Democritus thought atoms were indivisible & indestructible Lacked experimental support 4 th century B.C.

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Transcription:

Chapter 5

Democritus thought atoms were indivisible & indestructible Lacked experimental support 4 th century B.C.

Democritus thought atoms were indivisible & indestructible Lacked experimental support 4 th century B.C.

John Dalton (1766-1844) Dalton s Atomic Theory All elements composed of tiny, indivisible atoms Atoms of same element are identical. Atoms of 1 element are different from another element

Dalton s Atomic Theory (cont) Atoms of different elements can either physically mix or chemically combine in simple, whole number ratios to form compounds

Dalton s Atomic Theory (cont) Chemical Reactions occur when atoms are separated, joined or rearranged. Atoms of 1 element cannot change into another element by a chemical reaction.

Dalton s Theory Was tested experimentally Dalton formulated a hypotheses to explain his observations

Dalton s Theory is mostly accepted today Except that we now know atoms CAN be divided - into subatomic particles

JJ Thompson (1856-1940) discovered electrons using a cathode ray tube passed electric current through gases at low pressure

He sealed the gases in a tube fitted at both ends with electrodes (metal disks) Connected to source of high voltage electricity

Anode became positively charged Cathode became negatively charged

A glowing beam formed between the 2 electrodes Called the cathode ray

The cathode ray is attracted to metal plates that have a positive charge Negatively charged plates repelled the ray

Thompson knew like charges repel and opposite charges attract

The ray must be negatively charged particles moving at a high speed He called these particles electrons

Every gas did the same thing so every element must have electrons

JJ Thomson s model of the atom is called the plumpudding model the electrons were randomly placed throughout the atom

Robert Millikan (1868-1953) found quantity of charge in 1 electron (e - ) Also determined the ratio of the charge to the mass of 1 e - calculated the mass of 1 e -

Ernest Rutherford discovered the nucleus He had a thin piece of gold foil & bombarded it with alpha particles (helium nucleus) Most particles passed through the foil like he expected Some were deflected slightly

Other particles bounced back at him! He was as surprised as if he had sent a bowling ball at a tissue and it came back to hit him He figured that there must be a dense positive part of the atom, but most of the atom is empty space http://video.google.com/videosearch?q=rutherford%20experiment&um=1& ie=utf-8&sa=n&tab=wv#

Bohr proposed that electrons have a fixed energy and move in energy levels around the nucleus which is why they don t fall into the nucleus

The energy levels are like the rungs of a ladder electrons cannot be in between levels, and need a specific amount of energy to move from one to another

We haven t always known what the atom looked like There have been many different models throughout the past few hundred years

Dalton thought atoms were solid and indivisible JJ Thomson discovered the electron, & made the plumpudding model

Rutherford discovered the nucleus Bohr proposed electrons in orbitals around nucleus

Nucleus: massive center of the atom, holds the protons and neutrons Proton: positively charged particle

Neutron: nuclear particle, has NO charge! Electron: orbits the nucleus, negatively charged

Energy Level: where an electron can be found (e - orbital, e - shell) Ion: an atom with a charge, more or less e - than a neutral atom

Atomic Number: # of protons Mass Number: # of protons plus number of neutrons Isotope: atom with more or less neutrons than normal

A neutral atom will have the same number of electrons as it does protons

Atomic Mass: the weighted average of all the isotopes of an element

To find the number of neutrons: round the atomic mass to the nearest whole number, then subtract the # of protons