help Analysis ph Read Up to Twenty Custom color vacuum fluorescent with 40 character prompt line Two BNC, two pin tip, dual banana jacks for PT-100 style ATC probe With Tower Yes CE (110V/0V) RS232, recorder, Karl Fischer to mv N/A to to C 9 VDC line converter for 110/120/0/240 VAC 50/60 Hz Preset ph Endpoint Preset mv Endpoint First Derivative Titration Up to Ten Custom color vacuum fluorescent with 17 character prompt line Two BNC, two pin tip, ground, ATC, power, RS232 Meter Dispenser No CE RS232, recorder to mv N/A to to C 9 VDC line converter for 110/120/0/240 VAC 50/60 Hz Single Known Addition Double Known Addition Multiple Known Addition Serial Calibration Up to Ten Custom color vacuum fluorescent with 17 character prompt line Two BNC, two pin tip, ground, ATC,power, RS232 Meter Dispenser No CE

12 Accessories and Consumables Table of Contents Applications 960 AS KF 0607CA 0607CI Description of Accessories Model 960KF Volumetric Karl Fischer Accessory. Provides the hardware for performing Karl Fisher Moisture Analysis on the Model 960 Titrator Plus System. Includes KF vessel with drain valve, vessel top, KF electrode (977900) and KF adapter, stirrer with long shaft (096019), glass desiccant, side arm stopper, stand, septum, Teflon vessel O-ring, plugs, and O-rings. Model 607 Multi-Channel Electrode Switchbox, complete with accessories Includes BNC connecting cable (060710), U.S. standard connecting cable (060711), grounding cable (0607), RS232 interface cable (060712), dust caps (060715), and 110 VAC line converter (020120) Utilize up to six electrodes, calibration values are stored when used with EA 940 or Model V (Use with cable for Model 960) Model 607 Multi-Channel Electrode Switchbox, complete with accessories Includes BNC connecting cable (060710), U.S. standard connecting cable (060711), grounding cable (0607), RS232 interface cable (060712), dust caps (060715), and 110 VAC line converter (020120) Utilize up to six electrodes, calibration values are stored when used with EA 940 or Model V (Use with cable for Model 960) Auxilary Dispenser with tower, complete with dispenser probes, tubing kit, interface cable, dispenser base electrode holder, stirrer, power cord, and instruction manual, 115/230 V. Auxilary Dispenser without tower for use with AS3000 Series Autosampler. Includes dispenser probes, tubing kit, interface cable, power cord, and instruction manual, 115/230 V. Description of Consumables Tubing Kit. Includes: tube and connector for working solution bottle to AUTOdispenser; tube and connectors for AUTOdispenser to dispenser probe. Dispenser Probe, pkg of 2 and roll of cleaning wire, pkg of 1. Anti-Diffusion Dispenser Probe, One dispenser probe with six replaceable tips. For low-level analyses or dense titrants. Stirrer to fit electrode tower, includes stirrer paddle. Stirrer Paddle to fit , pkg of 3. Dip Tube with sealable cap to fit working solution bottle, pkg of 6. Gas Absorption Cartridge fits top of working solution bottle. Absorbs carbon dioxide and moisture. Absorbent not included. AUTOdispenser Calibration Kit includes five sealable plastic vials, 8 ml capacity. Bottles 475 ml, amber glass, for working solution, pkg of 12. Req. Cat. No Bottles 475 ml, translucent plastic, for working solution, pkg of 12. Req. Cat. No Electrode Storage Bottle, pkg of 3. Description of Printers 0900A0 0900A1 0900A2 0GLP30 0GLP31 PRT300 PRT301 55PR40 55PR49 Model 900A Thermal Printer, for Models 950/930, 110V. Model 900A Thermal Printer, for Models 950/930, 0V. Model 900A Thermal Printer, for Models 950/930, No Adapter, 0V. Ink Based, GLP Printer for Model 960 includes instruction manual, 110 V. Ink Based, GLP Printer for Model 960 includes step-down transformer, instruction manual, 0 V. Ink based, dot matrix 40 column printer with line cord and paper (small foot print). To use with the 960 order 0GLP05 printer cable; for 950/930 order 950EPN printer cable, 110V. Ink based, dot matrix 40 column printer with line cord and paper (small foot print). To use with the 960 order 0GLP05 printer cable; for 950/930 order 950EPN printer cable, 0V. Wide Thermal Printer. To use with the 960 order 960DPU printer cable; for 950/930 order 950DPU printer cable, 115 V. Wide Thermal Printer. To use with the 960 order 960DPU printer cable; for 950/930 order 950DPU printer cable, 0 V. Continue to next page

