CHEM 241 ALKYNES CHAP 9 ASSIGN
|
|
- Karen Cain
- 5 years ago
- Views:
Transcription
1 HEM 241 ALKYNES HAP 9 ASSIGN 1. What is the IUPA name of the following compound A. 5-propyl-3-heptyne B. 5-isopropyl-3-heptyne. 5-ethyl-3-octyne D. 4-ethyl-5-octyne 2. What is the correct IUPA name for the following molecule A. (Z )-3-Methyl-3-penten-1-yn-5-ol B. (E )-3-Methyl-3-penten-1-yn-5-ol. (E )-3-Methyl-2-penten-4-yn-1-ol D. (Z )-3-Methyl-2-penten-4-yn-1-ol E. (E )-4-Hydroxymethyl-3-methyl-3-penten-1-yne 3. Which of the following gives only one organic product on ozonolysis A. 2-hexyne B. 3-hexyne. 2-heptyne D. 3-heptyne 4. Predict the major product(s) in the reactions below. A. 1-nonyne B. 2-nonyne. cis-2-nonene D. trans-2-nonene 5. Which one of the following alkynes gives a single ketone in the acid-catalyzed hydration of each A. 2-decyne B. 3-decyne. 4-decyne D. 5-decyne 6. Which sequence of reactions works best in synthesizing cis-3-nonene 7. Which sequence of reactions below works best in carrying out the following conversion A. (1) HBr (2) excess NaNH 2 B. (1) Br 2 (2) excess NaNH 2. (1) Br 2, H 2 (2) excess NaNH 2 D. (1) H 2, H 2S 4(cat.) (2) excess NaNH 2 8. Which of the following is the correct IUPA name of the product for the reaction shown below A. cis-2-methyl-5-heptene B. trans-2-methyl-5-heptene. cis-6-methyl-2-heptene D. trans-6-methyl-2-heptene 9. When alkynes are treated with sodium metal, Na, in liquid ammonia, sodium acts as a A. Brønsted acid. B. Brønsted base.. reducing agent. D. catalyst. 1 P a g e
2 10. What is the product of the following reaction sequence A. 1-hexanol B. 2-hexanol. 1,2-hexanediol D. 1-hexene 11. What is the greatest number of atoms that you would expect to be co-linear in the molecule shown below A. five B. six. seven D. eight E. nine 12. What reagents are required to effect the following conversion A. Mg, ether B. H 3H 2- Na+. NaNH 2 (1 equiv.) D. NaNH 2 (2 equiv.) E. NaNH 2 (3 equiv.) 13. Select the best reaction sequence to make the following ketone. A. (1) propyne, NaNH 2 B. (1) acetylene, NaNH 2 (2) 1-bromobutane (2) 1-bromopentane (3) H 2, Hg 2+, H 2S 4 (3) H 2, Hg 2+, H 2S 4. (1) hexyne, NaNH 2 D. (1) 1-pentyne, NaNH 2 (2) bromomethane (2) bromoethane (3) H 2, Hg 2+, H 2S 4 (3) H 2, Hg 2+, H 2S How would you carry out the following conversion A. (1) H 2/Lindlar Pd (2) HBr B. (1) H 2/Lindlar Pd (2) HBr, peroxides. (1) HBr (1 eq) (2) H 2/Pd D. (1) Br 2 (1eq) (2) H 2/Pd 15. What is the major product of the reaction shown below A. 1,1-dichlorobutane B. 1,2-dichlorobutane. 2,2-dichlorobutane D. 1,12,2-tetrachlorobutane 16. Why can't methanol, H 3H, be used as a solvent for sodium amide, NaNH 2 A. Sodium amide is nonpolar and methanol is polar. B. Sodium amide is polar and methanol is nonpolar.. Sodium amide does an acid-base reaction with methanol. D. There would be no ion-dipole attractive forces between the two compounds. 2 P a g e
3 17. zonolysis of an alkyne gave the two compounds shown below. What is the IUPA name of the original alkyne A. 2,2-dimethyl-3-octyne B. 3,3-dimethyl-4-octyne. 2,2-dimethyl-3-heptyne D. 6,6-dimethyl-3-heptyne H 3H 2H 2 2H and (H 3) 3 2H 18. Which of the following ketones cannot be made by the acid-catalyzed hydration of an alkyne 19. Predict the product of the following reaction. A. 1-bromo-1-chlorocyclopentane. 1-bromocyclopentene B. 1-bromo-2-chlorocyclopentane D. cyclopentene 20. What is the only correct statement about cyclohexyne A. It is acidic. B. It has four 109 bond angles.. It is planar. D. It is too strained to be synthesized. 21. How many organic products do you expect from this reaction A. one B. two. three D. four H 3 H 2 cat. H 2 S 4 cat. HgS What major product results from this reaction A B 3 H 2 2 H 2 H D 23. The product of this reaction would be A. only (S) B. only (R). (R) + (S) D. achiral H H 3 H H 2 Pt only (S) 3 P a g e
