(G,x) polynomial and (G) index of Armchair Polyhex Nanotubes TUAC 6 [m,n]
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1 International Letters of Chemistry, Physis and Astronomy Online: ISSN: , Vol. 36, pp doi: / SiPress Ltd., Switzerland (G,x) polynomial and (G) index of Armhair Polyhex Nanotubes TUAC 6 [m,n] Mohammad Reza Farahani Department of Applied Mathematis, Iran University of Siene and Tehnology (IUST), Narmak, Tehran 16844, Iran address: Mr_Farahani@Mathdep.iust.a.ir, MrFarahani88@Gmail.om ABSTRACT Let G be a simple onneted graph with the vertex set V = V(G) and the edge set E = E(G), without loops and multiple edges. For ounting qo strips in G, Omega polynomial was introdued by Diudea and was defined as Ω(G,x ) = m( G, ). x, where m(g,) be the number of qo strips of length in the graph G. Following Omega polynomial, the Sadhana polynomial was defined by Ashrafi et al as Sd(G,x) = m( G, ) x. In this paper we ompute the Pi polynomial (G,x) = m( G, ).. x and Pi index (G ) = m ( G, ) E ( G ) of an infinite lass of Armhair Polyhex Nanotubes TUAC 6 [m,n]. Keywords: Moleular Graph; Armhair Polyhex Nanotubes and Nanotori; Omega polynomial; Pi polynomial; Pi index. 1. INTRODUCTION Let G be a simple moleular graph without direted and multiple edges and without loops, the vertex and edge-sets of whih being denoted by V(G) and E(G), respetively. Suppose G is a onneted moleular graph and u,vv(g). The distane d(u,v) between u and v is defined as the length of a minimum path between u and v. Two edges e = uv and f = xy of G e o f if and only if d(u,x) = d(v,y) = k and d(u,y) = d(v,x) = k+1 or vie versa, for a nonnegative integer k. The relation o is reflexive and symmetri but it is not neessary to be transitive, obviously. Set C(e): = {fe(g) e o f}), denote the subset of edges in G, o-distant to the edge e. If the relation o is transitive on C(e) then C(e) is alled an orthogonal ut (denoted by o) of G [1-10]. The graph G is alled o-graph if and only if the edge set E(G) a union of disjoint orthogonal uts. Observe o is a theta relation, (Djoković [11], and Winkler [12]): d(x,u) + d(y,v) d(x,v) + d(y,u) Theta is a o-relation if and only if G is a partial ube, as Klavžar [13] orretly stated in a reent paper. Relation is reflexive and symmetri but need not be transitive. SiPress applies the CC-BY 4.0 liense to works we publish:
2 202 Volume 36 If any two onseutive edges of an edge-ut sequene are topologially parallel within the same fae of the overing, suh a sequene is alled a quasi-orthogonal ut qo strip. Let m(g,) be the number of qo strips of length in the graph G. For ounting opposite edge strips qos of E(G), M.V. Diudea introdued the Omega polynomial of G [1-10] and was defined as Ω(G,x )= (, ) m G x It is easy to see that the first derivative of Omega polynomial Ω(G, x) (in x = 1) equals the number of edges in the graph. Following Omega polynomial, the Sadhana polynomial was defined by Ashrafi and o-authors [14] in 2008, as Sd(G,x) = m G x (, ). The Sadhana index Sd(G) for ounting qo strips in G was defined by Khadikar et. al [15-17] as first derivative of sadhana polynomial evaluated at x=1 1 i i k Sd(G) = Sd (G, x) = EG Another polynomial also related to the Sadhana polynomial is the Pi polynomial (G, x) and defined as: (G,x) = m( G, ).. x The first derivative (omputed at x=1) of this ounting polynomial provide its topologial index: (G)= (G,x) =, ( ) m G E G Ω(G,x) polynomial ount odistant edges in G while Sd(G,x) and Π(G,x), non-odistant edges. In hemial, physis and nano sienes, we have the appealing struture, espeially symmetri struture with hemial onstitution purporting [18,19]. One of the nanotube is Polyhex Nanotubes, that the struture of polyhex nanotubes is onsisting of the yles with length six C 6 in olumns. Sine polyhex nanotubes have more pratial in the hemial, physis and nano siene (see Figure 1). In Figures 1 and 2, one an see that the 3- dimentional and 2-dimentional graph of Armhair polyhex nanotubes TUAC 6 [m,n], where m,n are the numbers of rows/olumns of hexagon (C 6 ) in 2-dimentional pereption TUAC 6 [m,n]. In a series of papers [18-30], some properties and appliations and more historial details of nanotubes are presented and studed. In the present work we ompute the Pi polynomial (G,x) and Pi index (G) for an infinite lass of Nano-struture Armhair Polyhex Nanotubes TUAC 6. Throghout this paper our notation is standard and mainly taken from standard book of graph theory suh as [31-36].