13 Accessories and Consumables Table of Contents Applications 960 AS A4 0GLP07 55PR45 PRT302 0GLP08 0GLP10 0GLP A6 Description of Printer Consumables Printer Paper for Model 900A, pkg of 10. Printer Paper, 8 1/2 wide, pkg of 10 (Brother printer only). Printer Paper for the 55PR, pkg of 5 Printer Ribbon for PRT Printers Printer Cassette for use with GLP Printer, pkg of 10. (Brother printer only). Printer Ribbon for use with 0GLP02, 0GLP03, pkg of 1. Printer Ribbon, for use with 0GLP30 and 0GLP31, pkg of 1. Printer Battery, for Model 900A, pkg of 1. Description of Cables 0960AE 096ZXA 096SRT 096G PC GLP05 960DPU 950DPU 950EPN Model 960 to Mettler AE Series Balance Interface Cable. American Scientific Products Z Series or Fisher Scientific XA Series, Balance Interface Cable. Model 960 to Thermo Orion Analytical Balance, also 960 to Sartorius MP8, Sartorius A200S, or Ohaus G160D Balance Interface Cable. Model 960 to Ohaus G120 Balance Interface Cable. IBM PC to Model 960 and EA 940 Interface Cable. Cable Connects Model 960 to 607 Switchbox. Model 960 GLP Printer and EA940 Meter Interface Cable 60 long. Model 960 Cable to 55PR40 & 55PR49 printers. Model 950 and 930 splitter cable to 55PR40 & 55PR49 printers. Model 950 and 930 splitter cable to 0GLP30, 0GLP31, PRT300 & PRT301 printers. RS232 cable from Model 940 to Model 960. Description of EPROMS and Software 4753-A A01 DTPL20 DTPL DTPL 5.6 Rev. PROM Upgrade Kit Includes five PROMS, installation and instruction sheet. 6.1 Rev. PROM Upgrade Kit Includes five PROMS, installation and instruction sheet. (Required for use with the AS3000). Data PLUS2 is an easy to use, menu-driven software (DOS based operating system) designed to collect, sort, format and print all of your titration data from the Model 960 only. Includes only 5.25 ; 3.5 software diskettes and instruction manual. Data PLUS2 Includes 5.25 ; 3.5 diskettes, instruction manual, 0960PC interface cable, and adapter. Data PLUS2 Upgrade Kit Includes 5.25 ; 3.5 diskettes, instruction manual, 0960PC interface cable, adapter, and Rev. 6.1 EPROMS.

14 Electrodes and Solutions Table of Contents Applications 960 AS ATC Probes Epoxy Body ATC probe for use with EA 940 Glass Body ATC probe for use with EA BN Ammonia Analysis Ammonia Combination Gas-sensing, epoxy body electrode with BNC connector. Complete with 2 pkgs of 20 loose membranes, cap for loose membranes, filling solution, and accessories Internal Fill Solution, for 9512 Electrode, 60 ml bottle Loose membranes for 9512 Electrode, pkg of 20 Ammonia Standard (0.1 M NH 4 Cl), 475 ml bottle Ammonia ph adjusting ISA with color indicator, 475 ml bottle 9320BN 9720BN Calcium Analysis Calcium, Liquid membrane, PVC body electrode with two sensing modules and BNC connector. Use with single junction reference electrode. Calcium ionplus Sure-Flow Combination Epoxy body electrode with replaceable sensing module and BNC connector. Calcium Activity Standard (0.1 M CaCl 2 ), 475 ml bottle Replacement sensing module for Model Electrode Calcium Ionic Strength Adjuster (ISA), 475 ml bottle Calcium/Magnesium Reagent, 475 ml bottle Replacement Sensing Module for Model Calcium ionplus electrode Optimum Results A Filling Solution for Calcium electrode 9617BN BN SC 9781SC Chloride Analysis Chloride ionplus Sure-Flow Combination Epoxy body electrode with BNC connector. Optimum Results B Filling Solution for ionplus combination electrode, five 60 ml bottles Chloride Solid-state, epoxy body electrode with BNC connector. Use with Double Junction reference electrode Chloride Ionic Strength Adjuster, 475 ml bottle Chloride Activity Standard (0.1M NaCl), 475 ml bottle Chloride Activity Standard (1,000 ppm as Cl -), 475 ml bottle Combination Silver Billet Electrode for use in silver as well as chloride titration Silver Billet Half-Cell for silver as well as chloride titration, use with Double Junction reference electrode 9770BN Chlorine Analysis Residual Chlorine Combination Solid-state, epoxy body electrode with BNC connector Iodide Reagent for residual Chlorine electrode Acid Reagent for residual Chlorine electrode 9429BN BN Cupric (Copper) Analysis Cupric Solid-state, epoxy body half-cell electrode with BNC connector. Use with Double Junction reference electrode Cupric Activity Standard 0.1M Cu(NO 3 ) 2, 475 ml bottle. Cupric ionplus Sure-Flow Combination Epoxy body electrode with BNC Connector. Optimum Results D Filling Solution for ionplus combination electrodes BN BN Fluoride Analysis Optimum Results A Filling Solution for ionplus combination electrodes. Fluoride Solid-state, epoxy body half-cell electrode with BNC connector. Use with single junction reference electrode Fluoride Activity Standard (0.1M NaF), 475 ml bottle TISAB II - Total Ionic Strength Adjustor, 1 gallon TISAB II - Total Ionic Strength Adjustor, 4 x 1 gallon TISAB III - Total Ionic Strength Adjustor (concentrated), 475 ml bottle Fluoride ionplus Sure-Flow Solid-state Combination, epoxy body electrode with BNC connector Continue to next page

