Coordination Polymers Containing Ferrocene Backbone. Synthesis, Structure and Electrochemistry
|
|
|
- Arthur Franklin
- 6 years ago
- Views:
Transcription
1 Coordination Polymers Containing Ferrocene Backbone. Synthesis, Structure and Electrochemistry Vadapalli Chandrasekhar*, and Ramalingam Thirumoorthi Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur , India Tel: , Fax: / [ ] Prof. V. Chandrasekhar Department of Chemistry Indian Institute of Technology, Kanpur Kanpur , India Fax: (+91) vc@iitk.ac.in
2 Alternate procedure for the synthesis of 3-6: A mixture of 2 (0.050 g, mmol), 4-methylpyridine (0.005 g) /4,4 -bipyridine (0.008 g) or 4,4 - trimethylenebipyridine (0.010 g) or 4,4 -vinylenebipyridine (0.009 g) were heated in toluene (20 ml) under reflux for 2h. The reaction mixture was cooled and the solvent removed in vacuo to afford a yellow solid. This was washed with hexane (10 ml), Et 2 O (2 ml) dried and recrystallised to give pure samples of 3-6.
3 Figure S1. UV-visible spectra of 2-8.
4 Figure S2. ESI-MS of 2.
5 Figure S3. ESI-MS of 6. Inset picture shows the isotopic pattern of [(Ph 3 Sn) 2 LH(bpe)] +.
6 Figure S4. ESI-MS of 7.
7 Figure S5. ESI-MS of 8. Inset picture shows the isotopic pattern of [(n-bu 3 Sn) 4 (L)(LH)] +.
8
9 Figure S6. 2D polymeric structure of 8. Hydrogen atoms have been omitted.. Supramolecular structures of 2 and 5 Compound 2 shows an interesting supramolecular assembly in the solid-state due to two different types of π-stacking interactions. A C-H π interaction between the ferrocenyl C-H and the aromatic phenyl substituent on the tin (H22 π (2) Å) leads to the formation of a 1D polymer. Further, two such 1D polymers are interconnected by C-H of the edge of aryl with face of other aryl groups leading to a 2D polymer (H42 π (42); H41 π (41); H38 π (41); H39 π (41) Å) (Figure S7). In compound 5 we have observed interaction between two 1D polymers through dichloromethane due to two different C-H Cl interactions (H10 Cl (26) and H37 Cl (20) Å) between the chlorine atoms of dichloromethane and the C-H of the aryl group and a ferrocenyl group (Figure S8).
10 Figure S7. 2D polymeric structure of 2. 2D polymers arises due to two different C-H π interaction between molecules.
11 Figures S8. C-H Cl interactions between two different 1D polymers of 5. Except H10 and H37 remaining all the hydrogen atoms are removed for the clarity.
12 Table S1. Selected bond lengths (Å) and angles ( ) for compounds 2-5 Sn(1)-O(1) Sn(2)-O(2) Sn(1)-O(4) Sn(2)-O(3) 2.093(3) 2.061(3) 2.552(3) 2.794(3) 2 C(19)-O(1) C(30)-O(2) C(30)-O(3) C(19)-O(4) 1.324(5) 1.314(5) 1.225(5) 1.233(5) O(1)-Sn(1)-O(4) O(1)-Sn(1)-C(13) O(1)-Sn(1)-C(1) C(13)-Sn(1)-C(1) C(1)-Sn(1)-O(4) C(7)-Sn(1)-O(4) C(31)-Sn(2)-C(43) O(2)-Sn(2)-C(37) Sn(1)-O(2) Sn(1)-N(1) 55.93(10) (13) (13) (16) 83.10(13) (14) (17) (14) 2.146(4) 2.485(4) 3 O(1)-Sn(1)-C(7) C(13)-Sn(1)-C(7) C(1)-Sn(1)-C(7) C(13)-Sn(1)-O(4) O(2)-Sn(2)-C(31) O(2)-Sn(2)-C(43) C(31)-Sn(2)-C(37) C(43)-Sn(2)-C(37) O(1)-C(25) O(2)-C(25) 99.66(14) (16) (16) 81.55(13) (14) (14) (17) (16) 1.210(7) 1.301(6) C(19)-Sn(1)-C(7) C(19)-Sn(1)-O(2) C(7)-Sn(1)-O(2) C(19)-Sn(1)-C(13) C(7)-Sn(1)-C(13) Sn(1)-O(1) Sn(2)-O(3) Sn(1)-N(1) 126.4(2) 96.28(17) 97.86(16) (19) (19) 2.121(3) 2.121(3) 2.621(4) 4 O(2)-Sn(1)-C(13) C(19)-Sn(1)-N(1) C(7)-Sn(1)-N(1) O(2)-Sn(1)-N(1) C(13)-Sn(1)-N(1) Sn(2)-N(2) C(1)-O(1) C(1)-O(2) 89.54(17) 84.40(17) 83.97(16) (14) 87.64(17) 2.628(4) 1.314(6) 1.220(6) O(1)-Sn(1)-C(8) O(1)-Sn(1)-C(14) C(8)-Sn(1)-C(14) O(1)-Sn(1)-C(2) C(8)-Sn(1)-C(2) C(14)-Sn(1)-C(2) Sn(1)-O(1) Sn(2)-O(3) 98.82(16) 94.44(15) (19) 90.93(16) (18) (18) 2.135(4) 2.107(4) 5 C(42)-Sn(2)-O(3) C(42)-Sn(2)-C(30) O(3)-Sn(2)-C(30) C(42)-Sn(2)-C(36) O(3)-Sn(2)-C(36) C(30)-Sn(2)-C(36) C(32)-O(1) C(32)-O(2) (15) (18) 92.86(15) (18) 90.87(16) (19) 1.295(7) 1.237(7)
