1. A. Adam, M. Duewel, W. Brockner and M. Gjikaj Crystal structure of bis [(18-crown-6)potassium] hexathiodiphosphate(v) acetonitrile disolvate, [K(C
|
|
- Job Manning
- 6 years ago
- Views:
Transcription
1 1. A. Adam, M. Duewel, W. Brockner and M. Gjikaj Crystal structure of bis [(18-crown-6)potassium] hexathiodiphosphate(v) acetonitrile disolvate, [K(C 12 H 24 O 6 )] 2 (P 2 S 6 ) 2 CH 3 CN Z. Kristallogr. NCS 220 (2005) M. Gjikaj and W. Brockner Synthesis and vibrational spectrum of potassium (18-crown-6) hexathiodiphosphate(v) acetonitrile solvate, [K(18-crown-6)] 2 [P 2 S 6 ] 2 CH 3 CN Vibrational Spectroscopy 39 (2005) W. Brockner, A. Adam and M. Gjikaj Stabilisation of highly reactive naked anions : Synthesis, crystal structure and vibrational spectrum of [Na(12-crown-4) 2 ] 2 [P 2 S 6 ] CH 3 CN Z. Anorg. Allg. Chem. 632 (2006) A. Adam and M. Gjikaj Stabilisierung hochreaktiver nackter Anionen : Darstellung, Kristallstruktur und Schwingungsspektrum von [Na(12-Krone-4) 2 ] 2 [P 2 S 6 ] CH 3 CN Z. Kristallogr. Supp. 24 (2006) M. Gjikaj Ein neues Alkalimetall-Hexathiometadiphosphat, Rb 2 P 2 S 6 Z. Kristallogr. Supp. 24 (2006) C. Ehrhardt, W. Brockner and M. Gjikaj Rb 2 P 2 S 6 - A New Alkali Thiophosphate: Crystal Structure and Vibrational Spectra of Rubidium Hexathiodiphosphate(V) Z. Naturforsch. 61b (2006) F. Hinrichs and M. Gjikaj Crystal structure of hexaaquamagnesium diammonium hexathiodiphosphate(iv) dihydrate, [Mg(H 2 O) 6 ](NH 4 ) 2 [P 2 S 6 ] 2 H 2 O Z. Kristallogr. NCS 221 (2006) C. Ehrhardt and M. Gjikaj Crystal structure of strontium hexathiodiphosphate(iv) decahydrate, Sr 2 [P 2 S 6 ] 10 H 2 O Z. Kristallogr. NCS 221 (2006) 437.
2 9. A. Adam and M. Gjikaj Complexation of Alkali Triflates by Crown Ethers: Synthesis and Crystal Structure of [Na(12-crown-4) 2 ] [SO 3 CF 3 ], [Na(15-crown-5)] [SO 3 CF 3 ], [Rb(18-crown-6)] [SO 3 CF 3 ] and [Cs(18-crown-6)] [SO 3 CF 3 ] Z. Anorg. Allg. Chem. 632 (2006) C. Ehrhardt and M. Gjikaj New Hexachalcogeno Hypodiphosphates of the Alkali Metals: Synthesis, Crystal Structure and Vibrational Spectra of the Hexathiodiphosphate(IV) Hydrates K 4 [P 2 S 6 ] 4 H 2 O, Rb 4 [P 2 S 6 ] 6 H 2 O, and Cs 4 [P 2 S 6 ] 6 H 2 O Z. Anorg. Allg. Chem. 633 (2007) M. Gjikaj Synthesis, crystal structure and vibrational spectrum of [Na(15-crown-5)] 2 [P 2 S 6 ] 15. Jahrestagung der DGK, Bremen (2007), Coll. Abstr id W. Brockner and M. Gjikaj Crystal structure, vibrational spectrum and thermal behavior of the ammonium hexathiohypodiphosphate dihydrate, (NH 4 ) 4 P 2 S 6 2 H 2 O Z. Naturforsch. 62b (2007) M. Gjikaj, V. A. Zapol skii, J. C. Namyslo, D. E. Kaufmann Chemistry of polyhalogenated nitrobutadienes, 4: Reactions of Mono-, Bis-, and Tris(4- tolylthio) Derivatives of 2-Nitroperchlor-1,3-butadiene with α,β-bifunctional Nucleophiles Arkivoc (2007) M. Gjikaj, V. A. Zapol skii, J. C. Namyslo, D. E. Kaufmann Chemistry of Polyhalogenated Nitrobutadienes, 5: Synthesis and Reactions of Dichloromethyl Nitrovinylidene Ketones of Heterocycles Synlett 10 (2007) M. Gjikaj, A. Schmidt, B. Snovydovych, T. Habeck, P. Dröttboom, A. Adam N-Heterocyclic Carbenes of 5-Haloindazoles Generated by Decarboxylation of 5- Haloindazolium-3-carboxylates Eur. J. Org. Chem. (2007) 4909.