4 24. The product of this reaction would be A. only (S) B. only (R). (R) + (S) D. achiral 25. How many carbons lie in a straight line in 2-methyl-3-hexyne A. 2 B D The name of the following compound is: H 3H(H 2H 3)H 2 (H 3) 3 A. 6-ethyl-2,2-dimethyl-3-heptyne B. 2,2,6-trimethyl-3-octyne. tert-butylisopropylacetylene D. 2,6-dimethyl-3-heptyne 27. The sequence of steps needed for the conversion of 1-butene to 1-butyne is A. HBr/peroxides; then alcoholic KH B. Hl/no peroxides: then NaNH 2/liquid NH 3. Br 2/l 4; then NaNH 2/liquid NH 3 D. KMn 4 cold; then H 2S 4/heat 28. Which is the correct order of decreasing basicity in the anions (most basic to least basic) H NH 2 H H 3H 2 H 2=H A B D E A. A > B > > D > E B. D > E > B > > A. > B > D > A > E D. D > E > > B > A 29. Which reagent can distinguish between 1-hexyne and 1-hexene A. KMn 4 B. H 2S 4. Br 2/l 4 D. AgN 3/NH 4H 30. The sequence of reagents needed for the conversion of 1-bromopropane to propyne is A. alcoholic KH/heat; then Br 2/l 4; then NaNH 2/NH 3 B. (H 3) 3 - K + /heat; then HBr; then NaNH 2/NH 3. alcoholic KH/heat; then Br 2 /l 4; then H 2S 4 D. alcoholic KH, then H 2/Pt; then NaNH 2/NH Predict the major product of the following reaction. 4 P a g e
5 32. Identify compound Y. A. 2-bromobutane B. meso-2,3-dibromobutane. racemic (2R,3R) and (2S,3S)-2,3-dibromobutane D. 2,3-dibromo-2-butene NAME DATE ANSWER SHEET HEM 241 HAP 9 ASSIGN FALL P a g e
Chemistry 2321 OLD TEST QUESTIONS
hemistry 2321 Test No. 3 Professor M. Pomerantz LD TEST QUESTINS Select the best name for the compounds shown. 1. l 2 3 2 2-chloro-4-ethyl-5-heptyne 6-chloro-4-ethyl-2-heptyne 4-(2-chloropropyl)-2-hexyne
More informationChapter Name the following compounds: (a) 2,5-dimethyl-3-hexyne (b) 3,3-dimethyl-1-butyne (c) 2,4-octadiene-6-yne (d) 3,3-dimethyl-4-octyne (e)
hapter 8 8.1 Name the following compounds: 3 3 3 3 2,5-dimethyl-3-hexyne 3 3 3 3,3-dimethyl-1-butyne (c) 3 3 2,4-octadiene-6-yne (d) 3 3 2 2 2 3 3 3,3-dimethyl-4-octyne (e) 3 3 3 2 3 3 2,5,5-trimethyl-3-heptyne
More information1. What is the letter designation given to dumbbell shaped orbitals like the one depicted below?
1. What is the letter designation given to dumbbell shaped orbitals like the one depicted below? 2. Which of the following does not have an octet of electrons surrounding the central atom? A. B 3 B. C
More informationChemistry 2541, Fall 2017 Midterm Exam 3 (100 points)
Important notes: Chemistry 2541, Fall 2017 Midterm Exam 3 (100 points) - Please use the provided Scantron form for your answers; you can keep the sheet with the questions and can use it as scratch paper
More informationCH320/328 M Spring 2014
CH320/328 M Spring 2014 HW Set #3 Multiple Choice Identify the choice that best completes the statement or answers the question. There is only one correct response for each question. Carefully record your
More informationChapter 9 Alkynes. Introduction
hapter 9 Alkynes Introduction Alkynes contain a triple bond. General formula is n 2n-2. Two elements of unsaturation for each triple bond. MST reactions are like alkenes: addition and oxidation. Some reactions
More informationChem 145 Unsaturated hydrocarbons Alkynes
Dr. Seham ALTERARY Chem 145 Unsaturated hydrocarbons Alkynes Chapter 4 1434-1435 2013-2014 2 st semester By the end of this chapter you should be familiar with: Definition for Alkynes. Nomenclature of
More informationCH Organic Chemistry I (Katz) Practice Exam #3- Fall 2013
C2710 - rganic Chemistry I (Katz) Practice Exam #3- all 2013 Name: Score: Part I - Choose the best answer and write the letter of your choice in the space provided. (32 pts) 1. f the following, which reaction
More information1.8. Organic Chemistry. Practice Exam Organic Chem. System LENGTH: VOLUME MASS Temperature. 1 gal = 4 qt. 1 lb = 16 oz.
