TABLE OF CONTENTS CHAPTER TITLE PAGE DECLARATION DEDICATION ACKNOWLEDGEMENT ABSTRACT ABSTRAK

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vii TABLE OF CONTENTS CHAPTER TITLE PAGE DECLARATION DEDICATION ACKNOWLEDGEMENT ABSTRACT ABSTRAK TABLE OF CONTENTS LIST OF TABLES LIST OF FIGURES LIST OF ABBREVIATIONS LIST OF SYMBOLS ii iii iv v vi vii ix xi xv xvi 1 INTRODUCTION 1 1.1 Background of Study 1 1.2 Overview 2 1.3 Problem Definition 5 1.4 Objectives 5 1.5 Scope of Work 6 2 LITERATURE REVIEW 7 2.1 Electronics Packaging 7 2.2 Flip Chip Ball Grid Array (FCBGA) 9 2.3 Solder Reflow Process 12 2.4 Lead-Free Solder Material 14 2.5 Solder Joint Reliability (SJR) 19

viii 2.6 Constitutive Model for Solder Material 20 2.7 Solder Joint Fatigue Model 33 2.8 Solder Ball Shear Test 36 2.9 Cohesive Zone Model (CZM) 39 3 RESEARCH METHODOLOGY 46 4 SOLDER JOINT INELASTIC BEHAVIOR 48 4.1 Material Constitutive Model for SAC405 48 4.2 Validation of Material Model 53 4.3 Examination of Model for Creep Loading 56 5 ASSESSMENT OF SOLDER JOINT RELIABILITY 59 SUBJECTED TO TEMPERATURE LOADING 5.1 Finite Element Model 59 5.2 Reflow Cooling Process 64 5.3 Cyclic Temperature Loading 69 5.4 Fatigue Life Prediction Model 74 6 COHESIVE ZONE MODEL FOR SOLDER/PAD 77 INTERFACE FAILURE PROCESS 6.1 Finite Element Model 77 6.2 Mechanics of Solder Ball during Shear Push Test 81 6.3 Determination of Cohesive Zone Model Parameters 83 6.4 Mechanics Behavior of Solder/Pad Interface 87 7 CONCLUSIONS & RECOMMENDATIONS 91 7.1 Conclusions 91 7.2 Recommendations 93 REFERENCES 94

ix LIST OF TABLES TABLE NO. TITLE PAGE 2.1 Lead-free classification reflow profile [19] 13 2.2 Lead-free process classification temperature (T c ) [19] 14 2.3 Examples of lead-free solder materials with melting 15 temperatures and fatigue resistances [21] 2.4 SAC405 material properties and data 16 2.5 Some examples of inelastic strain models 21 2.6 Ramberg-Osgood plasticity model parameters for lead-free 22 solder materials 2.7 Power law creep model parameters for lead-free solder 22 materials 2.8 Hyperbolic sine creep model parameters for lead-free solder 23 materials 2.9 Parameters for Anand model 24 2.10 Anand model parameters for lead-free solder materials (a) 30 2.11 Anand model parameters for lead-free solder materials (b) 31 2.12 Modified Anand model parameters for lead-free solder 32 materials 2.13 Polynomial equation parameters of published modified Anand 32 models 2.14 Lead-free solder material fatigue models 35 2.15 Solder ball failure mode [85] 37 2.16 Parameters of damage equation [104] 44 4.1 Parameters of SAC405 Anand Model 49 4.2 Polynomial equation parameters of modified Anand models 50 5.1 Material properties used in BGA assembly model 62

x 5.2 Dimensions of BGA assembly models and temperature cycle 63 load cases 5.3 Distributions of von Mises stresses and equivalent inelastic 71 strains of critical solder joint during the first temperature cycle, TC1 5.4 Solder material models of double power law creep [115] and 74 hyperbolic sine creep [40] 6.1 Material properties used in model of solder ball shear test 79 6.2 Parameters of CZM for solder joint interface brittle fracture 80 6.3 Distributions of von Mises stresses and equivalent inelastic 82 strains at the solder joint symmetry plane with progressive tool displacement 6.4 Progression of damage distribution at solder joint interface 90