3 16. M. Gjikaj, A. Schmidt, T. Habeck, A. S. Lindner, B. Snovydovych, J. C. Namyslo, A. Adam Translation of Pseudo-Cross-Conjugation into Chemistry: Cycloadditions of Mesomeric Betaines to the New Ring System Spiro[indazole-3,3 -pyrrole] J. Org. Chem. 72 (2007) W. Brockner, J. Namyslo, A. Adam and M. Gjikaj Crown-ether enclosure generated by ionic liquid components Synthesis, crystal structure and Raman spectra of compounds of imidazolium based salts and 18-crown-6 CrystEngComm (2008) M. Gjikaj Crystal structure of Strontium Sodium Monothiophosphate Nonahydrate, SrNa[PO 3 S] 9 H 2 O Z. Kristallogr. NCS 223 (2008) M. Gjikaj Synthesis, Crystal Structure and Vibrational Spectrum of [EMI][(Na) 2 (OTf) 3 ] 15.Jahrestagung der DGK, Erlangen (2008) Coll. Abstr. 2B M. Gjikaj Synthesis and Crystal Structure of NaSr[PO 3 S] 9 H 2 O 16. Jahrestagung der DGK, Erlangen (2008) Coll. Abstr. 2B P. Wu and M. Gjikaj [1,2-P 2 S 8 ] 2 - a New Member of the Thiophosphate Family: Synthesis, Crystal Structure and Vibrational Spectrum of [NH 4 (2.2.2-cryptand)] 2 [1,2- P 2 S 8 ] and [NH 4 (18-crown-6)] 2 [1,2-P 2 S 8 ] H 2 O. Z. Anorg. Allg. Chem. 634 (2008) M. Gjikaj Crystal structure of bis(1,3-dimethylimidazolium hydrogen sulfate) 18-crown-6 (2:1), [C 5 H 9 N 2 ] 2 [HSO 4 ] 2 C 12 H 24 O 6 Z. Kristallogr. NCS 223 (2008) 379.
4 23. M. Gjikaj, V. A. Zapol skii, J. C. Namyslo, C. Altug, D. E. Kaufmann Chemistry of Polyhalogenated Nitrobutadienes, 6: A New Ring Closure Approach to Perfunctionalized 5-Nitropyrimidines Synthesis (2008) M. Gjikaj, A. Schmidt, B. Snovydovych, N-Heterocyclic Carbenes of Indazole. Ring Enlargement Reactions by alpha- Haloketones and Dehalogenations of Vicinal Dihalides Synthesis (2008) T. Xie, W. Brockner and M. Gjikaj, Uncommon compounds in antimony pentachloride ionic liquid systems: Synthesis, crystal structure and vibrational spectra of the complexes [TPT] [SbCl 6 ] and [Cl-EMIm] [SbCl 6 ] Z. Anorg. Allg. Chem. 635 (2009) T. Xie and M. Gjikaj Synthesis, crystal structure and vibrational spectrum of 2,3,5-triphenyltetrazolium hexachloroniobate(v) and oxotetrachloroniobate(v) acetonitrile, [TPT] [NbCl 6 ] and [TPT] [NbOCl 4 (CH 3 CN)] Z. Anorg. Allg. Chem. (2009) in press. 27. F. Stiemke, M. Gjikaj, D. E. Kaufmann Novel Approaches to Amino-Prostaglandins and Isoprostans, Part 1: Synthesis and Modification of Triazatricyclic Systems J. Org. Chem. (2009). 28. F. Stiemke, M. Gjikaj, D. E. Kaufmann Novel Triphenylarsinyl-functionalized N-Heterocyclic Carbene Ligands in Palladiumcatalyzed Reactions J. Organomet. Chem. 694 (2009) E. Schaumann, G. Harms, F. Genrich, M. Gjikaj, G. Adiwidjaja Functionalized Esters as Bis-Electrophiles in a Silicon-Induced Domino Synthesis of Annulated Carbocycles, Tetrahedron 65 (2009) 5577.
5 30. A. Schmidt, A. Rahimi, M. Gjikaj Sulfanyl-substituted [3]-Cumulenes and 1,3-Butadienes from a Tetrakis(pyridinium)- substituted Butadiene Synthesis (2009) S. Scherbakow, J. C. Namyslo, M. Gjikaj, A. Schmidt Syntheses of Amidines from Thioamides, Mediated by the N-Heterocyclic Carbene Indazol-3-ylidene Synlett (2009) A. Schmidt, A. Rahimi, M. Gjikaj Thieme Chemistry Journal Awardees - Where are they now? [3]-Cumulenes, Sulfanylsubstituted Butadienes and Functionalized Thiophenes Starting from Polypyridinium Salts. Synlett (2009), accepted for publication. 33. T. Xie, W. Brockner and M. Gjikaj Formation and crystal structure of 2,3,5-triphenyltetrazolium hexachlorophosphate and dichlorophosphate(v), [TPT][PCl 6 ] and [TPT][PO 2 Cl 2 ] Z. Naturforsch. 64b (2009) in press. 34. J. Ch. Leye, M. Gjikaj and A. Adam Synthesis, Crystal Structures, Thermal Properties and Spectroscopic Characterization of Complex Chloridotitanates(IV) with ionic liquids Eur. J. Inorg. Chem. (2009) in press.