rganic hemistry Practice Exam rganic hem Name (last) (First) Read all questions before you start. Show all work and explain your answers to receive full credit. Report all numerical answers to the proper
More informationH C C C C H C H C C H H. Cl H CH 3 O. Br CH 3 OH H 3 C. H Br H
CEMISTRY 313-61 MITERM # 3 answer key June 17, 2005 Statistics: Average: 69 pts (69%); ighest: 96 pts (96%); Lowest: 46 pts (46%) Number of students perfming at above average: 16 (53%) 1. (10 pts) Mark
More informationChapter 9 Alkynes. Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
Chapter 9 Alkynes Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display. 9.1 Sources of Alkynes Acetylene Industrial preparation of acetylene is by dehydrogenation of
More informationCHEM 2311 HW1. COMPLETELY FILL THE BOXES IN DARK PENCIL, i.e.:, NOT or or STRUCTURE
EM 2311 W1 Provide answers to the following multiple choice questions on the Scantron form provided in lecture. Make sure that you put your name and bubble in your GTID # on the answer form. MPLETELY FILL
More information3) Oxidation of tertiary alcohol yields A) Aldehyde B) No reaction C) Ketone D) Carboxylic acid
ALKYL HALIDES 18- The reaction of Propyl bromide with Na is A) Nucleophilic addition. B) Nucleophilic substitution. C) Electrophilic substitution. D) Electrophilic addition. 25) Which of the following
More informationH C C C C H C H C C H OH. Cl H CH 3. Br CH 3. H Br H OH H 3 C. CHEMISTRY MIDTERM # 3 June 17, Name...
Name... CEMISTRY 313-61 MIDTERM # 3 June 17, 2005 The total number of points in this midterm is 100. The total exam time is 90 min (1.5 h). Good luck! 1. (10 pts) Mark as true (T) false () the following
More information212 LSW ALKYNES S04. Alkynes
Alkynes Doubly unsaturated functional group Terminal alkynes, R-- 1) 2) 3) 4) Nomenclature: Functional group suffix = Disubstituted alkynes, R--R' Monosubstituted alkynes, R-- Stability: Substituted alkynes
More informationSECTION-I (SINGLE CORRECT CHOICE)
SECTI-I (SIGLE CRRECT CICE) 1. Which of the following phrases are not correctly associated with an S1 reaction? 1. Rearrangement is possible. 2. Rate is affected by solvent polarity. 3. The strength of
More informationST. JOSEPH S COLLEGE OF ARTS & SCIENCE (AUTONOMOUS) ST. JOSEPH S COLLEGE ROAD, CUDDALORE CH101T ORGANIC CHEMISTRY I (SEMESTER-I)
UNIT I 1. The hybridization involved in the formation of acetylene is a) sp b) sp 2 c) sp 3 d) sp 3 d 2. The IUPAC name of is 1. 3-hexene b) 4-hexene c) 3-hexyne d) 4-hexyne 3. -------- is the type of
More informationCHEM 2312 practice final. Version - II
EM 2312 practice final Version - II The following standardized final examination covers the entire introductory year of organic chemistry (EM 2311 and 2312 at Georgia Tech). The exam consists of 70 multiple
More informationStudy Union: CHM 2210 Final Exam Review 1. The following molecules are related in what manner?
Study Union: CHM 2210 Final Exam Review 1. The following molecules are related in what manner? A) They are isotopes B) They are constitutional isomers C) They are the same structure D) They are composed
More information1) (100 pts) 5) (20 pts) 3) (35 pts) 4) (25pts. Total (200 pts) More Tutorial at
Name: Perm number: Question 1) (100 pts) 2) (20 pts) 3) (35 pts) 4) (25pts 5) (20 pts) Total (200 pts) Your score 1. MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers
More informationtbuo OtBu Br 1) B 2 H 6 /THF OH 2) OH - + H 2 O 2 NaNH 2 NH3 Na NH 3 /-35 C CH 3 CCH 2 CHCH 3
EM 12A Name KEY EXAM II all 2003 1.(16 pts) Draw the structure of the major product expected from each of the following sets of reactants. Specify stereochemistry where appropriate. + 2 Pt + 2 2 2 + enantiomer
More informationmuch more stable then the
8.1 Give the structure and name of the product that would be obtained from the ionic addition of I to propene. I I I 8.3 Provide mechanistic explanations for the following observations:(a)the addition
More informationChapter 13 Unsaturated Hydrocarbons
hapter 1 1 hapter 1 Unsaturated ydrocarbons Solutions to In-hapter Problems 1.1 To draw a complete structure for each condensed structure, first draw in the multiple bonds. Then draw in all the other s
More informationChemistry 2541, Fall 2017 Midterm Exam 2 (100 points)
Chemistry 2541, Fall 2017 Midterm Exam 2 (100 points) Important notes: - Please use the provided Scantron form for your answers; you can keep the sheet with the questions and can use it as scratch paper
More informationChapter 13 Alkenes and Alkynes & Aromatic Compounds
Chapter 13 Alkenes and Alkynes & Aromatic Compounds Chapter Outline 13.1 Alkenes and Alkynes 13.2 Nomenclature of Alkenes and Alkynes 13.3 Cis Trans Isomers 13.4 Alkenes in Food and Medicine 13.6 Reactions
More informationCHE 275 REACTIONS OF ALKENES: ADDITION REACTIONS CHAP 8 ASSIGN
HE 275 REATINS F ALKENES: ADDITIN REATINS HAP 8 ASSIGN 1. Which reagent or test could be used to distinguish between 2-methyl-2-pentene and 2-methylpentane? A. Br 2/l 4 B. KMn 4,. oncd. H 2S 4 D. Two of
More informationStudy Union: CHM 2210 Final Exam Review 1. The following molecules are related in what manner?