15 Electrodes and Solutions Table of Contents Applications 960 AS BN 9682BN Lead Analysis Lead Activity Standard [0.1M Pb(ClO4)2], 475 ml bottle Lead Solid-state Combination, epoxy body half-cell electrode with BNC connector. Use with Double Junction reference electrode Lead ionplus Sure-Flow Combination Epoxy body electrode with BNC connector. Optimum Results B Filling Solution for Lead electrode BN 9707BN Nitrate Analysis Nitrate Activity Standard (0.1M), 475 ml bottle. Replacement Sensing Module for 9307 electrode, pkg of 3. Nitrate Interference Suppresser, 475 ml bottle. Nitrate Liquid membrane PVC body electrode with two sensing modules and BNC connector. Use with Double Junction reference electrode. Nitrate ionplus Sure-Flow Combination Epoxy body electrode with BNC connector. Optimum Results F Filling Solution for ionplus series. Nitrate Ionic Strength Adjuster (ISA), 475 ml bottle. Replacement Sensing Module for Model ionplus combination electrode. 8102BN 8104BN BN 8165BN 9102BN 9104BN 9166SC 9172BN ph Analysis ROSS Combination, glass ph electrode with BNC connector. ROSS Glass body, rugged bulb, combination ph electrode with connector, general-purpose use. ROSS Epoxy body with bulb gaurd combination ph electrode with BNC connector, rugged general purpose use. ROSS Sure-Flow Combination glass body ph electrode with BNC connector. Recommended for all sample types, especially dirty, viscous-type samples. ROSS Sure-Flow Combination, epoxy body ph electrode with BNC connector. Recommended for soil samples, viscous samples, field, and plant use. Glass body, Ag/AgCl internal, combination ph electrode with BNC connector. Recommended for general purpose and precision measurements. Easy-to-clean, hard-nose bulb Glass body, combination ph electrode, for routine measurements, Ag/AgCl internal with BNC connector. ph Electrode for use with most titrators, use in thick, viscous samples. Glass body Ag/AgCl Sure-Flow Combination ph electrode with BNC connector. For ph determinations in hydrofluoric or other acid fluorides. ph 4.01 buffer (color-coded pink), 475 ml bottle. ph 5.00 buffer (color-coded orange), 475 ml bottle. ph 7.00 buffer (color-coded yellow), 475 ml bottle. ph buffer (color-coded blue), 475 ml bottle. ph All in One buffer kit includes one pint bottle of the 4.01, 7.00, buffers, electrode storage solution, 475 ml and electrode storage bottle BN 9719BN Potassium Analysis 0.1M KCl Standard, 475 ml bottle. Replacement Sensing Module for 9319 Electrode. Ionic Strength Adjuster, 475 ml bottle. Potassium, liquid membrane PVC body electrode with two sensing modules and BNC connector. Use with Double Junction reference electrode. Potassium ionplus Sure-Flow Combination Epoxy body electrode, with BNC connector. Optimum Results E Filling Solution for Potassium electrode. Replacement Sensing Module for Model ionplus combination electrode. Continue to next page

16 Electrodes and Solutions Table of Contents Applications 960 AS Reference Electrodes ROSS Sure-Flow Reference Electrode Glass body with pin-tip connector. For all sample types. Use with ROSS Model 8101 ph Sensing Half Cell and ROSS Model 8411 Sodium Sensing Half Cell. ROSS General purpose reference, pin-tip connector for use with ROSS Model 8101 ph Sensing Half Cell. 3M KCl filling solution, used with all ROSS ph Electrodes, five 60 ml bottles. Single Junction Epoxy Body, Ag/AgCl internal, easy-to-clean sleeve junction. The recommended reference electrode for precise ph measurement and for many ISE measurements. Shipped with Filling Solution. Double junction, epoxy body, easy-to-clean sleeve junction. Recommended for all ISE measurements. Shipped with two filling solutions, and , uses a variety of filling solutions BN 8611BN Sodium Analysis Sodium Standard Solution, three 475 ml bottles (1M NaCl with ISA), one 475 ml Sodium ISA, and instruction sheet ROSS Sodium