Organic Chemistry 112 A B C - Syllabus Addendum for Prospective Teachers
Chapter Organic Chemistry 112 A B C - Syllabus Addendum for Prospective Teachers Ch 1-Structure and bonding Ch 2-Polar covalent bonds: Acids and bases McMurry, J. (2004) Organic Chemistry 6 th Edition
More informationSolubility Properties
Solubility Properties X-ray crystal structure of : dicyclohexyl[18]crown-6 and potassium complex of [18]crown-6. Structures are different: In the solid state In polar and apolar solvent As a complex 1
More informationCHAPTER 7: CHEMICAL FORMULAS AND CHEMICAL COMPOUNDS. Chemistry 1-2 Enriched Mr. Chumbley
CHAPTER 7: CHEMICAL FORMULAS AND CHEMICAL COMPOUNDS Chemistry 1-2 Enriched Mr. Chumbley SECTION 1: CHEMICAL NAMES AND FORMULAS While the bulk of the content will come from the Naming Chemical Compounds
More informationA New Alkali Thiophosphate: Crystal Structure and Vibrational Spectra of Rubidium Hexathiodiphosphate(V)
Rb 2 P 2 S 6 A New Alkali Thiophosphate: Crystal Structure and Vibrational Spectra of Rubidium Hexathiodiphosphate(V) Mimoza Gjikaj, Claus Ehrhardt, and Wolfgang Brockner Institute of Inorganic and Analytical
More informationBig Idea: Matter & Atoms
Big Idea: Matter & Atoms Naming Ionic Compounds Naming Covalent Compounds Naming Acids Naming Hydrates The cation (positive ion) is written first Takes the same name as the element if only forms one charge
More informationEnols and Enolates. A type of reaction with carbonyl compounds is an α-substitution (an electrophile adds to the α carbon of a carbonyl)
Enols and Enolates A type of reaction with carbonyl compounds is an α-substitution (an electrophile adds to the α carbon of a carbonyl) E+ E In the preceding chapters, we primarily studied nucleophiles
More informationFormation and Crystal Structure of 2,3,5-Triphenyltetrazolium Hexachlorophosphate and Dichlorophosphate(V), [TPT] + [PCl 6. ] and [TPT] + [PO 2
Formation and Crystal Structure of 2,3,5-Triphenyltetrazolium Hexachlorophosphate and Dichlorophosphate(V), [TPT] + [PCl 6 ] and [TPT] + [PO 2 Cl 2 ] Tao Xie, Wolfgang Brockner, and Mimoza Gjikaj Institut
More information3 Writing Formulas and Naming Compounds
3 Writing Formulas and Naming Compounds 6(D) Before You Read Shakespeare asked, What s in a name? In this section, you are going to learn what the names of chemical compounds can tell you. On the lines
More informationinsoluble partial very soluble (< 0.1 g/100ml) solubility (> 1 g/100ml) Factors Affecting Solubility in Water
Aqueous Solutions Solubility is a relative term since all solutes will have some solubility in water. Insoluble substances simply have extremely low solubility. The solubility rules are a general set of
More informationNomenclature. Naming Compounds
Nomenclature Naming Compounds Ionic Compounds Metal bonding with non-metal One atom gains electrons, one atom loses electrons Exist as ions with full highest energy levels. Are held together in a giant
More informationLecture Notes Chem 51C S. King Chapter 24 Carbonyl Condensation Reactions
Lecture Notes Chem 51C S. King Chapter 24 Carbonyl Condensation Reactions I. Reaction of Enols & Enolates with ther Carbonyls Enols and enolates are electron rich nucleophiles that react with a number
More informationJEFFERSON COLLEGE COURSE SYLLABUS CHM201 ORGANIC CHEMISTRY II. 5 Credit Hours. Prepared by: Richard A. Pierce
JEFFERSON COLLEGE COURSE SYLLABUS CHM201 ORGANIC CHEMISTRY II 5 Credit Hours Prepared by: Richard A. Pierce Revised Date: January 2008 by Ryan H. Groeneman Arts & Science Education Dr. Mindy Selsor, Dean
More informationQ1. Ionisation energies provide evidence for the arrangement of electrons in atoms. 1s 2... (1) (2)
Q1. Ionisation energies provide evidence for the arrangement of electrons in atoms. (a) Complete the electron configuration of the Mg + ion. 1s 2... (b) (i) State the meaning of the term first ionisation
More informationPage 1 of 9. Sessional Examination (November 2017) Max Marks: 20 Date: Time: One Hour. Model Answers
Page 1 of 9 Sessional Examination (November 2017) Class: B. Pharm-II yr (III sem) Subject: Pharma Org. Chem-II Max Marks: 20 Date: 14.11.2017 Time: One Hour Model Answers Q. 1. Solve the following (ANY
More informationA. Loupy, B.Tchoubar. Salt Effects in Organic and Organometallic Chemistry
A. Loupy, B.Tchoubar Salt Effects in Organic and Organometallic Chemistry 1 Introduction - Classification of Specific Salt Effects 1 1.1 Specific Salt Effects Involving the Salt's Lewis Acid or Base Character
More informationIonic Compounds and Metals
Ionic Compounds and Metals Chapter 7 Ch. 7.1 Chemical bond Cation Anion Vocabulary Ch. 7.2 Ionic bond Ionic compound Binary compound Crystal lattice Electrolyte Lattice energy 2 Objectives Define a chemical
More informationUNIT 12 Chemical Bonding. Practice Problems
Name Period CRHS Academic Chemistry UNIT 12 Chemical Bonding Practice Problems Due Date Assignment On-Time (100) Late (70) 12.1 12.2 12.3 12.4 12.5 Warm-Up EC Notes, Homework, Exam Reviews and Their KEYS
More informationElements and the Periodic Table
CHAPTER 6 Elements and the Periodic Table 6.2 Properties of Groups of Elements There are millions and millions of different kinds of matter (compounds) composed of the same 92 elements. These elements
More informationCHEM 1105 S10 January 21, 2014
CHEM 1105 S10 January 21, 2014 Chapter 3: Compounds and Formulas Today: Types of compounds: Ionic vs. covalent Naming ionic compounds Naming binary covalent compounds (two elements only) Ionic Bonding
More informationCHEM 103 Naming Compounds
CHEM 103 Naming Compounds Lecture Notes February 7, 2006 Prof. Sevian 1 Agenda How we name compounds depends on what kind of compounds they are Ionic compounds Molecular compounds Acids are molecular compounds
More informationMacroscopic, particle and symbolic representations of aqueous reactions
Macroscopic, particle and symbolic representations of aqueous reactions Name: DS: Learning Objective: After completing this activity, you should be able to understand the difference between macroscopic,
More informationHow many valence electrons are in an atom of magnesium?
