Littelfuse, Inc. - Supplier Environmental, Health and Safety (EHS) Specification P
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1 Littelfuse, Inc. - Supplier Environmental, Health and Safety (EHS) Specification P RELESE REVISION DESCRIPTION OF CHNGE ORIGINTOR DTE Final Version D. Untiedt 5/19/06 B Updated to include recent changes in the RoHS Directive. dded RECH requirements.. Cesista 7/5/13 1
2 Table of Contents 1 Introduction Page(s) Purpose 3 Scope 3 Supplier Responsibilities 3 Definitions 3 2 Specifications Compliance with Regulatory Requirements and EHS Management Systems 4 Equipment Safety Requirements 4 Restricted/Prohibited Materials 4 Packaging Requirements 4 Reporting Requirements for Restricted/Prohibited Materials 4 Health & Safety Reporting Requirements 5 Verification of Compliance 5 Corrective ction Process for Non-compliances 5 3 ppendices ppendix LF Environmental, Health & Safety Policy 6 ppendix B List of Banned and Restricted Substances 7 ppendix C - IPC Form Material Composition Declaration
3 1 Introduction Purpose This specification provides general requirements to suppliers regarding Littefuse Inc s EHS specification with regard to regulatory compliance, EHS management systems, banned and restricted substances, packaging, and product environmental content reporting. 1.2 Scope This standard applies to all equipment,, parts, components, packaging, or products supplied to Littelfuse, Inc. 1.3 Supplier Responsibilities It is the responsibility of all suppliers to comply with the requirements listed in this standard. 1.4 Definitions Homogeneous material - material that is of uniform composition throughout and that cannot be mechanically disjointed into different. Examples of " " would be individual types of plastics, ceramics, glass, metals, alloys, paper, board, resins and coatings. The term mechanically disjointed means that the can be, in principle, separated by a mechanical action such as unscrewing, cutting, crushing, grinding and abrasive processes. Materials Chemical compounds and formulated substances that are supplied for the production of parts. Examples of are: plastics/ resins, metals, coatings, paint, adhesives, etc. Parts Mechanical parts, electrical devices, or assembles. Substance Chemical elements and their compounds. Substance is either a material or a constituent of a material. Substance is not a constituent of a component or product. Each Substance will have a unique CS (Chemical bstractive Service) identifier assigned to it. Supplier Material Declaration material declaration is a declaration that discloses all (100%) of the that are found in the supplied material/ parts and all (100%) of the substances that are contained in those. ll or substances that are intentionally added, or not intentionally added must be disclosed on the material declaration. 3
4 Material Safety Data Sheet (MSDS) Material Safety Data Sheet (MSDS) is a document that contains information on the potential hazards (health, fire, reactivity and environmental) of the chemical and how to work safely with the chemical. 2 Specifications Regulatory Compliance and EHS Management Systems ll Littelfuse Inc. suppliers shall comply with all applicable EHS laws and regulations in the countries in which they operate, and provide services and products. t a minimum, ll Littelfuse Inc. suppliers shall implement an EHS management system that is compliant with the ISO and OHSS standards. Equipment Specifications ll new, refurbished or leased equipment supplied to Littelfuse, Inc., shall comply with section 3 of Littelfuse New Equipment Specifications. Banned and Restricted Substances ny substance identified in ppendix B that is used in any, parts, components and products supplied to Littelfuse, Inc. shall not exceed the specified threshold limits except where exemptions are noted and declared. Packaging Requirements The specifications in this section pertain to all packaging purchased by or on the behalf of Littelfuse, Inc. TBLE 1 List of Banned and Restricted Packaging Materials Substance Threshold Limit Exemptions Ozone depleting substances (Class I & Class II CFC's and HCFC's) Not Present None Heavy Metals - Cadmium, Chromium VI, Lead and Mercury Compounds 100 ppm (sum of incidental concentrations) None Polyvinyl Chloride and other Halogenated plastics or polymers Not Present None Expanded polystyrene (EPS) foam Not Present None Reporting Requirements for Banned and Restricted Substances ll Littelfuse, Inc. suppliers shall complete a Supplier Material Declaration for all, parts, components, packaging and products supplied to Littelfuse, Inc. This level of disclosure is required for Littelfuse, Inc. to meet the requirements of 4
5 Directive 2011/65/EU, WEEE, as well as our customer requirements. The Supplier Material Declaration shall be submitted at the Homogeneous Material Level using Form IPC , Distribute, Class 6 as identified in ppendix C. This form shall be completed upon initial delivery of products or. Suppliers shall be required to resubmit the Supplier Material Declaration if any information previously reported has changed or if new information becomes available to make the declaration more accurate. Based on industry requirements, additional reporting, such as a 3 rd party test report conducted according to ISO/IEC or a material declaration such those specified by IMDS International Material Data System, may be required. Health & Safety Reporting Requirements ll Littelfuse, Inc. suppliers shall submit a Material Safety Data Sheet (MSDS) for all, parts, components, packaging and products supplied to Littelfuse, Inc. MSDS s shall be submitted upon initial delivery of products or and when any revisions have occurred to the MSDS. Supplier Verification of Compliance Upon request by Littelfuse, Inc. the supplier shall provide documentation verifying compliance of, parts, components, packaging or products using analytical testing or other suitable means approved by Littelfuse, Inc. (Example: 3 rd party test report conducted according to ISO/IEC 62321) Corrective ction Process for Non-compliances Once a non-compliance has been found, follow P Supplier Rejects and Corrective ction Resolution procedure to initiate a supplier corrective action request. 5
6 ppendix Littelfuse Environmental, Health & Safety Policy 6
7 ppendix B List of Banned and Restricted Substances Substance/ Category CS #/ EC # 1,2,3 Trichlorobenzene ,2,4 Trichlorobenzene ,3,5 Trichlorobenzene Ethoxyethanol Methoxyethanol ,4-Dinitrotoluene ,4'- Diaminodiphenylmetha ne (MD) 5-tert-butyl-2,4,6- trinitro-m-xylene (musk xylene) crylamide lkanes, C10-13, chloro (Short Chain Chlorinated Paraffins) mmonium dichromate Threshold Level (Reporting level) LF Internal Limit Reference Regulation/ Standard or Customer Requirement 7