13 Sn(1)-N(2) Sn(2)-N(1) 2.598(4) 2.667(5) C(43)-O(3) C(43)-O(4) 1.313(7) 1.216(7) C(20)-Sn(1)-C(26) C(20)-Sn(1)-O(1) C(26)-Sn(1)-O(1) C(20)-Sn(1)-C(14) C(26)-Sn(1)-C(14) O(1)-Sn(1)-C(14) C(20)-Sn(1)-N(2) C(26)-Sn(1)-N(2) 129.5(2) 95.17(18) 97.37(17) 115.4(2) 113.5(2) 89.56(18) 84.54(18) 83.33(17) O(1)-Sn(1)-N(2) C(14)-Sn(1)-N(2) C(50)-Sn(2)-O(3) C(50)-Sn(2)-C(56) O(3)-Sn(2)-C(56) C(50)-Sn(2)-C(44) O(3)-Sn(2)-C(44) C(56)-Sn(2)-C(44) Table S2. Selected bond lengths (Å) and angles ( ) for compounds (14) 89.95(18) 97.19(17) 126.9(2) 96.47(19) 116.5(2) 89.89(19) 114.6(2) Sn(1)-O(1) Sn(1)-N(1) 2.127(3) 2.579(4) 6 O(1)-C(6) O(2)-C(6) 1.316(6) 1.214(6) C(13)-Sn(1)-O(1) C(13)-Sn(1)-C(7) O(1)-Sn(1)-C(7) C(13)-Sn(1)-C(19) O(1)-Sn(1)-C(19) C(7)-Sn(1)-C(19) Sn(1)-O(1) Sn(2)-O(2) 99.31(17) 124.4(2) 95.09(17) 116.5(2) 89.23(17) (19) 2.138(3) 2.494(3) 7 C(7)-Sn(1)-C(19) C(13)-Sn(1)-N(1) O(1)-Sn(1)-N(1) C(7)-Sn(1)-N(1) C(19)-Sn(1)-N(1) C(4)-O(1) C(4)-O(2) (19) 83.35(16) (14) 82.94(17) 90.02(17) 1.278(5) 1.229(5) C(2)-Sn(1)-C(3) C(2)-Sn(1)-C(1) C(3)-Sn(1)-C(1) C(2)-Sn(1)-O(1) C(3)-Sn(1)-O(1) Sn(1)-O(1) Sn(1)-O(2) Sn(1)-O(3) 123.4(2) 119.7(3) 115.4(3) 95.81(17) 97.28(18) 2.156(3) 2.444(4) 2.507(8) 8 O(1)-Sn(1)-O(2) C(1)-Sn(1)-O(1) C(2)-Sn(1)-O(2) C(3)-Sn(1)-O(2) C(13)-O(1) C(13)-O(2) (12) 89.08(18) 83.37(16) 88.47(17) 1.275(6) 1.251(6) C(5)-Sn(1)-C(1) C(5)-Sn(1)-C(9) C(1)-Sn(1)-C(9) C(5)-Sn(1)-O(1) C(1)-Sn(1)-O(1) C(9)-Sn(1)-O(1) C(9)-Sn(1)-O(3) O(1)-Sn(1)-O(3) 122.0(2) 111.3(2) 124.1(2) 89.90(17) 97.58(19) 98.43(18) 107.3(2) 131.0(2) C(5)-Sn(1)-O(2) C(1)-Sn(1)-O(2) C(9)-Sn(1)-O(2) O(1)-Sn(1)-O(2) C(5)-Sn(1)-O(3) C(1)-Sn(1)-O(3) O(2)-Sn(1)-O(3) 83.51(17) 81.73(19) 88.75(18) (13) 42.1(2) 101.1(2) 41.74(19)
Supporting Information
Supporting Information Wiley-VCH 2008 69451 Weinheim, Germany Supporting Information Unmasking Representative Structures of TMP-Active Hauser and Turbo Hauser Bases Pablo García-Álvarez, David V. Graham,
Selective total encapsulation of the sulfate anion by neutral nano-jars
Supporting Information for Selective total encapsulation of the sulfate anion by neutral nano-jars Isurika R. Fernando, Stuart A. Surmann, Alexander A. Urech, Alexander M. Poulsen and Gellert Mezei* Department
Electronic supplementary information. Strong CIE activity, multi-stimuli-responsive fluorescence and data
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 2015 Electronic supplementary information Strong CIE activity, multi-stimuli-responsive
Electronic Supporting Information
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2014 Electronic Supporting Information Assembly of HeterobimetallicNi II -Ln III (Ln III
Ru(II)-Catalyzed Annulation of Benzamidines and Alkynes by C-H/N-H Activation: A Facile Synthesis of 1- Aminoisoquinolines. Supporting Information
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2017 Ru(II)-Catalyzed Annulation of Benzamidines and Alkynes by C-H/N-H Activation:
C-H Activation Reactions of Ruthenium N-Heterocyclic Carbene. Complexes: Application in a Catalytic Tandem Reaction Involving C-C
SUPPORTING INFORMATION C-H Activation Reactions of Ruthenium N-Heterocyclic Carbene Complexes: Application in a Catalytic Tandem Reaction Involving C-C Bond Formation from Alcohols Suzanne Burling, Belinda
Supplemental Information
Supplemental Information Template-controlled Face-to-Face Stacking of Olefinic and Aromatic Carboxylic Acids in the Solid State Xuefeng Mei, Shuanglong Liu and Christian Wolf* Department of Chemistry,
Tetrahydrofuran (THF) was distilled from benzophenone ketyl radical under an argon