How many valence electrons are in an atom of magnesium? 1. 2 2. 3 3. 4 4. 5 2 3 4 5 How many dots around a silicon atom in a Lewis Dot? 1. 2 2. 4 3. 6 4. 8 2 4 6 8 What is the charge on the strontium ion?
More informationBig Chemistry Quiz/Review
Big Chemistry Quiz/Review Name: 1.Indicate if each statement is true or false. (10 marks) T for True or F for False Statement Each element in a group on the periodic table has the same number of electrons
More informationHyperlearning MCAT Instructor Qualifying Exam Organic Chemistry
Hyperlearning MCAT Instructor Qualifying Exam Organic Chemistry 30 Questions (5 pages); Time limit = 45 minutes Use of books or notes is not permitted. 1. When analyzed with a polarimeter, which of the
More informationc. How many mm Hg are in 3.5 atm? b. How many seconds are in 28 hours?
Chemistry Fall Final Study Guide Unit 1: Matter, Elements & the Periodic Table 1. How many sig figs are in the following numbers? a. 89,501 b. 0.0290 c. 5,700 d. 2,000. e. 0.30600 2. Use the Conversion
More informationA dynamic, luminescent and entangled MOF as a qualitative sensor for volatile. organic solvents and quantitative monitor for acetonitrile vapour
Electronic Supplementary Information (ESI) for A dynamic, luminescent and entangled MOF as a qualitative sensor for volatile organic solvents and quantitative monitor for acetonitrile vapour Jun-Hao Wang,
More informationKey ideas: In EAS, pi bond is Nu and undergoes addition.
Objective 7. Apply addition and elimination concepts to predict electrophilic aromatic substitution reactions (EAS) of benzene and monosubstituted benzenes. Skills: Draw structure ID structural features
More informationFIVE MEMBERED AROMATIC HETEROCYCLES
FIVE MEMBERED AROMATIC HETEROCYCLES 63 Electrophilic aromatic substitution reaction of five membered aromatic heterocycles X = O, S or NH a-substitution b-substitution The Substitution is regioselective
More informationAtoms seldom exist as particles in nature. Oxygen you breathe and water you drink are combinations of that are held together by chemical bonds.
Ch 6 & 7 Ionic Bonding and Nomenclature Student Guided Notes Introduction to Chemical Bonding Atoms seldom exist as particles in nature. Oxygen you breathe and water you drink are combinations of that
More informationCHEMICAL COMPOUNDS AND THEIR CHARACTERISTIC PROPERTIES
Seminar_2 1. Chemical compounds and their characteristic properties. 2. Types of chemical bonds (theses). 3. Basic types of complex compounds (theses). 4. Stability of complex compounds. TEST 2_ Chemical
More informationNaming/Writing Chemical Formulas
Naming/Writing Chemical Formulas Chemical formulas A molecule s chemical formula tells you the ratio of atoms of each element in the compound. 2H 2 O Superscript Hydrogen How many of the element in front
More informationReactions in Aqueous Solutions Chang & Goldsby modified by Dr. Hahn
Reactions in Aqueous Solutions Chang & Goldsby modified by Dr. Hahn Chapter 4 Copyright McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
More informationPhysical Properties. Alcohols can be: CH CH 2 OH CH 2 CH 3 C OH CH 3. Secondary alcohol. Primary alcohol. Tertiary alcohol
Chapter 10: Structure and Synthesis of Alcohols 100 Physical Properties Alcohols can be: CH 3 CH 3 CH CH 2 OH * Primary alcohol CH 3 OH CH * CH 2 CH 3 Secondary alcohol CH 3 CH 3 * C OH CH 3 Tertiary alcohol
More informationOccurs when electrons are transferred electrostatic attractions (btw positive & negative atoms)
Ionic Bonding Ionic Bonding Occurs when electrons are transferred from one atom to another, forming two ions The ions stay together because of electrostatic attractions (btw positive & negative atoms)
More informationComplete Volume List for Science of Synthesis Volumes
Complete List for Science of Synthesis s Knowledge Update s Publication Date 1 Complete List for Science of Synthesis, by Georg Thieme Verlag KG ISBN/DOI Knowledge Update 2018/1 2018 502 978-3-13-242313-8
More informationChapter 2. The Components of Matter
Chapter 2. The Components of Matter 1 The Periodic Table (Section 2.6) 13 Al 26.981 Main Idea: 1. Groups: Old numbering system: New IUPAC numbering system: 2. Periods: 3. Know the names and properties
More informationCARBONYL COMPOUNDS: OXIDATION-REDUCTION REACTION
CARBONYL COMPOUNDS: OXIDATION-REDUCTION REACTION Introduction Several functional groups contain the carbonyl group Carbonyl groups can be converted into alcohols by various reactions Structure of the Carbonyl
More information2. Match the following NMR spectra with one of the following substances. Write you answer in the box along side the spectrum. (16 points) A B C D E F
2. Match the following NM spectra with one of the following substances. Write you answer in the box along side the spectrum H H (16 points) A B C H D E F 1. Match the following compounds with their 13
More information» Composed of more than one type of atom chemically bonded.» A pure substance, meaning its properties are the same throughout the substance.