Study Union: CHM 2210 Final Exam Review 1. The following molecules are related in what manner? A) They are isotopes B) They are constitutional isomers C) They are the same structure D) They are composed
More informationCHEM120 - ORGANIC CHEMISTRY WORK SHEET Answer the following questions with respect to compounds (A) and (B):
EM120 - RGANI EMISTRY WRK SEET 1 1. Answer the following questions with respect to compounds (A) and (B): (B) (A) 5 2 ( 3 ) 2 6 3 2 2 2 ( 3 ) 3 1 2 4 3 () 2 2 3 3 1 3 2 3 (a) Draw the bond-line notation
More informationOCH 3. 3-butyn-2-ol 3-hydroxy-1-butyne
Alkynes, Part I eading: Wade chapter 9, sections 9-1- 9-8 Study Problems: 9-29, 9-32, 9-36 Key oncepts and Skills: Explain why alkynes are more acidic than alkanes or alkenes; show how to generate nucleophilic
More informationName. Department of Chemistry SUNY/Oneonta. Chem Organic Chemistry I. Examination #3 - November 8, 2004 ANSWERS
Name Department of hemistry SUNY/neonta hem 221 - rganic hemistry I Examination #3 - November 8, 2004 ANSWERS INSTRUTINS --- This examination has two parts. The first part is in multiple choice format;
More informationUnit 14: Organic Chemistry REGENTS CHEMISTRY
REGENTS CHEMISTRY 1 Organic compounds contain carbon atoms which bond to one another in chains, rings, and networks to form a variety of structures. Organic compounds can be named using the IUPAC system.
More information% % Important Concepts. Problems. Problems C h a p t e r
Problems C h a p t e r 1 3 599 Important Concepts 1. The rules for naming alkynes are essentially the same as those formulated for alkenes. Molecules with both double and triple bonds are called alkenynes,
More informationTime Allowed: 60 minutes MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question.
INTRODUCTION TO ORGANIC AND BIOCHEMISTRY QUIZ 5 Time Allowed: 60 minutes MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question. 1) What is the IUPAC name
More informationDepartmental Final Examination. Organic Chemistry I Caffein
Departmental Final Examination rganic Chemistry I 2423 Caffein Name CEMISTRY 2423 FINAL EXAM FALL, 2005 DIRECTINS: A periodic table is attached at the end of this exam. Please answer all questions as completely
More informationChemistry Fall Semester 2007; Midterm 3 Exam
1 Chemistry 2521 Fall Semester 2007; Midterm 3 Exam December 7, Friday, 1:00 to 1:50 pm This exam has 7 problems (100 pts) on 9 pages. Make sure your copy is complete and correct. Printed Name (Last, First)
More informationUNIT (7) ORGANIC COMPOUNDS: HYDROCARBONS
UNIT (7) RGANI MPUNDS: YDRARBNS rganic chemistry is the study carbon containing compounds. 7.1 Bonding in rganic ompounds rganic compounds are made up of only a few elements and the bonding is almost entirely
More informationChemistry 51 Exam #3. Name KEY November 20, 2001
Chemistry 51 Exam #3 Name KEY November 20, 2001 This exam has nine (9) questions. Please check before beginning to make sure no questions are missing. All scratch work must be done on the attached blank
More informationPractice Packet Unit 11: Organic Chemistry
Regents Chemistry: Mr. Palermo Practice Packet Unit 11: Organic Chemistry www.mrpalermo.com 1 LESSON 1: Introduction to Organic Chemistry 1. How many times does carbon bond and why? 2. A student investigated
More informationChapter 12 Alkenes and Alkynes
BR M 102 lass Notes hapter 12 Page 1 of 8 hapter 12 Alkenes and Alkynes * alkenes = double bonds * alkynes triple bonds * aromatics or arenes alternating double and single bonds such as in benzene * saturated
More informationChemistry 2202 Unit 3 Test Section 1 &
Chemistry 2202 Unit 2 Test 2 Section 1 & 2 Page 1 of 6 Chemistry 2202 Unit 3 Test Section 1 & 2-2006 Part 1 Multiple Choice: Complete using the answer form on page 4. (20 points) 1. What is the main idea
More informationChapter 3 Alkenes and Alkynes. Excluded sections 3.15&3.16
Chapter 3 Alkenes and Alkynes Excluded sections 3.15&3.16 3.1 Definition and Classification Alkene: a hydrocarbon that contains one or more carboncarbon double bonds. ethylene is the simplest alkene. Alkyne:
More informationCHE 325 ORGANOMETALLIC COMPOUNDS CHAP 15 ASSIGN. , would be? CH 3 CHOCH 2 CH 2 OH CH 3 CHCH 2 CH 2 OH A B C D E
HE 325 RGNMETLLI MPUNDS HP 15 SSIGN 1. The final product, D, in the following reaction sequence, H 2 H 2 HH P 3 Mg ether B H 3 D, would be? HH 2 H 2 H HH 2 H 2 HH 2 H 2 H HH 2 HH 2 B D E 2. What is the
More informationCHEM 242 ORGANOMETALLIC COMPOUNDS CHAP 15 ASSIGN. , would be? CH 3 CHOCH 2 CH 2 OH CH 3 CHCH 2 CH 2 OH A B C D E
HEM 242 RGNMETLLI MPUNDS HP 15 SSIGN 1. The final product, D, in the following reaction sequence, H 2 H 2 HH P 3 Mg ether B H 3 D, would be? HH 2 H 2 H HH 2 H 2 HH 2 H 2 H HH 2 HH 2 B D E 2. What is the
More informationChemistry 210 Organic Chemistry I Winter Semester 2001 Dr. Rainer Glaser
hemistry 210 rganic hemistry I Winter Semester 2001 Dr. Rainer Glaser Examination #3 Alkenes and Alkynes. Structure, Synthesis and Reactions. Friday, April 20, 2001, 9:00-9:50 Name: Answer Key Question
More informationChem 1120 Midterm points Dr. Luther Giddings
Chem 1120 Midterm 1 100 points Dr. Luther Giddings Name Instructions: This is a closed book, closed notebook test. You may not discuss this exam with anyone, either during or after the exam, until it has
More informationChemistry 2321 OLD TEST QUESTIONS CH 3
Test No. 2 hemistry 2321 LD TEST QUESTNS Professor M. Pomerantz 1. n the following reaction the electrophile is: 3 3 + the group none of these 2. Given the reaction shown and the bond dissociation energies
More informationC h a p t e r T e n : Alkynes. Tazarotene, a synthetic acetylenic retinoid used to treat acne
C h a p t e r T e n : Alkynes N S Tazarotene, a synthetic acetylenic retinoid used to treat acne CHM 321: Summary of Important Concepts YConcepts for Chapter 10: Alkynes I. Structure and bonding A. sp-hybridization
More informationThis reactivity makes alkenes an important class of organic compounds because they can be used to synthesize a wide variety of other compounds.
This reactivity makes alkenes an important class of organic compounds because they can be used to synthesize a wide variety of other compounds. Mechanism for the addition of a hydrogen halide What happens
More informationCHEM120 - ORGANIC CHEMISTRY WORKSHEET 1
EM120 - RGANI EMISTRY WRKSEET 1 Some of the objectives To understand and know the hybridization concept Be able to distinguish different geometries, including basic bond lengths and angles within organic
More informationREACTION AND SYNTHESIS REVIEW
REACTION AND SYNTHESIS REVIEW A STUDENT SHOULD BE ABLE TO PREDICT PRODUCTS, IDENTIFY REACTANTS, GIVE REACTION CONDITIONS, PROPOSE SYNTHESES, AND PROPOSE MECHANISMS (AS LISTED BELOW). REVIEW THE MECHANISM
More informationName. Department of Chemistry SUNY/Oneonta. Chem Organic Chemistry I. Examination #3 - November 11, 2002 ANSWERS
Name INSTRUTINS Department of hemistry SUNY/neonta hem 221 - rganic hemistry I Examination #3 - November 11, 2002 ANSWERS This examination has two parts. The first part is in multiple choice format; the
More informationChemistry M11 Spring 2010 Examination #3 ANSWER KEY pp. 1
Chemistry M11 Spring 2010 Examination #3 ASWER KEY pp. 1 or Questions 1 2, consider the hydrogenation of trans-3-methyl-2-pentene in the presence of a transition metal catalyst. 1. C Determine the major
More informationCHAPTER HYDROCARBONS. Chapterwise Previous year Qs. (a) Na (b) HCl in H2O (c) KOH in C2H5OH (d) Zn in alcohol. Ans: (c)
122 CHAPTER HYDROCARBONS 1. Acetylenic hydrogens are acidic because [1989] Sigma electron density of C Hbond in acetylene is nearer to carbon, which has 50% s- character Acetylene has only open hydrogen
More informationCHAPTER 3 ALKENES, ALKYNES & CONJUGATE DIENES
CHEM 244 PRINCIPLES OF ORGANIC CHEMISTRY I FOR CHEMICAL ENGINEERING STUDENTS, COLLEGE OF ENGINEERING PRE-REQUISITES COURSE; CHEM 101 CREDIT HOURS; 2 (2+0) Dr. Mohamed El-Newehy Chemistry Department, College
More informationOrganic Chemistry. Carey/Giuliano 9th edition. Chapter 7
Organic Chemistry Carey/Giuliano 9th edition Chapter 7 Copyright 2014 The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Question 1 Which of the following compounds is chiral?