8 Substance/ Category CS #/ EC # nthracene nthracene oil nthracene oil, anthracene paste nthracene oil, anthracene paste, anthracene fraction nthracene oil, anthracene paste,distn. lights nthracene oil, anthracene-low liphatic CHCs See nnex Threshold Level (Reporting level) (Total)/ Intentionally added ntimony trioxide sbestos See nnex 0.1 (Total)/ Intentionally added LF Internal Limit Reference Regulation/ Standard or Customer Requirement EU 76/769/EEC ChemRRV Joint Industry Guide (JIG) 101 NNEX XVII of RECH Regulation (EC) No ; 76/769/EEC, Marketing and Use of Dangerous Substances and amendments: (83/478/EEC; 85/610/EEC; 87/217/EEC; 91/659/EEC; 99/77/EEC). United States: Toxic Substances Control ct (restricts new uses); Occupational Safety and Health ct (29 CFR ). ChemRRV 8
9 Substance/ Category zocolorants CS #/ EC # See nnex Beryllium oxide Benzyl butyl phthalate (BBP) Bis (2-ethylhexyl) phthalate Boric acid Brominated flame retardants (other than PBBs,PBDEs, or HBCDD) CS# EC# CS# CS# & EC# & See nnex Bromine Cadmium/cadmium compounds See nnex Chlorine Threshold Level (Reporting level) Intentionally added (1000 ppm) of the product (1000 ppm) of the product (1000 ppm) of the product (1000 ppm) of plastic material 900 ppm or 0.09% 0.01% by weight (100 ppm) of % by weight (5 ppm) of battery 900 ppm or 0.09% LF Internal Limit 800 ppm or 0.08% 800 ppm or 0.08% 80 ppm or 0.08% 800 ppm or 0.08% Reference Regulation/ Standard or Customer Requirement 76/769/EEC, Marketing and Use of Dangerous Substances and amendments: (2002/61/EC; 2003/03/EEC). DIGITLEUROPE 3/CECED/ e 4/ EER guidance rticle 33 and 7.2 of RECH Regulation (EC) No (Candidate list of SVHC for authorization ) rticle 33 and 7.2 of RECH rticle 33 and 7.2 of RECH Regulation (EC) No (Candidate list of SVHC for authorization ) DIGITLEUROPE 3/CECED/ e 4/ EER guidance IPC-4101 and IEC The International Electrochemical Commission s (IEC) Definition of Halogen-Free (IEC :2003) NNEX XVII of RECH Regulation (EC) No ; 2002/95/EC and 2005/618/EC China MII Methods; Korea RoHS; Japan J-MOSS; US/C SB-20/50 Swiss Ordinance on Reduction of Risk from Chemical Products; EU Directive 2006/66/EC 5.4 The International Electrochemical Commission s (IEC) Definition of Halogen-Free 9
10 Substance/ Category CS #/ EC # Threshold Level (Reporting level) LF Internal Limit Reference Regulation/ Standard or Customer Requirement (IEC :2003) Chromic acid Chromium VI compounds See nnex Cobalt(II) carbonate Cobalt(II) diacetate Cobalt dichloride CS# EC# Cobalt(II) dinitrate Cobalt(II) sulphate Diarsenic pentoxide Diarsenic trioxide CS# EC# CS# EC# Dichromic acid (1000 ppm) of (1000 ppm) of the product (1000 ppm) of the product (1000 ppm) of the product 800 ppm or 0.08% EU Directive 2002/95/EC and 2005/618/EC; NNEX XVII of RECH Regulation (EC) No ; China MII Methods; Korea RoHS; Japan J-MOSS; US/C SB-20/50 rticle 33 and 7.2 of RECH Regulation (EC) No (Candidate list of SVHC for authorization ) rticle 33 and 7.2 of RECH Regulation (EC) No (Candidate list of SVHC for authorization ) rticle 33 and 7.2 of RECH Regulation (EC) No (Candidate list of SVHC for authorization ) 10
11 Substance/ Category Dibutyl phthalate (DBP) Bis (2- ethylhexyl)phthalate (DEHP) Di-isobutyl phthalate (DIBP) Di-isodecycl phthalate (DIDP) Diisononyl phthalate (DINP) Di-n-octyl phthalate (DNOP) Dibutyltin (DBT) compounds Dioctyltin (DOT) compounds CS #/ EC # CS# EC# CS# EC# CS# & EC # & CS# & EC# & CS # EC# See nnex See nnex Dimethyl fumarate Threshold Level (Reporting level) (1000 ppm) of the product (1000 ppm) of the product (1000 ppm) of the product (1000 ppm) of the product (1000 ppm) of the product (1000 ppm) of the product (1000 ppm) of tin in a material (1000 ppm) of tin in a material % by weight (0.1 ppm) in a material LF Internal Limit Reference Regulation/ Standard or Customer Requirement rticle 33 and 7.2 of RECH Regulation (EC) No (Candidate list of SVHC for authorization ) rticle 33 and 7.2 of RECH Regulation (EC) No (Candidate list of SVHC for authorization ) rticle 33 and 7.2 of RECH Regulation (EC) No (Candidate list of SVHC for authorization ) rticle 33 and 7.2 of RECH Regulation (EC) No (Candidate list of SVHC for authorization ) rticle 33 and 7.2 of RECH Regulation (EC) No (Candidate list of SVHC for authorization ) rticle 33 and 7.2 of RECH Regulation (EC) No (Candidate list of SVHC for authorization ) COMMISSION DECISION 2009/425/EC COMMISSION DECISION 2009/425/EC COMMISSION DECISION 2009/251/EC 11
12 Substance/ Category Disodium tetraborate, anhydrous Fluorinated greenhouse gases (PFC, SF6, HFC) CS #/ EC # See nnex Formaldehyde Hexabromocyclododec ane (HBCDD) and all major diastereoisomers Lead/lead compounds Lead chromate Lead chromate molybdate sulphate red (C.I. Pigment Red 104) Lead sulfochromate yellow (C.I. Pigment Yellow 34) Mercury/mercury compounds See nnex See nnex CS# EC# CS# EC# CS# EC# See nnex Threshold Level (Reporting level) (1000 ppm) of the product Intentionally added Intentionally added (1000 ppm) of the product (1000 ppm) of (1000 ppm) of the product of the product Intentionally added or (1 000 ppm) at material LF Internal Limit 800 ppm or 0.08% 800 ppm or 0.08% 800 ppm or 0.08% Reference Regulation/ Standard or Customer Requirement EU Reg. No. 842/2006 US/C CRB Rule rticle 33 and 7.2 of RECH Regulation (EC) No (Candidate list of SVHC for authorization ) EU Directive 2002/95/EC and 2005/618/EC; NNEX XVII of RECH Regulation (EC) No ; China MII Methods; Korea RoHS; Japan J-MOSS; US/C SB-20/50 rticle 33 and 7.2 of RECH Regulation (EC) No (Candidate list of SVHC for authorization ) Regulation (EC) No (Candidate list of SVHC for authorization ) Regulation (EC) No (Candidate list of SVHC for authorization ) NNEX XVII of RECH Regulation (EC) No ; EU Directives 2002/95/EC and 2005/618/EC; China MII Methods; Korea RoHS; Japan J-MOSS; US/C SB-20/50;Vermont act relating to comprehensive management of exposure to mercury; Rhode Island General Laws and amendment of 2007; Louisiana Mercury Risk 12
