Water Pollution Studies for the Lower Grand River, Michigan

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Water Pollution Studies for the Lower Grand River, Michigan Dr. Joan B. Rose rosejo@msu.edu Dr. Phanikumar Mantha phani@msu.edu Rebecca Ives, Shikha Singh and Theng Theng Fong and Chao Peng

Grand River, MI Longest river in Michigan at 420 km (260 miles) Water shed drains an area of 14, 431 km 2 (5572 mi 2 ) Trout and salmon stream Pasture and cropland comprise of 63% of river basin (EPA)

96 Great Lake Beaches Exceed WQS 2003-2005 Ottawa County *There are 41 Inland and GL Beaches on the MI TMDL List

MDOT Water Impairment map-2003 a 7 7 Grand River @ M-11 CSO & Pathogens a Grand River CSO & Pathogens

Web of Surface Water Impact Septic Tank Agriculture CAFO Wildlife CSO s Wastewater Treatment Plant Rivers and Streams Lakes Beaches Soil Direct / Indirect Compromization of Human Health Sediment Sand

Study Site: The Grand River Watershed (I) Minnesota Lake Superior Michigan Wisconsin Lake Huron Minnesota Lake Michigan Michigan Iowa Illinois The Grand River Watershed Indiana Ohio Lake Erie New York Pennsylvania

The objectives of this study 1) Examine the occurrence of fecal bacterial indicators, E.coli, Enterococci, Clostridium and coliphage, as well as parasitic pathogens Cyrptosporidium and Giardia along the Grand River 2) Examine the relative levels of Bacterial fecal indicators and coliphage in sediments 3) Examine spatial changes in water quality 4) Evaluate the transport of contaminants in the river

Study Site: The Grand River Watershed (II)

Study Reach

Observed vs Simulated Rhodamine First Site: Wealthy St. Bridge u= 0.4429 m/s; D=1.00012 m2/s; St= 311.027 s; Eps= 0.0828961;

Observed vs Simulated Rhodamine: Second Site: 28 th St. Bridge u=0.512527 m/s D=4.06903 m2/s St=1519.03 s Eps=0.112668

Observed vs. Simulated Rhodamine Third Site: Lake Michigan Drive Bridge u=0.533052 m/s D=5.11896 m2/s St=2072.66 s Eps=0.145672

Observed vs Simulated Rhodamine: Fourth Site: 68 th St. Bridge (SCUFA) u=0.529935 m/s D=1.01021 m2/s St=1772.61 s Eps=0.104519

Observed vs Simulated (PRD1) First Site: Wealthy St. Bridge u=0.438312 m/s D=0.790225 m2/s St=437.299 s Eps= 0.0950008

Observed vs Simulated (PRD1) Second Site: 28 th St. Bridge u=0.505494 m/s D=2.93609 m2/s St=1433.24 s Eps=0.0908734

Observed vs Simulated (PRD1) Third Site: LM Drive Bridge u=0.507342 m/s D=8.49032 m2/s St= 3117.46 s Eps=0.106299

Rhodamine vs PRD1 Recovery Ratio (Estimated from Average Breakthrough Curve)

Water Parameters Water Temperature:15.9-18 C ph: 8.5 and 9.0. Average daily stream-flow:3190 ft 3 /s Sampling stations Distance from injection site (km) Wealthy St. Bridge 4.54 28th St. Bridge 13.56 Lake Michigan Dr Bridge 27.88

Results PRD1 Average reduction per km: 3.97% Travel distance per hour: 0.50 km/hr Rhodamine Average reduction per km: 3.73% Travel distance per hour: 0.49 km/hr

PRD-1 PRD1 Count (pfu/ml) 2500 2000 1500 1000 WC WR WL TR TC TL LL LR TB 500 0 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 Time after injection (hr)

Arrival Time at Each Site ESTIMATED ARRIVAL AT LK MICHIGAN 7:20 AM THE NEXT DAY INJECTION 7:20 23:00 10:00 14:00

Conclusions Model was able to predict the observed Rhodamine and PRD1 concentrations well. Rhodamine recovery factors are comparable to the numbers from other similar studies in the US and around the world Comparison of recovery factors shows that PRD1 undergoes additional losses (sorption, inactivation)

Sites sampled 1/week June to Sept and 1/month from Oct. to Dec.

Geometric mean of E.coli in sediment and surface water at Beaches and Parks 10000 CFU (log scale) 1000 100 10 E.coli in sediment / 100 g dw E.coli in water / 100 ml 1 Beach Park

Geometric mean of Enterococci in Sediment and Surface water at Beaches and Parks 10000 CFU (log scale) 1000 100 10 Enterococci in sediment / 100 g dw Enterococci in water / 100 ml 1 Beach Park

Geometric mean of C.perfringens in sediment and surface water at Beaches and Parks 10000 CFU (log scale) 1000 100 10 C.perfringens in sediment / 100 g dw C.perfringens in water / 100 ml 1 Beach Park

Geometric mean of Coliphage in sediment and surface water at Beaches and Parks PFU (log scale) 10000 1000 100 10 Coliphage in sediment / 100 g dw Coliphage in water / 100 ml 1 Beach Park

Parasite Geometric means (Oo)cysts /10L 4 3.5 3 2.5 2 1.5 1 0.5 Crypto Giardia 0 1 2 3 Riverside Deer Creek North Beach

Sites sampled 1/week June to Sept and 1/month from Oct. to Dec.

4.00 3.00 2.00 1.00 0.00 E. coli Enterococci 4.00 39 22 21 74 54 55 119 3.00 2.00 1.00 9 39 75 0.00 Lower Middle Upper Reaches of the Grand River Lower Middle Upper Reaches of the Grand River E.coli in surface water /100mL (logscale) Enterococci in surface water /100mL (logscale)

Clostridium Coliphage perfringens 4 4 3 2 1 77 76 71 3 2 910 1 39 41 26 C.perfringens in surface water /100mL (logscale) Coliphage in surface water /100mL (logscale) 75 83 0 0 67 Lower Middle Upper Reaches of the Grand River Lower Middle Upper Reaches of the Grand River

Indicator Violations in the River for full body contact 26.6 % samples exceeded the US EPA Enterococci criterion 9.4 % samples exceeded US EPA criterion for E.coli 5.5 % samples exceeded Michigan standard for E.coli 10.2% samples exceeded the Hawaii fresh water criteria for C. perfringens

Summary Sediments are a likely source of bacteria. There is a dilution effect downstream. There is an accumulation or increase at Deer Creek and Riverside Park. There is slightly greater impact at the North Shore. Enterococci could be used as another bacteria for issuing beach advisories. Coliphage and Clostridium can be used and they indicate lower risk from the sand and at the beach. Parasites show a small risk at the beach.

Future Protection of Public Health The transport modeling can now be used to advise the public at the beach after spills, large rain events that carry sediments and/or CSOs. Food and drink should be separated from wet & play areas and the hands should be sanitized after playing in the sand. Continue to examine the hot spots including Deer Creek and River Side Park. Use the sewage markers for enterococci and examine the viability of Cryptosporidium in the river. Explore ways to handle the contaminated sediments. Continue to Improve infrastructure.