SUPPLEMENTARY METHODS Solvents, reagents and synthetic procedures All reactions were carried out under an argon atmosphere unless otherwise specified. Tetrahydrofuran (THF) was distilled from benzophenone
1G (bottom) with the phase-transition temperatures in C and associated enthalpy changes (in
Supplementary Figure 1. Optical properties of 1 in various solvents. UV/Vis (left axis) and fluorescence spectra (right axis, ex = 420 nm) of 1 in hexane (blue lines), toluene (green lines), THF (yellow
Supplementary Material
10.1071/CH17506_AC CSIRO 2018 Australian Journal of Chemistry 2018, 71(5), 341-347 Supplementary Material Magnesium alkoxide complexes of (benzimidazolylmethyl)amino ligands: Synthesis and applications
Stille-type cross coupling reactions with tetraalkynyl stannanes
Stille-type cross coupling reactions with tetraalkynyl stannanes Andrey S. Levashov,* Dmitriy S. Buriy, Valeriy V. Konshin and Alexey A. Andreev (deceased) Kuban State University, 149 Stavropolskaya Str.,
Red Color CPL Emission of Chiral 1,2-DACH-based Polymers via. Chiral Transfer of the Conjugated Chain Backbone Structure
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2015 Red Color CPL Emission of Chiral 1,2-DACH-based Polymers via Chiral Transfer of the Conjugated
Supporting Information. A rapid and efficient synthetic route to terminal. arylacetylenes by tetrabutylammonium hydroxide- and
Supporting Information for A rapid and efficient synthetic route to terminal arylacetylenes by tetrabutylammonium hydroxide- and methanol-catalyzed cleavage of 4-aryl-2-methyl-3- butyn-2-ols Jie Li and
Electronic Supplementary Information
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information for uminum complexes containing salicylbenzoxazole
Mariana Gonda, Marcos Nieves, Elia Nunes, Adela López de Ceráin, Antonio Monge, María Laura Lavaggi, Mercedes González and Hugo Cerecetto
Phenazine, -dioxide scaffold as selective hypoxic cytotoxin pharmacophore. Structural modifications looking for further DA topoisomerase II-inhibition activity Mariana Gonda, Marcos ieves, Elia unes, Adela
Supporting Information. Cells. Mian Wang, Yanglei Yuan, Hongmei Wang* and Zhaohai Qin*
Electronic Supplementary Material (ESI) for Analyst. This journal is The Royal Society of Chemistry 2015 Supporting Information Fluorescent and Colorimetric Probe Containing Oxime-Ether for Pd 2+ in Pure
Supporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Supporting Information TEMPO-catalyzed Synthesis of 5-Substituted Isoxazoles from Propargylic
Supporting Information
Supporting Information New Hexaphosphane Ligands 1,3,5-C 6 H 3 {p-c 6 H 4 N(PX 2 ) 2 } 3 [X = Cl, F, C 6 H 3 OMe(C 3 H 5 )]: Synthesis, Derivatization and, Palladium(II) and Platinum(II) Complexes Sowmya
Supporting Information
ne-pot synthesis of pyrrolidino- and piperidinoquinolinones by three-component aza-diels Alder reactions of -arylimines with in situ generated cyclic enamides. Wenxue Zhang, Yisi Dai, Xuerui Wang, Wei
Syntheses and Structures of Mono-, Di- and Tetranuclear Rhodium or Iridium Complexes of Thiacalix[4]arene Derivatives
![Syntheses and Structures of Mono-, Di- and Tetranuclear Rhodium or Iridium Complexes of Thiacalix[4]arene Derivatives](/thumbs/88/115555933.jpg "Syntheses and Structures of Mono-, Di- and Tetranuclear Rhodium or Iridium Complexes of Thiacalix[4]arene Derivatives")
Supplementary Information Syntheses and Structures of Mono-, Di- and Tetranuclear Rhodium or Iridium Complexes of Thiacalix[4]arene Derivatives Kenji Hirata, Toshiaki Suzuki, Ai Noya, Izuru Takei and Masanobu
Supporting information
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 205 A simple and greener approach
Supporting Information Reagents. Physical methods. Synthesis of ligands and nickel complexes.