13 Substance/ Category CS #/ EC # Threshold Level (Reporting level) LF Internal Limit Reference Regulation/ Standard or Customer Requirement Reduction ct Nickel Ozone Depleting Substances Perchlorates Perfluorooctane sulfonate (PFOS) Pitch, coal tar, high temp. Phenol,2-(2H- benzotriazol-2-yl)-4,6- bis(1,1-dimethylethyl) 1 Polybrominated biphenyls (PBBs) See nnex See nnex See nnex See nnex Intentionally added; where prolonged skin contact is expected Intentionally added % by weight (0.006 ppm) of the product Intentionally added Intentionally added (1 000 ppm) in material 800 ppm or 0.08% NNEX XVII of RECH Regulation (EC) No Law Concerning the Protection of the Ozone Layer through the Control of Specified Substances and others (Japanese law), Montreal Protocol, 1990 revision of rticle 611 of the Clean ir ct (US law), 76/769/EEC, marketing and Use of Dangerous Substances and amendments: (94/60/EEC; 97/64/EEC) US/C DTSC Rulemaking NNEX XVII of RECH Regulation (EC) No and Commission Regulation (EC) No 552/2009; 5.3 Declaration of EU Directive 2006/122/EC Compliance (PFOS Restriction); Canadian Environmental Protection ct SOR/SOR/ Japan Law concerning the evaluation of chemical substances EU Directive 2002/95/EC and 2005/618/EC; China MII Methods; Korea RoHS; Japan J-MOSS 13
14 Substance/ Category Polybrominated diphenylethers (PBDEs) Polychlorinated biphenyls (PCBs) and specific substitutes Polychlorinated terphenyls (PCTs) Polychlorinated naphthalenes (more than 3 chlorine atoms) Polyvinyl chloride (PVC) CS #/ EC # See nnex See nnex See nnex See nnex See nnex Potassium chromate Potassium dichromate Radioactive substances Refractory Ceramic Fibres, luminosilicate Refractory Ceramic Fibres, Zirconia luminosilicate See nnex See nnex See nnex Threshold Level (Reporting level) (1 000 ppm) in material Intentionally added Intentionally added Intentionally added (1 000 ppm) of the product Intentionally added (1 000 ppm) of the product (1 000 ppm) of the product LF Internal Limit 800 ppm or 0.08% Reference Regulation/ Standard or Customer Requirement EU Directive 2002/95/EC and 2005/618/EC; China MII Methods; Korea RoHS; Japan J-MOSS Japan Law concerning the evaluation of chemical substances; NNEX XVII of RECH Regulation (EC) No ; US TSC. Japan Law concerning the evaluation of chemical substances; NNEX XVII of RECH Regulation (EC) No ; US TSC. Japan Law concerning the evaluation of chemical substances IEEE1680 (EPET: Electronic Product Environmental ssessment Tool) EU-D 96/29/Euratom; Japan Law for the Regulation of Nuclear Source Material, Nuclear Fuel Material, and Reactors, 1986; US NRC rticle 33 and 7.2 of RECH Regulation (EC) No (Candidate list of SVHC for authorization ), rticle 33 and 7.2 of RECH Regulation (EC) No (Candidate list of SVHC for authorization ), 14
15 Substance/ Category Shortchain chlorinated paraffins (C10 C13) CS #/ EC # See nnex Sodium chromate Sodium dichromate Tetraboron disodium heptaoxide, hydrate ( and ) Trichloroethylene Tris(2- chloroethyl)phosphate TCEP Tetraboron disodium heptaoxide, hydrate 1 Tri-substiituted organostannic compounds Tributyl tin oxide (TBTO) CS# EC# CS# EC# See nnex CS# EC# Threshold Level (Reporting level) (1 000 ppm) of the product (1000 ppm) of the product (1000 ppm) of tin in a material 7 Intentionally added or by weight (1000 ppm) of the product LF Internal Limit Reference Regulation/ Standard or Customer Requirement rticle 33 and 7.2 of RECH Regulation (EC) No (Candidate list of SVHC for authorization ), Norway Product Regulations FOR ; Swiss Ordinance on Reduction of Risk from Chemical Products rticle 33 and 7.2 of RECH Regulation (EC) No (Candidate list of SVHC for authorization ) Commission Decision 2009/425/EC; Japan Law concerning the evaluation of chemical substances ; Japan Law concerning the evaluation of chemical substances rticle 33 and 7.2 of RECH Regulation (EC) No 15
16 Substance/ Category CS #/ EC # Threshold Level (Reporting level) LF Internal Limit Reference Regulation/ Standard or Customer Requirement (Candidate list of SVHC for authorization ) 16
17 nnex : Detailed Substance Lists with and/or EC Numbers TBLE 2 liphatic CHCs liphatic CHCs Tetrachloromethane ,1,2,2-Tetrachloroethane ,1,1,2-Tetrachloroethane Pentachloroethane Trichloromethane (Chloroform) ,1,1-Trichloroethane ,1,2-Trichloroethane ,1-Dichloroethylene TBLE 3 sbestos sbestos sbestos ctinolite mosite (Grunerite) nthophyllite Chrysotile Crocidolite Tremolite TBLE 4 zocolorants zocolorants biphenyl-4-ylamine Benzidine chloro-o-toluidine naphthylamine o-aminoazotoluene nitro-o-toluidine chloroaniline methoxy-m-phenylenediamine ,4 -methylenedianiline ,3 -dichlorobenzidine ,3 -dimethoxybenzidine ,3 -dimethylbenzidine ,4 -methylenedi-o-toluidine methoxy-m-toluidine ,4 -methylene-bis(2-chloroaniline) ,4 -oxydianiline ,4 -thiodianiline o-toluidine methyl-m-phenylenediamine ,4,5-trimethylaniline o-anisidine
18 zocolorants 4-amino azobenzene TBLE 5 Brominated Flame Retardants (other than PBBs, PBDEs or HBCDD) Brominated Flame Retardants (other than PBBs, PBDEs or CS HBCDD) Numbers Brominated flame retardant which comes under notation of ISO code number FR(14) [liphatic/alicyclic brominated compounds] - Brominated flame retardant which comes under notation of ISO code number FR(15) [liphatic/alicyclic brominated compounds in combination with antimony compounds] - Brominated flame retardant which comes under notation of ISO code number FR(16) [romatic brominated compounds excluding brominated diphenyl ether and biphenyls)] - Brominated flame retardant which comes under notation of ISO code number FR(17) [romatic brominated compounds excluding brominated diphenyl ether and biphenyls) in combination with antimony compounds] - Brominated flame retardant which comes under notation of ISO code number FR(22) [liphatic/alicyclic chlorinated and brominated compounds] - Brominated flame retardant which comes under notation of ISO code number FR(42) [Brominated organic phosphorus compounds] - Poly(2,6-dibromo-phenylene oxide) Tetra-decabromo-diphenoxy-benzene ,2-Bis(2,4,6-tribromo-phenoxy) ethane ,5,3,5 -Tetrabromo-bisphenol (TBB) TBB, unspecified TBB-epichlorhydrin oligomer TBB-TBB-diglycidyl-ether oligomer TBB carbonate oligomer TBB carbonate oligomer, phenoxy end capped TBB carbonate oligomer, 2,4,6-tribromo-phenol terminated TBB-bisphenol -phosgene polymer Brominated epoxy resin end-capped with tribromophenol Brominated epoxy resin end-capped with tribromophenol TBB-(2,3-dibromo-propyl-ether) TBB bis-(2-hydroxy-ethyl-ether) TBB-bis-(allyl-ether) TBB-dimethyl-ether Tetrabromo-bisphenol S TBBS-bis-(2,3-dibromo-propyl-ether) ,4-Dibromo-phenol ,4,6-tribromo-phenol Pentabromo-phenol ,4,6-Tribromo-phenyl-allyl-ether Tribromo-phenyl-allyl-ether, unspecified Bis(methyl)tetrabromo-phthalate Bis(2-ethylhexyl)tetrabromo-phthalate