Half-cell, glass body electrode with BNC connector, includes one bottle each of Sodium Reconditioning Solution (841113), Sodium ISA (841111), Sodium Known Addition Standard (841109), Sodium Standard, 1,000 ppm (841108), Reference Electrode Filling Solution (900010), instruction manual, and application sheet. Use with ROSS Sure-Flow Reference Electrode, ROSS Sure-Flow Sodium Combination glass electrode with BNC connector Includes the same accessories as 8411BN Ionic Strength Adjuster, 475 ml bottle Internal Fill Solution (2M NH 4 Cl) For use with 8003 or 9002 Reference Electrode when used with 8411 Sodium Electrode, and for use with 8611 Combination Sodium Electrode, (five 50 ml bottles). Recommended fill solution for sodium measurements above 0.2 ppm (10-5 M) Known Addition Standard (1,000 ppm Na+ for sodium analysis ± M Na+ with ISA) 475 ml bottle Sodium Electrode Storage Solution, 475 ml bottle Reconditioning Solution for sodium electrodes, 9811, 8411 and BN Surfactant Analysis Surfactant Electrode with BNC connector, includes Hyamine 16, 0.05M (475 ml), Sodium Lauryl Sulfate standard, 0.01M (60 ml), Sample Additive (475 ml), and instruction manual. Use with Double Junction reference electrode. Hyamine 16 titrant, 0.05M, 475 ml bottle Sodium Lauryl Sulfate, 0.01M (SLS) standard, 60 ml Sample Additive, diluted Triton X-100, 475 ml Non-Ionic Surfactant Reagent, 475 ml bottle Non-Ionic Surfactant Titrant, 475 ml bottle SC 9416BN BN SC 9781SC 9778SC Special Tests and Analysis Internal Fill Solution, for 9678 Electrode, Five 60 ml bottles. Use for samples with total ionic strength of less than 0.2 M Internal Fill Solution, for 9678 Electrode, Five 60 ml bottles. Use for samples with total ionic strength of greater than 0.2 M Ag/AgCl Glass Combination Electrode for many titrators, or vessel requiring standard tapered joint Silver/Sulfide Solid-state, epoxy body electrode BNC connector. Use with Double Junction reference electrode Sulfate Standard (0.1M Na 2 SO 4 ), 475 ml bottle. Alkaline Reagent (10M NaOH), 475 ml bottle. Redox Sure-Flow Combination, easy-to-clean junction, epoxy body electrode with BNC connector. Recommended for dirty, viscous, or oily samples, sample fill solution included. Iodide Reagent, five 60 ml bottles. Acid Reagent, 475 ml bottle Glass Karl Fischer Double Platinum Electrode (KF adapter required) Karl Fischer Adapter Combination Silver Billet Electrode for use in silver as well as chloride titration Silver Billet Half-Cell for silver as well as chloride titration Glass Combination Redox/ORP for Redox titrations

17 Blending Volumetric Karl Fischer Titrator Table of Contents Applications Turbo2 AF8 AF7/AF7LC 18 TURBO2 Sample Blending at 7500 rpm - complete moisture extraction from sample into solution with little or no sample preparation 50 ppm to 100% Moisture Measurement Range - handle wide range of sample moisture levels with one instrument Large 750 ml Titration Vessel - allows multiple sample analyses to be run using same solvent(s) SEARCH Titration Mode - find the optimum blending time for new samples with unknown moisture levels High Precision Titrant Delivery System - uninterrupted titrant delivery system with peristaltic pump and internal calibration menu for validation Water Jacket Vessel - use with circulating bath to help warm solvent, enhances moisture extraction in difficult samples Specifications Combine the standard technique of Karl Fischer moisture analysis with a high speed blender revolving at 7500 rpm and you have the TURBO2. This technique eliminates the problem of moisture loss or gain associated with standard sample preparation procedures. When linked to an analytical balance, the TURB02 becomes a semiautomatic analyzer capable of handling a continuous throughput of samples. To accommodate a wide range of materials, a large access port in the vessel top plate permits the introduction of samples up to 28 mm (1-1/8 ) in diameter. In addition, the end-point detection electrode is built into the vessel sidewall, giving it complete protection from the movement of solids during blending. Electronic monitors and safety interlocks ensure that the user is protected from unsafe instrument operation. The TURBO2 is an excellent way to analyze moisture in pharmaceutical, confectionery or solid samples that typically require a lot of sample preparation. Sample preparation has been a great source of error in moisture