3 International Letters of Chemistry, Physis and Astronomy Vol Figure 1. A 3-dimentional lattie of Armhair Polyhex Nanotubes TUAC 6. Figure 2. A 2-dimentional lattie of Armhair Polyhex Nanotubes TUAC 6 [m,n] and its hotizontal edge e i and oblique edges f i and h i. 2. RESULTS AND DISCUSSION In this setion we present expliit formulas for the Pi polynomial (G,x) and Pi index (G) of an Armhair Polyhex Nanotubes TUAC 6. Theorem 1. Consider the Armhair polyhex nanotubes TUAC 6 [m,n] m,n ϵ N ; the Pi polynomials and its index are alulated by formulas: (TUAC 6 [m,n], x) = 2m[(n + 1)x 6mn+4m n-1 + (2n + 1)x 6mn+4m 2n-1 ]
4 204 Volume 36 and (TUAC 6 [m,n]) = 23[18mn mn -5n 2 + 8m - 6n - 2] Proof. Let G = TUAC 6 [m,n] be the the Armhair polyhex nanotubes and m and n be the number of hexagons in rows and olumns of G. From Figures 1 and 2, it is easy to see that the number of verties/arbon atoms and edges/hemial bonds of TUAC 6 [m,n], are equal to V(TUAC 6 [m,n]) = 4m(n+1) and E(TUAC 6 [m,n]) = 6mn+4m. By aording to Figure 2, we denote all hotizontal edge in i th olumn by e i and all oblique edges in i th olumn by f i (right) and h i (left), then one an see that for all quasiorthogonal uts C(e i ), C(f j ) and C(h l ): There are 2m number of C(e i ) with size C(e i ) = n+1 and m number of C(f j ) and C(h l ) with same size C(f i ) = C(h i ) = 2n+1. So we have the following relations for Armhair polyhex nanotubes G = TUAC 6 [m,n]: (TUAC 6 [m,n],x) = TUAC m n = m 6,, x E TUAC6 mn, 6 4 ( i) 6 4 ( i) 2 m C( e ). x mn mc e m C( f ). x mn mc f i i m Ch ( ). x i 6mn4 mc( h i ) = 2m (n+1)x 6mn+4m n-1 +m (2n + 1)x 6mn+4m 2n-1 6mn+4m 2n-1 + m (2n + 1)x = 2m[(n + 1)x 6mn+4m n-1 + (2n + 1)x 6mn+4m 2n-1 ] The first derivative (omputed at x=1) of (TUAC 6 [m,n],x) polynomial provide the Pi index of an Armhair Polyhex Nanotubes TUAC 6 as follows: (TUAC 6 [m,n]) = (TUAC 6 [m,n],1) and this ompletes the proof. = m 6,, E 6, TUAC m n TUAC m n = 2m[(n + 1)(6mn + 4m n 1) + (2n + 1)(6mn + 4m 2n 1)] = 23[18mn mn 5n 2 + 8m 6n 2] 3. CONCLUSION In this paper, I was ounting a new ounting topologial polynomial and its index for a family of arbon nanotubes" Armhair polyhex nanotubes TUAC 6 [m,n]". (G,x) polynomial and its index are useful for ounting the quasi-orthogonal ut qo strip in struture of onneted nanotubes and onneted nanostrutures.
