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Europass Curriculum Vitae Personal information First name(s) / Surname(s) Barbara Chiavarino Address(es) Dipartimento di Chimica e Tecnologie del Farmaco, Università di Roma La Sapienza, P.le A. Moro 5, I-00185 Roma, Italy Telephone(s) (+) 39 (0)6 49913634 Mobile: Fax(es) (+) 39 (0)6 49913602 E-mail barbara.chiavarino@uniroma1.it Nationality Italian Date of birth 1967 Gender Female Occupational field research associate in General and Inorganic Chemistry (03/B1) Work experience Dates 1998- Occupation or position held research associate Main activities and responsibilities Scientific research, teaching Name and address of employer Università degli Studi di Roma La Sapienza Sector Inorganic Chemistry Dates 1996 Occupation or position held Grant in Chemistry Science of the Italian National Research Council Main activities and responsibilities Name and address of employer Sector Scientific research Università degli Studi di Roma La Sapienza and the Italian National Research Council Inorganic Chemistry Education and training Dates 1992-1996 Page 1/5 - Curriculum vitae of

Title of qualification awarded PhD in Pharmaceuticals Science at the University La Sapienza of Rome 1992 graduated in Chimica e Tecnologia Farmaceutiche at the University La Sapienza of Rome, with the result of 110/110, with an experimental thesis under the supervision of Professor Prof. Pierluigi Giacomello. 1986 Education Liceo Scientifico S. Cannizzaro in Rome. the University La Sapienza of Rome Dates 1986-1992 Title of qualification awarded She graduated in Chimica e Tecnologia Farmaceutiche with the result of 110/110, with an experimental thesis under the supervision of Professor Prof. Pierluigi Giacomello. the University La Sapienza of Rome Dates 1981-1986 Title of qualification awarded scientific high-school Liceo Scientifico S. Cannizzaro in Rome. Personal skills and competences - Intermolecular interactions (ion-ligand interactions, hydrogen bonds, ion-pi interactions, molecular recognition of biological molecules) - Ionic complexes and ion-molecule reactions - Chemical reaction mechanisms (e.g., proton transfer, substitution reactions, catalytic processes) - Infrared spectroscopy of molecular ions - Mass spectrometry Mother tongue(s) Italian Other language(s) French, English Self-assessment Understanding Speaking Writing European level (*) Listening Reading Spoken interaction Spoken production Franch C2 C2 C2 C2 C1 English B1 B2 B1 B2 B2 (*) Common European Framework of Reference for Languages Additional information - She serves as reviewer for some scientific journals such as Journal of Pyhysical Chemistry, Journal of Mass Spectrometry. Receiving Annexes Wednesday from 10.30 a.m. to 12.30 a.m. List any items attached. Page 2/5 - Curriculum vitae of

Scientific Publication 1. Lanucara, F.; Chiavarino, B.; Crestoni, M. E.; Scuderi, D.; Sinha, R. K.; Maitre, P.; Fornarini, S Naked Five-Coordinate FeIII(NO) Porphyrin Complexes: Vibrational and Reactivity Features. Inorg. Chem. (2011), 50, 4445-4452. 2. Coletti, C.; Re, N.; Scuderi, D.; Maître, P.; Chiavarino, B.; Fornarini, S.; Lanucara, F.; Sinha, R. K.; Crestoni, M. E. IRMPD spectroscopy of gaseous protonated S-nitrosocaptopril, a biologically active, synthetic amino acid. Physical Chemistry Chemical Physics, (2010), 12, 13455-13467 3. Sinha, R. K.; Maître, P.; Piccirillo, S.; Chiavarino, B.; Crestoni, M. E.; Fornarini, S. Cysteine radical cation: a distonic structure probed by gas phase IR spectroscopy Physical Chemistry Chemical Physics, (2010), 12, 9794-9800 4. Chiavarino, B.; Crestoni, M. E.; Fornarini, S.; Lanucara, F.; Lemaire, J.; Maitre, P.; Scuderi, D. Molecular complexes of simple anions with electron-deficient arenes: spectroscopic evidence for two types of structural motifs for bare anion-arene interactions Chemistry European Journal (2009), 15, 8185-8195 5. Chiavarino, B.; Crestoni, M. E.; Fornarini, S.; Lanucara, F.; Lemaire, J.; Maitre, P. Structure and mid-ir Spectroscopy of Protonated Carbonic Acid in the Gas Phase ChemPhysChem (2009), 10, 520-522 6. Chiavarino, B.; Crestoni, M. E.; Di Rienzo, B.; Fornarini, S.; Lanucara, F. Site-selectivity of Protonation in Gaseous Toluene Physical Chemistry Chemical Physics (2008), 10, 5507-5509 7. Chiavarino, B.; Crestoni, M. E.; Fornarini, S.; Rovira, C. Unravelling the Intrinsic Features of NO Binding to Iron(II)- and Iron(III)-hemes Inorganic Chemistry (2008) 47 (17), 7792-7801 8. Chiavarino, B.; Crestoni, M. E.; Fornarini, S.; Lanucara, F.; Lemaire, J.; Maitre, P.; Scuderi, D. Direct Probe of NO Vibration in the Naked Ferric Heme Nitrosyl Complex ChemPhysChem (2008) 9, 826-828 9. Chiavarino, B.; Cipollini, R.; Crestoni, M. E.; Fornarini, S.; Lanucara, F.; Lapi, A. Probing the Compound I-like Reactivity of a Bare High-Valent Oxo Iron Porphyrin Complex: the Oxidation of Tertiary Amines Journal of the American Chemical Society (2008) 130, 3208-321 10. Chiavarino, B.; Crestoni, M. E.; Fornarini, S.; Lanucara, F.; Lemaire, J.; Maitre, P.; Scuderi, D. Infrared Spectroscopy of Isolated Nucleotides. 1. The cyclic 3,5 -Adenosine Monophosphate Anion International Journal of Mass Spectrometry (2008) 270, 111-117 11. Chiavarino, B.; Crestoni, M. E.; Fornarini, S.; Lanucara, F.; Lemaire, J.; Maitre, P. Meisenheimer Complexes Positively Characterized as Stable Intermediates in the Gas Phase Angewandte Chemie International Edition (2007) 46, 1995-1998 12. Chiavarino, B.; Crestoni, M. E.; Fornarini, S.; Rovira, C. Protonated Heme Chemistry European Journal (2007) 13, 776-785 13. Chiavarino, B.; Crestoni, M. E.; Fornarini, S.; Lemaire, J.; Maitre, P.; Mac Aleese L. π-complex Structure of Gaseous Benzene-NO Cations Assayed by IR Multiple Photon Dissociation Spectroscopy Journal of the American Chemical Society (2006) 128, 12553-12561 14. Chiavarino, B; Crestoni, M. E.; Fornarini, S.; Dopfer, O.; Lemaire, J.; Maitre, P. IR Spectroscopic Features of Gaseous C7H7O + Ions: Benzylium versus Tropylium Ion Structures. Journal of Physical Chemistry A (2006), 110, 9352-9360. Page 3/5 - Curriculum vitae of

15. Dopfer, O.; Lemaire, J.; Maitre, P.; Chiavarino, B.; Crestoni, M. E.; Fornarini, S. IR spectroscopy of protonated toluene: Probing ring hydrogen shifts in gaseous arenium ions. International Journal of Mass Spectrometry (2006), 249/250 149-154. 16. Chiavarino, B.; Crestoni, M. E.; Fornarini, S.; Lemaire, J.; MacAleese, L.; Maitre, P. Infrared spectroscopy of protonated phenylsilane in the gas phase. ChemPhysChem (2005), 6, 437-440 17.Angelelli, F.; Chiavarino, B.; Crestoni, M. E.; Fornarini, S. Binding of Gaseous Fe(III)-Heme Cation to Model Biological Molecules: Direct Association and Ligand Transfer Reactions. Journal of the American Society for Mass Spectrometry (2005), 16, 589-598 18.Chiavarino, B.; Crestoni, M. E.; Fornarini, S.; Lemaire, J.; Maitre, P.; Mac Aleese L. Infrared Absorption Features of Gaseous Isopropyl Carbocations. ChemPhysChem (2004) 5, 1679-1685 19. Jones, W.; Boissel, P.; Chiavarino, B.; Crestoni, M. E.; Fornarini, S.; Lemaire, J.; Maitre, P. Infrared fingerprint of protonated benzene. Angewandte Chemie International Edition (2003), 42, 2057-2059 Angewandte Chemie (2003) 115, 2103-2105 20.Chiavarino, B.; Crestoni, M. E.; Fornarini, S.; Kuck, D. Cation-π Interactions in the Gas Phase Methylation of α,ω -Diphenylalkanes. Journal of Physical Chemistry A (2003), 107, 4619-4624. 21.Chiavarino, B.; Crestoni, M. E.; Fornarini, S. The Trimethylsilylation of Acetylene Chemical Communications (2002) 1418-1419 22. Chiavarino, B.; Crestoni, M. E.; Fornarini, S. Gas Phase Dioxygen Activation by Binuclear Manganese Clusters Chemistry European Journal (2002) 8, 2740-2746 23. Baiocchi, E.; Bietti, M.; Chiavarino, B.; Crestoni, M. E.; Fornarini, S. The Deprotonation of Benzyl Alcohol Radical Cations: a Mechanistic Dichotomy in the Gas Phase as in Solution. Chemistry European Journal (2002) 8, 532 24. Chiavarino, B.; Crestoni, M. E.; Andrey A. F.; Fornarini, S. The Protonation of Gaseous Cyclopropane Chemistry European Journal (2001) 7, 2916-2921 25. Cacace, F.; Chiavarino, B.; Crestoni, M. E. Fast interconversion of C4H7 + cations in the gas phase and in a gaseous microsolvated environment. Chemistry--A European Journal (2000), 6, 2024-2031. 26. Chiavarino, B.; Crestoni, M. E.; Fornarini, S. A Gas Phase Study of the Ionic Alkylation of Benzocycloalkenes Journal of the American Chemical Society (2000) 122, 5397 27. Chiavarino, B.; Crestoni, M. E.; Di Marzio, A.; Fornarini, S.; Rosi, M. Gas Phase Ion Chemistry of Borazine, an Inorganic Analogue of Benzene Journal of the American Chemical Society (1999) 121, 11204 28. Chiavarino, B.; Crestoni, M. E.; Fornarini, S. Electrophilic Substitution of Gaseous Borazine Journal of the American Chemical Society (1999) 121, 2619 29.Chiavarino, B.; Crestoni, M. E.; Di Rienzo, B.; Fornarini, S. Gas Phase H/D Exchange between Arenium Ions and Selected Bases. The Site of Protonation of Sim Aromatics Journal of the American Chemical Society (1998) 120, 10856-10862 Page 4/5 - Curriculum vitae of

30. Chiavarino, B.; Crestoni, M. E.; Fornarini, S. Radiolytic Silylation of Alkenes and Alkynes by Gaseous R3Si + Ions. Stereochemical Evidence for the β -Silyl Effect. Journal of the American Chemical Society (1998), 120, 1523-1527. Works Textbooks (Chapters, etc.) Page 5/5 - Curriculum vitae of