Name: 1. Ignoring C-H absorptions, what characteristic IR absorption(s) would be expected for the functional group shown below?
|
|
- Brian Potter
- 5 years ago
- Views:
Transcription
1 Chemistry 262 Winter 2018 Exam 3 Practice The following practice contains 20 questions. Thursday s 90 exam will also contain 20 similar questions, valued at 4 points/question. There will also be 2 unknown analysis problems valued at 10 points each, giving an opportunity for 10 extra credit points Name: 1. Ignoring C- absorptions, what characteristic IR absorption(s) would be expected for the functional group shown below? a. A peak around 1700 cm -1 b. A peak around 3300 cm -1 c. A peak around 1650 cm -1 d. A peak around 2250 cm -1 e. None of the absorbance values listed would indicate the functional group above 2. Ignoring C- absorptions, what characteristic IR absorption(s) would be expected for the functional group shown below? CN a. A peak around 1700 cm -1 b. A peak around 3300 cm -1 c. A peak around 1650 cm -1 d. A peak around 2250 cm -1 e. None of the absorbance values listed would indicate the functional group above
2 3. An optically active compound of molecular formula C 7 12, reacts with cold, dilute KMn 4 and gives a characteristic IR band around 3300 cm -1. n catalytic hydrogenation a new optically active compound is formed, with a formula C Which of the following compounds is a possible candidate? I II III IV V a. I b. II c. III d. IV e. V 4. IR evidence for the presence of an alkene would be most difficult for which of the following molecules? a. b. c. d. e.
3 5. Predict the splitting pattern you would observe for the proton at C1 of 2,3- dimethyl-2-phenylbutane a. Singlet b. Doublet c. Quartet d. Septet e. ctet 6. For the following compound, how many different signals would be observed in a proton NMR (presuming all were well resolved)? a. 4 b. 5 c. 6 d. 7 e Which of the following best represents the approximate predicted chemical shift and coupling for the hydrogen indicated with the arrow? a. 1.1 ppm, singlet b. 2.1 ppm, doublet c. 3.4 ppm, singlet d. 3.5 ppm, quartet e. 4.5 ppm, singlet
4 8. Which of the following best represents the approximate predicted chemical shift and coupling for the hydrogen indicated with the arrow? a. 1.0 ppm, quartet b. 2.4 ppm, singlet c. 2.4 ppm, triplet d. 2.4 ppm, quartet e. 3.0 ppm, quartet 9. Which of the following best represents the approximate predicted chemical shift and coupling for the hydrogen indicated with the arrow? a. 5.4 ppm, doublet b. 1.0 ppm, multiplet c. 2.0 ppm, doublet d. 1.0 ppm, doublet e. 5.4 ppm, multiplet 10. Assuming all are resolved, how many different signals would be observed in the 1 -NMR of the following compound? a. 1 b. 2 c. 3 d. 4 e. 5
5 11. ow many signals would be observed in the 1 -NMR of trans-1,2- dichlorocyclopropane? a. 1 b. 2 c. 3 d. 4 e Which of the following compounds would consist of one triplet, one singlet, and one quartet? a. 2-chloro-4-methylpentane b. 3-chloro-2-methylpentane c. 3-chloropentane d. 1-chloro-2,2-dimethylbutane e. 3-chloro-3-methylpentane 13. An organic compound absorbs strongly in the IR at 1687 cm -1. The 1 -NMR for the compound consists of 2 signals a singlet at 2.1 ppm and a multiplet centered at 7.1 ppm. The MS shows significant peaks at m/z 120, 105, and 77. The above information is consistent with which of the following structures? I II III a. I b. II c. III d. IV e. V IV V
6 14. Which of the indicated protons has its 1 -NMR signal furthest downfield? Cl III I C C C II C IV V a. I b. II c. III d. IV e. V 15. Assuming all are resolved, how many different signals would be observed in the 13 C-NMR of the following compound? S S a. 4 b. 5 c. 6 d. 7 e Assuming all peaks are resolved, which of the following would give rise to 4 peaks in both the 1 -NMR and broadband decoupled 13 C-NMR spectra? Br I II III IV a. I b. II c. III d. IV e. More than one of the above
7 17. The broadband decoupled 13 C-NMR spectrum of a hexylchloride exhibits 5 signals. Which of the following consistent with this information? a. CC 2 C 2 Cl b. Cl C 2 CC 2 c. C C d. Cl CCC 2 e. Cl C C Cl
8 18. An unknown compound of formula C gives the following 1 -NMR spectrum. The broadband decouple 13 C-NMR spectrum shows a characteristic peak at 174 ppm. Which of the following structures is consistent with this information? PPM a. b. c. d. e.