Supporting Information for Catalytic Water Oxidation by A Bio-inspired Nickel Complex with Redox Active Ligand Dong Wang* and Charlie O. Bruner Department of Chemistry and Biochemistry and Center for Biomolecular
Supporting Text Synthesis of (2 S ,3 S )-2,3-bis(3-bromophenoxy)butane (3). Synthesis of (2 S ,3 S
Supporting Text Synthesis of (2S,3S)-2,3-bis(3-bromophenoxy)butane (3). Under N 2 atmosphere and at room temperature, a mixture of 3-bromophenol (0.746 g, 4.3 mmol) and Cs 2 C 3 (2.81 g, 8.6 mmol) in DMS
Supporting Information
Supporting Information An efficient and general method for the Heck and Buchwald- Hartwig coupling reactions of aryl chlorides Dong-Hwan Lee, Abu Taher, Shahin Hossain and Myung-Jong Jin* Department of
Supporting Information
Supporting Information An Extremely Active and General Catalyst for Suzuki Coupling Reactions of Unreactive Aryl Chlorides Dong-Hwan Lee and Myung-Jong Jin* School of Chemical Science and Engineering,
A versatile electronic hole in one-electron oxidized Ni II bissalicylidene
Electronic Supplementary Information for manuscript: A versatile electronic hole in one-electron oxidized Ni II bissalicylidene phenylenediamine complexes Olaf Rotthaus, Olivier Jarjayes,* Carlos Perez
Synthesis and characterization of a new triptycene based tripod
Synthesis and characterization of a new triptycene based tripod Jesús Sanmartín Matalobos a,*, Ana M. García Deibe a, Matilde Fondo a, J. Luis Pérez Lustres b, Sourav Bhowmick c and Neeladri Das c adpto.
Chia-Shing Wu, Huai-An Lu, Chiao-Pei Chen, Tzung-Fang Guo and Yun Chen*
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry Supporting Information Water/alcohol soluble electron injection material containing azacrown ether groups: Synthesis, characterization
Reversible dioxygen binding on asymmetric dinuclear rhodium centres
Electronic Supporting Information for Reversible dioxygen binding on asymmetric dinuclear rhodium centres Takayuki Nakajima,* Miyuki Sakamoto, Sachi Kurai, Bunsho Kure, Tomoaki Tanase* Department of Chemistry,
Aziridine in Polymers: A Strategy to Functionalize Polymers by Ring- Opening Reaction of Aziridine
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information (ESI) Aziridine in Polymers: A Strategy to Functionalize
Department of Chemistry, Indian Institute of Technology, Kharagpur , India
One-dimensional Coordination Polymers of Bis-(3-pyridylacrylamido)ethane: Influence of Anions and Metal Ions on Their Solid State [2+2] Photochemical Polymerization and Dimerization Reactions Mousumi Garai
ph-responsive assembly and disassembly of a supramolecular cryptand-based pseudorotaxane driven by π-π stacking interaction
ph-responsive assembly and disassembly of a supramolecular cryptand-based pseudorotaxane driven by π-π stacking interaction Xuzhou Yan, Mingming Zhang, Peifa Wei, Bo Zheng, Xiaodong Chi, Xiaofan Ji, and
Supporting Information
Supporting Information Distinct Mechanoresponsive Luminescence, Thermochromism, Vapochromism and Chlorine Gas Sensing by a Solid-State Organic Emitter S1 Figure S1. 1 H NMR (in CDCl 3 ) spectra of as synthesized
Supporting Information. for. Angew. Chem. Int. Ed. Z Wiley-VCH 2003
Supporting Information for Angew. Chem. Int. Ed. Z50567 Wiley-VCH 2003 69451 Weinheim, Germany Metallacarborane-Based Nanostructures: A Carbon-Wired Planar Octagon** Haijun Yao, Michal Sabat, and Russell
Electronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry B. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Rapid detection of intracellular Cys
An unexpected highly selective mononuclear zinc complex for adenosine diphosphate (ADP)
This journal is The Royal Society of Chemistry 213 Supplementary Information for An unexpected highly selective mononuclear zinc complex for adenosine diphosphate (ADP) Lei Shi, Ping Hu, Yanliang Ren and
Supplementary Information
Supplementary Information Supramolecular polymerization of hydrogen-bonded rosettes with anthracene chromophores: regioisomeric effect on nanostructures Deepak D. Prabhu, Keisuke Aratsu, Mitsuaki Yamauchi,
Supporting Information
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2015 Supporting Information Single-Crystal-to-Single-Crystal Transformation of an Anion Exchangeable