» Composed of more than one type of atom chemically bonded.» A pure substance, meaning its properties are the same throughout the substance.» Separated chemically not physically» No overall charge; they
More informationOrganic Reactions Susbstitution S N. Dr. Sapna Gupta
Organic Reactions Susbstitution S N 2 Dr. Sapna Gupta Kinetics of Nucleophilic Reaction Rate law is order of reaction 0 order is when rate of reaction is unaffected by change in concentration of the reactants
More informationChapter 21. Organic Chemistry 4 th Edition Paula Yurkanis Bruice. More About Amines. Heterocyclic Compounds
Organic Chemistry 4 th Edition Paula Yurkanis Bruice Chapter 21 More About Amines. Heterocyclic Compounds Irene Lee Case Western Reserve University Cleveland, OH 2004, Prentice Hall Amines An amine is
More informationGeneral Chemistry II FINAL EXAMINATION
General Chemistry II 141 FINAL EXAMINATIN PART I ( points each) CHEM 141 (Fall 009) Version AF09 Multiple choice - scantron. Please D NT write or mark on this paper. Write your correct answer on 1. Which
More informationOrganic Reactions Susbstitution S N. Dr. Sapna Gupta
Organic Reactions Susbstitution S N 2 Dr. Sapna Gupta Kinetics of Nucleophilic Reaction Rate law is order of reaction 0 order is when rate of reaction is unaffected by change in concentration of the reactants
More informationKOT 222 Organic Chemistry II
KOT 222 Organic Chemistry II Course Objectives: 1) To introduce the chemistry of alcohols and ethers. 2) To study the chemistry of functional groups. 3) To learn the chemistry of aromatic compounds and
More informationAMINES. 3. From your knowledge of the effects involved, predict or explain experimental results. Important areas include:
AMINES A STUDENT SHOULD BE ABLE TO: 1. Name given the structure, and draw the structure given the name of amines and common nitrogen heterocycles (pyrrole and pyridine). Also, give the classification of
More informationChap 11. Carbonyl Alpha-Substitution Reactions and Condensation Reactions
Chap 11. Carbonyl Alpha-Substitution eactions and Condensation eactions Four fundamental reactions of carbonyl compounds 1) Nucleophilic addition (aldehydes and ketones) ) Nucleophilic acyl substitution
More informationKJM 3200 Required Reading (Pensum), Fall 2016
KJM 3200 Required Reading (Pensum), Fall 2016 John McMurry: Organic Chemistry 8 nd ed. or Paula Y. Bruice, Organic Chemistry 7 nd ed. as specified below, as specified below. Lise-Lotte Gundersen KJM 3200.
More information... [1] (ii) Draw a dot-and-cross diagram to show the bonding in NH 3
1 Chemists have developed models for bonding and structure which are used to explain different properties. (a) Ammonia, NH 3, is a covalent compound. Explain what is meant by a covalent bond. Draw a dot-and-cross
More informationName Date Period Ionic Bonding Puzzle Activity
Name Date Period Ionic Bonding Puzzle Activity Introduction When metals and non-metals chemically react, the atoms will tend to form ions or charged atoms. Ions form because electrons are either gained
More informationChapter 5: Nomenclature
Chem 1025 Prof George W.J. Kenney, Jr Introductory Chemistry, Zumdahl Decoste, 6th ed Last Update: 21July09 Chapter 5: Nomenclature These Notes are to SUPPLIMENT the Text, They do NOT Replace reading the
More informationOCR (A) Chemistry A-level. Module 6: Organic Chemistry and Analysis
OCR (A) Chemistry A-level Module 6: Organic Chemistry and Analysis Organic Synthesis Notes by Adam Robertson DEFINITIONS Heterolytic fission: The breaking of a covalent bond when one of the bonded atoms
More informationChapter 19 Substitutions at the Carbonyl Group
Chapter 19 Substitutions at the Carbonyl Group In Chapter 18 Additions to the Carbonyl Groups In Chapter 19 Substitutions at the Carbonyl Group O O - - O - O R Y R C+ Y R Y Nu -Ȳ R N u + Y=goodleavinggroup
More informationDr. Ahmad Al-Sheikh. Petra University Faculty of pharmacy & Medical Sciences P.O.BOX Amman - Jordan
Dr. Ahmad Al-Sheikh Petra University Faculty of pharmacy & Medical Sciences P.O.BOX 961343 Amman - Tel: (00962 6 ) 5155901 (home) Tel: (00962 77 ) 6160080 (mobile) Tel: (00962 6) 5799560 ext. 759 (work)
More information6. (a) NF 3 is nitrogen trifluoride. (b) HI is hydrogen iodide. (c) BBr 3 is boron tribromide.