9 19. Which of the following compounds of formula C 6 14 would give a MS base peak of m/z = 43? a. C 2 C 2 C 2 C 2 b. ( C 2 ) 2 C c. ( ) 3 CC 2 d. ( ) 2 CC( ) 2 e. None of these 20. The data below for the isotope envelope of the molecular ion region of a halogen containing species are consistent with the presence of what halogens for the compound in question? M +, I = % M + + 2, I = 64.0 % M + + 4, I = 10.0 % a. 1 Br b. 1 Cl c. 1 Br, 1 Cl d. 2 Br e. 2 Cl
Name: 1. Ignoring C-H absorptions, what characteristic IR absorption(s) would be expected for the functional group shown below?
Chemistry 262 Winter 2018 Exam 3 Practice The following practice contains 20 questions. Thursday s 90 exam will also contain 20 similar questions, valued at 4 points/question. There will also be 2 unknown
More informationCHEM 242 NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY CHAP 14B ASSIGN
CHEM 242 NUCLEAR MAGNETIC RESNANCE SPECTRSCPY CHAP 14B ASSIGN 1. A proton NMR spectrum is observed to contain following the pattern below; what do you conclude? A. This must be a quartet that is part of
More informationChem 2320 Exam 1. January 30, (Please print)
Chem 2320 Exam 1 January 30, 2006 Name: (first) (last) (Please print) Last 4 digits of I.D. I. Multiple Choice ( /20) Score /60 II /15 III /25 Total score /100 I. Multiple choice questions. (3 points each).
More informationPaper 12: Organic Spectroscopy
Subject Chemistry Paper No and Title Module No and Title Module Tag Paper 12: Organic Spectroscopy 31: Combined problem on UV, IR, 1 H NMR, 13 C NMR and Mass - Part III CHE_P12_M31 TABLE OF CONTENTS 1.
More informationHWeb27 ( ; )
HWeb27 (9.1-9.2; 9.12-9.18) 28.1. Which of the following cannot be determined about a compound by mass spectrometry? [a]. boiling point [b]. molecular formula [c]. presence of heavy isotopes (e.g., 2 H,
More informationI pledge my honor that I have neither given nor received aid on this examination
Chemistry 220b, Section 1 Exam 1 (100 pts) Tuesday, February 3, 2015 Chapters 13, 15, 16 Name Write and sign the VU onor Pledge: I pledge my honor that I have neither given nor received aid on this examination
More informationIR, MS, UV, NMR SPECTROSCOPY
CHEMISTRY 318 IR, MS, UV, NMR SPECTROSCOPY PROBLEM SET All Sections CHEMISTRY 318 IR, MS, UV, NMR SPECTROSCOPY PROBLEM SET General Instructions for the 318 Spectroscopy Problem Set Consult the Lab Manual,
More information11. Proton NMR (text , 12.11, 12.12)
2009, Department of Chemistry, The University of Western Ontario 11.1 11. Proton NMR (text 12.6 12.9, 12.11, 12.12) A. Proton Signals Like 13 C, 1 H atoms have spins of ±½, and when they are placed in
More information4) protons experience a net magnetic field strength that is smaller than the applied magnetic field.
1) Which of the following CANNOT be probed by an spectrometer? See sect 16.1 Chapter 16: 1 A) nucleus with odd number of protons & odd number of neutrons B) nucleus with odd number of protons &even number
More informationNUCLEAR MAGNETIC RESONANCE AND INTRODUCTION TO MASS SPECTROMETRY
NUCLEAR MAGNETIC RESONANCE AND INTRODUCTION TO MASS SPECTROMETRY A STUDENT SHOULD BE ABLE TO: 1. Identify and explain the processes involved in proton ( 1 H) and carbon-13 ( 13 C) nuclear magnetic resonance
More informationCHEM Chapter 13. Nuclear Magnetic Spectroscopy (Homework) W
CHEM 2423. Chapter 13. Nuclear Magnetic Spectroscopy (Homework) W Short Answer 1. For a nucleus to exhibit the nuclear magnetic resonance phenomenon, it must be magnetic. Magnetic nuclei include: a. all
More informationOrganic Chemistry 1 CHM 2210 Exam 4 (December 10, 2001)
Exam 4 (December 10, 2001) Name (print): Signature: Student ID Number: There are 12 multiple choice problems (4 points each) on this exam. Record the answers to the multiple choice questions on THIS PAGE.