More informationOrganic Chemistry. Alkynes
For updated version, please click on http://ocw.ump.edu.my Organic Chemistry Alkynes by Dr. Seema Zareen & Dr. Izan Izwan Misnon Faculty Industrial Science & Technology seema@ump.edu.my & iezwan@ump.edu.my
More informationNomenclature of Organic Compounds Identification of Functional Groups
Hydrocarbons Nomenclature of Organic ompounds Identification of Functional Groups Alkanes - also known as saturated hydrocarbons or the paraffin series because all bond sites between carbon atoms and between
More informationFinal Exam Professor R. Hoenigman
I pledge to uphold the CU onor Code: CEM 3311-100 Spring 2007 Final Exam Professor R. oenigman Signature Name (printed) Last four digits of your student ID number Recitation TA Recitation number, day,
More informationBASIC NOMENCLATURE. The names of the groups you must be able to recognize and draw are:
A STUDENT SHOULD BE ABLE TO: BASIC NOMENCLATURE 1. Give examples of, and recognize when given the structure, representatives of the following classes of compounds. Alkyl halides (1, 2, 3 ) Alcohols (1,
More informationUnit 2 Review: Organic Chemistry. 1. Terms for which you should be able to write or apply the definitions:
Unit 2 Review: Organic Chemistry 1. Terms for which you should be able to write or apply the definitions: organic compound aliphatic hydrocarbons saturated miscible functional group aromatic hydrocarbons
More informationChemistry 234 (Organic I review) George A. O Doherty Please also refer to the Alkene Addition handout
Chemistry 234 (Organic I review) George A. O Doherty Please also refer to the Alkene Addition handout So far we have built upon our understanding of the questions I and II, which deal with the number of
More informationCHEM 242 ETHERS, EPOXIDES, AND SULFIDES CHAP 17 ASSIGN
CHEM 242 ETHERS, EPOXIDES, AND SULFIDES CHAP 17 ASSIGN 1. Which of the following is the correct name of the compound below? A) benzyl ethyl ether B) ethyl phenyl ether C) ethylbenzene ether D) ethoxy phenoxy
More informationAs time allows, additional practice questions for Exam 2 follow. This is an incomplete collection. Content & emphasis will vary.
Chem 226 Exam 2 Fall 2005: will cover Bruice, Chaps 3 through 6; Note: review e-mail & inclass quizzes and Worksheets, suggest on-line practice questions and quizzes plus ACS rganic Chemistry Guide As
More informationREVIEW PROBLEMS Key. 1. Draw a complete orbital picture for the molecule shown below. Is this molecule chiral? Explain. H H.
rganic hemistry II (E325) REVIEW PRBLEMS Key 1. Draw a complete orbital picture for the molecule shown below. Is this molecule chiral? Explain. 3 3 sp3 orbital p orbital sp2 orbital s orbital molecule
More informationCHAPTER 9. ALKYNES: AN INTRODUCTION TO ORGANIC SYNTHESIS
CAPTER 9. ALKYNES: AN INTRDUCTIN T RGANIC SYNTESIS Alkyne Nomenclature. Like alkenes, number so the alkyne gets the lowest number. Name the following two molecules: 3 C C CC 2 C 2 C(C 3 ) 2 Cl If, however,
More informationCH 3 CH 2 C=CCH 2 CH 3 CH 2 CH 2 OH
CHE 325 ALCOLS, DIOLS, AND THIOLS CHAP 15 ASSIGN 1. What is the correct IUPAC name for the following compound? CH 2 C=CCH 2 CH 2 CH 2 A. 3-methyl-4-ethyl-3-hexen-6-ol B. 4-ethyl-3-methyl-3,6-hexenol C.
More informationExam 2 Chem 109a Fall 2004
Exam 2 Chem 109a Fall 2004 Please put your name and perm number on both the exam and the scantron sheet. Next, answer the following 34 multiple-choice questions on the scantron sheet. Then choose one A-type
More informationPractice Multiple-Choice Questions for Ending Chem 21 and/or Starting Chem 22
Practice Multiple-Choice Questions for Ending Chem 21 and/or Starting Chem 22 Includes information from chapters 5-10 of the third edition of Klein s Organic Chemistry text. 1. Which of the following compounds
More informationChapter 15 Answers to Questions
Chapter 15 Answers to Questions 1. Structural formulas show all the covalent bonds between atoms. In condensed formulas, the lines depicting carbon-hydrogen bonds are removed. 2. Space-filling models provide
More informationChemistry 110. Bettelheim, Brown, Campbell & Farrell. Introduction to General, Organic and Biochemistry Chapter 12 Alkenes & Alkynes.
Chemistry 110 Bettelheim, Brown, Campbell & Farrell Ninth Edition Introduction to General, Organic and Biochemistry Chapter 12 Alkenes & Alkynes Chapter 12 Alkenes are hydrocarbons which have one or more
More informationChemistry 110 Bettelheim, Brown, Campbell & Farrell Ninth Edition Introduction to General, Organic and Biochemistry Chapter 12 Alkenes & Alkynes
Chemistry 110 Bettelheim, Brown, Campbell & Farrell Ninth Edition Introduction to General, Organic and Biochemistry Chapter 12 Alkenes & Alkynes Chapter 12 Alkenes are hydrocarbons which have one or more
More information3. (4 pts) Provide structures for the following compounds: CH 3 C H H C C - Na + acetylene 1-penten-4-yne (R)-3-butyn-2-ol sodium acetylide
CEMTRY 313-01 MDTERM # 3 answer key November 18, 2008 tatistics: Average: 74 pts (74%); ighest: 97 pts (97%); Lowest: 38 pts (38%) Number of students perfming at above average: 35 (56%) Number of students
More informationChapter 3. Alkenes And Alkynes
Chapter 3 Alkenes And Alkynes Alkenes ydrocarbons containing double bonds C C double bond the functional group center of reactivity Molecular Formula of Alkene Acyclic alkene: C n 2n Cyclic alkene: C n
More information350 Organic Chemistry I Winona State University
350 Organic Chemistry I Winona State University Exam #4B, December 9, 2013 Professor T. Nalli Name General Instructions: Write your name in the space provided above and on the provided Scan-tron form.
More informationCHEM Exam 2 ANSWER KEY
CEM 3311-200 Exam 2 ANSWER KEY ctober 23, 2012 Time: 2 ours Please copy and sign the onor Pledge on the scantron sheet in the space below the double lines. I pledge that n my honor, as a University of
More information1. Which statement is not true of nucleophillic substitution reactions?!
Mock Exam 3 CH 235-2F Ch. 7, 8, 9, and 11 Multiple Choice: 1. Which statement is not true of nucleophillic substitution reactions? a. SN1 proceeds through a cation intermediate. b. SN2 occurs with inversion
More information1. What are the respective hybridizations of the atoms numbered 1 to 4 in this compound?
EM 331: hapter 1/2: Structures (Atoms, Molecules, Bonding) 1. What are the respective hybridizations of the atoms numbered 1 to 4 in this compound? N 2 N 2 N 1 2 3 4 2. What hybrid orbitals are used to
More informationOrganic Chemistry. REACTIONS Grade 12 Physical Science Mrs KL Faling
Organic Chemistry REACTIONS Grade 12 Physical Science Mrs KL Faling SUBSTITUTION REACTIONS This is a reaction where an atom or group of atoms is replaced by another atom or group of atoms Substitution
More informationAlkane and Alkene Reactions
Name: Date: Pd: Alkane and Alkene Reactions 1. Give the structure (structural fmula and condensed structural fmula) of the maj ganic product of the following reactions. a. hexane and chline Reaction Type:
More informationsp 2 geometry tetrahedral trigonal planar linear ΔH C-C ΔH C-H % s character pk a 464 KJ/mol 33% 44
hapter 10: Alkynes 10.1 Introduction to Alkynes ~ 111 ~ 122 1.06 Å 180 1.1 Å ~ 116 1.08 Å 1.54 Å 1.34 Å 1.20 Å hybridization of sp 3 sp 2 sp geometry tetrahedral trigonal planar linear 368 KJ/mol 632 KJ/mol
More informationUnit 5: Organic Chemistry
Unit 5: Organic Chemistry Organic chemistry: discipline in chemistry focussing strictly on the study of hydrocarbons compounds made up of carbon & hydrogen Organic compounds can contain other elements
More informationChemistry 201. MW 12:00pm 1:15pm Examination #2 August 15 th Bronco ID. Question Score Possible Points. 1 (12pts) 2 (24pts) 3 (25pts)
Chemistry 201 MW 12:00pm 1:15pm Examination #2 August 15 th 2016 Name Bronco ID. Question Score Possible Points 1 (12pts) 2 (24pts) 3 (25pts) 4... (12pts) 5 (27pts). Total (100pts) 1. Read each question
More information7ALKENES AND ALKYNES I:
7ALKENES AND ALKYNES I: PROPERTIES AND SYNTESIS. ELIMINATION REATIONS OF ALKYL ALIDES SOLUTIONS TO PROBLEMS 7.1 (a) (E )-1-omo-1-chlo-1-pentene (E )-1-omo-1-chlopent-1-ene (E )-2-omo-1-chlo-1-iodo-1-butene
More informationC h a p t e r N i n e: Addition Reactions of Alkenes
C h a p t e r N i n e: Addition Reactions of Alkenes. H C 2 H Biosynthesis of a prostaglandin from arachidonic acid: intermediate intramolecular radical addition CHM 321: Summary of Important Concepts
More informationHYDROCARBON COMPOUNDS
YDROARBON OMPOUNDS hapter Quiz lassify each of these statements as always true, AT; sometimes true, ST; or never true, NT. 1. ydrocarbons are unsaturated. 22.2 2. The IUPA name for 3(2)33 is butane. 22.1
More informationFAMILIES of ORGANIC COMPOUNDS