6. (a) NF 3 is nitrogen trifluoride. (b) HI is hydrogen iodide. (c) BBr 3 is boron tribromide. (d) C 6 H 14 is hexane. 7. (a) C 8 H 18 is octane. (b) P 2 S 3 is diphosphorus trisulfide. (c) OF 2 is oxygen
More informationName: Student Number: University of Manitoba - Department of Chemistry CHEM Introductory Organic Chemistry II - Term Test 2
Name: Student Number: University of Manitoba - Department of Chemistry CHEM 2220 - Introductory Organic Chemistry II - Term Test 2 Thursday, March 12, 2015; 7-9 PM This is a 2-hour test, marked out of
More informationJEFFERSON COLLEGE COURSE SYLLABUS CHM201 ORGANIC CHEMISTRY II. 5 Credit Hours. Prepared by: Richard A. Pierce. Revised by: Sean Birke October, 2013
JEFFERSON COLLEGE COURSE SYLLABUS CHM201 ORGANIC CHEMISTRY II 5 Credit Hours Prepared by: Richard A. Pierce Revised by: Sean Birke October, 2013 Ms. Linda Abernathy, Math, Science & Business Division Chair
More informationCHEM 121 Introduction to Fundamental Chemistry. Summer Quarter 2008 SCCC. Lecture 7.
CHEM 121 Introduction to Fundamental Chemistry Summer Quarter 2008 SCCC Lecture 7 http://seattlecentral.edu/faculty/lcwest/che121 Forces Between Particles Noble Gas Configurations Ionic Bonding Ionic Compounds
More informationLearning Guide for Chapter 13 - Alkynes
Learning Guide for Chapter 13 - Alkynes I. Introduction to Alkynes - p 1 II. Natural ccurrence and Uses of Alkynes - p 5 III. Physical Properties of Alkynes - p 7 IV. Spectroscopy of Alkynes - p 7 V. Nomenclature
More informationNOMENCLATURE a systematic way of naming chemical compounds
NOMENCLATURE a systematic way of naming chemical compounds So far, we have looked at two types of compounds and. Ionic compounds are formed when oppositely ions stick together. There are two reasons why
More informationChapter 19: Amines. Introduction
Chapter 19: Amines Chap 19 HW: (be able to name amines); 37, 39, 41, 42, 44, 46, 47, 48, 53-55, 57, 58 Introduction Organic derivatives of ammonia. Many are biologically active. Chap 19: Amines Slide 19-2
More informationChemistry 234 Chapter 16 Problem Set. 3) Predict the product and draw the active electrophile for each reaction shown below.
Chemistry 234 Chapter 16 Problem Set Electrophilic Aromatic Substitution 1) Predict the product and draw the mechanism for electrophile generation for each of the following reactions. (a) 2 Fe 3 (b) HN
More informationAcid-Base Character of Salt Solutions. Cations. Cations are potentially acidic, but some have no effect on ph.
Acid-Base Character of Salt Solutions The ph of a salt solution will depend on the acidbase nature of both the cation and anion. Cations Cations are potentially acidic, but some have no effect on ph. M(H
More informationChemistry Senior Final Exam Review
Name: Hour: Teacher: ROZEMA / CHEMISTRY Chemistry Senior Final Exam Review You will take your final exam on Tuesday May 29, 2018 (during 6 th Hour). Your final exam is a mixture of written and multiple
More informationTHE BIG IDEA: ELECTRONS AND THE STRUCTURE OF ATOMS. BONDING AND INTERACTIONS.
HONORS CHEMISTRY - CHAPTER 9 CHEMICAL NAMES AND FORMULAS OBJECTIVES AND NOTES - V18 NAME: DATE: PAGE: THE BIG IDEA: ELECTRONS AND THE STRUCTURE OF ATOMS. BONDING AND INTERACTIONS. Essential Questions 1.
More informationReactions at α-position
Reactions at α-position In preceding chapters on carbonyl chemistry, a common reaction mechanism observed was a nucleophile reacting at the electrophilic carbonyl carbon site NUC NUC Another reaction that
More informationTheoretical and Experimental Studies on Alkali Metal Phenoxyacetates
Spectroscopy: An International Journal Volume 27 (2012), Issue 5-6, Pages 321 328 doi:10.1155/2012/498439 Theoretical and Experimental Studies on Alkali Metal Phenoxyacetates E. Regulska, M. Samsonowicz,
More informationUNIT IV PPT #3 Ka and Kb KEY.notebook. November 23, WHAT IS Ka? UNIT IV. CALCULATIONS USING Ka. WHAT IS Ka? Nov 10 9:42 PM.
