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1 Publications M. Tromp, J. A. van Bokhoven, M. T. Garriga Oostenbrink, J. H. Bitter, K. P. de Jong, D. C. Koningsberger, Influence of the Generation of Mesopores on the Hydroisomerization Activity and Selectivity of n-hexane over Pt/Mordenite, J. Catal. 2000, 190, J. A. van Bokhoven, M. Tromp, D. C. Koningsberger, J. T. Miller, J. A. Z. Pieterse, J. A. Lercher, B. A. Williams, H. H. Kung, An Explanation for the Enhanced Activity for Light Alkane Conversion in Mildly Steamed Dealuminated Mordenite: The Dominant Role of Adsorption, J. Catal. 2001, 202, M. Tromp, J. A. van Bokhoven, A. M. Arink, J. H. Bitter, G. van Koten, D. C. Koningsberger, Cu K-edge EXAFS Characterisation of Copper(I) Arenethiolate Complexes in both the Solid and Liquid State: Detection of the Cu-Cu Coordination, Chem. Eur. J. 2002, 8(24), (Chapter 3 of this thesis). M. Tromp, J. A. van Bokhoven, R. J. van Haaren, G. P. F. van Strijdonck, A. M. J. van der Eerden, P. W. N. M. van Leeuwen, D. C. Koningsberger, Structure-Performance Relations in Homogeneous Pd Catalysis by In Situ EXAFS Spectroscopy, J. Am. Chem. Soc. 2002, 124(50), (Chapter 6a of this thesis). M. Tromp, J. R. A. Sietsma, J. A. van Bokhoven, G. P. F. van Strijdonck, R. J. van Haaren, A. M. J. van der Eerden, P. W. N. M. van Leeuwen, D. C. Koningsberger, Deactivation Processes of Homogeneous Pd Catalysts using In Situ Time Resolved Spectroscopic Techniques, Chem. Comm. 2003, (Chapter 6b of this thesis). S. S. van Berkel, A. van der Hoogenband, M. Tromp, P. W. N. M. van Leeuwen, G. P. F. van Strijdonck, Formation of Aryl-Nitrogen Bonds Using bis-µ-hydroxy Copper(II)-Based Catalysts, Chem. Comm., submitted for publication (Chapter 7a of this thesis). M. Tromp, J. A. van Bokhoven, M. Q. Slagt, G. van Koten, D. E. Ramaker, D. C. Koningsberger, Atomic XAFS as a Probe of Charge Redistribution within Organometallic Complexes, J. Am. Chem. Soc., accepted for publication (Communication of Chapter 5 of this thesis). M. Tromp, S. S. van Berkel, S. G. Fiddy, G. P. F. van Strijdonck, J. A. van Bokhoven, P. W. N. M. van Leeuwen, D. C. Koningsberger, Novel Combined Time-Resolved ED-XAFS / UV-Vis set-up to Study Homogeneous Catalytic Reactions, Angew. Chem. Int. Ed., submitted for publication (combination of parts of Chapter 2 and Chapter 7b of this thesis). 197
2 M. Tromp, J. A. van Bokhoven, G. P. F. van Strijdonck, P. W. N. M. van Leeuwen, D. C. Koningsberger, D. E. Ramaker, Probing the Molecular Orbitals and Charge Distribution in Organometallic (PP)Pd(XX) Complexes. A Pd K-edge study, J. Am. Chem. Soc., submitted for publication (Chapter 4 of this thesis). M. Tromp, M. Q. Slagt, R. J. M. Klein Gebbink, G. van Koten, D. E. Ramaker, D. C. Koningsberger, Atomic XAFS as a Probe of Charge Redistribution within Organometallic Complexes, J. Am. Chem. Soc., submitted for publication (Full paper, Chapter 5 of this thesis). M. Tromp, S. S. van Berkel, A. van den Hoogenband, M. C. Feiters, B. de Bruin, P. W. N. M. van Leeuwen, G. P. F. van Strijdonck, Multi-technique Approach to Reveal the Mechanism of Cu(II) Catalzyed Arylation