xi LIST OF FIGURES FIGURE NO. TITLE PAGE 1.1 Intel CPU transistors double every ~ 18 months [5] 2 1.2 FSCSP electronics package [7] 3 1.3 Pin count trends [10] 4 1.4 Pitch trends [10] 4 2.1 The hierarchy of electronics packaging [16] 8 2.2 Ranges of pin counts and clock frequency for several types of 10 IC devices and SMT electronics packaging technologies [16] 2.3 Schematic of FCBGA assembly 10 2.4 FCBGA assembly process [17] 11 2.5 Reflow profile [19] 13 2.6 Sn-Ag-Cu ternary phase diagram [29] 16 2.7 SAC405 Young s modulus, E at various temperatures and 17 strain rates 2.8 SAC405 yield stress, σ y at various temperatures and strain rates 17 2.9 SAC405 tensile strength, UTS at various temperatures and 18 strain rates 2.10 SAC405 ductility at various temperatures and strain rates 18 2.11 Types of deformation (warpage) of electronics assemblies: 19 (a) Convex (Happy face) and (b) Concave (Sad face) 2.12 Crack growth process at the top region of SAC405 BGA solder 20 joint that subjected to cyclic temperature [37] 2.13 Experimental curves of stress versus strain at strain rate of 1 x 25 10-3 s -1 [35] 2.14 Experimental curves of stress versus strain at temperature of 25 C [35] 25

xii 2.15 Flow chart of determination of Anand model parameters 28 2.16 Examples of experimental data and Anand model curves of 29 stress versus inelastic strain at strain rate of 1 x 10-3 s -1 [35] 2.17 Examples of experimental data and Anand model curves of 29 stress vs inelastic strain at temperature of 25 0 C [35] 2.18 Typical hysteresis loop [81] 34 2.19 Experimental test of solder ball shear [85] 36 2.20 IMC thickness versus aging time [88] 38 2.21 Percentage of brittle failure of SAC405 solder ball shear test 38 for various shear tool speeds and aging times: (a) Specimen with ENIG surface finish and (b) Specimen with OSP surface finish [88] 2.22 Typical curves of force versus displacement for solder ball 39 shear test [11] 2.23 Strain softening constitutive models [105] 40 2.24 Bilinear constitutive model: (a) Double cantilever and 41 (b) Bilinear traction-separation model [105] 2.25 Traction-separation response 43 2.26 Fracture envelope for interface debonding 44 3.1 Overall research methodology 46 4.1 3D chart of Anand parameter, h 0 (MPa) value for range of 51 temperatures between 180 and 600 K and range of strain rates up to 0.01s -1 4.2 Contour chart of Anand parameter, h 0 (MPa) value for range of 51 temperatures between 180 to 600 K and range of strain rates up to 0.01s -1 4.3 Chart of Anand parameter, s 0 (MPa) value for range of 52 temperatures between 100K and 1000K 4.4 Effect of strain rates and test temperatures on saturation stress 53 level of SAC405 solder 4.5 Experimental and predicted stress-inelastic strain curves for SAC405 solder at strain rate of 10-3 s -1 and different test temperature levels 54

xiii 4.6 Experimental and predicted stress-inelastic strain curves for 54 SAC405 solder at test temperature of 423 K and different straining rates 4.7 Stress versus inelastic strain at strain rate of 1 x 10-4 s -1 and 55 several temperatures 4.8 Stress versus inelastic strain at temperature of 348 K and 56 several strain rates 4.9 Curve of inelastic strain versus time at temperature of 343 K 57 and constant stress of 14.7 MPa 4.10 Chart of strain rate versus steady-state stress. Data obtained 57 from modified Anand model simulation and equation while experimental data obtained from [115]. Six different specimens are named as s1, s2, s3, s4, s5 and s6 5.1 Exploded view of the geometry and dimensions of the quarter 60 assembly 5.2 FE model of quarter BGA assembly. Inset figure shows the 61 refined FE mesh of the critical solder joint 5.3 Temperature profile 62 5.4 25 micron-thick mesh for solder mask defined interface (dark 63 region) 5.5 Z-axis deformation of 3D test assembly after reflow process 64 5.6 Z-axis deformation of silicon die, substrate and PCB along the 65 diagonal plane 5.7 Location of critical solder joint (D4) 66 5.8 Stress distribution in a single row of solder joints for the 66 diagonal plane (45 degree) with deformation scale factor of 20 5.9 Evolution of von Mises stress and equivalent inelastic strain in 67 the critical SAC405 solder throughout the solder reflow cooling 5.10 von Mises stress distribution in the critical solder joint at 25 0 C following the solder reflow cooling process. Inset figure shows the distribution of full critical solder joint 68

