Preventing New Groundwater Pollution Problems from Old Oilfield Areas. Oklahoma Corporation Commission

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Preventing New Groundwater Pollution Problems from Old Oilfield Areas Patricia Billingsley, Brownfields Manager, Oklahoma Corporation Commission

Last year I presented a case study about subdivision water wells polluted by brine from 1940s-50s era oilfield gathering lines. Today I am going to 1) Summarize a couple of pollution cases; 2) Briefly discuss old oilfield groundwater pollution statewide; and 3) Discuss what Oklahoma is doing via rules to minimize future groundwater pollution problems from historic oil and gas activity

OK Once Looked Like This (View From S to N Across River Toward OKC) River 11/29/2013 3

Or this -Tonkawa, 90 years ago

Historic Oil & Gas Fields (>500,000 wells) Affect >60% of Oklahoma

Corp Comm Has Taken > 2000 Groundwater Samples Over 20 Years Both suburban and rural, most near older oilfields with activity started pre-1980, before modern regulations; Most collected after complaint/problem, so The data is biased toward the bad. There are also areas with Remnant soil pollution.

Methodology; Pollutants Water samples were taken in seeps and springs; shallow monitoring wells near spills; domestic, public, and agricultural water wells of all depths. Oilfield related pollutants include --Petroleum, salinity,and boron from oil & gas production & saline produced water (brine) --Barium is found in oilfield drilling mud Nitrate, is NOT oilfield septic and agriculture

The following maps show where water quality standards were EXCEEDED in groundwater. Major aquifers are Blue; Dense Old Oilfields are Black 70% of exceeds appear in or within 1 mile of pre-1980 dense oilfields; rest is scattered near few-well clusters or old injection wells

Petroleum, Water Wells, all Depths Major aquifers are Blue; Old Oilfields are Black

Heavy Metals in Water Wells just 10 Major aquifers are blue Major aquifers are Blue; Old Oilfields are Black

Salinity Exceeds, Water Wells Ouch! Major aquifers are Blue; Old Oilfields are Black

Other Pollutant Exceeds, Water Wells Major aquifers are Blue; Old Oilfields are Black

Madeline Dillner s talk Wednesday Morning, in the Waste Minimization/Pollution Prevention session, will go into the water sampling results, and data problems, in much more detail

Pollutant Focus Today I will focus mainly on salt/salinity the biggest soil and groundwater problem Oil and gas wells produce more water than oil 252,000,000 gallons PER DAY in OK, in 2012 The USGS database of Produced Oilfield water show Oklahoma oilfield brines contain up to 18% salt, while seawater is ~3% salt SALT DOES NOT DEGRADE It just moves, soil to water

What Does It Matter, to OK s People? Groundwater : Supplies ~40% of all water used in Oklahoma Provides water to > 300 Oklahoma cities and towns Supplies water to 295,000 Oklahomans with domestic wells Supplies 73% of all Irrigation water for Agriculture -It is our food too!

I am going to summarize 2 typical case studies in Central OK. Where I also have geophysical data, so We can show where the pollution originated, and How it is moving through the subsurface.

Example 1 -Recent Case, 2011 15 year old gated community in NW OKC Homeowner complaints of salty water, 2011. Was a historic, until 1980s, oilfield area, so Our Field Inspector sampled their water wells. We later learned that two original homeowners had had bad wells in their backyard, with later new wells in the front yards. Red Flag!

Area was once an oilfield-green dots Oilfield Site Location

WEST EDMOND OIL FIELD CIRCA 1945

Sampling Results Wells ~300 deep; only reached ~150 backyard SO4 TDS or Na/Cl Who Na ppm Cl ppm ppm TotlSolSalts Z 1314 3323 798 7597 0.395 L 665 2171 370 4996 0.306 C 438 1047 722 3247 0.418 D 210 460 357 1756 0.457 N 184 139 302 1095 0.662 B Front yard 92 417 79 1327 0.441 B Backyard 1600 Exceeds Chloride secondary drinking water standards Na/Cl Ratio <0.6 indicates oilfield source Sulfate SO4 from natural BaSO4, which makes Rose Rocks

Where there were Oilfield Tank, now we have New Homes Tank group @ end of gathering system

