Dark Current Limiting Mechanisms in CMOS Image Sensors

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Dark Current Limiting Mechanisms in CMOS Image Sensors Dan McGrath BAE Systems Information and Electronic Systems Integration Inc., Lexington, MA 02421, USA, << Fairchild Imaging, San Jose, CA 95135, USA >> robert.mcgrath@baesystems.com Steve Tobin [BAE Systems, Lexington, MA 02421, USA] Vincent Goiffon, Marius Sergent, Pierre Magnan [ISAE-SUPAERO, Université de Toulouse, Toulouse, France] Alexandre Le Roch [CNES, Toulouse, France] 1

Introduction to Dark Current Definition: Dark current is the signal from a typical pixel that is not due to photons Dark current is physical charge Dark current in current technology is not understood Understanding is needed to drive improvement Corollary: Photo-carrier collection tends toward equilibrium Dark current caused by thermal processes does the same Dark current is a chargedomain offset in dark frames & in image frames 2

The present state & mystery [1] Synthetic dark image appears grainy Surface plot shows combination of grainy gray & of snow spikes Dark current is what happens in every pixel Defects happen only in some pixels not the subject of this talk 3

The present state & mystery [2] R.H. Dyck, M.D. Jack, Low Light Level Performance of a Charge-Coupled Area Imaging Device, 1974 CCD Workshop, Edinburgh, UK 1974: Room temperature dark current of 2 na/cm2 temperature dependence is SRH (E g /2) 2015: Room temperature dark current of 0.4 pa/cm2 5000x improvement temperature dependence is bandgap (E g ) M.Kobayashi, et al, A Low Noise and High Sensitivity Image Sensor with Imaging and Phase-Difference Detection AF in All Pixels, 2015 IISW, Vaal, Netherlands Canon Inc. 20 pa/cm2 60C 5000x improvement in Dark Current; Shift in temperature dependence indicates shift in mechanism 4

The present state & mystery [3] Dark current data for a selection of worldclass CIS foundries: Dark current has progressed with nominal 10x scaling per technology node Dark current in a technology seems best characterized per pixel area Commercial applications have & are pushing development as constant improvement At some point there is a limit: defect-free silicon limited or device-limited Neither is understood 5

Pixel I want to acknowledge Nobu Terenishi s talks also exploring root cause of diffusion dark current Dark current sites within pixel: 1. TX edge: diffusion from interface (E g ); lucky drift from interface (E g /2); interface stress (E g ); 2. FD injection: blooming forward bias; 3. Other junction: forward bias or carrier injection; 4. STI interface: diffusion from interface (E g ); interface stress (E g ); 5. Pinning layer: diffusion from interface (E g ); interface stress (E g ); doping-based SRH (E g ); 6. Deep depletion: SRH from contamination (E g /2); 7. Lightly doped region: diffusion from weak SRH (E g /2 or E g ); 8. Back interface: diffusion from weak interface SRH (E g ); 9. Contact substrate current (Eg) Many possibilities exist for dark current in the pixel 6

Pixel: Dark current sources Metallics Source Location Dependence Comments Interface states Substrate diffusion current Pinning layer diffusion current STI diffusion current Back surface diffusion current Contact diffusion current Photodiode depletion region TX-gate-edge depletion region Bulk silicon (depleted & undepleted) Photodiode pinning layer E g /2 temperature dependence (~10C doubling); Photodiode depletion area & volume E g /2 temperature dependence (~10C doubling); TX gate width dependence E g temperature dependence (~6C doubling); Pixel area dependence Presence of un-depleted substrate E g temperature dependence (~6C doubling); Pixel area dependence STI edge E g temperature dependence (~6C doubling); STI length STI depth Back interface for thinned device E g or E g /2 temperature dependence Pixel area dependence Reduced by bulk gettering, use of screen oxides, cleaning & implant contamination control Should be isolated from photodiode by bulk barrier Minority carrier diffusion Should be reduced by BSI thinning Sensitive to dielectric-induced stress Sensitive to STI corner stress Impact of STI engineering & depth has reduced Mitigated by accumulation in present BSI Contact E g temperature dependence (~6C doubling) Diffusion through substrate from contact Gate injection TX edge Weak temperature dependence Gate voltage dependence Gate-induced diode leakage Spill back dark current TX edge Weak temperature dependence Non-linear TX gate voltage dependence TX edge E g or E g /2 temperature dependence TX gate width dependence Should be isolated from photodiode by bulk barrier Due to high fields Isolated from photodiode by bulk barrier Dopants Bulk silicon E g temperature dependence SRH with shallow traps Auger / Impact ionization Should be isolated from photodiode by bulk barrier Bulk silicon E g temperature dependence Requires valence band momentum transfer More possibilities other than contamination & interface states exist for dark current 7