determination in pharmaceutical products such as tablets, gelcaps or caplets. The TURB02 will blend the sample, extract, and analyze the moisture in the same vessel then printout a report containing results, methods & statistics for FDA compliance. Simply, weigh and introduce any solid or semi-solid sample such as tablets, pills, candy, or gum into the vessel and obtain an accurate moisture result in minutes Description of Instruments TURBO2 Blending Volumetric Karl Fischer Titrator Complete with built-in printer, 750 ml titration vessel, dual RS-232 interface, line cord, spare silicone pump tubing and extra roll of printer paper, VAC, Hz TURBO2 Blending Volumetric Karl Fischer Titrator Complete with built-in printer, 750 ml titration vessel, dual RS-232 interface, line cord, spare silicone pump tubing and extra roll of printer paper, 0V Description of Accessories and Consumables TURBO2 Drying Tubes, for protection against moisture ingress emission, pkg of 3 TURBO2 Printer Paper Rolls, pkg of 3 TURBO2 750 ml Glass Titration Vessel TURBO2 Platinum End-Point Detection Electrode TURBO2 Blender Drive Belt TURBO2 Water-Jacketed Titration Vessel TURBO2 Silicone Pump Tubing, 1.0 mm bore, pkg of 5 TURBO2 Marprene Pump Tubing, 1.0 mm bore, pkg of 5 TURBO2 Shaft Seal Replacement Kit TURBO2Teflon Stopper and Teflon Encapsulated O-Ring TURBO2 3.5 Ft Extension Cable From Console to Titration Vessel TURBO2 Maintenance and Consumables Kit

18 Volumetric Karl Fischer Titrator Table of Contents Applications Turbo2 AF8 AF7/AF7LC 19 Model AF8 Broad Operating Range - 50 ppm to 100% moisture. Special Reagent Delivery - stepper motor-controlled, high precision peristaltic pump. Unique Glass-to-Glass Vessel - sealing design ensures there is always a moisture tight seal to the reaction vessel, no rubber gaskets that can be attacked by organic solvents. RS232 Interfaces - connection with balances and computers. Built-in Thermal Printer - hard copy printout provides a comprehensive record of results, method, and statistics. Visible Bar Graph easily indicates vessel solution moisture status from across the laboratory. Specifications Accessories & Consumables The Model AF8 sets international standards for rapid determination of moisture in a wide range of materials. Push button convenience with the highest accuracy and precision are all designed into the Model AF8. Operating reagent, solvent and waste containers are plumbed directly to the titration vessel, creating a fully sealed chemical handling system. The Model AF8 s peristaltic pump unique continuous titrant dispensing system eliminates the inconvenience of refilling burettes. The modular design has the advantage of keeping corrosive chemicals away from the electronics, providing maximum long-term reliability. A top-entry opening of the vessel can be opened to the width of a syringe needle for liquids or wider to accommodate solid samples up to 23 mm across. The complete titration procedure from the introduction of a sample to the presentation of results is carried out by a microprocessor-control led routine, which can be pre-programmed by the operator to optimize conditions best suited to the particular material being analyzed. Calibration confidence is assured because the standardization routine automatically rejects flawed results. Statistics can be performed on up to 25 sequential samples and may calculate the mean moisture level, standard deviation, the coefficient of variance and the number of samples analyzed. An extract time can be programmed to occur between adding the sample to the vessel and carrying out the titration. There is a choice of two modes for sample analysis. The more common option is sample only, where miscible liquids or soluble solids are titrated directly after addition to the vessel. The background mode is most useful for insoluble solids where a delayed titration is necessary to fully extract the enclosed moisture Description of Instruments Model AF8 Karl Fischer Volumetric Titrator Complete with built-in printer, large & small titration vessels, small vessel adaptor, dual RS-232 interface, large & small stir bars, reagent & waste bottles, spare silicone pump tubing and extra roll of printer paper VAC, Hz Model AF8 Karl Fischer Volumetric Titrator Complete with built-in printer, large & small titration vessels, small vessel adaptor, dual RS-232 interface, large & small stir bars, reagent & waste bottles, spare silicone pump tubing and extra roll of printer paper VAC, Hz Description of Accessories AF8 Drying Tubes, for protection against moisture ingress and sulfur dioxide emission, pkg of 3 (Also fits AF5 KF Titrator) AF8 Small Titration Vessel, 100 ml capacity (Also fits AF5 KF Titrator) AF8 Large Titration Vessel. 