xiv 5.11 Equivalent inelastic strain distribution in the critical solder 69 joint at 25 o C following the solder reflow cooling process. Inset figure shows the distribution of full critical solder joint 5.12 Evolution of von Mises stress and equivalent inelastic strain 70 during the first two temperature cycles, TC1 5.13 Cartesian stress-strain components at critical location for the 72 first three temperature cycles 5.14 Hysteresis loop for equivalent (von Mises) stress-equivalent 73 strain for the first temperature cycle with dwell time 5.15 Fatigue lives versus calculated values of accumulated inelastic 76 strain and plastic work density for different prescribed solder constitutive behavior 6.1 FE model of half solder ball shear test 78 6.2 Two examples of mesh densities at solder joint interface: 79 (a) Fine Mesh Density and (b) Course Mesh Density 6.3 Curves of solder joint interface mechanics behavior 81 6.4 Mesh sensitivity study at solder joint interface cohesive 83 element 6.5 FE predicted curves of force versus displacement of shear tool 84 6.6 Comparison of shear energies between the experimental data 85 [11,88] and FE results with tensile strengths of 810 MPa, 830 MPa and 850 MPa 6.7 Comparison of shear forces between the experimental data 86 [11,88] and FE results with tensile strengths of 810 MPa, 830 MPa and 850 MPa 6.8 Distribution of normal stress, S n at the solder/pad interface 87 plane during the onset of fracture 6.9 Evolution of tensile stress, S n, resultant shear stress, S s and 88 damage, φ at the critical location 6.10 Loading path at the critical location 88 6.11 Curve of percentage of fracture area versus time 89

xv LIST OF ABBREVIATIONS BGA - Ball Grid Array BK - Benzeggagh-Kenane C4 - Controlled Collapse Chip Connection CTE - Coefficient thermal expansion CZM - Cohesive zone model ENIG - Electroless Nickel Immersion Gold FC - Flip-Chip FCBGA - Flip Chip Ball Grid Array FE - Finite element FSCSP - Folded Stacked Chip Scale Package IC - Integrated circuit IMC - Intermetallics compound NSMD - Non-solder mask defined OSP - Organic Solderability Perservative PBGA - Plastic Ball Grid Array PCB - Printed circuit board PDA - Personal digital assistant PGA - Pin Grid Array PTH - Plated Through Hole SAC - Sn-Ag-Cu SAC405 - Sn4.0Ag0.5Cu SJR - Solder joint reliability SMT - Surface Mount Technology SMD - Solder mask defined

xvi LIST OF SYMBOLS E - Young s modulus N f - Number of cycle to failure UTS - Tensile strength σ y - Yield stress v - Poisson s ratio T L - Liquidus melting temperature T S - Solidus melting temperature ε T - Total strain ε e - Elastic strain ε in - Total inelastic strain ε p - Time-independent plastic strain ε Cr - Time-dependent creep strain ε vp - Time-dependent visco-plastic strain ε& p - Inelastic strain rate σ - Stress T - Temperature s - Anand model internal variable s 0 - Anand model initial value of internal variable Q/R - Anand model activation energy A - Anand model pre-exponential factor ξ - Anand model stress multiplier m - Anand model strain rate sensitivity of stress h 0 - Anand model hardening coefficient ŝ - Anand model coefficient for deformation resistance saturation. value n - Anand model strain rate sensitivity of saturation value

xvii a - Anand model strain rate sensitivity of hardening coefficient s* - Anand model saturation value of internal variable G & i - Parameters of strain-based fatigue model H & j - Parameters of energy-based fatigue model ε in,acc - Acumulated inelastic strain per cycle W in,acc - Acumulated plastic work density per cycle σ - Total stress range ε - Total strain range ε e - Total elastic strain range ε p - Total inelastic strain range δ - Separation δ F - Separation at failure δ pp - Separation at failure for perfectly plastic criterion δ pro - Separation at failure for progressive softening criterion δ lin - Separation at failure for linear softening criterion δ Ne - Separation at failure for Needleman criterion δ reg - Separation at failure for regressive softening criterion G C - Critical fracture energy δ e - Elastic extension P - Force L - Thickness R - Area σ C - Material strength K p - Stiffness δ 0 - Separation at damage initiation D - Damage S n - Cohesive element normal stress S s1 - Cohesive element shear stress at direction-1 S s2 - Cohesive element shear stress at direction-2 0 S n 0 S s1 0 S s2 - Cohesive element tensile strength - Cohesive element shear strength at direction-1 - Cohesive element shear strength at direction-2 C - Failure envelope parameter G I - Mode I strain energy release rate

xviii G II - Mode II strain energy release rate G IC - Mode I critical strain energy release rate G IIC - Mode II critical strain energy release rate η - BK mixed-mode parameter S s - Cohesive element resultant shear stress K n - Cohesive element tensile modulus K s - Cohesive element shear modulus p - Quadratic coefficient of quadratic equation q - Linear coefficient of quadratic equation r - Constant coefficient of quadratic equation - Discriminant of quadratic equation U y - Displacement in axis-y UR x - Rotation about axis-x UR z - Rotation about axis-z U x - Displacement in axis-x UR y - Rotation about axis-y UR z - Rotation about axis-z R SR - Reflow cooling rate T - Range of temperature cycles T TC - Ramp rate of temperature cycles t dwell - Dwell time σ vm - von Mises stress τ 13 - Shear stress at direction-13 τ 23 - Shear stress at direction-23 σ 33 - Normal stress at direction-33 φ - Damage