Dark Current Temperature Dependence TCAD can generate a prediction for defect-free silicon with ~E g temperature dependence Curve # 1 2 3 4 5 6 Parameters Ea (ev) 1.18 0.64 1.18 1.16 1.28 1.29 Bulk SRH, mid-gap X Et=0, tau=1e-3 s Bulk SRH, near band edge X Et=0.5, tau=4.6e-8 s Front surface SRH, mid-gap X Et=0, Nit=1e11 cm-2 Back surface SRH, mid-gap X X Et=0, Nit=1e11 cm-2 Back surface fixed charge X X X X X Qf=-1e12 cm-2 3-d simulation of pixel dark current mechanisms. E t is the SRH trap energy relative to mid-gap. E a is the activation energy from the slope of the curve. Ref. 1) H. Rhodes et al, "The Mass Production of Second Generation 65 nm BSI CMOS Image Sensors, 2011 IISW, Hokkaido, Japan E g temperature dependence can result from various mechanisms Front or back surface generation & diffusion SRH for traps near the band edge SRH for dopants TCAD has hooks to simulate dark current due to process & design TCAD has limit because it does not consider that carriers are quantized 8

Characterization: probing the pixel Temperature dependence - Dramatic due to exponential dependence of Boltzmann equation - Leads to use of doubling temperature as metric: - Eg/2 ~ 11 C/doubling - Eg ~ 6 C/doubling Voltage dependence - Biasing shapes the depletion region - Changes the volume - Creates inversion layers - Changes the dopants - Moves barriers Device operation is a window into pixel dynamics 9

Log # pixels in image Dark Current Spectroscopy (DCS) Many bright defects per pixel Many small defects per pixel + interface states + few bright defects Many small defects per pixel Few quantized defects per pixel many pixels with no dark current! Fewer defects Impact in the Photon Counting World: Reduced dark current is critical for photon counting imagery The dark current changes from looking like background noise to looking like false positive signal Dark current will be a random phenomenon quantized in space & time Dark Signal Generation Rate Progression of dark current in the pixel Dark current quantization means that in the extreme-low dark current required for photon counting most pixels most the time will have no dark current 10

Trap Energy Log # pixels in image 2-d DCS from dark image offset Dark Signal Generation Rate from dark image offset & dark image noise Interface states Substitutional defect Substitutional defect E g 2 E g Dark Signal Generation Rate Many more possibilities exist for dark current 11

Past progress & present mystery Past progress: Initially uniform dark current was dominated by interface states; these were eliminated by use of inversion & pinning layers: CCD & CIS pinned photodiodes Snow-like dark current addressed by using DCS as a tool to relegate metallics to be only bright pixels through contamination control & gettering Dark current temperature dependence shifted from ~11 C/doubling to ~6 C/doubling Root cause is needed to have actionable improvement Present conundrum: Manufacturing improvements aimed at contamination does not address ~6 C/doubling Categorizing ~6 C/doubling as diffusion current does not provide an actionable root cause - Dark current diffusion is backwards from p-n junction diffusion (e- flow is from p- to-n instead of n-to-p) - Question of whether diffusion in image sensor without recombination - No root cause connecting dark current & process 12

Limits of dark current in silicon [1] Simplistic model for deep-depleted photodiode a. Model is for deep-depletion photodiode, undepleted pinning layer & undepleted substrate b. E g = 1.12eV c. Lifetime is limited by Auger process: a. electron promoted into conduction band b. hole created in valence band c. electron or hole that conserves momentum d. Generation lifetime equals equilibrium recombination lifetime: τ 1 2 = 2.5 10 3 s e. No recombination occurs because electrons generated are swept away due to electric fields f. Charge generation depends on n, the concentration difference from equilibrium M. S. Tyagi and R. Van Overstraeten, Minority carrier recombination in heavily-doped silicon, Solid-State Electron.,vol. 26, pp. 577 1983. Calculations carried out for nominal T = 27C Simple model based on Auger process looks at pinning layer + depleted PD + undepleted 13