WHAT IS Ka? Recall: Find ph of 0.100 M HCl. But What is ph of 0.10 M HF? UNIT IV Ka and Kb CALCULATIONS USING Ka I. [H 3O + ] (or ph) from Ka Ex. Find the [H 3O + ] in 0.10 M HF. WHAT IS Ka? Look at equilibrium
More informationCHEMISTRY 263 HOME WORK
Lecture Topics: CHEMISTRY 263 HOME WORK Module7: Hydrogenation of Alkenes Hydrogenation - syn and anti- addition - hydrogenation of alkynes - synthesis of cis-alkenes -synthesis of trans-alkenes Text sections:
More informationReview Multiple Choice Questions
Chapter 2 Matter and Changes Review Multiple Choice Questions 1. The random molecular motion of a substance is greatest when the substance is a. condensed b. a liquid c. frozen d. a gas 2. After elements
More informationCHEM 1364 Test #1 (Form A) Spring 2010 (Buckley)
Name CHEM 1364 Test #1 (Form A) Spring 2010 (Buckley) If you get stuck on one item, just go to the next and come back later. Point possibilities are indicated in parentheses to the right of each problem
More informationOrganic Chemistry. Introduction to Organic Molecules and Functional Groups
For updated version, please click on http://ocw.ump.edu.my Organic Chemistry Introduction to Organic Molecules and Functional Groups by Dr. Seema Zareen & Dr. Izan Izwan Misnon Faculty Industrial Science
More informationD) A majority of α particles will pass through a thin metal sheet undeflected, while a small percentage scatter wildly.
4. What was the experimental basis for determining that the nucleus occupies a very small fraction of the volume of an atom? A) Neutral particles are emitted when a sheet of beryllium is bombarded with
More informationChapter 12 Alcohols from Carbonyl Compounds: Oxidation-Reduction and Organometallic Compounds
Chapter 12 Alcohols from Carbonyl Compounds: Oxidation-Reduction and Organometallic Compounds Introduction Several functional groups contain the carbonyl group Carbonyl groups can be converted into alcohols
More informationJulio Alvarez-Builla, Juan Jose Vaquero,
Edited by Julio Alvarez-Builla, Juan Jose Vaquero, and Jose Barluenga Modern Heterocyclic Chemistry Volume 1 WILEY- VCH WILEY-VCH Verlag GmbH & Co. KG aa List of Contributors XV Volume 1 1 Heterocyclic
More information**The partially (-) oxygen pulls apart and surrounds the (+) cation. The partially (+) hydrogen pulls apart and surrounds the (-) anion.
#19 Notes Unit 3: Reactions in Solutions Ch. Reactions in Solutions I. Solvation -the act of dissolving (solute (salt) dissolves in the solvent (water)) Hydration: dissolving in water, the universal solvent.
More informationMarkanda National College, Shahabad, Markanda. Department of Chemistry. Lesson Plan of Chemistry, B.Sc-1, Semester-1
Markanda National College, Shahabad, Markanda Department of Chemistry Lesson Plan of Chemistry, B.Sc-1, Semester-1 Paper-II-PHYSICAL CHEMISTRY And Paper-I-INORGANIC CHEMISTRY Name of Teacher: Suresh Kumar
More informationMOLES AND EQUATIONS. Answer all questions. Max 51 marks. Mark../51...% Grade. Paddington Academy 1
MOLES AND EQUATIONS Answer all questions Max 51 marks Name.. Mark../51...% Grade Paddington Academy 1 1. In the sixteenth century, a large deposit of graphite was discovered in the Lake District. People
More information1. What is a chemical bond? 2. What is the octet rule? Why do atoms in bonding follow it?
Name: Date: Chemistry ~ Ms. Hart Class: Anions or Cations 1. What is a chemical bond? 2. What is the octet rule? Why do atoms in bonding follow it? 3. What are oxidation numbers? How do we find them? 4.
More informationAcid / Base Properties of Salts
Acid / Base Properties of Salts n Soluble ionic salts produce may produce neutral, acidic, or basic solutions depending on the acidbase properties of the individual ions. n Consider the salt sodium nitrate,
More informationCh 20 Carboxylic Acids and Nitriles
Ch 20 Carboxylic Acids and Nitriles Carboxylic Acids (RCO 2 H) are compounds with an OH attached to a carbonyl. Nitriles (RC N) are compounds a carbon-nitrogen triple bond. Naming Carboxylic Acids 1. Replace
More informationSpring Term 2012 Dr. Williams (309 Zurn, ex 2386)
Chemistry 242 Organic Chemistry II Spring Term 2012 Dr. Williams (309 Zurn, ex 2386) Web Page: http://math.mercyhurst.edu/~jwilliams/ jwilliams@mercyhurst.edu (or just visit Department web site and look
More informationSn1 or Sn2 Reactions: A Guide to Deciding Which Reaction is Occurring
Sn1 or Sn2 Reactions: A Guide to Deciding Which Reaction is Occurring The following is a discussion of the approach you should use in order to determine if a chemical reaction occurs via a Sn1 or Sn2 mechanism.