1941 Aerial Showing Drill Rigs, Pits Dry salty pit Drill rig shadows Oil Well Spots Pit with water Pit Outlines

Old Pits & Wells, Modern Air Photo GW Flow Toward Spring Oil Well Spots Oil Well Spots Pit Outlines Pit outlines

Geophysics 3D, both saline plumes larger Plume Backyard Plume ANOMALY AT D HOUSE ANOMALY AT B HOUSE UNPLUGGED WELLS EXISTING DOMESTIC WELLS

Geophysics Linear Saline Plume, Backyard STAKE LOCATIONS SALT WATER PLUME Geophysical Array CF03 Resistivity Values <= 1 ohm-meter Depth ~ 20 Feet

Geophysics, IP METAL! Was A Gathering Line With a Hole STAKE LOCATIONS METAL (Now Rust) HOLE - PIPELINE BREAK Geophysical Array CF03 IP Induced Potential Values > 100 ms Depth ~ 20 Feet

1951 Aerial Linear Scars Were Gathering Line System? 1951 AERIAL PHOTO LARGER LOW RESISTIVITY ANOMALY 2 nd LOW RESISTIVITY ANOMALY; 1951 SURFACE SCAR OIL/BRINE PIPELINE GATHERING SYSTEM If straight line surface scars, 1951, = Pipelines

First Water Well What Happened Later Water Well SALT WATER IN PIPE 30 FEET HENNESSEY SHALE GARBER SANDSTONE AQUIFER

Conclusions Old (1940 s-80s) Oilfield Activity Caused problem highly saline brine leaks; Open, surface to 300 deep gravel pack water well construction channeled shallow pollutants down into the Garber Aquifer. In effect, the water wells, by their standard design, polluted themselves -and the aquifer Especially the unplugged backyard wells. All wells are now plugged.

Another Example started late 1990 s Water Well Samples, T Hills Edmond Address Sodium ppm Chloride ppm Total Soluble Salts 3101 Sherrywood 153 577 1518 3009 Timothy 308 928 2066 200 Stony Trail 377 1001 2363 3005 Sherrywood 410 1056 2373 2901 Sherrywood 1237 2402 3001 Timothy Way 575 1258 2924 Produced Water, Darwin #1 T Hills Oil Well 79,830 123,947 222,996

Another Example Saline Plume Moving S in Subdivision

Old Pits on the Garber Sandstone Leaked, Wells helped move salt deeper into aquifer Data Fresh Saline Deeper Aquifer Salinity Pit Model Processed Data Showing Inferred Groundwater Conditions

Edmond A Bonus! T Hills homes: groundwater pollution plume moving SOUTH since 1990s 90 per year, dozens of water wells being ruined Apparent Source: Old pits Special Bonus stream and reservoir Spring Creek Lake Arcadia

Because of problems in old oilfields and cases like the above, Corp Comm is has mapped old (pre 1980) well fields, especially on Oklahoma s aquifers Before 1980, pit design, well plugging oversite, field inspection etc. not as rigorous as after; For example, no regular Mechanical Integrity testing of injection wells was done then, is done now.

More Wells/Oilfields, More Pollution Red is Dense Oilfields

More Wells/Oilfields, More Pollution

Unfortunately, many of these old pre- 1980 oilfields are just open fields today SoPollution Risks are often NOT obvious to developers or well drillers So All of our Old Oilfield maps are being loaded onto OWRB s map viewer, for viewing by anyone on the internet

New Rules Request Made to OWRB To help prevent shallow pollutants from traveling down water well gravel packs into aquifer(s) - In the higher risk areas Corp Comm has mapped (old oil wells, pits etc <1400 apart, >16 per square mile), Corp Comm has requested a New Rule requiring future water wells to be cased and cemented from the surface to at least 30 deep, gravel pack only BELOW 30 RULEMAKING THIS FALL

Agency, Town, Water District Maps These GIS maps can be made by aquifer, county, town, or Water District. Regional planners (COGS) & town building permit departments can also use them??? So far, 2COGs -ACOG and INCOG -have our map coverages and have agreed to make old oilfield maps for any city/town that wants them, for planning purposes; working on the rest

Red is Dense Oilfields Water Supply Lakes Indian Nations Council of Govern ments Area

Town Example -Map for Slaughterville City permit Dept - Pre-test for salt here BEFORE buildings get permitted? Or want groundwater pre-testing before home water wells are installed here or require city/rwd water

Questions?