PERATURAN PEMARKAHAN CHEMISTRY 4541

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1 PENTAKSIRAN DIAGNOSTIK AKADEMIK SBP 04 SIJIL PELAJARAN MALAYSIA PERATURAN PEMARKAHAN CHEMISTRY 454

2 SULIT 454 PENTAKSIRAN DIAGNOSTIK AKADEMIK SBP 04 SKEMA KERTAS CHEMISTRY 454/ C 6 C C 7 C C 8 B 4 D 9 D 5 D 0 D 6 C A 7 D A 8 A B 9 D 4 B 0 C 5 D D 6 D D 7 A A 8 D 4 A 9 B 5 B 40 C 6 A 4 C 7 D 4 A 8 C 4 B 9 C 44 B 0 A 45 B B 46 D A 47 A B 48 C 4 B 49 C 5 B 50 A Hak Cipta BPSBPSK SULIT

3 SULIT SECTION A Question Mark scheme Sub Mark Total Mark (a) Electron (b).8 (c) (i) The atomic size of potassium is bigger The attraction force between nucleus/proton and electron is weaker Easier to donate valence electron (ii) Potassium moves very fast/ rapidly on the surface of water Burns with reddish purple/ lilac flame Produce hiss/pop sound Any two (d) (i) Atoms of the same element which have the same number of proton (proton number) but different number of neutrons (nucleon number) (ii) To detect the leakage of underground pipes TOTAL 9 Question Mark scheme Sub Mark Total Mark (a) (i) n = A = Carbon- / C- (ii) 0.5 x 6.0 x 0 x 5 =.505 x 0 4 (b) (i) To allow oxygen to enter the crucible (ii) Lead is less reactive metal towards oxygen// lead react slowly with oxygen (c) (i) Number of mol CuCO = 6. = 6. = () 4 mol CuCO : mol CO 0.05 mol CuCO : 0.05 mol CO Volume of CO gas = 0.05 x 4 /. dm TOTAL Hak Cipta BPSBPSK SULIT

5 SULIT Question Mark scheme Sub Mark Total Mark 4 a) i) Oxidation number of iron = + ii) Carbon iii) Reducing agent iv) FeO + C 4Fe + CO // + FeO + CO Fe + CO correct formula for reactant and product - balanced chemical equation b) i) Brown colour ii) Bromine iii) 0 to - iv) Reduction v) Acidified potassium manganate(vii) solution // Acidified potassium dichromate (VI) solution Total Hak Cipta BPSBPSK SULIT

6 SULIT Question Explanation Mark Σ Mark 5 a) i) Molecule b) ii) Test tube P Hydrogen ion is not present/ ethanoic acid exists as molecule R : water is not present X = Sulpuric acid is a diprotic acid while hidrochloric acid is a monoprotic acid Double concentration of hydrogen ion c) i) Hydrogen chloride Reject: Hydrochloric acid ii) Acidic iii) Procedure: Add distilled water Add silver nitrate solution Observation: A white precipitate formed Total Hak Cipta BPSBPSK SULIT

8 SULIT Section B (0 marks) Question Rubric Marks Total Mark 7(a) (i). Heat change = mc = // 70 Joule//.7 kj 50. Number of mol of water 0.05mol 000 (ii). Heat of neutralisation 70.7 // Jmol // 54.6kJmol. 6.5 o C // same.. Potassium hydroxide and sodium hydroxide are strong alkali// Both alkali are ionize completely in water// Number of moles of hydroxide ion in both alkali is the same 7(b) (i) Example of reaction: Set : Neutralization between acid and alkali// combustion ethanol/ alkane/ alkene// precipitation of silver chloride/ lead(ii) chloride // any suitable reaction. Set : Decomposition of carbonate/ nitrate salts // dissolving ammonium salts in water// any suitable reaction (ii) Set I Set II 7(c) Type of reaction Temperature change Energy content Energy change Exothemic reaction// heat is released to surrounding. Temperature of the mixture increases. The total energy content of reactants is higher than products. Chemical energy to heat energy. Endothermic reaction // Heat is absorbed from surrounding. Temperature of the mixture decreases. The total energy content of reactants is lower than products. Heat energy to chemical energy.. Heat of combustion of butanol is higher than propanol.. The number of carbon atom per molecule of butanol is higher/ greater than propanol.. The number of carbon dioxide and water molecules formed is higher/ greater. 4. More heat energy is released Total Hak Cipta BPSBPSK SULIT