5 International Letters of Chemistry, Physis and Astronomy Vol Referenes [1] M.V. Diudea, Carpath. J. Math. 22 (2006) [2] M.V. Diudea, S. Cigher, A.E. Vizitiu, O. Ursu, P.E. John. Croat. Chem. Ata 79(3), (2006) [3] P.E. John, A.E. Vizitiu, S. Cigher, M.V. Diudea, MATCH Commun. Math. Comput. Chem. 57 (2007) [4] M.V. Diudea, S. Cigher, P.E. John. MATCH Commun. Math. Comput. Chem. 60 (2008) [5] M.V. Diudea, S. Cigher, P.E. John, MATCH Commun. Math. Comput. Chem. 60 (2008) [6] M.V. Diudea, I. Gutman, L. Jäntshi, Moleular Topology, NOVA, New York, [7] A.E. Vizitiu, S. Cigher, M.V. Diudea, M.S. Floresu, MATCH Commun. Math. Comput. Chem. 57(2) (2007) [8] M.V. Diudea, A. Ilić, Carpath. J. Math. 20(1) (2009) [9] M.V. Diudea, MATCH Commun. Math. Comput. Chem. 2010, 64, 569. [10] A.R. Ashrafi, M. Jalali, M. Ghorbani, M.V. Diudea. MATCH, Commun. Math. Comput. Chem. 60 (2008), [11] D.Ž. Djoković, J. Combin. Theory Ser. B 14 (1973) 263. [12] P.M. Winkler, Disrete Appl. Math. 8 (1984) 209. [13] S. Klavžar, MATCH Commun. Math. Comput. Chem. 59 (2008) 217. [14] A.R. Ashrafi, M. Ghorbani, M. Jalali, Int. J. Chem. 47A(4) (2008) [15] P.V. Khadikar, S. Joshi, A. V. Bajaj, D. Mandloi, Med. Chem. Lett. 14 (2004) [16] P.V. Khadikar, V. K. Agrawal, S. Karmarkar. Bioorg. Med. Chem. 2(10) (2002) [17] P.V. Khadikar, D. Mandoli, Sadhana, Bioinformatis Trends 1 (2006) [18] S. Iijima, Nature 354 (1001) 56. [19] D.S. Bethune, C.H. Kiang, M.S. Devries, G. Gorman, R. Savoy, J. Vazquez, A. Beyers, IBID 363 (1993) 605. [20] I. Gutman, S. Klavžar, ACH Models Chem. 133 (1996) [21] M.V. Diudea, MATCH, Commun. Math. Comput. Chem. 45 (2002) [22] A.R. Ashrafi, G. R. Vakili-Nezhaad, Journal of Physis: Conferene Series 29 (2006) [23] S. Yousefi, H. Yousefi-Azari, A.R. Ashrafi, M. H. Khalifeh, JSUT 33(3) (2008) [24] A. Iranmanesh, Y. Alizadeh, Digest. J. Nanomater. Bios 4 (2009) [25] H. Shabani, A.R. Ashrafi, Digest. J. Nanomater. Bios 4 (2009)
6 206 Volume 36 [26] S. Alikhani, M.A. Iranmanesh, Digest. J. Nanomater. Bios 5 (2010) 1-7. [27] M.R. Farahani. Proeedings of the Romanian Aademy Series B Chemistry 15(1) (2013) 3-6. [28] M.R. Farahani, Journal of Advanes in Physis 3(1) (2013) [29] M.R. Farahani, Ata Chim. Slov. 59 (2012) [30] M.R. Farahani, Le Matematihe 69(2) (2014). [31] N. Trinajstić, Chemial Graph Theory, (seond ed.) CRC Press, Boa Raton, FL, (1992). [32] R. Todeshini and V. Consonni, Handbook of Moleular Desriptors, Weinheim, Wiley- VCH, (2000). [33] N. Trinajstić, I. Gutman, Croat. Chem. Ata 75 (2002) [34] Mohammad Reza Farahani, International Letters of Chemistry, Physis and Astronomy 12 (2014) [35] Mohammad Reza Farahani, International Letters of Chemistry, Physis and Astronomy 12 (2014) [36] Mohammad Reza Farahani, International Letters of Chemistry, Physis and Astronomy 13(1) (2014) ( Reeived 17 June 2014; aepted 27 June 2014 )
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