Reactions, Chem. Eur. J., submitted for publication (Chapter 7b of this thesis). A. M. Arink, M. Tromp, J. T. B. H. Jastrzebski, D. C. Koningsberger, G. van Koten, Structural information on copper(i) arenethiolates and organo(thiolato)cuprates using EXAFS and NMR, in preparation. M. Tromp, D. E. Ramaker, D. C. Koningsberger, Demonstration, Explanation and Validation of AXAFS in Homogeneous and Heterogeneous Catalytic Systems, in preparation. G. Rothenberg, M. Tromp, G. P. F. van Strijdonck, Detailed Mechanistic Studies on the Deactivation of Homogeneous Pd Complexes using In Situ Spectroscopic Techniques, in preparation (in addition to Chapter 6b of this thesis). M. Lutz, M. Tromp, G. P. F. van Strijdonck, A. L. Spek, Crystal Structure of [(TMEDA)Cu(Imidazolate)] 3, in preparation (in addition to Chapter 7b of this thesis). Conference proceeding J.H. Bitter, J.A. van Bokhoven, M. Tromp, A.H. Janssen, K.P. de Jong, D.C. Koningsberger, Enhancement of the activity and selectivity of hydro-isomerization of n-hexane over Pt/H- Mordenite by mesopore generation, Abstracts ZMPC2000, Sendai (Japan), August ,
3 Special Articles Mitch Jacobi, Solution-Phase Catalyst Probe: Homogeneous reactions mechanism yields X-ray absorption method, Chemical & Engineering News, December 23, 2002, CENEAR 2002, 80(51), 8. Gabby Zegers, Momentopnamen van Katalytische Systemen, Chemisch2Weekblad 2003, 99(4), Oral Presentations M. Tromp, J. A. van Bokhoven, G. van Koten, D. C. Koningsberger, Development of Energy Dispersive XAFS for the Investigation of Homogeneous Reaction Intermediates, National Research School Combination Catalysis Work Conference, Utrecht, The Netherlands, November M. Tromp, J. A. van Bokhoven, R. J. van Haaren, G. P. F. van Strijdonck, P. W. N. M. van Leeuwen, D. C. Koningsberger, Characterization of (P-P)Pd(allyl) Catalysts in Solid State and Solution, Kristal- en Structuurchemie Symposium, Lunteren, The Netherlands, April M. Tromp, J. A. van Bokhoven, R. J. van Haaren, G. P. F. van Strijdonck, P. W. N. M. van Leeuwen, D. C. Koningsberger, Exploration of X-ray Absorption Fine Structure Spectroscopy for the In Situ study of Homogeneous Catalysts, 10 th Symposium on the relations between Homogeneous and Heterogeneous Catalysis, Lyon, France, July Leeuwen, D. C. Koningsberger, 'In situ Study of the Formation of Inactive Clusters in the Pdcatalyzed Allylic Alkylation Reaction using Energy Dispersive XAFS', EuropaCat V, Limerick, Ireland, September Leeuwen, D. C. Koningsberger, 'Application of In Situ X-ray Absorption Fine Structure Spectroscopy in Homogeneous Catalysis', Colloquium for the Institute of Molecular Chemistry, University of Amsterdam, Amsterdam, The Netherlands, October Leeuwen, D. C. Koningsberger, In Situ Study of the Pd-Catalysed Substitution Reaction and Its Deactivation: An (Energy Dispersive) XAFS Study, 3 rd Netherlands Catalysis and Chemistry Conference, Noordwijkerhout, The Netherlands, March