More informationCHEM311 FALL 2005 Practice Exam #3
EM311 FALL 2005 Practice Exam #3 Instructions: This is a multiple choice / short answer practice exam. For the multiple-choice questions, there may be more than one correct answer. If so, then circle as
More informationCLASSIFICATION OF ALKYL HALIDES, ALCOHOLS, THIOLS, ETHERS, AND SULFIDES NOMENCLATURE OF ALKYL HALIDES, ALCOHOLS, THIOLS, ETHERS, AND SULFIDES
Chemistry 262 Winter 2018 Final Exam Practice The following practice contains 44 problems and mimics Monday s 150 point final, which will also contain 44 problems valued at 3.5 points each with approximately
More informationOrganic Chemistry 321 Workshop: Spectroscopy NMR-IR Problem Set
Organic Chemistry 321 Workshop: Spectroscopy NMR-IR Problem Set 1. Draw an NMR spectrum for each of the following compounds. Indicate each peak by a single vertical line (for example, a quartet would be
More informationUCF - ORGANIC CHEMISTRY 2 - PROF. GERASIMOVA UCF PROF. GERASIMOVA EXAM REVIEW 1.
UCF PROF. GERASIMOVA EXAM REVIEW 1 www.clutchprep.com 1 PRACTICE: Determine the index of hydrogen deficiency (degrees of unsaturation) for the following molecule. Antipsychotic - Haloperidol = C 21 H 23
More informationCHEMISTRY Organic Chemistry Laboratory II Spring 2019 Lab #5: NMR Spectroscopy
Team Members: Unknown # CHEMISTRY 244 - Organic Chemistry Laboratory II Spring 2019 Lab #5: NMR Spectroscopy Purpose: You will learn how to predict the NMR data for organic molecules, organize this data
More information4) protons experience a net magnetic field strength that is smaller than the applied magnetic field.
1) Which of the following CANNOT be probed by an spectrometer? See sect 16.1 Chapter 16: 1 A) nucleus with odd number of protons & odd number of neutrons B) nucleus with odd number of protons &even number
More informationOrganic Chemistry II (CHE ) Examination I February 11, Name (Print legibly): Key. Student ID#:
rganic hemistry II (HE 232-001) Examination I February 11, 2009 Name (Print legibly): Key (last) (first) Student ID#: PLEASE observe the following: You are allowed to have scratch paper (provided by me),
More informationThe resonance frequency of the H b protons is dependent upon the orientation of the H a protons with respect to the external magnetic field:
Spin-Spin Splitting in Alkanes The signal arising from a proton or set of protons is split into (N+1) lines by the presence of N adjacent nuclei Example 1: Bromoethane The resonance frequency of the H
More informationORGANIC - EGE 5E CH UV AND INFRARED MASS SPECTROMETRY
!! www.clutchprep.com CONCEPT: IR SPECTROSCOPY- FREQUENCIES There are specific absorption frequencies in the functional group region that we should be familiar with EXAMPLE: What are the major IR absorptions
More informationCHEM 213 FALL 2018 MIDTERM EXAM 2 - VERSION A
CEM 213 FALL 2018 MIDTERM EXAM 2 - VERSIN A Answer multiple choice questions on the green computer sheet provided with a PENCIL. Be sure to encode both your NAME and Registration Number (V#). You will
More informationHour Examination # 4
CHEM 346 Organic Chemistry I Fall 2014 Exam # 4 Solutions Key Page 1 of 12 CHEM 346 Organic Chemistry I Fall 2014 Instructor: Paul Bracher Hour Examination # 4 Wednesday, December 3 rd, 2014 6:00 8:00
More information1. Predict the structure of the molecules given by the following spectral data: a Mass spectrum:m + = 116
Additional Problems for practice.. Predict the structure of the molecules given by the following spectral data: a Mass spectrum:m + = IR: weak absorption at 9 cm - medium absorption at cm - NMR 7 3 3 C
More informationOAT Organic Chemistry - Problem Drill 19: NMR Spectroscopy and Mass Spectrometry
OAT Organic Chemistry - Problem Drill 19: NMR Spectroscopy and Mass Spectrometry Question No. 1 of 10 Question 1. Which statement concerning NMR spectroscopy is incorrect? Question #01 (A) Only nuclei
More informationChem 213 Final 2012 Detailed Solution Key for Structures A H
Chem 213 Final 2012 Detailed Solution Key for Structures A H COMPOUND A on Exam Version A (B on Exam Version B) C 8 H 6 Cl 2 O 2 DBE = 5 (aromatic + 1) IR: 1808 cm 1 suggests an acid chloride since we
More informationDepartment of Chemistry SUNY/Oneonta. Chem Organic Chemistry I
Department of Chemistry SUNY/Oneonta Chem 221 - Organic Chemistry I Examination #4 - ANSWERS - December 11, 2000 Answer to question #32 corrected 12/13/00, 8:30pm. INSTRUCTIONS This examination is in multiple
More informationThe Use of NMR Spectroscopy