Electronic Supplementary Information. for. A New Strategy for Highly Selective Fluorescent Sensing of F - and
Electronic Supplementary Information for A New Strategy for Highly Selective Fluorescent Sensing of F - and Zn 2+ with Dual Output Modes Yinyin Bao, Bin Liu, Fanfan Du, Jiao Tian, Hu Wang, Ruke Bai* CAS
Supporting Information
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2017 Supporting Information Sulfonato-imino copper(ii) complexes : fast and general Chan-
Supporting Information Water-soluble 1,2,4-Triazole with Diethylene Glycol Monoethyl Ether
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is The Royal Society of Chemistry 2014 Supporting Information Water-soluble 1,2,4-Triazole with Diethylene
Electropolymerization of cobalto(5,10,15-tris(4-aminophenyl)- 20-phenylporphyrin) for electrochemical detection of antioxidant-antipyrine
Supplementary material Electropolymerization of cobalto(5,10,15-tris(4-aminophenyl)- 20-phenylporphyrin) for electrochemical detection of antioxidant-antipyrine Sambandam Anandan* a, Arumugam Manivel a,
A Photocleavable Linker for the Chemoselective Functionalization of Biomaterials
Electronic Supplementary Information A otocleavable Linker for the Chemoselective Functionalization of Biomaterials Liz Donovan and Paul A. De Bank* Department of armacy and armacology and Centre for Regenerative
Large-scale synthesis of alkyne-linked tripodal porphyrins via palladiummediated coupling conditions
Supporting information for Chemical Communication Large-scale synthesis of alkyne-linked tripodal porphyrins via palladiummediated coupling conditions Lok H. Tong, Sofia I. Pascu, Thibaut Jarrosson and
Supporting Information. for. A two step synthesis of a key unit B precursor of. cryptophycins by asymmetric hydrogenation
Supporting Information for A two step synthesis of a key unit B precursor of cryptophycins by asymmetric hydrogenation Benedikt Sammet, Mathilde Brax and Norbert Sewald* Address: Bielefeld University,
David L. Davies,*, 1 Charles E. Ellul, 1 Stuart A. Macgregor,*, 2 Claire L. McMullin 2 and Kuldip Singh. 1. Table of contents. General information
Experimental Supporting Information for Experimental and DFT Studies Explain Solvent Control of C-H Activation and Product Selectivity in the Rh(III)-Catalyzed Formation of eutral and Cationic Heterocycles
Indium Triflate-Assisted Nucleophilic Aromatic Substitution Reactions of. Nitrosobezene-Derived Cycloadducts with Alcohols
Supporting Information Indium Triflate-Assisted ucleophilic Aromatic Substitution Reactions of itrosobezene-derived Cycloadducts with Alcohols Baiyuan Yang and Marvin J. Miller* Department of Chemistry
Nickel Cobalt Thiospinel Nanoparticles as Hydrodesulfurization Catalysts: Importance of Cation Position, Structural Stability and Sulfur Vacancy
Nickel Cobalt Thiospinel Nanoparticles as Hydrodesulfurization Catalysts: Importance of Cation Position, Structural Stability and Sulfur Vacancy Kun Guo a,b, Yi Ding c, Jun Luo c, and Zhixin Yu a,b * a
SUPPORTING INFORMATION
Iron nanoparticles in the coupling of alkyl halides with aryl Grignard reagents. Robin B. Bedford, Michael Betham, Duncan W. Bruce, Sean A. Davis, Robert M. Frost and Michael Hird. SUPPORTING INFORMATION
Supporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information Synthesis of Poly(dihydroxystyrene-block-styrene) (PDHSt-b-PSt) by the RAFT
Electronic Supplementary data. Metal exchange in lithiocuprates: implications for our. understanding of structure and reactivity
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2017 1 Electronic Supplementary data Metal exchange in lithiocuprates: implications for our
Supporting information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 2015 Supporting information Porosity induced emission: exploring color-controllable
PD Research Report for the 2014 year
PD Research Report for the 2014 year Name(Research group) GAYEN KRISHNANKA SHEKHAR (Professor T. Hamura s group, Graduate School of Science and Technology) Research Theme Synthesis of functionalized heptacenes
Synthesis of 1,2-glycerol carbonate from carbon dioxide: the role of methanol in fluid phase equilibrium
Electronic Supplementary Data Synthesis of 1,2-glycerol carbonate from carbon dioxide: the role of methanol in fluid phase equilibrium S Podila, L Plasseraud, H Cattey & D Ballivet-Tkatchenko* Université
Supporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 205 Supporting Information Synthesis and Structures of N-Arylcyano-β-diketiminate Zinc Complexes
SYNTHESIS AND ANTIBACTERIAL EVALUATION OF NOVEL 3,6- DISUBSTITUTED COUMARIN DERIVATIVES
SYNTHESIS AND ANTIBACTERIAL EVALUATION OF NOVEL 3,6- DISUBSTITUTED COUMARIN DERIVATIVES 1 Ravibabu Velpula, 1 Ramesh Gondru, 2 Yashodhara Velivela and 1 Rajitha Bavantula* 1 Department of Chemistry, National
Electronic Supporting Information for
Electronic Supporting Information for An efficient long fluorescence lifetime polymer-based sensor based on europium complex as chromophore for the specific detection of F -, CH 3 COO - -, and H 2 PO 4
Prabhat Gautam, Bhausaheb Dhokale, Shaikh M. Mobin and Rajneesh Misra*
Supporting Information Ferrocenyl BODIPYs: Synthesis, Structure and Properties Prabhat Gautam, Bhausaheb Dhokale, Shaikh M. Mobin and Rajneesh Misra* Department of Chemistry, Indian Institute of Technology
Supplementary Information
Supplementary Information C aryl -C alkyl bond formation from Cu(ClO 4 ) 2 -mediated oxidative cross coupling reaction between arenes and alkyllithium reagents through structurally well-defined Ar-Cu(III)
Electronic Supporting Information For. Accessing Heterobiaryls through Transition Metal-Free C-H Functionalization. Content
Electronic Supporting Information For Accessing Heterobiaryls through Transition Metal-Free C-H Functionalization Ananya Banik, Rupankar Paira*,, Bikash Kumar Shaw, Gonela Vijaykumar and Swadhin K. Mandal*,
Significant improvement of dye-sensitized solar cell. performance by a slim phenothiazine based dyes
Significant improvement of dye-sensitized solar cell performance by a slim phenothiazine based dyes Yong Hua, a Shuai Chang, b Dandan Huang, c Xuan Zhou, a Xunjin Zhu, *a,d Jianzhang Zhao, c Tao Chen,
Supporting Information
Supporting Information An Alternative Approach to Synthesis of 3-(4-chloro butyl)-1h-indole -5-carbonitrile: A key intermediate of Vilazodone hydrochloride, an antidepressant drug Anitha N, Sudhakar Reddy
SUPPORTING INFORMATION
SUPPRTIG IFRMATI Silver-catalyzed furoquinolines synthesis: From nitrogen effects to the use of silver imidazolate polymer as a new and robust silver catalyst Evelyne Parker, a icolas Leconte, b Thomas
Supporting Information. Copyright Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2008
Supporting Information Copyright Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, 2008 Synthesis of Axially Chiral 4,4 -Bipyridines and their Remarkably Selective Self- Assembly into Chiral Metallo-Supramolecular
Electronic Supplementary Information. Pd(diimine)Cl 2 Embedded Heterometallic Compounds with Porous Structures as Efficient Heterogeneous Catalysts
Electronic Supplementary Information Pd(diimine)Cl 2 Embedded Heterometallic Compounds with Porous Structures as Efficient Heterogeneous Catalysts Sheng-Li Huang, Ai-Quan Jia and Guo-Xin Jin* Experimental
Supplementary Information
Supplementary Information NE Difference Spectroscopy: SnPh 3 CH (b) Me (b) C()CH (a) Me (a) C()N Me (d) Me (c) Irradiated signal Enhanced signal(s) (%) Me (a) Me (c) 0.5, Me (d) 0.6 Me (b) - Me (c) H (a)
Supporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 205 Supporting Information ortho-alkenylation of anilines with aromatic terminal alkynes over nanosized
Synthesis and Use of QCy7-derived Modular Probes for Detection and. Imaging of Biologically Relevant Analytes. Supplementary Methods
Synthesis and Use of QCy7-derived Modular Probes for Detection and Imaging of Biologically Relevant Analytes Supplementary Methods Orit Redy a, Einat Kisin-Finfer a, Shiran Ferber b Ronit Satchi-Fainaro
pyrazoles/isoxazoles library using ketene dithioacetals
Water mediated construction of trisubstituted pyrazoles/isoxazoles library using ketene dithioacetals Mahesh M. Savant, Akshay M. Pansuriya, Chirag V. Bhuva, Naval Kapuriya, Anil S. Patel, Vipul B. Audichya,
Tuning Porosity and Activity of Microporous Polymer Network Organocatalysts by Co-Polymerisation
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information Tuning Porosity and Activity of Microporous Polymer Network Organocatalysts