19 Brominated Flame Retardants (other than PBBs, PBDEs or HBCDD) CS Numbers 2-Hydroxy-propyl-2-(2-hydroxy-ethoxy)-ethyl-TBP TBP, glycol-and propylene-oxide esters N,N -Ethylene bis-(tetrabromo-phthalimide) Ethylene-bis(5,6-dibromo-norbornane-2,3-dicarboximide) ,3-Dibromo-2-butene-1,4-diol Dibromo-neopentyl-glycol Dibromo-propanol Tribromo-neopentyl-alcohol Poly tribromo-styrene TBLE 6 Brominated Flame Retardants (other than PBBs, PBDEs or HBCDD) Brominated Flame Retardants (other than PBBs, PBDEs or HBCDD) Tribromo-styrene Dibromo-styrene grafted PP Poly-dibromo-styrene Bromo-/Chloro-paraffins Bromo-/Chloro-alpha-olefin Vinylbromide Tris-(2,3-dibromo-propyl)-isocyanurate Tris(2,4-Dibromo-phenyl) phosphate Tris(tribromo-neopentyl) phosphate Chlorinated and brominated phosphate ester Pentabromo-toluene Pentabromo-benzyl bromide ,3-Butadiene homopolymer,brominated Pentabromo-benzyl-acrylate, monomer Pentabromo-benzyl-acrylate, polymer Decabromo-diphenyl-ethane Tribromo-bisphenyl-maleinimide Tetrabromo-cyclo-octane ,2-Dibromo-4-(1,2 dibromo-methyl)-cyclo-hexane Tetrabromophthalic acid Na salt Tetrabromo phthalic anhydride Octabromo-1,1,3-trimethyl-1-phenylindane (FR-1808) Other Brominated Flame Retardants - TBLE 7 Cadmium/Cadmium Compounds Cadmium/Cadmium Compounds Cadmium Cadmium oxide Cadmium sulfide Cadmium chloride
20 Cadmium sulfate Other cadmium compounds - TBLE 8 Chromium VI Compounds Chromium VI Compounds EC Numbers Chromium (VI) oxide Barium chromate Calcium chromate Chromium trioxide Lead (II) chromate Lead chromate molybdate sulphate red Lead sulfochromate yellow Sodium chromate Sodium dichromate Strontium chromate Potassium dichromate Potassium chromate Zinc chromate Other chromium VI compounds - TBLE 9 Dibutyltin Compounds (DBT) Dibutyltin Compounds Dibutyltin oxide Dibutyltin diacetate Dibutyltin dilaurate Dibutyltin maleate Other dibutyltin compounds - TBLE 10 Dioctyltin Compounds (DOT) Dioctyltin Compounds Dioctyl Tin Oxide Dioctyltin dilaurate Other Dioctyltin compounds - TBLE 11 Fluorinated Greenhouse Gases Perfluorocarbons (PFC), Sulfur hexafluoride (SF6) & Hydrofluorocarbons (HFC) Fluorinated Greenhouse Gases Tetrafluoromethane (Carbon tetrafluoride, PFC-14)
21 Fluorinated Greenhouse Gases Hexafluoroethane (PFC-116) Octafluoropropane (PFC-218) Decafluorobutane (PFC-31-10) Dodecafluoropentane (PFC-41-12) Tetradecafluorohexane (PFC-51-14) Octafluorocyclobutane (PFC-c318) Sulfur Hexafluoride (SF6) Trifluoromethane (HFC-23) Difluoromethane (HFC-32) Methyl fluoride (HFC-41) H,3H-Decafluoropentane (HFC-43-10mee) Pentafluoroethane (HFC-125) ,1,2,2-Tetrafluoroethane (HFC-134) ,1,1,2-Tetrafluoroethane (HFC-134a) ,1-Difluoroethane (HFC-152a) ,1,2-Trifluoroethane (HFC-143 ) ,1,1-Trifluoroethane (HFC-143a) H-Heptafluoropropane (HFC-227ea) ,1,1,2,2,3-Hexafluoro-propane ( HFC-236cb) ,1,1,2,3,3-Hexafluoropropane (HFC-236ea) ,1,1,3,3,3-Hexafluoropropane (HFC-236fa) ,1,2,2,3-Pentafluoropropane (HFC-245ca) ,1,1,3,3-Pentafluoropropane (HFC-245fa) ,1,1,3,3-Pentafluorobutane (HFC-365mfc) TBLE 12 Hexabromocyclododecane (HBCDD) HBCDD and all Major Diastereoisomers EC Numbers Hexabromocyclododecane (HBCDD) and and lpha-hexabromocyclododecane N Beta-hexabromocyclododecane N Gamma-hexabromocyclododecane N TBLE 13 Lead/lead Compounds Lead/Lead Compounds EC Numbers Lead Lead (II) sulfate Lead (II) carbonate Lead (II) chromate Lead chromate molybdate sulphate red (C.I. Pigment Red 104)
22 Lead/Lead Compounds EC Numbers Lead hydrocarbonate Lead hydrogen arsenate Lead acetate Lead (II) acetate, trihydrate Lead phosphate Lead selenide Lead (IV) oxide Lead (II,IV) oxide Lead (II) sulfide Lead (II) oxide Lead (II) carbonate basic Lead hydroxidcarbonate Lead (II) phosphate Lead sulfochromate yellow (C.I. Pigment Yellow 34) Lead/Lead Compounds EC Numbers Lead (II) titanate Lead sulfate, sulphuric acid, lead salt Lead sulphate, tribasic Lead stearate Other lead compounds - Mercury /Mercury Compounds TBLE 14 Mercury /Mercury Compounds Mercury Mercuric chloride Mercury (II) chloride Mercuric sulfate Mercuric nitrate Mercuric (II) oxide Mercuric sulfide Other mercury compounds - 22
23 TBLE 15 Ozone Depleting Substances Chlorofluorocarbons (CFC), Halons, Hydrobromofluorocarbons (HBFC), Hydrochlorofluorocarbons (HCFC) and others Ozone Depleting Substances Trichlorofluoromethane (CFC-11) Dichlorodifluoromethane (CFC-12) Chlorotrifluoromethane (CFC-13) Pentachlorofluoroethane (CFC-111) Tetrachlorodifluoroethane (CFC-112) ,1,2,2-Tetrachloro-1,2-difluoroethane (CFC-112) ,1,1,2-Tetrachloro-2,2-difluoroethane (CFC-112a) Trichlorotrifluoroethane (CFC-113) , 1,1,2-Trichloro-1,2,2 trifluoroethane (CFC-113) ,1,1-Trichloro-2,2,2 trifluoroethane (CFC-113a) Dichlorotetrafluoroethane (CFC-114) Monochloropentafluoroethane (CFC-115) Heptachlorofluoropropane (CFC-211) ,1,1,2,2,3,3-Heptachloro-3-fluoropropane (CFC-211aa) 1,1,1,2,3,3,3-Heptachloro-2-fluoropropane (CFC-211ba) Hexachlorodifluoropropane (CFC-212) Pentachlorotrifluoropropane (CFC-213) Tetrachlorotetrafluoropropane (CFC-214) 1,2,2,3-Tetrachloro-1,1,3,3- tetrafluoropropane (CFC-214aa) 1,1,1,3-Tetrachloro-2,2,3,3- tetrafluoropropane (CFC-214cb) Trichloropentafluoropropane (CFC-215) ,2,2-Trichloropentafluoropropane (CFC-215aa) ,2,3-Trichloropentafluoropropane (CFC-215ba) ,1,2-Trichloropentafluoropropane (CFC-215bb) - 1,1,3-Trichloropentafluoropropane (CFC-215ca) - 1,1,1-Trichloropentafluoropropane (CFC-215cb) Dichlorohexafluoropropane (CFC-216) Chloroheptafluoropropane (CFC-217) Bromochloromethane (Halon-1011) Dibromodifluoromethane (Halon-1202) Bromochlorodifluoromethane (Halon-1211) Bromotrifluoromethane (Halon-1301)
24 Ozone Depleting Substances Dibromotetrafluoroethane (Halon-2402) Tetrachloromethane (carbon tetrachloride) ,1,1-Trichloroethane (methylchloroform) Bromomethane (methyl bromide) Bromoethane (ethyl bromide) Bromopropane (n-propyl bromide) Trifluoroiodomethane (trifluoromethyl iodide) Chloromethane (methyl chloride) Dibromofluoromethane (HBFC-21 B2) Bromodifluoromethane (HBFC-22 B1) Bromofluoromethane (HBFC-31 B1) Tetrabromofluoroethane (HBFC-121 B4) Tribromodifluoroethane (HBFC-122 B3) - Dibromotrifluoroethane (HBFC-123 B2) Bromotetrafluoroethane (HBFC-124 B1) Tribromofluoroethane (HBFC-131 B3) - Dibromodifluoroethane (HBFC-132 B2) Bromotrifluoroethane (HBFC-133 B1) Dibromofluoroethane (HBFC-141 B2) Bromodifluoroethane (HBFC-142 B1) Bromofluoroethane (HBFC-151 B1) Hexabromofluoropropane (HBFC-221 B6) - Pentabromodifluoropropane (HBFC-222 B5) - Tetrabromotrifluoropropane (HBFC-223 B4) - Tribromotetrafluoropropane (HBFC-224 B3) - Dibromopentafluoropropane (HBFC-225 B2) Bromohexafluoropropane (HBFC-226 B1) Pentabromofluoropropane (HBFC-231 B5) - Tetrabromodifluoropropane (HBFC-232 B4) - Tribromotrifluoropropane (HBFC-233 B3) - Dibromotetrafluoropropane (HBFC-234 B2) - Bromopentafluoropropane (HBFC-235 B1) Tetrabromofluoropropane (HBFC-241 B4) - Tribromodifluoropropane (HBFC-242 B3) Dibromotrifluoropropane (HBFC-243 B2) Bromotetrafluoropropane (HBFC-244 B1) Tribromofluoropropane (HBFC-251 B3)