Spektroskopi Molekul Organik (SMO): Nuclear Magnetic Resonance (NMR) Spectroscopy All is adopted from McMurry s Organic Chemistry The Use of NMR Spectroscopy Used to determine relative location of atoms
More informationExperiment 2 - NMR Spectroscopy
Experiment 2 - NMR Spectroscopy OBJECTIVE to understand the important role of nuclear magnetic resonance spectroscopy in the study of the structures of organic compounds to develop an understanding of
More informationNuclear spin and the splitting of energy levels in a magnetic field
Nuclear spin and the splitting of energy levels in a magnetic field Top 3 list for 13 C NMR Interpretation 1. Symmetry 2. Chemical Shifts 3. Multiplicity 13 C NMR of C 3 O 1 NMR of C 3 O 13 C NMR of C
More informationCHEMISTRY 216 WINTER TERM 2007 END OF TERM EXAM. Time Allowed 2 hours
EMISTRY 216 WITER TERM 2007 ED F TERM EXAM Time Allowed 2 hours ame KEY GSI ame ID umber Lab Section Write legibly. Illegible or messy answers will not be graded. Read these instructions carefully. In
More informationChapter 9. Nuclear Magnetic Resonance. Ch. 9-1
Chapter 9 Nuclear Magnetic Resonance Ch. 9-1 1. Introduction Classic methods for organic structure determination Boiling point Refractive index Solubility tests Functional group tests Derivative preparation
More informationORGANIC - CLUTCH CH ANALYTICAL TECHNIQUES: IR, NMR, MASS SPECT
!! www.clutchprep.com CONCEPT: PURPOSE OF ANALYTICAL TECHNIQUES Classical Methods (Wet Chemistry): Chemists needed to run dozens of chemical reactions to determine the type of molecules in a compound.
More informationCHEM311 FALL 2005 Practice Exam #3
CHEM311 FALL 2005 Practice Exam #3 Instructions: This is a multiple choice / short answer practice exam. For the multiple-choice questions, there may be more than one correct answer. If so, then circle
More informationORGANIC - CLUTCH CH ANALYTICAL TECHNIQUES: IR, NMR, MASS SPECT
!! www.clutchprep.com CONCEPT: PURPOSE OF ANALYTICAL TECHNIQUES Classical Methods (Wet Chemistry): Chemists needed to run dozens of chemical reactions to determine the type of molecules in a compound.
More informationCH 3. mirror plane. CH c d
CAPTER 20 Practice Exercises 20.1 The index of hydrogen deficiency is two. The structural possibilities include two double bonds, a double do 20.3 (a) As this is an alkane, it contains only C and and has
More informationCEM 351, Fall 2010 Midterm Exam 1 Friday, October 1, :50 2:40 p.m. Room 138, Chemistry
Name (print) Signature Student # EM 351, Fall 2010 Midterm Exam 1 Friday, ctober 1, 2010 1:50 2:40 p.m. Room 138, hemistry Wright N. Swers 1.(20 2.(20.. 3.(20 4.(20 5.(20 6.(20 Section Number (2 pts extra
More informationDepartment of Chemistry SUNY/Oneonta. Chem Organic Chemistry I. Examination #4 - December 9, 2002 ANSWERS
INSTRUCTINS Department of Chemistry SUNY/neonta Chem 221 - rganic Chemistry I Examination #4 - December 9, 2002 ANSWERS This examination is in multiple choice format; the questions are in this Exam Booklet
More information4) protons experience a net magnetic field strength that is smaller than the applied magnetic field.
1) Which of the following CANNOT be probed by an NMR spectrometer? See sect 15.1 Chapter 15: 1 A) nucleus with odd number of protons & odd number of neutrons B) nucleus with odd number of protons &even
More informationUsing NMR and IR Spectroscopy to Determine Structures Dr. Carl Hoeger, UCSD
Using NMR and IR Spectroscopy to Determine Structures Dr. Carl Hoeger, UCSD The following guidelines should be helpful in assigning a structure from NMR (both PMR and CMR) and IR data. At the end of this
More informationNuclear Magnetic Resonance Spectroscopy
13 Nuclear Magnetic Resonance Spectroscopy Solutions to In-Text Problems 13.1 (b) Apply Eq. 13.2b with = 360 MHz. chemical shift in Hz = δ = (4.40)(360) = 1584 Hz 13.2 (b) Follow the same procedure used
More informationChemistry 14C Winter 2017 Exam 2 Solutions Page 1
Chemistry 14C Winter 2017 Exam 2 Solutions Page 1 Statistics: High score, average, and low score will be posted on the course web site after exam grading is complete. Some questions have more than one
More informationDepartment of Chemistry SUNY/Oneonta. Chem Organic Chemistry I. Examination #4 - December 7, 1998*
Department of hemistry SUNY/neonta hem 221 - rganic hemistry I Examination #4 - December 7, 1998* INSTRUTINS --- This examination is in multiple choice format; the questions are in this Exam Booklet and
More information1. Which of the following compounds is the weakest base?