275 ml capacity (Also fits AF5 KF Titrator) AF8 Silicone Pump Tubing, 1.0 mm bore, pkg of 5 AF8 Marprene Pump Tubing, 1.0 mm bore, pkg of 5 AF8 Printer Paper rolls, pkg of 3 AF8 Platinum Electrode Module for titration end-point and solution level detection AF8 Maintenance and Consumables Kit AF8 3.5 Ft Extension Cable From Console to Titration Vessel

19 Coulometric Karl Fischer Titrator Table of Contents Applications Turbo2 AF8 AF7/AF7LC 20 Model AF7 & AF7LC Fastest Coulometric Titrator in the Industry - 20,000 micrograms (20 mg) of water titrated per minute - (AF7, high current mode) Completely Sealed Chemical Handling System - integral pump controlled from keypad, easy, safe replenishment of reagents without opening vessel to environmental humidity (AF7) Instrument monitoring of anolyte/catholyte life, detecting and current generating electrodes - no need for operator monitoring (AF7 & AF7LC) Ion-permeable membrane separating anode and cathode chambers - eliminates the problem of clogged ceramic disks (AF7 & AF7LC) User-prompted methods with simple YES/NO or numeric data entry - up to three methods stored in memory - (AF7 & AF7LC) Built-in GLPdoc printer - provides comprehensive record of results, methods and statistics (AF7 & AF7LC) Model AF7 Description of Instruments Accessories & Cables Accessories & Consumables Specifications Model AF7LC Utilizing the extremely accurate technique of coulometric iodine generation, Thermo Orion coulometric titrators take moisture measurement to new limits of performance within a wide measuring range of 1 ppm to 100% H 2 O. The Model AF7 is a universal titrator for measuring both high and low moisture, while the Model AF7LC is specifically designed for optimum performance at low moisture levels. These two titrators make coulometric titrations a routine measurement technique, giving the user reliable results with unmatched speed and accuracy. The AF7 is the universal answer for the widest range of moisture analyses, offering coulometric accuracy and precision at volumetric titrator speed. You can even use the same sample size as you would for a volumetric titration. The AF7 s flexibility is reflected in its ability to perform coulometric titrations at both low and high currents. The AF7 titration vessel has exceptionally large-area platinum electrodes which, when used with high conductivity reagents, provides the current necessary to operate at the titration rate of 20 mg per minute analysis of water, the typical rate of volumetric titrators. Reagent handling (AF7), titration control and auxiliary commands are clearly defined on the keypad zone. The AF7LC performs sample analyses in the 10 ppm moisture range routinely and can operate at 1 ppm with CV s of 0.3%. It is an absolute method, which eliminates the need for calibration of reagents. Instrument set-up and titrations are simple to perform - just press the YES/NO keys or enter numeric variables in response to automatically generated questions on the 2 x 20 character liquid crystal display. Each entry is monitored, out-of-range entries are rejected and the acceptable range is displayed. The ability to program and store up to three titration methods - eliminates the need to re-enter analysis parameters each time the instrument is turned on. Titrations are fully automatic with continuous indication of their progress. The rate of titration and accumulated water analyzed are shown on the display and are regularly updated. The moisture status in the vessel is continuously presented on a bar graph display. Suspect results are flagged and, if requested, can be deleted from the final statistical calculations. Interfaces directly with a compatible analytical balance; making it possible to semi-automate the sample handling process, thus eliminating weight entry errors. The AF7LC vessel is compact and is specifically designed for repetitive sample analysis at low moisture concentrations. The use of ground glass joints completely eliminates moisture ingress, permitting the user to produce excellent CV s when working at or near detection limits.