25 Ozone Depleting Substances Dibromodifluoropropane (HBFC-252 B2) Bromotrifluoropropane (HBFC-253 B1) Dibromofluoropropane (HBFC-261 B2) Bromodifluoropropane (HBFC-262 B1) - Bromofluoropropane (HBFC-271 B1) Dichlorofluoromethane (HCFC-21) Chlorodifluoromethane (HCFC-22) Chlorofluoromethane (HCFC-31) Tetrachlorofluoroethane (HCFC-121) 1,1,2,2-Tetrachloro-1-fluoroethane (HCFC-121) 1,1,1,2-Tetrachloro-2-fluoroethane (HCFC-121a) Trichlorodifluoroethane (HCFC-122) ,2,2-Trichloro-1,1-difluoroethane (HCFC-122) ,1,2-Trichloro-1,2-difluoroethane (HCFC-122a) ,1,1-Trichloro-2,2-difluoroethane (HCFC-122b) Dichlorotrifluoroethane(HCFC-123) ,1-Dichloro-2,2,2-trifluoroethane (HCFC-123) ,2-Dichloro-1,1,2-trifluoroethane (HCFC-123a) ,1-Dichloro-1,2,2-trifluoroethane (HCFC-123b) Chlorotetrafluoroethane (HCFC-124) 2-chloro-1,1,1,2-tetrafluoroethane (HCFC-124) 1-chloro-1,1,2,2-tetrafluoroethane (HCFC-124a) Trichlorofluoroethane (HCFC-131) ( ) 1,1,2-Trichloro-2-fluoroethane (HCFC-131) 1,1,2-Trichloro-1-fluoroethane (HCFC131a) 1,1,1-Trichloro-2-fluoroethane (HCFC-131b) Dichlorodifluoroethane (HCFC-132) 1,2-Dichloro-1,2-difluoroethane (HCFC-132) 1,1-Dichloro-2,2-difluoroethane (HCFC-132a) 1,2-Dichloro-1,1-difluoroethane (HCFC-132b) 1,1-Dichloro-1,2-difluoroethane (HFCF-132c)
26 Ozone Depleting Substances Chlorotrifluoroethane (HCFC-133) 1-Chloro-1,2,2-trifluoroethane (HCFC-133) 2-Chloro-1,1,1-trifluoroethane (HCFC-133a) 1-Chloro-1,1,2- trifluoroethane (HCFC-133b) Dichlorofluoroethane(HCFC-141) 1,2-Dichloro-1-fluoroethane (HCFC-141) 1,1-Dichloro-2-fluoroethane (HCFC-141a) 1,1-Dichloro-1-fluoroethane (HCFC-141b) ( ) Chlorodifluoroethane (HCFC-142) Chloro-1,1-Difluoroethane (HCFC-142) Chloro-1,1-difluoroethane (HCFC-142b) Chloro-1,2-difluoroethane (HCFC-142a) Chlorofluoroethane (HCFC-151) 1-Chloro-2-fluoroethane (HCFC-151) 1-Chloro-1-fluoroethane (HCFC-151a) Hexachlorofluoropropane (HCFC-221) 1,1,1,2,2,3-Hexachloro-3-fluoropropane (HCFC-221ab) Pentachlorodifluoropropane (HCFC-222) 1,1,1,3,3-pentachloro-2,2-difluoropropane (HCFC-222ca)) 1,2,2,3,3-pentachloro-1,1-difluoropropane (HCFC-222aa) Tetrachlorotrifluoropropane (HCFC-223) 1,1,3,3-Tetrachloro-1,2,2-trifluoropropane (HCFC-223ca) 1,1,1,3-Tetrachloro-2,2,3-trifluoropropane (HCFC-223cb) Trichlorotetrafluoropropane (HCFC-224) 1,3,3-Trichloro-1,1,2,2-tetrafluoropropane (HCFC-224ca) 1,1,3-Trichloro-1,2,2,3-tetrafluoropropane (HCFC-224cb) 1,1,1-Trichloro-2,2,3,3-tetrafluoropropane (HCFC-224cc)
27 Ozone Depleting Substances Dichloropentafluoropropane (HCFC-225) 2,2-Dichloro-1,1,1,3,3-pentafluoropropane(HCFC-225aa) 2,3-Dichloro-1,1,1,2,3-pentafluoropropane (HCFC-225ba) 1,2-Dichloro-1,1,2,3,3-pentafluoropropane (HCFC-225bb) 3,3-Dichloro-1,1,1,2,2-pentafluoropropane (HCFC-225ca) 1,3-Dichloro-1,1,2,2,3-pentafluoropropane (HCFC-225cb) 1,1-Dichloro-1,2,2,3,3-pentafluoropropane(HCFC-225cc) 1,2-Dichloro-1,1,3,3,3-pentafluoropropane (HCFC-225da) 1,3-Dichloro-1,1,2,3,3-pentafluoropropane (HCFC-225ea) 1,1-Dichloro-1,2,3,3,3-pentafluoropropane(HCFC-225eb) Chlorohexafluoropropane (HCFC-226) 2-Chloro-1,1,1,3,3,3-hexafluoro-propane (HCFC-226da) Pentachlorofluoropropane (HCFC-231) 1,1,1,2,3-pentachloro-2-fluoro-propane (HCFC-231bb) Tetrachlorodifluoropropane (HCFC-232) 1,1,1,3-Tetrachloro-3,3-difluoropropane (HCFC-232fc) Trichlorotrifluoropropane (HCFC-233) 1,1,1-Trichloro-3,3,3-trifluoropropane (HCFC-233fb) Dichlorotetrafluoropropane (HCFC-234) 1,2-Dichloro-1,2,3,3-tetrafluoropropane (HCFC-234db) Chloropentafluoropropane (HCFC-235) 1-Chloro-1,1,3,3,3-pentafluoropropane (HCFC-235fa) Tetrachlorofluoropropane (HCFC-241) 1,1,2,3-Tetrachloro-1-fluoropropane (HCFC-241db) Trichlorodifluoropropane (HCFC-242) 1,3,3,Trichloro-1,1-difluoropropane (HCFC-242fa) Dichlorotrifluoropropane (HCFC-243) 1,1-Dichloro-1,2,2-trifluoropropane (HCFC-243cc) 2,3-Dichloro-1,1,1-trifluoropropane (HCFC-243db) 3,3-Dichloro-1,1,1-trifluoropropane (HCFC-243fa) Chlorotetrafluoropropane (HCFC-244) 3-Chloro-1,1,2,2-tetrafluoropropane (HCFC-244ca) 1-Chloro-1,1,2,2-tetrafluoropropane (HCFC-244cc) Trichlorofluoropropane (HCFC-251) 1,1,3-Trichloro-1-fluoropropane (HCFC-251fb) 1,1,2-Trichloro-1-fluoropropane (HCFC-251dc) Dichlorodifluoropropane (HCFC-252) 1,3-Dicloro-1,1-difluoropropane (HCFC-252fb) Chlorotrifluoropropane (HCFC-253) 3-Chloro-1,1,1-trifluoropropane (HCFC-253fb)
28 Ozone Depleting Substances Dichlorofluoropropane (HCFC-261) 1,1-Dichloro-1-fluoropropane (HCFC-261fc) 1,2-Dichloro-2-fluoro-propane (HCFC-261ba) Chlorodifluoropropane (HCFC-262) 1-Chloro-2,2-difluoropropane (HCFC-262ca) 2-Chloro-1,3-difluoropropane (HCFC-262da) 1-Chloro-1,1-difluoropropane (HCFC-262fc) Chlorofluoropropane (HCFC-271) 2-Chloro-2-fluoropropane (HCFC-271ba) 1-Chloro-1-fluoropropane (HCFC-271fb) TBLE 16 Perchlorate Compounds Perchlorate Compounds Lithium perchlorate Other perchlorate compounds - TBLE 17 PFOS Compounds PFOS Compounds Perfluoroctane Sulfonates (PFOS) C8F17SO2X, where X = OR, NR or other derivative - TBLE 18 Polybrominated Biphenyls (PBBs) Polybrominated Biphenyls (PBBs) Polybrominated Biphenyls Dibromobiphenyl Bromobiphenyl Bromobiphenyl Bromobiphenyl Tribromobiphenyl Tetrabromobiphenyl Pentabromobiphenyl Hexabromobiphenyl Hexabromo-1,1-biphenyl Firemaster FF Heptabromobiphenyl Octabromobiphenyl Nonabromobiphenyl
29 Polybrominated Biphenyls (PBBs) Decabromobiphenyl TBLE 19 Polybrominated Diphenyl Ethers (PBDEs) Diphenyl Ethers (PBDEs) Polybrominated Diphenyl Ethers (PBDEs) Bromodiphenyl ether Dibromodiphenyl ether Tribromodiphenyl ether Tetrabromodiphenyl ether Pentabromodidphenyl ether (note: Commercially available PeBDPO is a complex reaction mixture containing a variety of brominated diphenyloxides (CS number used for commercial grades of PeBDPO) Hexabromodiphenyl ether Heptabromodiphenyl ether Octabromodiphenyl ether Nonabromodiphenyl ether Decabromodiphenyl ether TBLE 20 Polychlorinated Biphenyls (PCBs) and specific substitutes Polychlorinated Biphenyls (PCBs) Polychlorinated Biphenyls (all isomers and congeners) Monomethyl-tetrachloro-diphenyl methane (Ugilec 141) Monomethyl-dichloro-diphenyl methane (Ugilec 121, Ugilec 21) Monomethyl-dibromo-diphenyl methane (DBBT) TBLE 21 Polychlorinated Terphenyls (PCTs) Polychlorinated Terphenyls (PCTs) Polychlorinated Terphenyls (all isomers and congeners)