Redox-Responsive Complexation between a. Pillar[5]arene with Mono ethylene oxide Substituents. and Paraquat
![Redox-Responsive Complexation between a. Pillar[5]arene with Mono ethylene oxide Substituents. and Paraquat](/thumbs/93/111729438.jpg "Redox-Responsive Complexation between a. Pillar[5]arene with Mono ethylene oxide Substituents. and Paraquat")
Redox-Responsive Complexation between a Pillar[5]arene with Mono ethylene oxide Substituents and Paraquat Xiaodong Chi, Min Xue, Yong Yao and Feihe Huang* MOE Key Laboratory of Macromolecular Synthesis
Organocatalytic asymmetric biomimetic transamination of aromatic ketone to optically active amine
Organocatalytic asymmetric biomimetic transamination of aromatic ketone to optically active amine Ying Xie, a Hongjie Pan, a Xiao Xiao, a Songlei Li a and Yian Shi* a,b a Beijing National Laboratory for
N-[2-(dimethylamino)ethyl]-1,8-naphthalimide Derivatives as Photoinitiators under LEDs
![N-[2-(dimethylamino)ethyl]-1,8-naphthalimide Derivatives as Photoinitiators under LEDs](/thumbs/95/123546849.jpg "N-[2-(dimethylamino)ethyl]-1,8-naphthalimide Derivatives as Photoinitiators under LEDs")
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 18 Supporting Information: -[2-(dimethylamino)ethyl]-1,8-naphthalimide Derivatives as Photoinitiators
Electronic Supplementary Information
Electronic Supplementary Information Early-Late Heterobimetallic Rh-Ti and Rh-Zr Complexes via Addition of Early Metal Chlorides to Mono- and Divalent Rhodium Dan A. Smith and Oleg V. Ozerov* Department
Solid-Supported DNA for Asymmetric Synthesis: a Stepping Stone toward Practical Applications
Solid-Supported DA for Asymmetric Synthesis: a Stepping Stone toward Practical Applications Soyoung Park, * a Keiichi Ikehata, a and iroshi Sugiyama*,a,b,c a Department of Chemistry, Graduate School of
Highly Efficient Blue Electroluminescence Using Delayed- Fluorescence Emitters with Large Overlap Density between Luminescent and Ground States
Highly Efficient Blue Electroluminescence Using Delayed- Fluorescence Emitters with Large Overlap Density between Luminescent and Ground States Katsuyuki Shizu,,, Hiroki Noda, Hiroyuki Tanaka, Masatsugu
Supporting Information
Supporting Information for Macromol. Chem. Phys, DOI: 10.1002/macp.201700302 Phase Segregation in Supramolecular Polymers Based on Telechelics Synthesized via Multicomponent Reactions Ansgar Sehlinger,
Supporting Information. Identification and synthesis of impurities formed during sertindole
Supporting Information Identification and synthesis of impurities formed during sertindole preparation I. V. Sunil Kumar* 1, G. S. R. Anjaneyulu 1 and V. Hima Bindu 2 for Address: 1 Research and Development
Supporting Information
Supporting Information Precision Synthesis of Poly(-hexylpyrrole) and its Diblock Copolymer with Poly(p-phenylene) via Catalyst-Transfer Polycondensation Akihiro Yokoyama, Akira Kato, Ryo Miyakoshi, and
Supporting Information. for. Angew. Chem. Int. Ed. Z Wiley-VCH 2003
Supporting Information for Angew. Chem. Int. Ed. Z53001 Wiley-VCH 2003 69451 Weinheim, Germany 1 Ordered Self-Assembly and Electronic Behavior of C 60 -Anthrylphenylacetylene Hybrid ** Seok Ho Kang 1,
Supporting Information. Excited State Relaxation Dynamics of Model GFP Chromophore Analogs: Evidence for cis-trans isomerism
Supporting Information Excited State Relaxation Dynamics of Model GFP Chromophore Analogs: Evidence for cis-trans isomerism Shahnawaz Rafiq, 1 Basanta Kumar Rajbongshi, 1 isanth. air, Pratik Sen,* and
SUPPLEMENTARY INFORMATION
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 SUPPLEMENTARY INFORMATION Novel hydrogen- and halogen-bonding anion receptors based on 3- iodopyridinium
Halogen halogen interactions in diiodo-xylenes
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) for CrystEngComm. This journal is The Royal Society
Supplementary Information. Solvent-Dependent Conductance Decay Constants in Single Cluster. Junctions
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2016 Supplementary Information Solvent-Dependent Conductance Decay Constants in Single Cluster
Rare double spin canting antiferromagnetic behaviours in a. [Co 24 ] cluster