I. Multiple-choice Questions Fall 2018 1. Which of the following compounds is the weakest base? a. C3C2 b. C3C2 c. N3 d. C3 e. N2 2. Which of the following functional groups is indicated by a strong and
More informationProton NMR. Four Questions
Proton NMR Four Questions How many signals? Equivalence Where on spectrum? Chemical Shift How big? Integration Shape? Splitting (coupling) 1 Proton NMR Shifts Basic Correlation Chart How many 1 H signals?
More informationCHEM1102 Worksheet 4 Answers to Critical Thinking Questions Model 1: Infrared (IR) Spectroscopy
CEM1102 Worksheet 4 Answers to Critical Thinking Questions Model 1: Infrared (IR) Spectroscopy 1. See below. Model 2: UV-Visible Spectroscopy 1. See below. 2. All of the above. 3. Restricted to the identification
More informationChemistry 51 Summer 2007 Final Exam
Chemistry 51 Summer 2007 Final Exam 1. This is a two-hour, closed book exam. All answers are to be put on the question sheets. 2. Use the backsides of these pages for scratch paper. None other permitted.
More informationORGANIC - BROWN 8E CH NUCLEAR MAGNETIC RESONANCE.
!! www.clutchprep.com CONCEPT: 1 H NUCLEAR MAGNETIC RESONANCE- GENERAL FEATURES 1 H (Proton) NMR is a powerful instrumental method that identifies protons in slightly different electronic environments
More informationPaper 12: Organic Spectroscopy
Subject hemistry Paper No and Title Module No and Title Module Tag Paper 12: Organic Spectroscopy 34: ombined problem on UV, IR, 1 H NMR, 13 NMR and Mass- Part 6 HE_P12_M34 TABLE OF ONTENTS 1. Learning
More informationAnswers to Assignment #5
Answers to Assignment #5 A. 9 8 l 2 5 DBE (benzene + 1 DBE) ( 9 2(9)+2-9 8+1+1 = 10 ˆ 5 DBE) nmr pattern of two doublets of equal integration at δ7.4 and 7.9 ppm means the group (the δ7.9 shift) IR band
More informationNMR Nuclear Magnetic Resonance Spectroscopy p. 83. a hydrogen nucleus (a proton) has a charge, spread over the surface
NMR Nuclear Magnetic Resonance Spectroscopy p. 83 a hydrogen nucleus (a proton) has a charge, spread over the surface a spinning charge produces a magnetic moment (a vector = direction + magnitude) along
More informationExperiment 11: NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY
Experiment 11: NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY Purpose: This is an exercise to introduce the use of nuclear magnetic resonance spectroscopy, in conjunction with infrared spectroscopy, to determine
More informationStructure Determination: Nuclear Magnetic Resonance Spectroscopy
Structure Determination: Nuclear Magnetic Resonance Spectroscopy Why This Chapter? NMR is the most valuable spectroscopic technique used for structure determination More advanced NMR techniques are used
More informationTechnique Experiment 1-1
Chemistry 335. Technique Experiment 1A: Separation of Benzoin and Benzil Name: Date: Benzoin 1. Physical Properties (5 points) Color R f TLC Mobile Phase Amount isolated (mg) Mass recovery (%) 2. IR Spectrum
More informationPAPER No.12 :Organic Spectroscopy MODULE No.29: Combined problem on UV, IR, 1 H NMR, 13 C NMR and Mass - Part I
Subject Chemistry Paper No and Title Module No and Title Module Tag 12: rganic Spectroscopy 29: Combined problem on UV, IR, 1 H NMR, 13 C NMR and Mass - Part I CHE_P12_M29 TABLE F CNTENTS 1. Learning utcomes
More informationObjective 4. Determine (characterize) the structure of a compound using IR, NMR, MS.
Objective 4. Determine (characterize) the structure of a compound using IR, NMR, MS. Skills: Draw structure IR: match bond type to IR peak NMR: ID number of non-equivalent H s, relate peak splitting to
More information4. NMR spectra. Interpreting NMR spectra. Low-resolution NMR spectra. There are two kinds: Low-resolution NMR spectra. High-resolution NMR spectra
1 Interpreting NMR spectra There are two kinds: Low-resolution NMR spectra High-resolution NMR spectra In both cases the horizontal scale is labelled in terms of chemical shift, δ, and increases from right
More informationChapter 13 Structure t Determination: Nuclear Magnetic Resonance Spectroscopy
John E. McMurry www.cengage.com/chemistry/mcmurry Chapter 13 Structure t Determination: ti Nuclear Magnetic Resonance Spectroscopy Revisions by Dr. Daniel Holmes MSU Paul D. Adams University of Arkansas
More information4) protons experience a net magnetic field strength that is smaller than the applied magnetic field.
1) Which of the following CANNOT be probed by an spectrometer? See sect 15.1 Chapter 15: 1 A) nucleus with odd number of protons & odd number of neutrons B) nucleus with odd number of protons &even number
More informationStructure solving based on IR, UV-Vis, MS, 1 H and 13 C NMR spectroscopic data. Problem solving session
Structure solving based on IR, UV-Vis, MS, 1 H and 13 C NMR spectroscopic data Problem solving session S. SANKARARAMAN DEPARTMENT OF CHEMISTRY INDIAN INSTITUTE OF TECHNOLOGY MADRAS CHENNAI 600036 sanka@iitm.ac.in
More informationNuclear Magnetic Resonance Spectroscopy: Purpose: Connectivity, Map of C-H framework
Nuclear Magnetic Resonance Spectroscopy: Purpose: Connectivity, Map of C- framework Four Factors of Proton NMR (PMR OR NMR):. Symmetry: Number of chemically different protons (symmetry) as shown by number
More informationNMR = Nuclear Magnetic Resonance
NMR = Nuclear Magnetic Resonance NMR spectroscopy is the most powerful technique available to organic chemists for determining molecular structures. Looks at nuclei with odd mass numbers or odd number
More informationBasic Concepts of NMR: Identification of the Isomers of C 4 O 2. by 1 H NMR Spectroscopy
Basic Concepts of NM: Identification of the Isomers of C H 8 O by H NM Spectroscopy Objectives NM spectroscopy is a powerful tool in determining the structure of compounds. Not only is it able to give
More informationOther problems to work: 3-Chloropentane (diastereotopic H s), 1- chloropentane.
Let s look at some specific examples. Dichloroacetaldehyde, l 2 HHO, has two inequivalent toms, H1 and H2. We expect to see two resonances, one at around δ 10.5 ppm and one around δ 5.5 ppm. (The H2 resonance
More informationNuclear Magnetic Resonance Spectroscopy (NMR)
OCR Chemistry A 432 Spectroscopy (NMR) What is it? An instrumental method that gives very detailed structural information about molecules. It can tell us - how many of certain types of atom a molecule
More information12-June-2016 Chemsheets A Page 1
www.chemsheets.co.uk 12-June-2016 Chemsheets A2 1070 Page 1 SECTION 1 1 H NMR Why compounds absorb radiowaves (background information beyond specifications) NMR (nuclear magnetic resonance) is a very powerful
More informationCHEM 2430 Organic Chemistry I Fall Instructor: Paul Bracher. Final Examination
CHEM 2430 Organic Chemistry I Fall 2015 Final Exam Solutions Key Page 1 of 10 CHEM 2430 Organic Chemistry I Fall 2015 Instructor: Paul Bracher Final Examination Friday, December 11 th, 2015 12:00 1:50
More informationOrganic Chemistry II (CHE ) Final Examination April 30, Name (Print legibly):
rganic hemistry II (E 232-002) Final Examination April 30, 2007 Name (Print legibly): (last) (first) PLEASE observe the following: You are allowed to have scratch paper (provided by me), and a simple model
More informationChemistry 14C Summer 2017 Second Midterm Exam Page 1
Chemistry 14C Summer 2017 Second Midterm Exam Page 1 Begin this exam by gently removing the last two pages of this exam. Nothing o n these pages will be graded. They will be discarded before grading. Please
More informationOrganic Chemistry II (CHE ) Examination I March 1, Name (Print legibly): _KEY _. Student ID#: _
Organic Chemistry II (CHE 232-002) Examination I March 1, 2007 Name (Print legibly): _KEY _ (last) (first) Student ID#: _ PLEASE observe the following: You are allowed to have scratch paper (provided by
More informationOrganic Chemistry II* (CHE ) Examination I March 1, Name (Print legibly): KEY. Student ID#:
Organic Chemistry II* (CHE 232-002) Examination I March 1, 2007 Name (Print legibly): KEY (last) (first) Student ID#: PLEASE observe the following: You are allowed to have scratch paper (provided by me),
More informationExam I 19 April 2004 Name:
Chem 317 S04 Page 1 of 7 Kantorowski Exam I 19 April 2004 Name: This exam contains 6 pages of questions confirm this once you begin The last page is a spectral data table that can be removed You will have
More informationCHEM Review for test 1 (ch12-15). F17. Stafford
CHEM Multiple Choice Identify the choice that best completes the statement or answers the question. 1. What range of wavelengths corresponds to the infrared region of the electromagnetic spectrum? a. 200-400
More informationOrganic Chemistry I Exam 3 Fall 2001 November 30, Which of the following compounds corresponds to the spectral data given below?
. Which of the following compounds corresponds to the spectral data given below? one of these. The reaction energy diagram given below corresponds to which of the following reactions? TS TS TS Br + R RI
More information*Assignments could be reversed. *
Name Key 5 W-Exam No. Page I. (6 points) Identify the indicated pairs of hydrogens in each of the following compounds as (i) homotopic, (ii) enantiotopic, or (iii) diastereotopic s. Write the answers as
More informationAQA A2 CHEMISTRY TOPIC 4.10 ORGANIC SYNTHESIS AND ANALYSIS TOPIC 4.11 STRUCTURE DETERMINATION BOOKLET OF PAST EXAMINATION QUESTIONS
AQA A2 CHEMISTRY TOPIC 4.10 ORGANIC SYNTHESIS AND ANALYSIS TOPIC 4.11 STRUCTURE DETERMINATION BOOKLET OF PAST EXAMINATION QUESTIONS 1 1. Consider the following reaction sequence. CH 3 CH 3 CH 3 Step 1
More informationTo Do s. Answer Keys are available in CHB204H
To Do s Read Chapters 2, 3 & 4. Complete the end-of-chapter problems, 2-1, 2-2, 2-3 and 2-4 Complete the end-of-chapter problems, 3-1, 3-3, 3-4, 3-6 and 3-7 Complete the end-of-chapter problems, 4-1, 4-2,
More informationClickers. a. I watched all 5 videos b. The dog ate my iphone
Clickers a. I watched all 5 videos b. The dog ate my iphone 40% 33% 33% 40% 59% 67% of you: Watch youtube! PRBLEMS: Complete end of chapter 13 problems 1 10 from Lab Manual Answers 1 NMR Protons (nucleus
More informationTo Do s. Answer Keys are available in CHB204H
To Do s Read Chapters 2, 3 & 4. Complete the end-of-chapter problems, 2-1, 2-2, 2-3 and 2-4 Complete the end-of-chapter problems, 3-1, 3-3, 3-4, 3-6 and 3-7 Complete the end-of-chapter problems, 4-1, 4-2,
More informationChapter 14 Spectroscopy
hapter 14 Spectroscopy There are four major analytical techniques used for identifying the structure of organic molecules 1. Nuclear Magnetic Resonance or NMR is the single most important technique for
More informationLecture 5 Still More nmr
Lecture 5 Still More nmr three spins February 5, 2019 Supplemental Problem Chlorocyclobutane Origins of Signal Splitting B 0 H b Magnetic field of H b subtracts from the applied field; H b signal appears
More informationFri 6 Nov 09. More IR Mass spectroscopy. Hour exam 3 Fri Covers Chaps 9-12 Wednesday: Review
Fri 6 Nov 09 our exam 3 Fri 11-13 Covers Chaps 9-12 Wednesday: Review More IR Mass spectroscopy Good web site for IR, Mass, NMR spectra: http://riodb01.ibase.aist.go.jp/sdbs/cgi-bin/cre_index.cgi?lang=eng
More informationSpectroscopy. Empirical Formula: Chemical Formula: Index of Hydrogen Deficiency (IHD)
Spectroscopy Empirical Formula: Chemical Formula: Index of Hydrogen Deficiency (IHD) A)From a structure: B)From a molecular formula, C c H h N n O o X x, Formula for saturated hydrocarbons: Subtract the
More informationAnswers to Problem Set #2
hem 242 Spring 2008 Answers to Problem Set #2 1. For this question we have been given the molecular formula, 3 5 l. Looking at the IR, the strong signal at 1720 cm 1 tells us that we have a carbonyl (we
More informationCHM 233 : Fall 2018 Quiz #9 - Answer Key
HM 233 : Fall 2018 Quiz #9 - Answer Key Question 1 M25c How many different signals would you expect to see in a proton-decoupled carbon nmr spectrum of the following compound? A 3 B 4 6 D 8 3 1 2 carbons
More information10-1 You might start this exercise by drawing all of the isomers of C7H16 of which there are nine:
Copyright 2010 James K Whitesell 10-1 You might start this exercise by drawing all of the isomers of C7H16 of which there are nine: Pick one with both secondary and tertiary carbon atoms and simply add
More informationMOP. Mechanism? Objectives. Energy hill for dehydrohalogenation. Last lecture. LQ#1) A) Draw the MOP B) Name MOP
0% 0% 0% 0% 1. 2.. 4. 2-bromo-,-dimethylpentane strong base salt dissolved in corresponding conjugate acid Given these conditions, select the mechanism that leads to the MP. Sodium isopropoxide Mechanism?
More informationChapter 13: Molecular Spectroscopy
Chapter 13: Molecular Spectroscopy Electromagnetic Radiation E = hν h = Planck s Constant (6.63 x 10-34 J. s) ν = frequency (s -1 ) c = νλ λ = wavelength (nm) Energy is proportional to frequency Spectrum
More informationChapter 15 Lecture Outline
Organic Chemistry, First Edition Janice Gorzynski Smith University of Hawaii Chapter 5 Lecture Outline Introduction to NMR Two common types of NMR spectroscopy are used to characterize organic structure:
More informationTo Do s. Read Chapter 3. Complete the end-of-chapter problems, 3-1, 3-3, 3-4, 3-6 and 3-7. Answer Keys are available in CHB204H
Read Chapter 3. To Do s Complete the end-of-chapter problems, 3-1, 3-3, 3-4, 3-6 and 3-7 Answer Keys are available in CB204 NMR Chemical Shifts Further Discussion A set of spectral data is reported when
More informationCHE 230 Organic Chemistry Exam 4, May 4, 2000
CE 230 rganic Chemistry Exam 4, May 4, 2000 Name Student ID No. Before you begin this exam : First: You are allowed to have a calculator and a simple model set at your seat. Please put away all other materials.
More information(2) After dissolving a solid in a solvent at high temperature, the solution is not filtered.
Name Key 216 W13-Exam No. 1 Page 2 I. (10 points) The goal of recrystallization is to obtain purified material with a maximized recovery. For each of the following cases, indicate as to which of the two
More informationSometimes the DEPT function stops working or the undergraduate NMRs at your University don't have the DEPT option. This is the situation here.
) Calculate the degree of unsaturation for the formula (C9H2) ( pt) H-NMR NMR (Show structure fragment work in spectrum) (2 pts) 2H 8H 3 2 3 C-NMR (Show structure fragments work in spectrum) (2 pts). Sometimes
More informationCH Exam #4 (Take Home) Date Due: 11/25,26/2013
CH2710 - Exam #4 (Take Home) Date Due: 11/25,26/2013 Section I - Multiple Choice - Choose the BEST answer from the choices given and place the letter of you choice in the space provided. 1. Energy absorbed
More informationYour Name: Question 1. 2D-NMR: C 6 H 10 O 2. (20 points)
Question 1. 2D-NMR: C 6 H 10 O 2. (20 points) Integrations show signals 3H 1 & 5, 2H for signal 4, and 1H each for signals 2 and 3. - Draw the structure. - Assign the hydrogens to signals 1 5 (that is,
More informationFaculty of Science Mid-Term Examination I. Chem 222/234 Introductory Organic Chemistry I
Student Name: Student ID #: Faculty of Science Mid-Term Examination I Chem 222/234 Introductory rganic Chemistry I Examiner: Professor James L. Gleason Tuesday, ctober 6, 2009 Associate Examiner: Professor
More informationChem 14C Lecture 1 Spring 2016 Exam 2 Solutions Page 1
Chem 14C Lecture 1 Spring 2016 Exam 2 Solutions Page 1 Statistics: High score, average, and low score will be posted on the course web site after exam grading is complete. Some questions have more than
More informationQualitative Analysis of Unknown Compounds
Qualitative Analysis of Unknown Compounds 1. Infrared Spectroscopy Identification of functional groups in the unknown All functional groups are fair game (but no anhydride or acid halides, no alkenes or
More informationClosed book exam, no books, notebooks, notes, etc. allowed. However, calculators, rulers, and molecular model sets are permitted.
Massachusetts Institute of Technology Organic Chemistry 5.13 Friday, September 26, 2003 Prof. Timothy F. Jamison Hour Exam #1 Name (please both print and sign your name) Official Recitation Instructor
More informationIn a solution, there are thousands of atoms generating magnetic fields, all in random directions.
Nuclear Magnetic Resonance Spectroscopy: Purpose: onnectivity, Map of - framework Process: In nuclear magnetic resonance spectroscopy, we are studying nuclei. onsider this circle to represent a nucleus
More information