1 SCH4U October 2016 Organic Chemistry Chemistry of compounds that contain carbon (except: CO, CO 2, HCN, CO 3 - ) Carbon is covalently bonded to another carbon, hydrogen and possibly to oxygen, a halogen
More informationAlkanes, Alkenes and Alkynes
Alkanes, Alkenes and Alkynes Hydrocarbons Hydrocarbons generally fall into 2 general groupings, aliphatic hydrocarbons and aromatic hydrocarbons. Aliphatic hydrocarbons contain chains and rings of hydrocarbons,
More informationQuímica Orgânica I. alkynes 2008/09. w3.ualg.pt\~abrigas QOI 0809 ALKYNE 1. w3.ualg.pt\~abrigas QOI 0809 ALKYNE 2
Química Orgânica I 2008/09 w3.ualg.pt\~abrigas QOI 0809 ALKYNE 1 alkynes w3.ualg.pt\~abrigas QOI 0809 ALKYNE 2 1 Name these: 3 propyne 3 2 2 Br 5-bromo-2-pentyne 5-bromopent-2-yne 3 3 3 2 3 2,6-dimethyl-3-heptyne
More informationCh08. Carbonyls. The carbonyl functional group. Exploring ketones, aldehydes and their reactions. version 1.0
Ch08 Carbonyls The carbonyl functional group. Exploring ketones, aldehydes and their reactions. version 1.0 Nick DeMello, PhD. 2007-2015 Important Dates This Wednesday: - Lab Checkout (you must check out
More informationHOMEWORK PROBLEMS: ALKYNES. 1. Provide the complete IUPAC name for the following compounds:
CEM 31 MEWRK PRBLEMS: ALKYNES 1. Provide the complete IUPAC name for the following compounds: 2. When the compound below is treated with one equivalent of B 3, where does it react Explain. Where would
More informationChemistry 210 Organic Chemistry I Fall Semester 2000 Dr. Rainer Glaser
Chemistry 210 Organic Chemistry I Fall Semester 2000 Dr. Rainer Glaser Examination #3 Alkenes and Alkynes. Structure, Synthesis and Reactions. Friday, November 17, 2000, 9:00-9:50 Name: Question 1. Alkenes
More information1. Name the following two compounds [8 pts]. Where it is important, points are explicitly allocated for stereochemistry.
1. Name the following two compounds [8 pts]. Where it is important, points are explicitly allocated for stereochemistry. 2. raw the structures of the following two compounds [8 pts]. cis-1-bromo-2,2-dimethyl-4-octene.
More informationOrganic Chemistry. M. R. Naimi-Jamal. Faculty of Chemistry Iran University of Science & Technology
Organic Chemistry M. R. Naimi-Jamal Faculty of Chemistry Iran University of Science & Technology Chapter 4-3: Continue Alkynes: An Introduction to Organic Synthesis Based on: McMurry s Organic Chemistry,
More informationHomework Problem Set 9 Iverson CH320M/328M Due Friday, November 30
omework Problem Set 9 Iverson C0M/8M Due Friday, November 0 NAME (Print): SIGNATURE: Chemistry 0M/8M Dr. ent Iverson 9th omework November 9, 08 Please print the first three letters of your last name in
More informationIntroduction & Definitions Catalytic Hydrogenations Dissolving Metal Reduction Reduction by Addition of H- and H+ Oxidation of Alcohols Oxidation of
CEM 241- UNIT 4 xidation/reduction Reactions Redox chemistry 1 utline Introduction & Definitions Catalytic ydrogenations Dissolving Metal Reduction Reduction by Addition of - and + xidation of Alcohols
More informationChapter 8: Chemistry of Alkynes (C n H 2n-2 )
hapter 8: hemistry of Alkynes ( n 2n-2 ) Bonding & hybridization Both are sp-hybridized Bond angles = 180 o 1 σ + 2 π bonds Linear around lassification R R R' σ bond energy: 88 kcal/mol π bond energy:
More information1. True or false: In a molecule, carbon always forms bonds with four other elements. 5. An unsaturated hydrocarbon must contain a or bond.
APTER 20 Organic hemistry 1. True or false: In a molecule, carbon always forms bonds with four other elements. False 2. A triple bond involves sharing electrons. a. 2 b. 3 c. 4 d. 5 e. 6 e. 6 3. ydrocarbons
More informationUnsaturated hydrocarbons. Chapter 13
Unsaturated hydrocarbons Chapter 13 Unsaturated hydrocarbons Hydrocarbons which contain at least one C-C multiple (double or triple) bond. The multiple bond is a site for chemical reactions in these molecules.
More informationOH OH OH CH 2 CH 2 C(CH 3 ) 2 (a) CH 3 CHCH 2 CHCH(CH 3 ) 2. (b)
hem 226 Problem Set #8 Fundamentals of rganic hemistry, 4 th edition, John McMurry. hapter 8 1. Give IUPA names for the following alcohols. 2 2 ( 3 ) 2 3 2 ( 3 ) 2 Longest chain = 6 carbons:...hexanediol.
More informationCHE1502. Tutorial letter 203/1/2016. General Chemistry 1B. Semester 1. Department of Chemistry
E1502/203/1/2016 Tutorial letter 203/1/2016 General hemistry 1B E1502 Semester 1 Department of hemistry This tutorial letter contains the answers to the questions in assignment 3. FIRST SEMESTER: KEY T
More information