30 TBLE 22 Polychlorinated Naphthalenes Polychlorinated Naphthalenes Polychlorinated Naphthalenes Other polychlorinated Naphthalenes - TBLE 23 (PVC) Polyvinyl Chloride Polyvinyl Chloride Polyvinyl chloride (PVC) Other Polyvinyl chlorides - TBLE 24 Radioactive Substances (Radioactive Isotope) Radioactive Substances Uranium Radon mericium Thorium Cesium Strontium Other radioactive substances - TBLE 25 Refractory Ceramic Fibers, luminosilicate Refractory Ceramic Fibers, luminosilicate are fibres covered by index number in nnex VI, part 3, table 3.2 of Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, and fulfill the two following conditions: a) l2o3 and SiO2 are present within the following concentration ranges: l2o3: % w/w, and SiO2: % w/w, or l2o3: % w/w, and SiO2: 48.5 Index Numbers
31 Refractory Ceramic Fibers, luminosilicate 54 % w/w, Index Numbers b) fibres have a length weighted geometric mean diameter less two standard geometric errors of 6 or less micrometres (μm) TBLE 26 Refractory Ceramic Fibers, Zirconia luminosilicate Refractory Ceramic Fibers, Zirconia luminosilicate are fibres covered by index number in nnex VI, part 3, table 3.2 of Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, and fulfill the two following conditions: a) l2o3, SiO2 and ZrO2 are present within the following concentration ranges: l2o3: % w/w, and SiO2: % w/w, and ZrO2: % w/w, Index Numbers b) fibres have a length weighted geometric mean diameter less two standard geometric errors of 6 or less micrometres (μm) TBLE 27 Short Chain Chlorinated Paraffins (SCCPs) Short Chain Chlorinated Paraffins (C10-C13) EC Numbers lkanes, C10-13, chloro lkanes, C10-12, chloro lkanes, C12-13, chloro
32 lkanes, chloro Chlorinated polyethylene Other Short Chain Chlorinated Paraffins - TBLE 28 Short Chain Chlorinated Paraffins (SCCPs) Tri-substituted Organostannic Compounds Triphenyltin-N, N-dimethyldithiocarbamate Triphenyltinfluoride Triphenyltinacetate Triphenyltinchloride Triphenyltinhydroxide Triphenyltin fattyacid((9-11)salt) Triphenyltinchloroacetate Tributyltinmethacrylate Bis(tributyltin)fumalate Tributyltinfluoride Bis(tributyltin)2,3-dibromosuccinate Tributyltinacetate Tributyltinlaurate Bis(tributyltin)phthalate Coplymer of alkyl(c=8) acrylate,methyl methacrylate and tributyltin methacrylate Tributyltinsulfamate Bis(tributyltin)maleate Tributyltinchloride Tributyltin cyclopentane carbonate = mixture Tributyltin-1,2,3,4,4a,4b,5,6,10,10a-decahydro-7-isoplopyl- 1,4a-dimethyl-1-phenanthrencarboxylatemix Other tri-substituted organostannic compounds - 32
33 # TBLE 29 Candidate List for Substances of Very High Concern Substance Name CS # nthracene ,4'- Diaminodiphenylmethane Dibutyl phthalate Cobalt dichloride Diarsenic pentaoxide Diarsenic trioxide Sodium dichromate, dihydrate tert-butyl-2,4,6-trinitro-m-xylene (musk xylene) 9 Bis (2-ethyl(hexyl)phthalate) (DEHP) Hexabromocyclododecane (HBCDD) lkanes, C10-13, chloro (Short Chain Chlorinated Paraffins) 12 Bis(tributyltin) oxide,hexabutyldistannoxane Lead hydrogen arsenate Triethyl arsenate Benzyl butyl phthalate SVHC Published Date ,4-Dinitrotoluene nthracene oil nthracene oil, anthracene paste nthracene oil, anthracene paste, anthracene fraction 20 nthracene oil, anthracene paste,distn. lights nthracene oil, anthracene-low
34 # SVHC Substance Name CS # Published Date 22 Diisobutyl phthalate Lead chromate Lead chromate molybdate sulphate red (C.I. Pigment Red 104) Lead sulfochromate yellow (C.I. Pigment Yellow 34) Pitch, coal tar, high temp Tris(2-chloroethyl)phosphate crylamide Trichloroethylene Boric acid Disodium tetraborate, anhydrous Tetraboron disodium heptaoxide, hydrate Sodium chromate Potassium chromate mmonium dichromate Potassium dichromate Ethoxyethanol Methoxyethanol Chromic acid Chromium trioxide Cobalt(II) carbonate Cobalt(II) diacetate Cobalt(II) dinitrate Cobalt(II) sulphate ,2,3-Trichloropropane ,2-Benzenedicarboxylic acid, di-c6-8- branched alkyl esters, C7-rich ,2-Benzenedicarboxylic acid, di-c7-11- branched and linear alkyl esters Methyl-2-pyrrolidone
35 # SVHC Substance Name CS # Published Date 49 2-Ethoxyethyl acetate / Hydrazine Strontium chromate Dichromium tris(chromate) Potassium hydroxyoctaoxodizincatedichromate Pentazinc chromate octahydroxide luminosilicate Refractory Ceramic Fibres (RCF) Zirconia luminosilicate Refractory Ceramic Fibres (Zr-RCF) Formaldehyde, oligomeric reaction products with aniline (technical MD) Bis(2-methoxyethyl) phthalate Methoxyaniline; o-nisidine (1,1,3,3-tetramethylbutyl)phenol, (4-tert Octylphenol) ,2-Dichloroethane Bis(2-methoxyethyl) ether rsenic acid Calcium arsenate Trilead diarsenate N,N-dimethylacetamide (DMC) ,2'-dichloro-4,4'-methylenedianiline (MOC) Phenolphthalein Lead azide Lead diazide
36 70 71 # Substance Name CS # Lead styphnate Lead dipicrate α,α-bis[4-(dimethylamino)phenyl]-4 (phenylamino)naphthalene-1-methanol (C-I- Solvent Blue 4) [with 0-1% of Michler's ketone (EC No ) or Michler's base (EC No )] 73 N,N,N',N'-tetramethyl-4,4'-methylenedianiline (Michler s base) 74 1,3,5-tris[(2S and 2R)-2,3-epoxypropyl]-1,3,5- triazine-2,4,6-(1h,3h,5h)-trione (β-tgic) SVHC Published Date Diboron trioxide ,2-bis(2-methoxyethoxy)ethane (TEGDME; triglyme) ,4'-bis(dimethylamino)-4''-(methylamino)trityl alcohol [with 0-1% of Michler's ketone (EC No ) or Michler's base (EC No )] Lead(II) bis(methanesulfonate) Formamide [4-[4,4'-bis(dimethylamino) benzhydrylidene]cyclohexa-2,5-dien-1- ylidene]dimethylammonium chloride (C-I- Basic Violet 3) [with 0-1% of Michler's ketone (EC No ) or Michler's base (EC No )] 81 1,2-dimethoxyethane; ethylene glycol dimethyl ether (EGDME) 82 [4-[[4-anilino-1-naphthyl][4- (dimethylamino)phenyl]methylene]cyclohexa- 2,5-dien-1-ylidene] dimethylammonium chloride (C-I- Basic Blue 26) [with 0-1% of Michler's ketone (EC No ) or Michler's base (EC No )] 83 1,3,5-Tris(oxiran-2-ylmethyl)-1,3,5-triazinane- 2,4,6-trione (TGIC)
37 # SVHC Substance Name CS # Published Date 84 4,4'-bis(dimethylamino)benzophenone (Michler s ketone) Pyrochlore, antimony lead yellow methoxy-m-toluidine (p-cresidine) Henicosafluoroundecanoic acid Hexahydromethylphthalic anhydride [1], Hexahydro-4-methylphthalic anhydride [2], Hexahydro-1-methylphthalic anhydride [3], Hexahydro-3-methylphthalic anhydride [4] [The individual isomers [2], [3] and [4] (including their cis- and trans- stereo isomeric forms) and all possible combinations of the isomers [1] are covered by this entry] 89 Cyclohexane-1,2-dicarboxylic anhydride [1], cis-cyclohexane- 1,2-dicarboxylic anhydride [2], trans-cyclohexane-1,2- dicarboxylic anhydride [3] [The individual cis- [2] and trans- [3] isomer substances and all possible combinations of the cisand trans-isomers [1] are covered by this entry] , , , , , Dibutyltin dichloride (DBTC) Lead bis(tetrafluoroborate) Lead dinitrate Silicic acid, lead salt minoazobenzene Lead titanium zirconium oxide Lead monoxide (lead oxide) o-toluidine ethyl-2-methyl-2-(3-methylbutyl)-1, oxazolidine 99 Silicic acid (H2Si2O5), barium salt (1:1), leaddoped [with lead (Pb) content above the applicable generic concentration limit for toxicity for reproduction Repr. 1 (CLP) or category 1 (DSD); the substance is a member of the group entry of lead compounds, with index number in Regulation (EC) No 1272/2008] 100 Trilead bis(carbonate)dihydroxide Furan
38 # SVHC Substance Name CS # Published Date 102 N,N-dimethylformamide (1,1,3,3-tetramethylbutyl)phenol, ethoxylated [covering well-defined substances and UVCB substances, polymers and homologues] Nonylphenol, branched and linear [substances with a linear and/or branched alkyl chain with a carbon number of 9 covalently bound in position 4 to phenol, covering also UVCB- and well-defined substances which include any of the individual isomers or a combination thereof] 105 4,4'-methylenedi-o-toluidine Diethyl sulphate Dimethyl sulphate Lead oxide sulfate Lead titanium trioxide cetic acid, lead salt, basic [Phthalato(2-)]dioxotrilead Bis(pentabromophenyl) ether (decabromodiphenyl ether; DecaBDE) 113 N-methylacetamide Dinoseb (6-sec-butyl-2,4-dinitrophenol) ,2-Diethoxyethane Tetralead trioxide sulphate N-pentyl-isopentylphthalate Dioxobis(stearato)trilead Tetraethyllead Pentalead tetraoxide sulphate Pentacosafluorotridecanoic acid Tricosafluorododecanoic acid Heptacosafluorotetradecanoic acid bromopropane (n-propyl bromide) Methoxyacetic acid methyl-m-phenylenediamine (toluene-2, diamine) 127 Methyloxirane (Propylene oxide) Trilead dioxide phosphonate o-aminoazotoluene
39 # SVHC Substance Name CS # Published Date 130 1,2-Benzenedicarboxylic acid, dipentylester, branched and linear 131 4,4'-oxydianiline and its salts Orange lead (lead tetroxide) Biphenyl-4-ylamine Diisopentylphthalate Fatty acids, C16-18, lead salts Diazene-1,2-dicarboxamide (C,C' azodi(formamide)) 137 Sulfurous acid, lead salt, dibasic Lead cyanamidate Cadmium Cadmium oxide Dipentyl phthalate (DPP) Nonylphenol, branched and linear, ethoxylated [substances with a linear and/or branched alkyl chain with a carbon number of 9 covalently bound in position 4 to phenol, ethoxylated covering UVCB- and well-defined substances, polymers and homologues, which include any of the individual isomers and/or combinations thereof] 143 mmoniumpentadecafluorootanoate (PFO) Pentadecafluorooctanoic acid (PFO)
40 Table 30 Exemptions (s stated in Directive 2011/65/EU unless otherwise noted) Scope and dates of Exemption applicability Exemption Number 1 1(a) 1(b) 1(c) 1(d) 1(e) 1(f) Mercury in single capped (compact) fluorescent lamps not exceeding (per burner): For general lighting purposes < 30 W: 5 mg For general lighting purposes 30 W and < 50 W: 5 mg For general lighting purposes 50 W and 150 W: 5 mg For general lighting purposes 150 W: 15 mg For general lighting purposes w ith circular or square structural shape and tube diameter < 17 mm For special purposes: 5 mg Expires on 31 December 2011; 3,5 mg may be used per burner after 31 December 2011 until 31 December 2012; 2,5 mg shall be used per burner after 31 December 2012 Expires on 31 December 2011; 3,5 mg may be used per burner after 31 December 2011 No limitation of use until 31 December 2011; 7 mg may be used per burner after 31 December (a) 2(a)(1) 2(a)(2) 2(a)(3) 2(a)(4) 2(a)(5) 2(b) 2(b)(1) 2(b)(2) 2(b)(3) 2(b)(4) Mercury in double-capped linear fluorescent lamps for general lighting purposes not exceeding (per lamp): Tri-band phosphor w ith normal lifetime and a tube diameter > 9 mm (e.g. T2): 5 mg Tri-band phosphor w ith normal lifetime and a tube diameter 9 mm and 17 mm (e.g. T5): 5 mg Tri-band phosphor w ith normal lifetime and a tube diameter 17 mm and 28 mm (e.g. T8): 5 mg Tri-band phosphor w ith normal lifetime and a tube diameter > 28 mm (e.g. T12): 5 mg Tri-band phosphor w ith long lifetime ( h): 8 mg Mercury in other fluorescent lamps not exceeding (per lamp): Linear halophosphate lamps w ith tube > 28 mm (e.g. T10 and T12): 10 mg Non-linear halophosphate lamps (all diameters): 15 mg Non-linear tri-band phosphor lamps w ith tube diameter > 17 mm (e.g. T9) Lamps for other general lighting and spec ial purposes (e.g. induction lamps) Expires on 31 December 2011; 4 mg may be used per lamp after 31 December 2011 Expires on 31 December 2011; 3 mg may be used per lamp after 31 December 2011 Expires on 31 December 2011; 3,5 mg may be used per lamp after 31 December 2011 Expires on 31 December 2012; 3,5 mg may be used per lamp after 31 December 2012 Expires on 31 December 2011; 5 mg may be used per lamp after 31 December 2011 Expires on 13 pril 2012 Expires on 13 pril 2016 No limitation of use until 31 December 2011; 15 mg may be used per lamp after 31 December 2011 No limitation of use until 31 December 2011; 15 mg may be used per lamp after 31 December
41 Exemption Number 3 3(a) 3(b) 3(c) 4(a) 4(b) 4(b)-I 4(b)-II 4(b)-III 4(c) 4(c)-I 4(c)-II 4(c)-III 4(d) 4(e) 4(f) Exemption Mercury in cold cathode fluorescent lamps and external electrode fluorescent lamps (CCFL and EEFL) for special purposes not exceeding (per lamp): Short length ( 500 mm) Medium length (> 500 mm and < 1500 mm) Long length (> 1500 mm) Mercury in other low pressure discharge lamps (per lamp) Mercury in High Pressure Sodium (vapour) lamps for general lighting purposes not exceeding (per burner) in lamps w ith improved colour rendering index Ra > 60: P < 155 W 155 W < P < 405 W P > 405 W Mercury in other High Pressure Sodium (vapour) lamps for general lighting purposes not exceeding (per burner): P < 155 W 155 W < P < 405 W P > 405 W Mercury in High Pressure Mercury (vapour) lamps (HPMV) Mercury in metal halide lamps (MH) Mercury in other discharge lamps for special purposes not specifically mentioned in this nnex Scope and dates of applicability No limitation of use until 31 December 2011; 3,5 mg may be used per lamp after 31 December 2011 No limitation of use until 31 December 2011; 5 mg may be used per lamp after 31 December 2011 No limitation of use until 31 December 2011; 13 mg may be used per lamp after 31 December 2011 No limitation of use until 31 December 2011; 15 mg may be used per lamp after 31 December 2011 No limitation of use until 31 December 2011; 30 mg may be used per burner after 31 December 2011 No limitation of use until 31 December 2011; 40 mg may be used per burner after 31 December 2011 No limitation of use until 31 December 2011; 40 mg may be used per burner after 31 December 2011 No limitation of use until 31 December 2011; 25 mg may be used per burner after 31 December 2011 No limitation of use until 31 December 2011; 30 mg may be used per burner after 31 December 2011 No limitation of use until 31 December 2011; 40 mg may be used per burner after 31 December 2011 Expires on 13 pril