Limits of dark current in silicon [2] Simplistic model for depleted volumes in photodiode 1. Available electrons are the valence band density of states: N V = 3.1 10 19 cm 3 2. Conduction band electron concentration given by Boltzmann equation: n = N V exp E g kt where kt = 0.025 ev 3. In equilibrium the recombination has exponential decay: τ 1 2 = 2.5 10 3 s 4. Generation process in all cases equals recombination in equilibrium characterized by the lifetime due to very small acceptor density: G = R = n τ 1 2 N G = V exp E g kt τ 1 2 = 450 e cm 3 s = 7 10 5 pa cm 3 dd G FSI (1.5 μm) = 9 10 9 pa cm 2 dd G BSI (2.5 μm) = 1.5 10 8 pa cm 2 Calculations carried out for nominal T = 27C Conclusion: Negligible dark current from depleted volumes 14

Limits of dark current in silicon [3] Simplistic model for undepleted substrate 1. Equilibrium concentration n = n 2 i N A where n i = 1.0 10 10 cm 3 2. Removing equilibrium constraint leads to exponential-decay recombination which is doping dependent: τ 1 2 from Figure 1 3. Generation process equals recombination in equilibrium characterized by the lifetime as acceptor density becoming very small: G = R = n τ 1 2 = n 2 i (N A τ 1 2) 4. Pinning layer is doped 3x10 18 cm -3 with 0.1 m depth: τ 1 2=10-6 s 5. Collection volume for FSI is doped 1x10 15 cm -3 with 6.5 m depth: τ 1 2=2x10-4 s 6. Collection volume for BSI is effectively zero G pin = G collect = 1.0 10 10 cm 3 2 (2 10 18 cm 3 10 6 s) = 3.5 10 7 cm 3 s 1 = 6 pin G (0.1 μm) = 6 10 5 pa cm 2 1.0 10 10 cm 3 2 (1 10 15 cm 3 10 4 s) = 1.4 10 9 cm 3 s 1 = 2 10 2 pa cm 3 collect G FSI(6.5 μm) = 1.4 10 1 pa cm 2 collect G BSI(0 μm) Conclusion: FSI undepleted substrate is dominant dark current pa = 0 cm 2 pa cm 3 Calculations carried out for nominal T = 27C 15

Limits of dark current in silicon [4] Dark current generation rate (27C) G FSI dd = G FSI (1.5 μm) = 9 10 9 pa pin + G (0.1 μm) collect + G FSI(6.5 μm) cm 2 + 6 10 5 pa cm 2 + 1.4 10 1 pa cm 2 = 1. 4 10 1 pa cm 2 G BSI dd = G BSI (2.5 μm) = 1.5 10 8 pa pin + G (0.1 μm) cm 2 + 6 10 5 = 6 10 5 pa cm 2 collect + G BSI(0 μm) pa cm 2 + 0 pa Calculations carried out for nominal T = 27C Dark current limit for simple model cm 2 Discussion Image sensors have not reached the limits of dark current possible in perfect silicon, so process improvements are still important to reach the fundamental limit FSI is approaching these limits due to the generation in the undepleted collection volume BSI could also approach this limit if it introduces thicker silicon enabled by better pixel-to-pixel isolation Process improvements that increase the depletion volume should lower the fundamental limits without trading off spectral response 16

Looking into a crystal ball darkly Conjectures: - Commercial pressures will continue to push to reduce dark current - General view that improvement is natural fallout from advancing technology nodes - Improvement would be helped by identifying root cause of the dominant defect(s) Dark current reduction is actionable - Understanding the root cause provides opportunity for designdriven improvement - Data is needed for actionable understanding - There will be a point where silicon rather than defects becomes the limitation only designdriven improvements will be possible 17

Illumination SRH theory has provided a means to understand & eliminate a predominant source of dark current Dark current has gone from gray background to quantized snow and back to gray background. It is about to again be quantized, this time in space & in time There is no root cause to understand the present dark current There is a need for data & analysis It is unclear when dark current will hit the limit of pure silicon where process improvements will no longer help. When there is an identified root cause then there is the possibility for improvement through design Understanding of dark current root cause and limits is needed 18

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