9 SULIT Question Rubric Marks Total marks 8(a) (i) Group 7 Atom has 7 valence electrons Period Atom has shells filled with electrons 4 (ii) Fe + B FeB // Fe + Cl FeCl Correct formula of reactants and product Balanced equation (iii). Element A more reactive than element B. Atomic size A is smaller than B. The nucleus force of attraction toward electrons become stronger// The attraction forces between proton and electrons become stronger 4. Easier to receive electrons 4 8(b) (i). Hydrogen atom has an electron arrangement of.. Nitrogen atom has an electron arrangement of.5.. Hydrogen and nitrogen atoms share electrons to achieve stable duplet/ octet electron arrangement. 4. One hydrogen atom contributes one electron for sharing, 5. One nitrogen atom contributes three electrons for sharing. 6. One nitrogen atom share electrons with three hydrogen atoms. [Sample of answer: One nitrogen atom contributes three valence electrons, while three hydrogen atoms, each contributes one valence electron to be shared to achieve stable electron arrangement ] 6 (ii). Boiling point of ammonia is lower than the room temperature// ammonia has low boiling point.. Ammonia exists as molecule// covalent compound.. Weak intermolecular/ Van der Waals forces between molecules. 4. Little/ less heat energy needed to overcome the force. 4 Total Hak Cipta BPSBPSK SULIT

10 SULIT Section C (0 marks) Question Rubric Marks Total marks 9(a) Cathode : Pure copper Electrolyte : Copper(II) sulphate/ nitrate/ chloride solution half equation at anode: Cu Cu + + e - half equation at cathode: Cu + + e - Cu 4 9(b) (i) X: Aluminium/ magnesium/ zinc / iron / tin/ lead [Reject : sodium /potassium] Reason: X is more electropositive than copper// X is located higher than copper in Electrochemical Series. Y: Silver/ aurum (gold) Reason: Y is less electropositive than copper// Y is located lower than copper in Electrochemical Series. (ii) Voltage of the cell is. V Negative terminal is X. 9(c) Procedure:. Metal strips are cleaned with sandpaper.. [ - 5] cm of each nitrate solution are poured into four separate test tubes.. A strip of metal P is placed into each of the solutions. 4. Observations on the deposition of metals are recorded. 5. Steps to 4 are repeated using strip metals Q, R and S to replace strip metal P. Result: Salt solution Metal strip Nitrate solution P : Deposition of metal occurs X: No deposition of metal occurs Nitrate solution Q Nitrate solution R Nitrate solution S P Q X R X X S X X X 4 Explanation: 6. Metal P can displace metals Q, R and S from their salt solutions. Thus, P is placed at the highest position in the electrochemical series. 7. Metal Q can only displace metals R and S from their salt solutions. Thus, metal Q is placed higher than metals R and S but lower than metal P in the electrochemical series. 8. Metal R can only displace metal S from its salt solution. Thus, metal R is placed higher than metal S but lower than metals P and Q in the electrochemical series. 9. Metal S cannot displace any metals from their salt solutions because it is placed at the lowest position in the electrochemical series. Total Hak Cipta BPSBPSK SULIT 0

11 SULIT 454 Question Rubric Marks Total marks 0(a) 9 Chemical equation: C H 7OH + O CO + 4H O// 0(b) Chemical equation: C H 7OH + 9O 6CO + 8H O Correct formula of reactants and product Balanced equation Volume of gas X. Based on equation; 9 mol O : mol CO 0. mol O : 0. mol CO. Volume of CO = 0. x 4 = 4.8dm //4800cm Structural formula of ester C 4 Name: propyl propanoate 0(c) Propanol Hydroxyl / -OH Ester C Carboxylate/ -COO Functional Group Solubility in Soluble in water Insoluble in water water Apparatus: test tubes, dropper. Materials: bromine water // acidified potassium manganate (VII) solution, hexane, hexane. Procedure:. [ 5] cm of liquid in bottle P is poured into a test tube.. cm / A few drop of bromine water// acidified potassium manganate(vii) solution is added to the test tube.. The mixture is shaken. 4. Any changes is observed and recorded. 5. Steps to 4 are repeated by using the liquid in bottle Q to replace the liquid in bottle P. Observation: Set Liquid in bottle P Liquid in bottle Q Liquid in bottle P is hexene. Liquid in bottle Q is hexane. [a: P is hexene, Q is hexane] Observation Brown bromine water decolourised // purple acidified potassium manganate(vii) solution decolourised. No change Total Hak Cipta BPSBPSK SULIT