42 Exemption Number 5(a) 5(b) 6(a) 6(b) 6(c) 7(a) 7(b) 7(c)-I 7(c)-II 7(c)-III 8(a) 8(b) 9 9(b) 11(a) 11(b) 12 13(a) Exemption Lead in glass of cathode ray tubes Lead in glass of fluorescent tubes not exceeding 0,2 % by w eight Lead as an alloy ing element in steel for machining purposes and in galvanized steel containing up to 0,35 % lead by w eight Lead as an alloy ing element in aluminium containing up to 0,4 % lead by w eight Copper alloy containing up to 4 % lead by w eight Lead in high melting temperature type solders (i.e. lead- based alloys containing 85 % by w eight or more lead) Lead in solders for servers, storage and storage array systems, netw ork infrastructure equipment for sw itching, signalling, trans mission, and netw ork management for telecommunications Electrical and electronic components containing lead in a glass or ceramic other than dielectric ceramic in capacitors, e.g. piezoelectronic devices, or in a glass or ceramic matrix compound Lead in dielectric ceramic in capac itors for a rated voltage of 125 V C or 250 V DC or higher Lead in dielectric ceramic in capac itors for a rated voltage of less than 125 V C or 250 V DC Cadmium and its compounds in one shot pellet type thermal cut-offs Cadmium and its compounds in electrical contacts Hexavalent chromium as an anticorrosion agent of the carbon steel cooling system in absorption refrigerators up to 0,75 % by w eight in the cooling solution Lead in bearing shells and bushes for refrigerantcontaining compressors for heating, ventilation, air conditioning and refrigeration (HVCR) applications Lead used in C-press compliant pin connector systems Lead used in other than C-press compliant pin connector systems Lead as a coating material for the thermal conduction module C-ringH Lead in w hite glasses used for optical applications Scope and dates of applicability Expires on 1 January 2013 and after that date may be used in spare parts for EEE placed on the market before 1 January 2013 Expires on 1 January 2012 and after that date may be used in spare parts for EEE placed on the market before 1 January 2012 May be used in spare parts for EEE placed on the market before 24 September 2010 Expires on 1 January 2013 and after that date may be used in spare parts for EEE placed on the market before 1 January 2013 May be used in spare parts for EEE placed on the market before 24 September
43 Exemption Number 13(b) (a) 18(b) Exemption Cadmium and lead in filter glasses and glasses used for reflectance standards Lead in solders consisting of more than tw o elements for the connection betw een the pins and the package of microprocessors w ith a lead content of more than 80 % and less than 85 % by w eight Lead in solders to complete a viable electrical connection betw een semiconductor die and carrier w ithin integrated circuit flip chip pac kages Lead in linear incandescent lamps w ith silicate coated tubes Lead halide as radiant agent in high intensity discharge (HID) lamps used for professional reprography applications Lead as activator in the fluorescent pow der (1 % lead by w eight or less) of discharge lamps w hen used as speciality lamps for diazoprinting reprography, lithography, insect traps, photochemical and curing processes containing phosphors such as SMS ((Sr,Ba) 2 MgSi 2 O 7 :Pb) Lead as activator in the fluorescent pow der (1 % lead by w eight or less) of discharge lamps w hen used as sun tanning lamps containing phosphors such as BSP (BaSi 2 O 5 :Pb) Lead w ith PbBiSn-Hg and PbInSn-Hg in specific compositions as main amalgam and w ith PbSn-Hg as auxiliary amalgam in very compact energy saving lamps (ESL) Lead oxide in glass used for bonding front and rear substrates of flat fluorescent lamps used for Liquid Crystal Displays (LCDs) Lead and cadmium in printing inks for the application of enamels on glasses, such as borosilicate and soda lime glasses Lead in finishes of fine pitch components other than connectors w ith a pitch of 0,65 mm and less Lead in solders for the soldering to machined through hole discoidal and planar array ceramic multilayer capacitors Lead oxide in surface conduction electron emitter displays (SED) used in structural elements, notably in the seal frit and frit ring Lead ox ide in the glass envelope of black light blue lamps Lead alloys as solder for transducers used in highpow ered (designated to operate for several hours at acoustic pow er levels of 125 db SPL and above) loudspeakers Lead bound in crystal glass as defined in nnex I (Categories 1, 2, 3 and 4) of Council Directive 69/493/EEC ( 1 ) Cadmium alloys as electrical/mechanical solder joints to electrical conductors located directly on the voice Scope and dates of applicability Expires on 1 January 2011 and after that date may be used in spare parts for EEE placed on the market before 1 January 2011 Expires on 1 September 2013 Expires on 1 January 2011 Expires on 1 June 2011 Expires on 1 June 2011 May be used in spare parts for EEE placed on the market before 24 September 2010 Expires on 1 June 2011 Expired on 24 September
44 Exemption Number Exemption coil in transducers used in high-pow ered loudspeakers w ith sound pressure levels of 100 db () and more Lead in soldering in mercury free flat fluorescent lamps (w hich e.g. are used for liquid crystal displays, design or industrial lighting) Lead oxide in seal frit used for making w indow assemblies for rgon and Krypton laser tubes Lead in solders for the soldering of thin copper w ires of 100 μm diameter and less in pow er transformers Lead in cermet-based trimmer potentiometer elements Mercury used as a cathode sputtering inhibitor in DC plas ma displays w ith a content up to 30 mg per display Lead in the plating layer of high voltage diodes on the basis of a zinc borate glass body Cadmium and cadmium oxide in thick film pastes used on aluminium bonded beryllium oxide Cadmium in colour converting II-V I LEDs (< 10 μg Cd per mm 2 of light-emitting area) for use in solid state illumination or display systems Scope and dates of applicability Expired on 1 July 2010 Expires on 1 July
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46 ppendix D IPC Form Material Composition Declaration (page 2) 46
47 ppendix E IPC Form Material Composition Declaration (page 3) 47
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