WACCM CCMI Simulations: Status and Analysis

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WACCM CCMI Simulations: Status and Analysis D. Kinnison, R. Garcia, A. Smith, D. Marsh, R. Neely, A. Conley, M. Mills, S. Tilmes, J-F Lamarque, A. Gettelman, & F. Vitt. (NCAR) 13 February 2014, WACCM Working Group Meeting, Boulder Colorado

Outline CCMI updates (over CMIP5) Status of CCMI Simulations Definition Completed Analysis Total column ozone (TOZ) and local ozone. Mean age-of-air Summarize / next step

CCMI Updates Since CMIP5 Updated chemical rate constants to JPL-2010. Additional organic halogens (no surrogates) were included 18 total. Include representation of very short lived (VSL) organic bromine. Included representation of Fluorine chemistry (F, HF, COF 2, COFCl). Additional tropospheric chemistry (Total of 164 Species and 450 reactions). Also creating a VSL mechanism for CCMI (Saiz-Lopez et al. 2012). Updated Heterogeneous Chemistry Module (Wegner et al., 2013). Update Wet (Neu) / Dry (land model) Deposition. New recommendation on future organic halogen evolution (WMO 2010). New Sulfate Surface Area Density (SAD) Time series (1960-2010). Improved representation of volcanic heating (R. Neely and A. Conley). Satellite output for SD simulations. Rate output now available (tagged to individual or sum of reactions).

CCMI Scenarios REFC1 (3-realizations) *** 1950-2010 Data Ocean QBO (nudged) TSMLT Mechanism (164 species, 459rxns) SV, Volcanic Heating and SAD for Chem. REFC1SD (2-simulations) *** 1975-2012 MERRA (50-hr nudging) QBO (internal to MERRA) TSMLT & MA (85 species; 287rxns) Mechanisms SV, Volcanic SAD for Chem. REFC2 (3-realizations) *** 1950-2100 *** RCP6.0 Interactive ocean QBO (nudged) MA Mechanism (14-tracers) SV, Volcanic Heating and SAD for Chem.

Total Column Ozone (REFC2; RCP6.0)

Comparison of CCMI Simulations: Global Annual TOZ SD simulations (MA vs TSMLT) differ by <5DU. SD Global obs (not shown) agree with SD results. FR FR simulations (MA vs TSMLT) differ by <5DU. REFC2 simulation returns to 1980 conditions at ~2050 (black line). Then flattens out after 2060? Offset of ~10DU between SD simulations and FR simulations.

Comparison to CMIP5 simulations: Gl Annual TOZ RCPs in Eyring et al., JGR, 2013 (below). SD Total obs change from 1960-2010 was ~16DU. RCP6.0 (models) returned to 1980 around 2060. FR RCP 6.0 in CCMI WACCM (above). FR WACCM TOZ change from 1960-2010 was ~15DU. FR WACCM RCP6.0 returned to 1980 around 2050.

GHG (RCP6.0), Chlorine, & Bromine LBC GHG, Colder T, more O 3 GHG, warmer T, CH 4 +Cl => HCl less O 3 GHG, Colder T, more O 3 Higher NOx less O 3 VSL included, Higher than CMIP5, Less O 3 It will be interesting to compare the CCMI WACCM to the CMIP5 WACCM. Declining ClOY, more O 3 Declining BrOY, more O 3 NOTE: The CMIP5 WACCM didn t run RCP6.0 and didn t have the extra VSL halogens.

Comparison of CCMI Simulations: Annual 25S-25N CMIP5 models and observations in Eyring et al., JGR, 2013 (below). No trend in total obs TOZ. Absolute Magnitude 265-270 DU. Thin red line is CESM (WACCM), Marsh et al., 2013. CCMI WACCM (above). FR WACCM has a small trend in total TOZ. The absolute magnitude is underestimate (~10DU) SD-WACCM agrees with observations in the tropics.

Comparison of CCMI Simulations: March 60N-90N CMIP5 models and observations in Eyring et al., JGR, 2013 (below). Total obs change from 1960-2010 was ~125DU (min/max). Thin red line is CESM (WACCM), Marsh et al., 2013. CCMI WACCM (above). FR WACCM total change from 1960-2010 was ~60DU (min/max). SD-WACCM doesn t get the observed minimum. MERRA T-bias of ~2K was noted in Brakebusch et al., 2013. More work is need here.

Comparison of CCMI Simulations: Oct 90S-60S CMIP5 models and observations in Eyring et al., JGR, 2013 (below). Total obs change from 1960-2010 was ~160DU. Thin red line is CESM (WACCM), Marsh et al., 2013. CCMI WACCM (above). FR WACCM total change from 1960-2010 was ~150DU. Good agreement with obs (see Garcia talk for more details). Note: Small difference is SD simulations between MA and TSMLT mechanisms.

October CESM1 (WACCM) Versions Ozonesondes, Solomon et al., 2005 Comments: The model results are taken from monthly mean output. For REFC1SD, one should look at daily output for each Ozonesonde. The minimum in O 3 density at ~70-80 hpa and the peak at ~20hpa is represented by both CCMI REFC1SD and REFC2. The vertical structure for CMIP5 is different in these regions. The maximum O 3 density at ~200hPa is represented by all three model versions. Overall, the CCMI simulation does a nice job of representing the O 3 density profile at South Pole Station.

Annual Average Mean AOA: 25S-25N SD has a similar trend compared to FR versions; absolute values are ~0.5 years older in SD.

Change in Annual Mean AOA (20 Year Climatology) REFC1.002 REFC1SD.002 4. 0 4. 5 3.5 4. 0 SD-FR 0.3 0.4-0.3 0.6

Change in Annual Mean Ozone (20 Year Climatology) REFC1 (TSMLT) SD - FR (molecules cm -3 ) Positive O 3 differences where SD-FR mean age is positive.

Conclusion Completed 3 realizations of both CCMI REFC1 and REFC2 simulations. Completed 2 SD-WACCM / MERRA simulations with two different chemical mechanisms (TSMLT, MA). Paper will be written on these sims. Preliminary examination of TOZ, Mean AOA, and Local Ozone. SD simulations grade out the highest; FR simulations have improved over CMIP5 in the polar regions (Garcia pres.). Has a global low bias in TOZ. Mean AOA is ~0.5 year younger than SD.

Future Work Additional Simulations: REFC2 MA, RCP8.5? (3-realizations) REFC2 MA, CMIP5 WACCM RCP6.0 (1-realization). REFC1 MA, (3-realizations) Have completed the REFC1 TSMLT sims. CCMI meeting: May 2014. Eventual release to community.

Thank you for your attention! Photo taken from GV by Pavel Romashkin (near Guam)