12 SULIT Kertas (a) Able to record all readings accurately to one decimal point with unit Answer : Set I (0.4 mol dm - ) Set II (0.0 mol dm - ) Set III (0.6 mol dm - ) Set IV (0. mol dm - ) Set V (0.08 mol dm - ) 7.0 s 0.0 s 5.0 s.0 s 50.0 s Able to record any 4 readings accurately / all readings correctly but without decimal point/without unit Able to record any readings correctly but without decimal point/without unit No response given or wrong response or less than correct readings 0 (b) (i) Able to state the observation correctly Suggested answer: Mark X disappears from sight// Precipitate/solid is formed // Solid covers X Able to state the observation less correctly Suggested answer: Mark X disappears Able to state idea of observation Suggested answer: Precipitate// Solid// Reaction occurs No response given / wrong response Hak Cipta BPSBPSK SULIT

13 SULIT 454 (b) (ii) Able to state the inference correctly Suggested answer: Sulphur is formed Able to state the inference less correctly Suggested answer: Acid reacts with sodium thiosulphate // Insoluble substance formed Able to state idea of inference Suggested answer: Reaction occurs Rate of reaction affected by concentration No response given / wrong response 0 (c) Able to complete the table with all correct value with decimal place Answer : Concentration/mol dm - Time / s / s - Time Able to complete the table with 4 correct values Able to complete the table with correct values No response given or wrong response Hak Cipta BPSBPSK SULIT

14 SULIT (d) Able to state all three variables correctly Suggested answer: Manipulated variable: Concentration of sodium thiosulphate solution Responding variable: Time taken for mark X to disappear from sight // rate of reaction Constant variable: Volume of sodium thiosulphate // Temperature // size of conical flask // concentration and volume of sulphuric acid Able to state any two variables correctly Able to state any one variables correctly No response or wrong response 0 (e) Able to state the relationship between the manipulated variable and responding variable correctly with direction. The higher / lower the concentration of sodium thiosulphate solution, the higher / lower the rate of reaction. // The higher / lower the concentration of sodium thiosulphate solution, the shorter the time taken for mark X to disappear from sight Able to state the relationship between manipulated variable and responding variable without stating the direction. The higher / lower the concentration of sodium thiosulphate, the faster/slower the rate of reaction Able to state an idea of the hypothesis Concentration affects the rate of reaction // The concentration change, the rate of reaction change No response or wrong response Hak Cipta BPSBPSK SULIT

15 SULIT Hak Cipta BPSBPSK SULIT

16 SULIT (f) Able to draw a graph of concentration following information () The axes are labeled correctly with unit x-axis : concentration (mol dm - ) against /time by showing the y-axis : /time (/s) () Uniform scale () size of the graph at least 50% of the graph paper (4) All points are transferred correctly (5) Smooth curve Able to draw a graph of concentration against /time by showing the following information () The axes are labeled correctly without unit () Uniform scale () All points are transferred correctly (4) Smooth curve Able to draw a graph of concentration against /time by showing the following information () The axes are labeled correctly without unit () Curve / straight line on the graph No response or wrong response 0 (g)(i) Able to state the relationship between the concentration of sodium thiosulphate solution and the rate of reaction correctly Suggested answer: The higher/lower the concentration of sodium thiosulphate solution, the rate of reaction increase/decrease Able to state the relationship between the concentration of sodium thiosulphate solution and the rate of reaction less correctly Suggested answer: The rate of reaction is directly proportional to the concentration of sodium thiosulphate// The higher the concentration of sodium thiosulphate, the rate of reaction decrease// The lower the concentration of sodium thiosulphate, the rate of reaction increase Hak Cipta BPSBPSK SULIT

17 SULIT Able to give a relevant idea Suggested answer: Rate of reaction is affected by concentration// Rate of reaction is changed by the concentration// Rate of reaction is inversely proportional with concentration No response or wrong response 0 Able to fulfil the following criteria (g)(ii) () Extend the line on the graph () Show on the graph the way to obtain the value of /time () State the time with unit /time = Time = /0.055 = 8.8 s//8. s Able to fulfil any two criteria Able to fulfil any one criteria No response or wrong response 0 (h) Able to state the operational definition accurately by stating what should be done and what should be observed What should be done : when sulphuric acid is added to a higher concentration sodium thiosulphate solution What should be observed : the time taken become shorter Time taken for mark X to disappear from sight// Time taken for mark X to disappear from sight when sulphuric acid is added into different concentration of sodium thiosulphate solution. Able to state the operational definition less accurately Time taken for mark X to disappear// Time taken// X mark disappear Hak Cipta BPSBPSK SULIT