4 M. Tromp, J. A. van Bokhoven, A. M. J. van der Eerden, G. van Koten, D. C. Koningsberger, G. P. F. van Strijdonck, P. W. N. M. van Leeuwen, Development of Energy Dispersive XAFS: The In Situ Study of Catalytic Reaction Intermediates, Debye Lecture, Utrecht, The Netherlands, May M. Tromp, S. van Berkel, S. G. Fiddy, G. P. F. van Strijdonck, J. A. van Bokhoven, P. W. N. M. van Leeuwen, D. C. Koningsberger, Development of Time-Resolved Spectroscopic Techniques for the In Situ Study of Homogeneous Catalytic Systems, International Congress on Operando Spectroscopy, Lunteren, The Netherlands, March M. Tromp, S. van Berkel, S. G. Fiddy, G. P. F. van Strijdonck, J. A. van Bokhoven, P. W. N. M. van Leeuwen, D. C. Koningsberger, Development of Time-Resolved Spectroscopic Techniques for the In Situ Study of Homogeneous Catalytic Systems, 4 th Netherlands Catalysis and Chemistry Conference, Noordwijkerhout, The Netherlands, March M. Tromp, S. van Berkel, S.G. Fiddy, G.P.F. van Strijdonck, J.A. van Bokhoven, P.W.N.M. van Leeuwen, D.C. Koningsberger, Development of Time-Resolved Spectroscopic Techniques for the In Situ Study of Homogeneous Catalytic Systems, 12 th International Conference on X-ray Absorption Fine Structure, Malmö, Sweden, June M. Tromp, D.C. Koningsberger, (Time-Resolved) XAFS Spectroscopy Techniques Applications in Homogeneous Catalysis, Inorganic Colloquium Cambridge University, Cambridge, United Kingdom, September Poster Presentations M. Tromp, M. T. Garriga Oostenbrink, J. H. Bitter, D. C. Koningsberger, On the relation between pore structure and activity/selectivity of hydro-isomerisation catalysts, KNCV Catalysis Congress, Lunteren, The Netherlands, May M. Tromp, J. A. van Bokhoven, G. P. F. van Strijdonck, A. M. Arink, P. W. N. M. van Leeuwen, G. van Koten, D. C. Koningsberger, 'Development of Energy Dispersive XAFS for the In Situ Study of Homogeneous Catalytic Reaction Intermediates', 2 nd Netherlands Catalysis and Chemistry Conference, Noordwijkerhout, The Netherlands, March M. Tromp, J. A. van Bokhoven, G. P. F. van Strijdonck, J. R. A. Sietsma, A. M. J. van der Eerden, P. W. N. M. van Leeuwen, D. C. Koningsberger, Deactivation of Homogeneous Pd Catalysts using In Situ Time Resolved Spectroscopic Techniques, 13 th International Symposium on Homogeneous Catalysis, Tarragona, Spain, September
5 M. Tromp, S. van Berkel, S.G. Fiddy, G.P.F. van Strijdonck, J.A. van Bokhoven, P.W.N.M. van Leeuwen, D.C. Koningsberger, Development of Time-Resolved Spectroscopic Techniques for the In Situ Study of Homogeneous Catalytic Systems, Symposium NRSCC, PEER Review, Eindhoven, The Netherlands, April M. Tromp, B. O Grady, G. van Koten, D.E. Ramaker, D.C. Koningsberger, Demonstration of Atomic XAFS, 12 th International Conference on X-ray Absorption Fine Structure, Malmö, Sweden, June M. Tromp, S. van Berkel, M. Kuil, A. van den Hoogenband, J. W. Terpstra, D. C. Koningsberger, P. W. N. M. van Leeuwen and G. P. F. van Strijdonck, C-C and C-N Bond Formations: Pd(0), Cu(I) or Cu(II)?, 12 th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis, Toronto, Canada, July Awards NRSC-Catalysis Award for Best Graduate Student Lecture, 4 th Netherlands Catalysis and Chemistry Conference, Noordwijkerhout, the Netherlands, March Poster Price, NRSCC Symposium, PEER Review, Eindhoven, April
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