More informationMCAT Organic Chemistry Problem Drill 10: Aldehydes and Ketones
MCAT rganic Chemistry Problem Drill 10: Aldehydes and Ketones Question No. 1 of 10 Question 1. Which of the following is not a physical property of aldehydes and ketones? Question #01 (A) Hydrogen bonding
More informationChemistry Section Review 7.3
Chemistry Section Review 7.3 Multiple Choice Identify the choice that best completes the statement or answers the question. Put the LETTER of the correct answer in the blank. 1. The molar mass of an element
More information1/4/2011. Chapter 18 Aldehydes and Ketones Reaction at the -carbon of carbonyl compounds
Chapter 18 Aldehydes and Ketones Reaction at the -carbon of carbonyl compounds The Acidity of the Hydrogens of Carbonyl Compounds: Enolate Anions Hydrogens on carbons to carbonyls are unusually acidic
More informationPaper No. 1: ORGANIC CHEMISTRY- I (Nature of Bonding and Stereochemistry)
Subject Chemistry Paper No and Title Paper 1: ORGANIC - I (Nature of Bonding Module No and Title Module Tag CHE_P1_M10 TABLE OF CONTENTS 1. Learning Outcomes 2. Introduction 3. Non-Covalent Interactions
More informationKetones and Aldehydes Reading Study Problems Key Concepts and Skills Lecture Topics: Structure of Ketones and Aldehydes Structure:
Ketones and Aldehydes Reading: Wade chapter 18, sections 18-1- 18-21 Study Problems: 18-43, 18-44,18-50, 18-51, 18-52, 18-59, 18-60, 18-62, 18-64, 18-72. Key Concepts and Skills: Interpret the IR, NMR,
More informationCHEM 103 Naming Compounds
CHEM 103 Naming Compounds Lecture Notes February 9, 2006 Prof. Sevian Chem 103 Please sit with your groups today. We will be doing a group problem at the end of class. 2 2005 H. Sevian 1 Agenda How we
More informationSuggested solutions for Chapter 30
s for Chapter 30 30 PRBLEM 1 uggest a mechanism for this synthesis of a tricyclic aromatic heterocycle. 2 Cl base A simple exercise in the synthesis of a pyridine fused to a pyrrole (or an indole with
More informationInfrared Characteristic Group Frequencies
Infrared Characteristic Group Frequencies Tables and Charts Second Edition GEORGE SOCRATES Brunei, The University of West London, Middlesex, United Kingdom JOHN WILEY & SONS Chichester New York Brisbane
More informationScience 1206 Ch. 3 - Chemical names, formulas and equations
Science 1206 Ch. 3 - Chemical names, formulas and equations 3.1 - Ionic and molecular compounds (pp. 98-107) Compounds A compound is a pure substance made of a combination of elements. The elements are
More informationCourse Syllabus. Department: Science & Technology. Date: April I. Course Prefix and Number: CHM 212. Course Name: Organic Chemistry II
Department: Science & Technology Date: April 2012 I. Course Prefix and Number: CHM 212 Course Name: Organic Chemistry II Course Syllabus Credit Hours and Contact Hours: 5 credit hours and 7 (3:3:1) contact
More informationChemical Formulas and Chemical Nomenclature. Mr. Matthew Totaro Legacy High School Honors Chemistry
Chemical Formulas and Chemical Nomenclature Mr. Matthew Totaro Legacy High School Honors Chemistry 1 Molecular View of Elements and Compounds 2 Atomic Elements Atomic Elements = elements whose smallest
More informationElectronic Supplementary Information
Electronic Supplementary Information Noncovalent Interactions in Halogenated Ionic Liquids: Theoretical Study and Crystallographic Implications Haiying Li, a Yunxiang Lu,* a Weihong Wu, Yingtao Liu, b
More informationSample Questions Chem 22 Student Chapters Page 1 of 5 Spring 2016
Sample Questions Chem 22 Student Chapters 13-18 Page 1 of 5 1. The vapor pressure of a liquid is the pressure, at equilibrium, of the a) solid above its liquid. b) liquid above its solid. c) gas above
More informationPlease bubble in your name (LAST NAME first) and student number on the scantron
CHEM 2130 Final Exam NAME: Please bubble in your name (LAST NAME first) and student number on the scantron 1) To initiate enolate formation, which proton should be removed? 1) 1 2) 2 3) 3 4) 4 5) 5 2)
More informationUNIT 4 REVISION CHECKLIST CHEM 4 AS Chemistry
UNIT 4 REVISION CHECKLIST CHEM 4 AS Chemistry Topic 4.1 Kinetics a) Define the terms: rate of a reaction, rate constant, order of reaction and overall order of reaction b) Deduce the orders of reaction
More informationChapter 11 The Chemical Elements
James T. Shipman Jerry D. Wilson Charles A. Higgins, Jr. Omar Torres Chapter 11 The Chemical Elements Chemical Classification of Matter Mass and Volume H 2 O, sugar, O 2, Fe H, Cu, Fe CO 2, H 2 O.. Which
More informationChapter 3 N S. Substitutions of Aromatic Heterocycles. M. R. Naimi-Jamal. With special thanks to Dr. Javanshir 1
Chapter 3 N S Substitutions of Aromatic Heterocycles O M. R. Naimi-Jamal With special thanks to Dr. Javanshir 1 Pyridines carrying strongly electron-withdrawing substituents, or heterocycles with additional
More informationName HONORS CHEMISTRY / / Oxide Reactions & Net Ionic Reactions
Name HONORS CHEMISTRY / / Oxide Reactions & Net Ionic Reactions The first type of reactions we will look at today are reactions between an oxide (a compound with oxygen as its anion) and water. There are
More information