18 SULIT Able to give an idea for the operational definition. Time for reaction to occurs No response given or wrong response 0 Able to classify all the reaction correctly (j) Fast reaction Neutralization Combustion Displacement Slow reaction Rusting Fermentation Corrosion Able to classify any 4 reaction correctly Able to classify any reaction correctly or reverse classification No response or wrong response 0 (a) Able to give the statement of problem correctly Does different carboxylic acids react with butanol produce esters with different odour? Able to give the statement of problem less correctly Does different carboxylic acids react with butanol gives different esters?// To study different carboxylic acids react with butanol to give esters with different odours. Able to give an idea about the statement of problem Different carboxylic acids/alcohol gives different esters. No response or wrong response Hak Cipta BPSBPSK SULIT

19 SULIT (b) Able to state all the variables correctly. Manipulated variable: Type of carboxylic acids// Methanoic acid, ethanoic acid and propanoic acid.. Responding variables: Esters / Odours produced. Fixed variable: butanol / alcohol used Able to state any two variable correctly Able to state any one variable correctly No response or wrong response 0 (c) Able to state the hypothesis correctly by stating the relationship between the manipulated variable and the responding variable When different carboxylic acids are used, the esters formed will give different odours. Able to state the hypothesis less correctly When different carboxylic used, different esters formed//esters with different odours formed when different carboxylic acids are used Able to state idea of the hypothesis Type of carboxylic acid affects esters formed No response or wrong response Hak Cipta BPSBPSK SULIT

20 SULIT (d) Able to give the apparatus and materials correctly and completely List of apparatus : Boiling tube, beaker, test tube holder, Bunsen burner, dropper, measuring cylinder OR Round bottom flask, beaker, Liebig condenser, measuring cylinder, Bunsen burner, dropper, porcelain chips List of materials : Glacial methanoic acid, ethanoic acid and propanoic acid, butanol, concentrated sulphuric acid, water Able to give the list of aapparatus and materials correctly but not complete List of apparatus : Boiling tube, Bunsen burner,dropper Or Round bottom flask,, Bunsen burner, dropper List of materials : Methanoic acid, ethanoic acid and propanoic acid, butanol concentrated sulphuric acid Able to give an idea of list of apparatus and materials Any container, any one acid// any one alcohol, No response or wrong response Hak Cipta BPSBPSK SULIT

21 SULIT 454 (e) Able to state all procedures correctly Situation. Pour [-5] cm butanol and [-5] cm glacial methanoic acid into a boiling tube.. Add a few drops of concentrated sulphuric acid into the mixture.. Heat the mixture gently. 4. Pour the mixture into beaker half-filled with water 5. Observe and record the product formed. 6. Repeat the experiment by replacing methanoic acid with ethanoic acid and propanoic acid. Situation. Pour [5-00] cm glacial methanoic acid into a round bottom flask and [5-00] cm butanol.. Put in a few pieces of porcelain chips into the flask. Add [5 0] cm of concentrated sulphuric acid into the mixture. 4. Reflux the mixture for about [0] minutes. 5. Observe and record the product formed. 6. Repeat the experiment by replacing methanoic acid with ethanoic acid and propanoic acid. Able to state steps,,,5 and 6 for Situation or Able to state steps,,4, 5, 6 for Situation Able to state an idea of the experiment. Add [any one] carboxylic acid and any alcohol into a [suitable container]. No response or wrong response 0 (f) Able to exhibit the tabulation of data correctly Tabulation of data has the following aspects:. Two columns and at least rows. Headings: Carboxylic acids/ Ester Observation. Name of acids/esters Carboxylic acid/ester Methanoic acid/butyl methanoate Ethanoic acid/butyl ethanoate Propanoic acid/buytl propanoate Observation Hak Cipta BPSBPSK SULIT

22 SULIT 454 Able to exhibit the tabulation of data but less accurately Tabulation of data has the following aspects:. Two columns and at least rows. One heading: Carboxylic acid/ester // Observation No response or wrong response 0 END OF MARK SCHEME Hak Cipta BPSBPSK SULIT

Jawapan. Chemistry. Chemistry Paper 1(4541/1) SOALAN ULANGKAJI SPM 2010 [4541/1] [4541/2] [4541/3]

Jawapan. Chemistry. Chemistry Paper 1(4541/1) SOALAN ULANGKAJI SPM 2010 [4541/1] [4541/2] [4541/3] SOALAN ULANGKAJI SPM 00 37 Jawapan Chemistry [454/] [454/] [454/3] Chemistry Paper (454/) A A 3 A 4 B 5 D 6 C 7 D 8 B 9 C 0 A B D 3 B 4 A 5 C 6 D 7 C 8 D 9 B 0 A A D 3 D 4 C 5 B 6 C 7 D 8 A 9 A 30 A 3