![Rare double spin canting antiferromagnetic behaviours in a. [Co 24 ] cluster](/thumbs/76/73822148.jpg "Rare double spin canting antiferromagnetic behaviours in a. [Co 24 ] cluster")
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Rare double spin canting antiferromagnetic behaviours in a [Co 24 ] cluster Guang-Ming Liang, Qing-Ling
Aggregation-induced emission enhancement based on 11,11,12,12,-tetracyano-9,10-anthraquinodimethane
Electronic Supplementary Information (ESI) Aggregation-induced emission enhancement based on 11,11,12,12,-tetracyano-9,10-anthraquinodimethane Jie Liu, ab Qing Meng, a Xiaotao Zhang, a Xiuqiang Lu, a Ping
Electronic Supplementary Information (12 pages)
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 A C 2 -responsive pillar[5]arene: synthesis and self-assembly in water Kecheng Jie, Yong Yao, Xiaodong
Stereoselective Synthesis of (-) Acanthoic Acid
1 Stereoselective Synthesis of (-) Acanthoic Acid Taotao Ling, Bryan A. Kramer, Michael A. Palladino, and Emmanuel A. Theodorakis* Department of Chemistry and Biochemistry, University of California, San
Electronic Supporting Information
Electronic Supporting Information Reactions of Tp(NH=CPh 2 )(PPh 3 )Ru Cl with HC CPh in the presence of H 2 O: Insertion/Hydration Products Chih-Jen Cheng, a Hung-Chun Tong, a Yih-Hsing Lo,* b Po-Yo Wang,
Rhenium(I)-Based Monocyclic- and Bicyclic Phosphine Oxide Coordinated. Supramolecular Complexes
Supporting Information Rhenium(I)-Based Monocyclic- and Bicyclic Phosphine Oxide Coordinated Supramolecular Complexes Bhaskaran Shankar, Ramar Arumugam, Palani Elumalai, and Malaichamy Sathiyendiran*,
Electronic Supplementary Information. Highly Efficient Deep-Blue Emitting Organic Light Emitting Diode Based on the
Electronic Supplementary Information Highly Efficient Deep-Blue Emitting rganic Light Emitting Diode Based on the Multifunctional Fluorescent Molecule Comprising Covalently Bonded Carbazole and Anthracene
SUPPORTING INFORMATION
Dynamic covalent templated-synthesis of [c2]daisy chains. Altan Bozdemir, a Gokhan Barin, a Matthew E. Belowich, a Ashish. Basuray, a Florian Beuerle, a and J. Fraser Stoddart* ab a b Department of Chemistry,
Experimental details
Supporting Information for A scalable synthesis of the (S)-4-(tert-butyl)-2-(pyridin-2-yl)-4,5-dihydrooxazole ((S)-t-BuPyx) ligand Hideki Shimizu 1,2, Jeffrey C. Holder 1 and Brian M. Stoltz* 1 Address:
1 Controlled emission colors and singlet triplet. 2 energy gaps of dihydrophenazine-based thermally. 3 activated delayed fluorescence emitters
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 015 1 Controlled emission colors and singlet triplet energy gaps of dihydrophenazine-based
Electronic Supporting Information. for. Group 13 Complexes of Dipyridylmethane, a Forgotten Ligand in Coordination Chemistry
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2015 Electronic Supporting Information for Group 13 Complexes of Dipyridylmethane, a Forgotten
Chiral Sila[1]ferrocenophanes
![Chiral Sila[1]ferrocenophanes](/thumbs/94/121763767.jpg "Chiral Sila[1]ferrocenophanes")
Supporting Information Thermal Ring-Opening Polymerization of Planar- Chiral Sila[1]ferrocenophanes Elaheh Khozeimeh Sarbisheh, Jose Esteban Flores, Brady Anderson, Jianfeng Zhu, # and Jens Müller*, Department
Electronic Supplementary Information. Jiani Wang, Lei Zhang, Qiong Qi, Shunhua Li* and Yunbao Jiang
Electronic Supplementary Information Specific ratiometric fluorescent sensing of Hg 2+ via the formation of mercury(ii) barbiturate coordination polymers Jiani Wang, Lei Zhang, Qiong Qi, Shunhua Li* and
Electronic Supplementary Information
Electronic Supplementary Information General and highly active catalyst for mono and double Hiyama coupling reactions of unreactive aryl chlorides in water Dong-Hwan Lee, Ji-Young Jung, and Myung-Jong
Aminoacid Based Chiral N-Amidothioureas. Acetate Anion. Binding Induced Chirality Transfer
Aminoacid Based Chiral -Amidothioureas. Acetate Anion Binding Induced Chirality Transfer Fang Wang, a Wen-Bin He, a Jin-He Wang, a Xiao-Sheng Yan, a Ying Zhan, a Ying-Ying Ma, b Li-Cai Ye, a Rui Yang,
SUPPORTING INFORMATION
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 SUPPORTING INFORMATION Activation of 1, 3-dioxolane by protic ionic liquid in aqueous media: