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1 Electronic Supplementary Material (ESI) for Materials Chemistry Frontiers. This journal is the Partner Organisations 2018 Supporting Information Metamagnetism with T N = 97 K in a Layered Assembly of Paddlewheel [Ru 2 ] Units and TCNQ: An Empirical Rule for Interlayer Distances Determining the Magnetic Ground State Wataru Kosaka, a,b Masahisa Itoh, b and Hitoshi Miyasaka* a,b a Institute for Materials Research, Tohoku University, Katahira, Aoba-ku, Sendai , Japan b Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza- Aoba, Aoba-ku, Sendai , Japan miyasaka@imr.tohoku.ac.jp Corresponding author* Prof. Dr. Hitoshi Miyasaka Institute for Materials Research, Tohoku University, Katahira, Aoba-ku, Sendai, Miyagi , Japan miyasaka@imr.tohoku.ac.jp Tel: FAX: S1
2 Fig. S1 Thermal gravimetric analysis (TGA) profiles of 1 with a heating rate of 5 K min 1 under N 2 atmosphere. S2
3 Fig. S2 Infrared spectra in the range of cm 1 Li + TCNQ(MeO) 2 measured on KBr pellets at room temperature. for 1, TCNQ(MeO) 2 0, and S3
4 Fig. S3 Powder reflection spectra of 1, Ru 2 (m-clphco 2 ) 4 (THF) 2, TCNQ(MeO) 2 0, and Li + TCNQ(MeO) 2 measured on pellets diluted with BaSO 4. S4
5 Fig. S4 Plot of DE H-L (DA) vs DE 1/2 (DA) for D 2 A and DA materials of [Ru II,II 2 ]/TCNQR x, DCNQIR x sets reported until now, where red circle, blue square, green diamond and cyan triangle plots represent N, 1e-I, 2e-I and 1.5e-I, respectively. Open and close plots correspond to D 2 A and DA compound, respectively. Purple triangle corresponds to the DA compound exhibits temperature and pressureinduced N-I phase transition. 1: [{Ru 2 (o-cf 3 PhCO 2 ) 4 }(TCNQ)], 1 2: [{Ru 2 (o- CF 3 PhCO 2 ) 4 }{TCNQ(Me) 2 }], 1 3: [{Ru 2 (o-cf 3 PhCO 2 ) 4 }(TCNQF 4 )], 1 4: [{Ru 2 (o- CH 3 PhCO 2 ) 4 }(BTDA-TCNQ)], 1 5: [{Ru 2 (p-ch 3 PhCO 2 ) 4 }(BTDA-TCNQ)], 1 6: [{Ru 2 (m- CH 3 PhCO 2 ) 4 }(BTDA-TCNQ)], 2, 3 7: [{Ru 2 (CF 3 CO 2 ) 4 }{TCNQ(MeO) 2 }], 4 8: [{Ru 2 (CF 3 CO 2 ) 4 }{TCNQ(Me) 2 }], 4 9: [{Ru 2 (CF 3 CO 2 ) 4 }(TCNQ)], 4, 5, 6 10: [{Ru 2 (CF 3 CO 2 ) 4 }(TCNQBr 2 )], 4,6 11: [{Ru 2 (CF 3 CO 2 ) 4 }(TCNQF 2 )], 4,6 12: [{Ru 2 (CF 3 CO 2 ) 4 }(TCNQCl 2 )], 4,6 13: [{Ru 2 (2,3,5,6-F 4 PhCO 2 ) 4 }{DCNQI(Me) 2 }], 7, 8, 9 14: [{Ru 2 (CF 3 CO 2 ) 4 }(TCNQF 4 )], 4,6, 10 15: [{Ru 2 (o-clphco 2 ) 4 }{TCNQ(MeO) 2 }], 11 16: [{Ru 2 (m- FPhCO 2 ) 4 }(BTDA-TCNQ)], 3, 12, 13 17: [{Ru 2 (p-fphco 2 ) 4 }(BTDA-TCNQ)], 14 18: [{Ru 2 (o- FPhCO 2 ) 4 }(BTDA-TCNQ)], 14 19: [{Ru 2 (4-Cl-2-MeOPhCO 2 ) 4 }(BTDA-TCNQ)], 15,16 20: [{Ru 2 (o- FPhCO 2 ) 4 }{TCNQ(MeO) 2 }], 17 21: [{Ru 2 (m-fphco 2 ) 4 }{TCNQ(MeO) 2 }], 17 22: [{Ru 2 (p- FPhCO 2 ) 4 }{TCNQ(MeO) 2 }], 17 23: [{Ru 2 (2,4,6-F 3 PhCO 2 ) 4 }(TCNQ)], 18 24: [{Ru 2 (F 5 PhCO 2 ) 4 }{DCNQI(Me) 2 }], 8 25: [{Ru 2 (2,3,5,6-F 4 PhCO 2 ) 4 }{DCNQI(MeO) 2 }], 9 26: [{Ru 2 (2,3,5,6-F 4 PhCO 2 ) 4 }(BTDA-TCNQ)], 19 27: [{Ru 2 (CF 3 CO 2 ) 4 }(BTDA-TCNQ)], 20 28: [{Ru 2 (3,4-Cl 2 PhCO 2 ) 4 }{TCNQ(EtO) 2 }], 21 29: [{Ru 2 (m-clphco 2 ) 4 }{TCNQ(MeO) 2 }]. S5
6 Fig. S5 Plots of DE H-L (DA) vs 2 E 1/2 (A) 1 E 1/2 (A). Numberings of compounds were given in the caption of Fig. S3. S6
7 Table S1 Selected bond lengths (Å) and angles ( ) in 1, where q represents dihedral angle between least-squares planes defined by phenyl ring of benzoate ligand and carboxylate-bridging mode (atom set of Ru 2 O 2 C). 1 Ru1 O (4) Ru1 O2a 2.006(4) Ru1 O (4) Ru1 O4a 2.010(4) Ru2 O (3) Ru2 O6b 2.064(4) Ru2 O (4) Ru2 O8b 2.060(4) Ru1 N (5) Ru2 N (5) Ru1 Ru1a (7) Ru2 Ru2b (7) Ru1a Ru1 N (13) Ru2b Ru2 N (12) Ru1 N1 C (4) Ru2 N2 C (4) q benzoate set benzoate set benzoate set benzoate set Symmetry codes: (a) x + 1, y + 2, z + 1, (b) x + 1, y + 1, z. Benzoate set-1 to -4: the phenyl group of C2 C8, C10 C16, C18 C24 and C26 C32, respectively. S7
8 Table S2 Comparison of bond lengths (Å) in TCNQ moiety and a charge of TCNQ (r) estimated based on the Kistenmacher relationship. 22 charge a b c d e r b Ref I (1) 1.441(1) 1.374(3) 1.448(4) 1.346(3) 0 23 II (7) 1.416(8) 1.420(1) 1.423(3) 1.373(1) (7) 1.401(7) 1.419(8) 1.432(7) 1.373(8) 1.08 c This work 1.158(7) 1.413(7) 1.409(7) a a a I: TCNQ, II: RbTCNQ. a average value, b estimated from average values, c r = A H [c/(b + d)] + B H with A H = and B H = S8
9 Fig. S6 Packing diagrams of 1. A view along a-axis (a) and c-axis (b), where atoms C, N, O, and Ru are represented in gray, blue, red, and purple, respectively. Crystallization solvents are depicted in cyan. The equatorial carboxylate ligands are located around the [Ru 2 ] units. Hydrogen atoms are omitted for clarity. S9
10 Fig. S7 Spin-flipping field at 1.8 K (H ex ) vs. inter-layer vertical distance (l 1, Fig. 2b) plots for 1 and relevant [Ru 2 ]/TCNQR x layered magnets reported previously, where the compound with ferromagnetic and antiferromagnetic ground states are colored in red and blue, respectively: 1, [{Ru 2 (m-clphco 2 ) 4 } 2 {TCNQ(MeO) 2 }] 3.3DCM 2TCE; 2, [{Ru 2 (CF 3 CO 2 ) 4 } 2 (TCNQF 4 )] 3(pxylene); 6,10 3, [{Ru 2 (o-fphco 2 ) 4 } 2 (BTDA-TCNQ)] 4DCM; 14 4, [{Ru 2 (o- ClPhCO 2 ) 4 }{TCNQ(MeO) 2 }] DCM; 11 5, [{Ru 2 (o-fphco 2 ) 4 }{TCNQ(MeO) 2 }] 4DCM; 17 6, [{Ru 2 (2,4,6-F 3 PhCO 2 ) 4 }(TCNQ)] 2DCM 2(p-xylene); 18 7, [{Ru 2 (p-fphco 2 ) 4 }(BTDA- TCNQ)] 2DCM 2(p-chlorotoluene). 14 S10
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